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1. 发明申请

WO2004033699A1 PROCESS FOR THE PREPARATION OF PHENOLIC CARBOXYLIC ACID DERIVATIVES BY ENZYMATIC CATALYSIS 审中-公开
标题翻译：通过酶催化法制备苯酚羧酸衍生物的方法
公开(公告)号：WO2004033699A1
公开(公告)日：2004-04-22
申请号：PCT/EP2003/010967
申请日：2003-10-02
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , BAISCH, Gabriele , SCHÖNING, Kai-Uwe , HARTWIG, Jemima , MAYER, Sandra, Franziska
发明人： ÖHRLEIN, Reinhold , BAISCH, Gabriele , SCHÖNING, Kai-Uwe , HARTWIG, Jemima , MAYER, Sandra, Franziska
IPC分类号： C12P7/42
CPC分类号： C12P7/62 , C12P7/6436 , C12P11/00 , C12P13/02 , C12P17/10
摘要： The present invention relates to an improved process for the preparation of phenolic carboxylic acid derivatives catalysed by biocatalytic esterification, transesterification or amidation of a corresponding lower alkyl ester. Biocatalysis is performed in the presence of suitable enzymes, e.g. hydrolases, especially esterases, amidases, lipases and proteases.
摘要翻译：本发明涉及通过相应的低级烷基酯的生物催化酯化，酯交换或酰胺化催化的酚羧酸衍生物的制备方法。在合适的酶存在下进行生物催化，例如水解酶，特别是酯酶，酰胺酶，脂肪酶和蛋白酶。

2. 发明申请

WO2003074718A1 ENZYMATIC PROCESS FOR PREPARING ORGANOSILICON GROUP CONTAINING PHOTOINITIATORS 审中-公开
标题翻译：用于制备含有光敏剂的有机硅基团的酶法
公开(公告)号：WO2003074718A1
公开(公告)日：2003-09-12
申请号：PCT/EP2003/001896
申请日：2003-02-25
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , SCHÖNING, Kai-Uwe , BAISCH, Gabriele , HARTWIG, Jemima , BAUDIN, Gisèle , JUNG, Tunja
发明人： ÖHRLEIN, Reinhold , SCHÖNING, Kai-Uwe , BAISCH, Gabriele , HARTWIG, Jemima , BAUDIN, Gisèle , JUNG, Tunja
IPC分类号： C12P9/00
CPC分类号： C07F7/0889 , C12P9/00
摘要： The invention relates to a process for preparing organosilicon group containing photoinitiators of the formula (I), wherein m is a number from 1 to 200; q is 0 or 1; A is IN-C(O)-O-CHR 3 -Y- or IN-C(O)-NH-CHR 3 -Y-; A’ is A or R 1 ’; R 1 and R 1 ’, R 2 and R 2 ’ are C 1 -C 18 alkyl or phenyl, or -(O) q -SiR 1 R 1 ’R2; R 3 is hydrogen or C 1 -C 6 alkyl, Y is a divalent group selected from C 1 -C 10 alkeylene, C 2 -C 10 alkenylene or -(CH 2 ) b -O-(CH 2 ) a -; and b are each independently of the other a number of 1 to 6; IN is a photolabile functional moiety of the formula (II) or (III), wherein R 4 is hydrogen or -C(O)-C(O)-OH or -C(O)-C(O)-OC 1 -C 6 alkyl and n is 1-3; R 5 and R 6 are C 1 -C 12 alkyl or together are cycloC 5 -C 7 alkyl; R 7 is hydroxy, C 1 -C 6 alkoxy or morpholinyl; X is -(CH 2 ) a -, -(CH 2 ) b -O-(CH 2 ) a - or -(CH 2 ) b -O-CO-(CH 2 ) a -; a and b are each independently of the other a number of 1 to 6; whereby the process is characterized in that a photolabile functional moiety containing a carboxy group (IN-COOH) or an alkoxycarbonyl group (IN-CO-OC 1 -C 6 alkyl) is reacted with a carbinol- or amino terminated organosilicon compound of the formula (IV), wherein m, R 1 and R 1 ’, R 2 and R 2 ’ are as defined above and B is -Y-CHR 3 -OH or -Y-CHR 3 -NH 2 ; B’ is B or R 1 ’, in the presence of an enzyme which catalyzes the esterification, transesterification or amidation reaction.
摘要翻译：本发明涉及一种制备含有式（I）的光引发剂的有机硅基团的方法，其中m为1至200的数; q为0或1; A是IN-C（O）-O-CHR 3 -Y-或IN-C（O）-NH-CHR 3 -Y-; A'是A或R1'; R1和R1'，R2和R2'是C1-C18烷基或苯基，或 - （O）q-SiR1R1'R2; R 3是氢或C 1 -C 6烷基，Y是选自C 1 -C 10亚乙烯基，C 2 -C 10亚烯基或 - （CH 2）b -O-（CH 2）a - 的二价基团。和b各自独立地为1至6的数; IN是式（II）或（III）的光不稳定官能部分，其中R4是氢或-C（O）-C（O）-OH或-C（O）-C（O）-OC1-C6烷基， n为1-3; R5和R6是C1-C12烷基或一起是环C 5 -C 7烷基; R7是羟基，C1-C6烷氧基或吗啉基; X是 - （CH 2）a - ， - （CH 2）b -O-（CH 2）a-或 - （CH 2）b -O-CO-（CH 2）a-; a和b各自独立地为1至6的数; 其特征在于含有羧基（IN-COOH）或烷氧基羰基（IN-CO-OC1-C6烷基）的光不稳定官能部分与式（IV）的甲醇或氨基封端的有机硅化合物反应，其中m，R1和R1'，R2和R2'如上所定义，B是-Y-CHR 3 -OH或-Y-CHR 3 -NH 2; 在催化酯化，酯交换反应或酰胺化反应的酶存在下，B'是B或R1'。

