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    • 3. 发明申请
    • DEGRADABLE MATERIAL
    • 可降解材料
    • WO2009095344A1
    • 2009-08-06
    • PCT/EP2009/050644
    • 2009-01-21
    • CIBA HOLDING INC.CIBA S.P.A.GARDI, StefanoSALA, MassimilianoPASTI, Claudia
    • GARDI, StefanoSALA, MassimilianoPASTI, Claudia
    • C08F218/14C09K3/00C08L101/06
    • C08J5/18B32B2307/712B32B2307/716B32B2410/00B32B2419/00B32B2439/00B32B2439/70B32B2553/00B32B2555/00C08J2323/02C08K5/0033C08K5/098C08K5/10C08K5/49C08L23/02C08L23/06C08L2201/06C08L2203/16C08L2205/025C08L2207/066C08L2666/02
    • A composition containing (a) an organic polymer, (b-l) one, two or more compounds of the formula (I) wherein m and n independently are an integer from 2 to 10 x 10 6 ; the recurring units X can have the same definition or different definitions, the recurring units Y can have the same definition or different definitions and the recurring units X and Y can have a random distribution or a block distribution; X is a group of the formula (ll-1-a) or (ll-1-b) and Y is a group of the formula (II-2); in which X 1 , X 2 , X 3 , X 4 and X 5 independently of one another are hydrogen, C 1 -C 4 alkyl or phenyl; A 1 and A 2 independently of one another are -O - 1/r M r+ , -O - N + (R 1 ) 4 , -O-R 2 or -N(R 3 ) 2 , or A 1 and A 2 together form the radical -O- or the group -N-O-A 0 ; A 3 and A 4 independently of one another are -O - 1/r M r+ , -O - N + (R 1 ) 4 , -O-R 2 Or -N(R 3 ) 2 , or A 3 and A 4 together form the radical -O- or the group -N-O-A 0 ; M is a metal cation of valency r with r being 1, 2, 3 or 4; R 1 , R 2 and R 3 independently of one another are hydrogen, C 1 -C 20 alkyl, C 3 -C 12 cycloalkyl unsubstituted or substituted by 1, 2 or 3 C 1 -C 4 alkyl; C 5 -C 12 cycloalkenyl unsubstituted or substituted by 1, 2 or 3 C 1 -C 4 alkyl; a bicyclic or tricyclic hydrocarbyl having 6 to 10 carbon atoms; phenyl unsubstituted or substituted by 1, 2 or 3 C 1 -C 4 alkyl; or C 7 -C 9 phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C 1 -C 4 alkyl; A 0 is for example hydrogen; Y 1 , Y 2 , Y 3 and Y 4 independently of one another are hydrogen, C 1 -C 4 alkyl or phenyl; and (b-ll) optionally one, two or more inorganic or organic salts of a transition metal.
    • 一种组合物,其包含(a)有机聚合物,(b-1)一种,两种或更多种式(I)的化合物,其中m和n独立地为2至10×10 6的整数; 循环单元X可以具有相同的定义或不同的定义,重复单元Y可以具有相同的定义或不同的定义,并且循环单元X和Y可以具有随机分布或块分布; X是式(II-1-a)或(II-1-b)的基团,Y是式(II-2)的基团。 其中X1,X2,X3,X4和X5彼此独立地是氢,C1-C4烷基或苯基; A1和A2彼此独立地为-O- 1 / r Mr +,-O- N +(R1)4,-O-R2或-N(R3)2,或A1和A2一起形成基团-O-或 组-NO-A0; A3和A4彼此独立地为-O- 1 / r Mr +, - N +(R1)4,-O-R2或-N(R3)2或A3和A4一起形成基团-O-或 组-NO-A0; M是化合价r的金属阳离子,r为1,2,3或4; R 1,R 2和R 3彼此独立地是氢,C 1 -C 20烷基,未被取代或被1,2或3个C 1 -C 4烷基取代的C 3 -C 12环烷基; 未被取代或被1,2或3个C 1 -C 4烷基取代的C 5 -C 12环烯基; 具有6至10个碳原子的双环或三环烃基; 未被取代或被1,2或3个C 1 -C 4烷基取代的苯基; 或未被取代或在苯基上被1,2或3个C 1 -C 4烷基取代的C 7 -C 9苯基烷基; A0是例如氢; Y 1,Y 2,Y 3和Y 4彼此独立地是氢,C 1 -C 4烷基或苯基; 和(b-11)任选的一种,两种或多种过渡金属的无机或有机盐。
