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21. 发明申请

WO2004082826A3 CATALYST COMPOSITION AND METHOD FOR CHLORINATING AROMATIC COMPOUNDS 审中-公开
标题翻译：催化剂组合物和方法用于氯化芳族化合物
公开(公告)号：WO2004082826A3
公开(公告)日：2004-11-18
申请号：PCT/US2004006182
申请日：2004-03-02
申请人： GEN ELECTRIC , HANCU DAN , COLBORN ROBERT EDGAR , KILMER RICHARD JOSEPH
发明人： HANCU DAN , COLBORN ROBERT EDGAR , KILMER RICHARD JOSEPH
IPC分类号： B01J31/22 , C07C17/12 , C07C25/02 , B01J31/02 , B01J31/04
CPC分类号： C07C25/02 , B01J31/0211 , B01J31/0215 , B01J31/04 , B01J31/226 , B01J31/26 , B01J2531/16 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/57 , B01J2531/64 , B01J2531/72 , B01J2531/824 , B01J2531/828 , B01J2531/845 , B01J2531/847 , B01J2540/225 , C07C17/12 , C07C25/125
摘要： Aromatic compounds such as toluene and o-xylene are chlorinated in the presence of a catalyst combination prepared by combining (A) at least one salt comprising a metal selected from the group consisting of a Group 4-12 metal, a lanthanide and an actinide; and a counterion; and (B) at least one organic sulfur compound, preferably phenothiazine-N-carbonyl chloride. The catalyst combination may include reaction products of (A) and (B). Under these conditions, production of the p-chloro isomer is optimized. In some embodiments said counterion is an organic counterion derived from at least one acidic organic compound selected from the group consisting of those with an approximate pKa value relative to water of at least about 3.
摘要翻译：芳族化合物如甲苯和邻二甲苯在存在催化剂组合的情况下进行氯化，所述催化剂组合通过组合（A）至少一种包含选自第4-12族金属，镧系元素和锕系元素的金属的盐; 和反抗; 和（B）至少一种有机硫化合物，优选吩噻嗪-N-碳酰氯。催化剂组合可以包括（A）和（B）的反应产物。在这些条件下，优化了对氯异构体的生产。在一些实施方案中，所述抗衡离子是衍生自至少一种酸性有机化合物的有机抗衡离子，所述酸性有机化合物选自具有至少约3的相对于水的近似pKa值的那些。

22. 发明申请

WO03054038A2 CATALYST COMPOSITION AND OLEFIN POLYMERIZATION USING SAME 审中-公开
标题翻译：使用相同的催化剂组合物和烯烃聚合
公开(公告)号：WO03054038A2
公开(公告)日：2003-07-03
申请号：PCT/US0239364
申请日：2002-12-09
申请人： CHEVRON PHILLIPS CHEMICAL CO
发明人： SMALL BROOKE L , MARCUCCI ANGEL JOSE
IPC分类号： C07F11/00 , C08F4/60 , C08F4/62 , C08F4/6392 , C08F4/659 , C08F4/68 , C08F4/685 , C08F4/69 , C08F10/02 , C08F110/02 , C08F210/16 , C08F10/00 , C08F10/14
CPC分类号： B01J31/18 , B01J31/1815 , B01J31/2204 , B01J31/24 , B01J2231/122 , B01J2231/20 , B01J2531/56 , B01J2531/62 , B01J2531/72 , C07F11/005 , C08F4/63912 , C08F4/6392 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2420/02 , C08F4/63904 , C08F2500/02 , C08F2500/23 , C08F210/14 , C08F4/69224 , C08F10/00 , C08F4/69232
摘要： Novel metal complexes, particularly chromium complexes, which contain at least one tridentate ligand are disclosed and prepared. Olefins, particularly ethylene, can be reacted to form butene and/or other homo- or co-oligomers and/or polymers with high alpha -olefin concentrations by contacting a metal catalyst which contains a transition metal, particularly chromium, complexes having per metal atom at least one tridentate ligand with N, O, or N and O coordinating sites.
摘要翻译：公开并制备了含有至少一个三齿配体的新型金属络合物，特别是铬络合物。烯烃，特别是乙烯可以通过使包含过渡金属的金属催化剂，特别是铬，具有每个金属原子的络合物接触，使烯烃和/或其它具有高α-烯烃浓度的均聚物或共低聚物和/或聚合物反应至少一个具有N，O或N和O配位点的三齿配位体。