3. 发明申请

WO2006094915A3 METAL OXIDE NANOPARTICLES COATED WITH SPECIFIC N-ACYLAMINOMETHYLENE PHOSPHONATES 审中-公开
公开(公告)号：WO2006094915A3
公开(公告)日：2006-09-14
申请号：PCT/EP2006/060302
申请日：2006-02-27
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , BAISCH, Gabriele
发明人： ÖHRLEIN, Reinhold , BAISCH, Gabriele
IPC分类号： C09C3/08 , C09C1/30 , C09C1/36 , C09C1/40 , C08F8/40 , C09D5/38
摘要： The present invention relates to new metal oxide nanoparticles coated with specific phosphonates, to the use of these nanoparticles as antimicrobials, especially in the home and personal care areas, to the production of such nanoparticles as well as to the new phosphonates and the corresponding process of production.

4. 发明申请

WO2003004450A1 PROCESS FOR THE PREPARATION OF INTERMEDIATES USEFUL IN THE SYNTHESIS OF STATIN DERIVATIVES ESPECIALLY 7-AMINO 3,5-DIHYDROXY HEPTANOIC ACID DERIVATIVES, AND INTERMEDIATES THEREOF 审中-公开
标题翻译：制备适用于特异性衍生物的中间体的方法，特别是7-氨基3,5-二羟基丙酸衍生物及其中间体
公开(公告)号：WO2003004450A1
公开(公告)日：2003-01-16
申请号：PCT/EP2002/007307
申请日：2002-07-02
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , BAISCH, Gabriele , END, Nicole , BURKHARDT, Stephan , STUDER, Martin
发明人： ÖHRLEIN, Reinhold , BAISCH, Gabriele , END, Nicole , BURKHARDT, Stephan , STUDER, Martin
IPC分类号： C07C67/30
CPC分类号： C07C235/74 , C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C12P7/62 , Y02P20/55
摘要： The invention relates to synthesis methods for the preparation of statin derivatives, which methods proceed by way of a key intermediate of formula I wherein X is halogen, acyloxy, activated hydrocarbyloxy, activated hydrocarbylthio or N(CH 3 )OCH 3 , R a is a hydroxy-protecting group, and R b is a carboxy-protecting group, and, as well as to the compound of formula I, to further intermediates and methods for their preparation by Friedel-Crafts acylation.
摘要翻译：本发明涉及用于制备他汀类衍生物的合成方法，该方法通过式I的关键中间体进行，其中X为卤素，酰氧基，活化的烃氧基，活性烃硫基或N（CH 3）OCH 3，R a为羟基保护基并且Rb是羧基保护基团，以及式I化合物，用于通过Friedel-Crafts酰化制备其进一步的中间体及其制备方法。

