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1. 发明申请

WO2004039933A1 USE OF METAL COMPLEX COMPOUNDS AS CATALYSTS FOR OXIDATION USING MOLECULAR OXYGEN OR AIR 审中-公开
标题翻译：使用金属复合化合物作为催化剂使用分子氧或空气进行氧化
公开(公告)号：WO2004039933A1
公开(公告)日：2004-05-13
申请号：PCT/EP2003/011635
申请日：2003-10-21
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WIEPRECHT, Torsten , SCHLINGLOFF, Gunther , XIA, Juntao , HEINZ, Uwe , SCHNEIDER, Albert , DUBS, Marie-Josée , BACHMANN, Frank , HAZENKAMP, Menno , DANNACHER, Josef
发明人： WIEPRECHT, Torsten , SCHLINGLOFF, Gunther , XIA, Juntao , HEINZ, Uwe , SCHNEIDER, Albert , DUBS, Marie-Josée , BACHMANN, Frank , HAZENKAMP, Menno , DANNACHER, Josef
IPC分类号： C11D3/395
CPC分类号： C11D3/3932 , C11D3/168
摘要： Use, as a catalyst for oxidation reactions using molecular oxygen and/or air, of at least one metal complex compound of formula (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z/(charge of Y), and L is a ligand of formula (2) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -S0 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -SR 13 , -S0 2 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -NR 14 R 15 ; -(C 1 -C 6 alkylene)-NR 14 R 15 ; -N (+) R 14 R 15 R 16 ; -(C 1 -C 6 alkylene)-N (+) R I4 R 15 R 16 ; -N(R 13 )-(C 1 -C 6 alkylene)-NR 14 R l5 ; -N[(C 1 -C 6 alkylene)-NR 14 R 15 ] 2 ; -N(R 13 )-(C I -C 6 alkylene)-N (+) R 14 R 15 R 16 ; -N[(C 1 -C 6 alkylene)-N (+) R 14 R 15 R16]2; -N(R l3 )-N-R l4 R 15 or -N(R 13 )N"R l4 R 15 R 16 , wherein R 13 is as defined above and R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 , together with the nitrogen atom linking them, form an unsubstituted or substituted 5-, 6- or 7-membered ring which may contain further hetero atoms.
摘要翻译：使用至少一种式（1）的金属络合物（其中Me是锰，钛，铁，钴，镍或铜）作为氧化反应的催化剂，使用分子氧和/或空气，X是配位或桥接基团，n和m各自独立地为具有1至8的整数，p为0至32的整数，z为金属络合物的电荷，Y为抗衡离子， q = z /（Y的电荷），L是式（2）的配体，其中R1，R2，R3，R4，R5，R6，R7，R8，R9，R10和R11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12，其中R 12在各种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 2 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -NR14R15; - （C 1 -C 6亚烷基）-NR 14 R 15; -N <（+）> R14R15R16; - （C 1 -C 6亚烷基）-N <（+）> RI4R15R16; -N（R13） - （C 1 -C 6亚烷基）-NR14Rl5; -N [（C1-C6亚烷基）-NR 14 R 15] 2; -N（R13） - （C 1 -C 6亚烷基）-N <（+）> R14R15R16; -N [（C1-C6亚烷基）-N <（+）> R14R15R16] 2; -N（R13）-N-R14R15或-N（R13）N“R14R15R16，其中R13如上所定义，R14，R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基或R 14和R 15与连接它们的氮原子一起形成未含或取代的可含有其它杂原子的5-，6-或7-元环。