23. 发明申请

WO02048039A1 CATALYSTS AND THE HYDROFORMYLATION OF OLEFINS 审中-公开
标题翻译：催化剂与烯烃加氢甲酰化反应
公开(公告)号：WO02048039A1
公开(公告)日：2002-06-20
申请号：PCT/NZ2001/000280
申请日：2001-12-12
IPC分类号： B01J21/08 , B01J23/02 , B01J23/46 , B01J31/22 , C07C45/50 , C01B33/46
CPC分类号： B01J31/1616 , B01J21/08 , B01J23/02 , B01J23/464 , B01J31/1683 , B01J31/223 , B01J31/26 , B01J31/30 , B01J31/4046 , B01J2231/321 , B01J2531/56 , B01J2531/62 , B01J2531/64 , B01J2531/72 , B01J2531/822 , B01J2531/842 , B01J2531/845 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： The invention discloses novel homogeneous catalysts for hydroformylation reactions comprising or including: a) a substantially amorphous silicate host, and b) a plurality of metal cationic species (preferably Rh(III) species) capable of catalysing a hydroformylation reaction, coordinated or otherwise bound to the host. The invention also discloses methods for making such a catalyst and applications for the catalyst.
摘要翻译：本发明涉及用于加氢甲酰化反应的新型均相催化剂，并且包含（a）基本上无定形的硅酸盐主体和（b）能够催化的多种金属阳离子物质（优选Rh（III）物质）加氢甲酰化反应，所述物质与该主体配位或相关。本发明还涉及制备这种类型的催化剂的方法以及该催化剂的应用。

24. 发明申请

WO01038280A1 METHOD FOR OXIDATION OF XYLENE DERIVATIVES 审中-公开
标题翻译：氧化衍生物的方法
公开(公告)号：WO01038280A1
公开(公告)日：2001-05-31
申请号：PCT/US2000/031719
申请日：2000-11-20
IPC分类号： C07D307/89 , B01J31/04 , B01J31/22 , C07B61/00 , C07C51/265 , C07C63/70 , C07C63/72
CPC分类号： B01J31/2234 , B01J31/04 , B01J31/2208 , B01J2531/16 , B01J2531/56 , B01J2531/64 , B01J2531/72 , B01J2531/842 , B01J2531/845 , C07C51/265 , C07C63/04 , C07C63/22
摘要： Xylene derivatives, such as chloro-ortho-xylene, are oxidized in the absence of solvent or added promoter in the presence of at least one metal catalyst. The primary products are chlorophthalic anhydride and chlorotoluic acid.
摘要翻译：二甲苯衍生物，如氯 - 邻 - 二甲苯，在不存在溶剂或加入助催化剂的情况下，在至少一种金属催化剂的存在下被氧化。主要产品为氯邻苯二甲酸酐和氯代甲酸。

25. 发明申请

WO00003802A1 NOVEL SOLID OXIDATION CATALYSTS, IN PARTICULAR FOR EPOXIDATION OF PROCHIRAL COMPOUNDS 审中-公开
标题翻译：新型固体氧化催化剂，特别是用于环氧化合物的环氧化
公开(公告)号：WO00003802A1
公开(公告)日：2000-01-27
申请号：PCT/FR1999/001750
申请日：1999-07-16
IPC分类号： B01J31/22 , B01J37/02 , C07D301/03 , B01J31/12
CPC分类号： B01J37/0238 , B01J31/223 , B01J37/0203 , B01J2231/72 , B01J2531/56 , B01J2531/57 , B01J2531/58 , B01J2531/62 , B01J2531/64 , B01J2531/66
摘要： The invention concerns recyclable solid oxidation catalysts comprising a metal compound of a pentavalent or hexavalent metal M and selected among the group consisting of tantalum, vanadium, niobium, chromium, molybdenum, tungsten, grafted at the surface of a solid oxide with at least one, preferably one, covalent bond between an oxygen atom of the solid oxide and the metal M atom, the grafted metal compound having at least two alkoxy groups bound to the metal by the oxygen atom. Preferably, at least 2 alkoxy groups bound to the metal M belong to a polyol unit, preferably diol. The invention also concerns oxidation methods, in particular epoxidation methods using same.
摘要翻译：本发明涉及可回收的固体氧化催化剂，其包含五价或六价金属M的金属化合物，选自钽，钒，铌，铬，钼，钨，其在至少一种固体氧化物的表面上接枝，优选在固体氧化物的氧原子和金属M原子之间的共价键，具有至少两个烷氧基的接枝金属化合物通过氧原子与金属键合。优选地，与金属M结合的至少2个烷氧基属于多元醇单元，优选二醇。本发明还涉及氧化方法，特别是使用它们的环氧化方法。