5. 发明申请

WO2007006648A1 (METH)ACRYLAMIDE PHOSPHORUS MONOMER COMPOSITION 审中-公开
标题翻译：（METH）丙烯酰胺磷单体组成
公开(公告)号：WO2007006648A1
公开(公告)日：2007-01-18
申请号：PCT/EP2006/063618
申请日：2006-06-28
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , CRACIUN, Liliana , POLISHCHUK, Orest , SCHRIVER, George William , BAISCH, Gabriele , ÖHRLEIN, Reinhold
发明人： CRACIUN, Liliana , POLISHCHUK, Orest , SCHRIVER, George William , BAISCH, Gabriele , ÖHRLEIN, Reinhold
IPC分类号： C08F30/02 , C09D143/02 , C09J143/02 , C07F9/38 , C07F9/40
CPC分类号： C09D143/02 , C07F9/4009 , C07F9/4056 , C07F9/5728 , C08F230/02 , C08K3/013 , C09C3/10 , C09D5/086 , C09J133/26 , C09J143/02 , Y10T428/254 , Y10T428/2857 , Y10T428/2887 , Y10T428/2913 , Y10T428/2933 , Y10T428/294 , Y10T428/2958 , Y10T428/2998 , Y10T428/31504 , Y10T428/31623 , Y10T428/31645 , Y10T428/31649 , Y10T428/31681 , Y10T428/31692 , Y10T428/31699 , Y10T428/31765 , Y10T428/31855 , Y10T428/31935
摘要： The present invention relates to polymerizable N-substituted acrylamide phosphorus- containing monomers, organic polymers formed from the same. Incorporation of said monomers into adhesives, pigment dispersants, coatings or films for polar surfaces or particles gives improved adhesive, anti-corrosive, and flame retardant properties.
摘要翻译：本发明涉及可聚合的N-取代丙烯酰胺含磷单体，由其形成的有机聚合物。将所述单体并入粘合剂，颜料分散剂，用于极性表面或颗粒的涂料或薄膜中提供了改进的粘合剂，抗腐蚀性和阻燃性能。

6. 发明申请

WO2004080963A1 PROCESS FOR THE PREPARATION OF INDOLE DERIVATIVES BY ENZYMATIC ACYLATION 审中-公开
标题翻译：通过酶学方法制备吲哚衍生物的方法
公开(公告)号：WO2004080963A1
公开(公告)日：2004-09-23
申请号：PCT/EP2004/050244
申请日：2004-03-03
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , END, Nicole , BAISCH, Gabriele
发明人： ÖHRLEIN, Reinhold , END, Nicole , BAISCH, Gabriele
IPC分类号： C07D209/24
CPC分类号： C07D209/24
摘要： A process for the preparation of compounds of formula (1), by enzymatic acylation to form compounds of formulae (3a) and (3a') and then reacting the compound of formula (3a) with a compound introducing the radical of formula -CH 2 -COOR 8 , R 8 being an organic radical, and then reducing, and optionally hydrolysing, the resulting compound of formula (4).
摘要翻译：通过酶促酰化制备式（1）化合物以形成式（3a）和（3a'）化合物的方法，然后使式（3a）化合物与引入式-CH 2 - 的基团的化合物反应， COOR 8，R 8为有机基团，然后还原并任选地水解得到的式（4）化合物。