2. 发明申请

WO2005068074A3 USE OF METAL COMPLEX COMPOUNDS COMPRISING PYRIDINE PRYIMIDINE OR S-TRIAZNE DERIVED LIGANDS AS CATALYSTS FOR OXIDATIONS WITH ORGANIC PEROXY ACIDS AND/OR PRECURSORS OF ORGANIC PEROXY ACID AND H2O2 审中-公开
公开(公告)号：WO2005068074A3
公开(公告)日：2005-07-28
申请号：PCT/EP2005/050000
申请日：2005-01-03
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WIEPRECHT, Torsten , HEINZ, Uwe , XIA, Juntao , SCHLINGLOFF, Gunther , DUBS, Marie-Josée
发明人： WIEPRECHT, Torsten , HEINZ, Uwe , XIA, Juntao , SCHLINGLOFF, Gunther , DUBS, Marie-Josée
IPC分类号： B01J31/18 , B01J31/04 , C07F13/00 , C07D213/22 , C07D401/14 , C11D3/39 , D06L3/02 , D06M11/50 , D21C9/10 , A61L2/18 , A61L12/12 , C07B33/00 , C07D301/14 , C11D11/02 , C11D17/06
摘要： The invention accordingly relates to the use as catalysts of at least one metal complex of formula (1) [L n Me m X p ] 2 Y q (1), wherein L is a ligand of formula (2) wherein Q 1 is N or CR 10 , Q 2 is N or CR 11 , and wherein the remaining substituents have the meanings as defined in the claims, for oxidation reactions with (A) organic peroxy acids and/or (B) precursors of organic peroxy acid, the later in combination with (B-1) H 2 O 2 and/or (B-2) a preecursor of H 2 O 2 , in particular in detergent compositions. Further possible uses related to epoxidation of olefins in organic synthesis, pulp and paper bleaching compositions, oxidative waste water treatment, automatic dishwasher formulations and disinfection compositions.

3. 发明申请

WO2005068075A1 USE OF A COMPOSITION COMPRISING METAL COMPLEX COMPOUNDS AND POLYPHOSPHONATES AS CATALYSTS FOR OXIDATIONS 审中-公开
标题翻译：使用包含金属复合化合物和聚氧乙烯醚作为催化剂进行氧化的组合物
公开(公告)号：WO2005068075A1
公开(公告)日：2005-07-28
申请号：PCT/EP2005/050003
申请日：2005-01-03
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , HEINZ, Uwe , WIEPRECHT, Torsten , XIA, Juntao , SCHLINGLOFF, Gunther , DUBS, Marie-Josée
发明人： HEINZ, Uwe , WIEPRECHT, Torsten , XIA, Juntao , SCHLINGLOFF, Gunther , DUBS, Marie-Josée
IPC分类号： B01J31/18
CPC分类号： B01J31/0259 , B01J31/0201 , B01J31/1815 , B01J31/182 , B01J2231/70 , B01J2231/72 , B01J2531/0238 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/84 , B01J2531/96 , B01J2540/42 , C11D3/364 , C11D3/3932 , C11D3/3935
摘要： The invention accordingly relates to the use of a composition comprising (i) at least one metal complex of formula (1) [L n Me m X p ] Z Y q (1), wherein all substituents have the meanings as defined in the claims and (ii) at least one polyphosphonate as oxidation catalyst for peroxide compounds, as well as to novel detergent compositions.
摘要翻译：因此，本发明涉及包含（i）至少一种式（1）的金属络合物[Ln MemXp] Yq（1））的组合物的用途，其中所有取代基具有如权利要求中所定义的含义，和（ii ）至少一种聚膦酸酯作为过氧化物化合物的氧化催化剂，以及新型洗涤剂组合物。

4. 发明申请

WO2012174704A1 BATTERY ELECTROLYTE SOLUTIONS CONTAINING AROMATIC PHOSPHITE COMPOUNDS 审中-公开
标题翻译：含有芳香族磷酸盐化合物的电解电解质溶液
公开(公告)号：WO2012174704A1
公开(公告)日：2012-12-27
申请号：PCT/CN2011/075941
申请日：2011-06-20
申请人： DOW GLOBAL TECHNOLOGIES LLC , HUANG, Qian , XIA, Juntao
发明人： HUANG, Qian , XIA, Juntao
IPC分类号： H01M10/0567 , H01M10/052
CPC分类号： H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M2300/0037 , H01M2300/004 , Y02T10/7011
摘要： A battery electrolyte solution contains from 0.1 to 10% by weight of tris(alkyl- substituted aryl) phosphite compound. The tris(alkyl-substituted aryl) phosphite compound provides increased thermal stability for the electrolyte, helping to reduce thermal degradation, thermal runaway reactions and the possibility of burning. The tris(alkyl-substituted aryl) phosphite compound has little or no adverse impact on the electrical properties of the battery, and in some cases actually improves battery performance.
摘要翻译：电池电解液含有0.1〜10重量％的三（烷基取代芳基）亚磷酸酯化合物。三（烷基取代的芳基）亚磷酸酯化合物为电解质提供增加的热稳定性，有助于减少热降解，热失控反应和燃烧的可能性。三（烷基取代的芳基）亚磷酸酯化合物对电池的电性能几乎没有或没有不利影响，并且在某些情况下实际上提高了电池性能。

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