26. 发明申请

WO98046352A1 METHOD FOR PRODUCING SILASESQUIOXANE METAL COMPLEXES, NOVEL SILASESQUIOXANE METAL COMPLEXES AND THE USE THEREOF 审中-公开
标题翻译：用于生产silasesquioxane金属络合物新silasesquioxane金属配合物及其用途
公开(公告)号：WO98046352A1
公开(公告)日：1998-10-22
申请号：PCT/EP1998/001932
申请日：1998-04-02
IPC分类号： B01J31/02 , B01J31/12 , B01J31/16 , B01J31/22 , C07D301/02 , C07D301/03 , C07F7/08 , C07F9/00 , C07F17/00 , C08G77/398 , C07D301/00 , C07F7/28
CPC分类号： C08G77/398 , B01J31/125 , B01J31/1675 , B01J31/2226 , B01J2231/70 , B01J2231/72 , B01J2531/0205 , B01J2531/0288 , B01J2531/46 , B01J2531/48 , B01J2531/56 , C07D301/02 , C07F7/0836 , C07F7/0838 , C07F9/00 , C07F9/005 , C07F17/00
摘要： The invention relates to a method for producing silasesquioxane metal complexes of general formula (II) {R SiO1,5)n(R SiO1,5)m[(B)q(O)r]}u(M)v(Y)w, wherein R stands for C5-C10-cycloalkyl, norbornyl, adamantyl; R means oxygen; B stands for H, OH, halogen, alkoxy, SiR y, wherein R can be C1-C4 alkyl, aryl or substituted silyl groups and y stands for 2 and 3, and R and R can be functionalized; M stands for metals of the IV to VII PSE sub-group; Y stands for C1-C20 alkyl or aryl groups devoid of betahydrogen, silyl, alkoxy, OH, halogen, oxo, imido, fluorenyl, indenyl, cyclopentadienyl, whereby the individual ligands can be substituted; n = 6 and 7; m = 0 and 1; q = 0-2; r = 0-2; u = 1-4; v = 1-4; w = 0-12, wherein a metal compound of the IV to VII PSE sub-group and at least one silasesquioxane of general formula (I) {(R SiO1,5)n(R SiO1,5)m[(H)p(B)q(O)r]}, in which R , B, n, m, q, r have the above-mentioned meaning, and R stands for OH and p equals 0-4, are suspended in an akylated aromatic hydrocarbon, optionally in the presence of a basic compound by stirring at -80 to +110 DEG C and the reaction product is separated at room temperature. The invention also relates to metal complexes which comprise an oxidic metal cluster containing titanium atoms, wherein each titanium atom has been coordinated x 6. The invention also describes the use of said metal complexes as catalysts for the oxidation or epoxidation of unsaturated hydrocarbons or alcohols, also in an aqueous medium.
摘要翻译：本发明涉及一种用于制备通式silasesquioxane - 金属配合物（II）的方法：{（R <1>的SiO 1.5）N（R <2A>的SiO 1.5）M [（B）Q（O）R]} U（M）v（Y）W，其中R <1> C5-C10环烷基，降冰片基，金刚烷基，R <2A>氧，BH，OH，卤素，烷氧基，SIR <3>ÿ其中R <3 可以是> C1-C4烷基，芳基或取代甲硅烷基，y为2和3，和R可以被官能化<1>和R <3>中，第四至第七过渡族的PTE的，Y C1-C20的M个金属不含有的β氢，甲硅烷基，烷氧基，OH，卤素，氧代，亚氨基，芴基，茚基，环戊二烯基，其中每个配体可被取代，n为6和7烷基或芳基，m为0和1，q 0 到2，r为0至2，u为1〜4，v为1至4，w为0至12，由第四至第七子组的金属化合物和通式中的至少一个silasesquioxane反应（I）：{R <1> 的SiO 1.5）N（R <2>的SiO 1.5）M [（H）p（B）q（O）R]}其中，R <1>，B，N，M，q，R如上述所定义具有R <2> OH和p为0至 4悬浮在烷基化芳族烃，可任选在一种碱性化合物的存在下，用在-80搅拌以110℃，将反应产物在室温下分离。和金属配合物中，其包括含原子的钛氧化金属簇，其中，每个钛原子配位了6倍。此外，使用这些金属配合物的描述作为催化剂用于不饱和烃类或醇的氧化或环氧化，也在水性介质中。