7. 发明申请

WO2007048721A1 COLOURED PARTICLES FOR ELECTROPHORETIC DISPLAYS 审中-公开
标题翻译：电泳显示器的彩色颗粒
公开(公告)号：WO2007048721A1
公开(公告)日：2007-05-03
申请号：PCT/EP2006/067415
申请日：2006-10-16
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , FONTANA, Margherita , BAISCH, Gabriele , GIESENBERG, Thomas , MICHAU, Laurent , ÖHRLEIN, Reinhold , MÜHLEBACH, Andreas
发明人： FONTANA, Margherita , BAISCH, Gabriele , GIESENBERG, Thomas , MICHAU, Laurent , ÖHRLEIN, Reinhold , MÜHLEBACH, Andreas
IPC分类号： C09C1/30 , C09C1/40 , C09C3/12 , G02F1/167
CPC分类号： G02F1/167 , B82Y30/00 , C01P2002/88 , C01P2004/62 , C01P2004/64 , C09C1/3081 , C09C1/407 , C09C3/12
摘要： The present invention discloses the use of functionalized particles as electrophoretic displaying particles, wherein the functionalized particles are SiO 2 , Al 2 O 3 or mixed SiO 2 and Al 2 O 3 particles comprising, covalently bound to an oxygen atom on the surface, a radical of formula (1), wherein R 1 and R 2 are independently of each other hydrogen, particle surface-O-, or a substituent, n is 1, 2, 3, 4, 5, 6, 7 or 8, B is the direct bond or a bridge member, and D is the residue of an organic chromophore.
摘要翻译：本发明公开了使用官能化颗粒作为电泳显示颗粒，其中官能化颗粒是SiO 2，Al 2 O 3 3或混合SiO 包含与表面上的氧原子共价结合的式（1）的基团，其中R（R 1）2和/ n 1和R 2 2彼此独立地为氢，颗粒表面-O-或取代基，n为1,2,3,4,5,6,7 或8，B是直接键或桥连构件，D是有机发色团的残基。

8. 发明申请

WO2004108799A1 NOVEL SURFACE-ACTIVE POLYSILOXANE PHOTOINITIATORS 审中-公开
标题翻译：新型表面活性聚硅氧烷光敏剂
公开(公告)号：WO2004108799A1
公开(公告)日：2004-12-16
申请号：PCT/EP2004/050952
申请日：2004-05-28
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ROGERS, Jonathan , BAUDIN, Gisèle , JUNG, Tunja , ÖHRLEIN, Reinhold , BAISCH, Gabriele
发明人： ROGERS, Jonathan , BAUDIN, Gisèle , JUNG, Tunja , ÖHRLEIN, Reinhold , BAISCH, Gabriele
IPC分类号： C08G77/38
CPC分类号： G03F7/029 , C08F2/50 , C08G77/38 , G03F7/0007 , G03F7/001 , G03F7/0037 , G03F7/0757
摘要： Polymeric photoinitiators of the formula I or II wherein n and m independently of one another are 3-5; o is 10-16; p is 4-8; R is phenyl-CO-CO-O-; Y and Y' independently of one another are C 1 -C 10 alkylene or -[(CH 2 ) a -O-(CH 2 ) b ] c - wherein a is 2-10, b is 0-10, c is 1-3; with the proviso that they are, however, at least 1 if the methylene group in question is between two oxygen atoms.
摘要翻译：其中n和m彼此独立的式I或II的聚合物光引发剂为3-5; o是10-16; p为4-8; R是苯基-CO-CO-O-; Y和Y'彼此独立地是C 1 -C 10亚烷基或 - [（CH 2）a -O-（CH 2）b] c - ，其中a是2-10，b是0-10，c是1-3; 但是，如果所讨论的亚甲基在两个氧原子之间，则它们至少为1。

