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    • 3. 发明申请
    • USE OF METAL COMPLEX COMPOUNDS AS CATALYSTS FOR OXIDATION USING MOLECULAR OXYGEN OR AIR
    • 使用金属复合化合物作为催化剂使用分子氧或空气进行氧化
    • WO2004039933A1
    • 2004-05-13
    • PCT/EP2003/011635
    • 2003-10-21
    • CIBA SPECIALTY CHEMICALS HOLDING INC.WIEPRECHT, TorstenSCHLINGLOFF, GuntherXIA, JuntaoHEINZ, UweSCHNEIDER, AlbertDUBS, Marie-JoséeBACHMANN, FrankHAZENKAMP, MennoDANNACHER, Josef
    • WIEPRECHT, TorstenSCHLINGLOFF, GuntherXIA, JuntaoHEINZ, UweSCHNEIDER, AlbertDUBS, Marie-JoséeBACHMANN, FrankHAZENKAMP, MennoDANNACHER, Josef
    • C11D3/395
    • C11D3/3932C11D3/168
    • Use, as a catalyst for oxidation reactions using molecular oxygen and/or air, of at least one metal complex compound of formula (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z/(charge of Y), and L is a ligand of formula (2) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -S0 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -SR 13 , -S0 2 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -NR 14 R 15 ; -(C 1 -C 6 alkylene)-NR 14 R 15 ; -N (+) R 14 R 15 R 16 ; -(C 1 -C 6 alkylene)-N (+) R I4 R 15 R 16 ; -N(R 13 )-(C 1 -C 6 alkylene)-NR 14 R l5 ; -N[(C 1 -C 6 alkylene)-NR 14 R 15 ] 2 ; -N(R 13 )-(C I -C 6 alkylene)-N (+) R 14 R 15 R 16 ; -N[(C 1 -C 6 alkylene)-N (+) R 14 R 15 R16]2; -N(R l3 )-N-R l4 R 15 or -N(R 13 )­N"R l4 R 15 R 16 , wherein R 13 is as defined above and R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 , together with the nitrogen atom linking them, form an unsubstituted or substituted 5-, 6- or 7-membered ring which may contain further hetero atoms.
    • 使用至少一种式(1)的金属络合物(其中Me是锰,钛,铁,钴,镍或铜)作为氧化反应的催化剂,使用分子氧和/或空气,X是配位或桥接基团 ,n和m各自独立地为具有1至8的整数,p为0至32的整数,z为金属络合物的电荷,Y为抗衡离子, q = z /(Y的电荷),L是式(2)的配体,其中R1,R2,R3,R4,R5,R6,R7,R8,R9,R10和R11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12,其中R 12在各种情况下为氢,阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13,-SO 2 R 13或-OR 13,其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -NR14R15; - (C 1 -C 6亚烷基)-NR 14 R 15; -N <(+)> R14R15R16; - (C 1 -C 6亚烷基)-N <(+)> RI4R15R16; -N(R13) - (C 1 -C 6亚烷基)-NR14Rl5; -N [(C1-C6亚烷基)-NR 14 R 15] 2; -N(R13) - (C 1 -C 6亚烷基)-N <(+)> R14R15R16; -N [(C1-C6亚烷基)-N <(+)> R14R15R16] 2; -N(R13)-N-R14R15或-N(R13)N“R14R15R16,其中R13如上所定义,R14,R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基 或R 14和R 15与连接它们的氮原子一起形成未含或取代的可含有其它杂原子的5-,6-或7-元环。