    • 6. 发明申请
    • DEGRADABLE MATERIAL
    • 可降解材料
    • WO2009135813A1
    • 2009-11-12
    • PCT/EP2009/055341
    • 2009-05-04
    • BASF SECIBA S.P.A.PASTI, ClaudiaLORENZETTI, CesareSCHLINGLOFF, GuntherGARDI, StefanoSALA, Massimiliano
    • PASTI, ClaudiaLORENZETTI, CesareSCHLINGLOFF, GuntherGARDI, StefanoSALA, Massimiliano
    • C08K5/00C08K5/098C08K5/17C08K5/34A01G13/02
    • A01G13/0275
    • A composition containing the components (A), (B-I) and (B-Il) wherein component (A) is an organic polymer; component (B-I) is an amine derivative of the formula (I) N(X 1 )(X 2 )(X 3 ) wherein X 1 is C 8 -C 36 alkyl or C 8 -C 36 alkenyl; X 2 is hydrogen, C 1 C 36 alkyl, C 2 -C 36 alkyl substituted by 1, 2 or 3 radicals selected from the group consisting of -OH and -N(Y 11 )(Y 12 ); C 8 -C 36 alkenyl or C 5 -C 8 cycloalkyl; or X 1 and X 2 , together with the nitrogen atom, form morpholino; X 3 is C 1 C 36 alkyl, C 2 -C 36 alkyl substituted by 1, 2 or 3 radicals selected from the group consisting of -OH and -N(Y 11 )(Y 12 ); C 8 -C 36 alkenyl, C 5 -C 8 cycloalkyl or a group of the formula (a) or the radicals X 2 and X 3 form together a group of the formula (b), (c) or (d) Y 11 and Y 12 are independently of one another hydrogen, C 8 -C 36 alkyl or C 2 -C 36 hydroxyalkyl; Y 21 and Y 22 are independently of one another a group -N(Y 11 )(Y 12 ) or morpholino; Y 31 is C 8 -C 36 alkyl or C 8 -C 38 alkenyl; Y 41 and Y 42 are independently of one another C 8 -C 36 alkyl or C 8 -C 38 alkenyl; Y 51 is C 8 -C 36 alkyl or C 8 -C 36 alkenyl; if X 2 and X 3 form together a group of the formula (d), X 1 can additionally be C 2 -C 36 hydroxyalkyl; and component (B-Il) is an inorganic or organic salt of a transition metal.
    • 含有组分(A),(B-I)和(B-II)的组合物,其中组分(A)是有机聚合物; 组分(B-I)是式(I)N(X1)(X2)(X3)的胺衍生物,其中X1是C8-C36烷基或C8-C36烯基; X2是氢,C1C36烷基,被1,2或3个选自-OH和-N(Y11)(Y12)的基团取代的C2-C36烷基。 C 8 -C 36烯基或C 5 -C 8环烷基; 或X1和X2与氮原子一起形成吗啉代; X3是C1C36烷基,被1,2和3个选自-OH和-N(Y11)(Y12)的基团取代的C2-C36烷基。 C 8 -C 36烯基,C 5 -C 8环烷基或式(a)的基团或基团X 2和X 3一起形成式(b),(c)或(d)的基团Y 11和Y 12彼此独立地为氢, C 8 -C 36烷基或C 2 -C 36羟烷基; Y 21和Y 22彼此独立地为基团-N(Y 11)(Y 12)或吗啉代; Y31是C8-C36烷基或C8-C38烯基; Y 41和Y 42彼此独立地为C 8 -C 36烷基或C 8 -C 38烯基; Y51为C8-C36烷基或C8-C36烯基; 如果X2和X3一起形成式(d)的基团,则X1可以另外是C 2 -C 36羟烷基; 和组分(B-11)是过渡金属的无机或有机盐。