9. 发明申请

WO2003004456A1 PROCESS FOR THE PREPARATION OF 7-AMINO SYN 3,5-DIHYDROXY HEPTANOIC ACID DERIVATIVES VIA 6-CYANO SYN 3,5-DIHYDROXY HEXANOIC ACID DERIVATIVES 审中-公开
标题翻译：通过6-氰基合成3,5-二羟基HEXANOIC酸衍生物制备7-氨基-3,5-二羟基丙酸衍生物的方法
公开(公告)号：WO2003004456A1
公开(公告)日：2003-01-16
申请号：PCT/EP2002/007309
申请日：2002-07-02
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , BAISCH, Gabriele , KIRNER, Hans Jörg , BIENEWALD, Frank , BURKHARDT, Stephan , STUDER, Martin
发明人： ÖHRLEIN, Reinhold , BAISCH, Gabriele , KIRNER, Hans Jörg , BIENEWALD, Frank , BURKHARDT, Stephan , STUDER, Martin
IPC分类号： C07C227/32
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： The invention relates to novel synthesis methods for the preparation of the intermediates, which are suitable for the preparation of statin derivatives, especially to novel synthesis methods of the intermediate of formula VI wherein R a and R c are each independently of the other hydrogen or a hydroxy-protecting group or together are a bridging hydroxy-protecting group, and R b is a carboxy-protecting group ,which methods are carried out by conversion of the intermediate of formula XIX wherein R a and R c are each independently of the other hydrogen or a hydroxy-protecting group, and R b is a carboxy-protective group.
摘要翻译：本发明涉及适用于制备他汀类衍生物的中间体的新型合成方法，特别是式VI中间体的新合成方法，其中R a和R c各自独立地为氢或羟基 - 保护基或一起是桥接羟基保护基，Rb是羧基保护基，该方法通过式XIX的中间体转化而进行，其中R a和R c各自独立地为氢或羟基保护基基团，Rb是羧基保护基。

10. 发明申请

WO2003004455A2 SYNTHESIS AND INTERMEDIATES 审中-公开
标题翻译：合成与中间体
公开(公告)号：WO2003004455A2
公开(公告)日：2003-01-16
申请号：PCT/EP2002/007308
申请日：2002-07-02
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , BAISCH, Gabriele , KIRNER, Hans, Jörg , BIENEWALD, Frank , BURKHARDT, Stephan , STUDER, Martin
发明人： ÖHRLEIN, Reinhold , BAISCH, Gabriele , KIRNER, Hans, Jörg , BIENEWALD, Frank , BURKHARDT, Stephan , STUDER, Martin
IPC分类号： C07C227/32
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： The invention relates to novel synthesis methods for the preparation of the intermediates, which are suitable for the preparation of statin derivatives, especially to novel synthesis methods of the intermediate of formula VI wherein R a ' and R c ' are each independently of the other hydrogen or a hydroxy-protecting group or together are a bridging hydroxy-protecting group, and R b is a carboxy-protecting group, which methods are carried out by conversion of the intermediate of formula XVI wherein R a ' and R c ' are each independently of the other hydrogen or a hydroxy-protecting group, R* and R** are each independently of the other hydrogen or an amide-protecting group, and R b is a carboxy-protecting group; which methods proceed to further new intermediates and methods for their preparation.
摘要翻译：本发明涉及制备适于制备他汀类衍生物的中间体的合成方法，特别是式（Ⅵ）中间体的合成方法，其中R a'和R c'各自独立地为氢或羟基保护基团或一起是桥接羟基保护基团，Rb是羧基保护基团，该方法通过式（XVI）的中间体的转化来进行，其中R a'和R c'各自独立地为氢或羟基保护基，R *和R **各自独立地为氢或酰胺保护基，Rb为羧基保护基; 哪些方法进行进一步的中间体及其制备方法。

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