27. 发明申请

WO1997042165A1 FLUORENE SUBSTITUTED WITH A GROUP COMPRISING A HETERO ATOM 审中-公开
标题翻译：采用包含异位原子的组取代荧光
公开(公告)号：WO1997042165A1
公开(公告)日：1997-11-13
申请号：PCT/NL1997000214
申请日：1997-04-23
申请人： DSM N.V. , GRUTER, Gerardus, Johannes, Maria , VAN BEEK, Johannes, Antonius, Maria , HERKLOTS, Marc
发明人： DSM N.V.
IPC分类号： C07C211/31
CPC分类号： B01J31/2226 , B01J31/181 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , C07C211/31 , C07C2603/18 , C07F17/00 , C08F4/61912 , C08F4/6192 , C08F10/00
摘要： Substituted fluorene compound which comprises at least one substituent of the form -RDR'n where R is a bonding group between the fluorene and the DR'n group, D is a hetero atom chosen from group 15 or 16 of the Periodic System of the Elements, R' is a substituent and n is the number of R' groups bonded to D and application thereof as a ligand in a metal complex. Metal complexes in which at least one of these cyclopentadiene compounds is present as a ligand are useful as catalysts for the polymerisation of alpha-olefins.
摘要翻译：取代的芴化合物，其包含至少一种形式-RDR'n的取代基，其中R是芴和DR'n基团之间的键合基团，D是选自元素周期系统的第15或16族的杂原子，R'是取代基，n是与D结合的R'基团的数目，以及作为金属络合物中配体的应用。其中至少一种这些环戊二烯化合物作为配体存在的金属络合物可用作α-烯烃聚合的催化剂。

28. 发明申请

WO1995035164A1 OLEFIN POLYMERIZATION CATALYST 审中-公开
标题翻译： OLEFIN聚合催化剂
公开(公告)号：WO1995035164A1
公开(公告)日：1995-12-28
申请号：PCT/US1995006794
申请日：1995-05-26
申请人： MOBIL OIL CORPORATION
发明人： MOBIL OIL CORPORATION , KISSIN, Yury Viktorovich , MINK, Robert, Ivan
IPC分类号： B01J31/16
CPC分类号： C08F10/00 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/16 , B01J31/182 , B01J31/223 , B01J31/2243 , B01J2231/12 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , C08F2410/04 , C08F4/645 , C08F4/64 , C08F4/651
摘要： A catalyst composition for olefin polymerization and copolymerization which contains a complex of Ti, V, Zr, or Hf with a bidentate ligand or a tridentate ligand and a cocatalyst mixture containing dialkylaluminum halide and dialkylmagnesium. The bidentate ligands are described by general formulas Z-R-Z or Z-R-W-R-Z where R is an alkylene, cycloalkylene, arylene, or alkylarylene group; W is CH2, O, S, N-R', or SiR'2 where R' is an alkyl or aryl grup; and Z is O, S, N-H, or C(=O)-O. The tridentate ligands are described by formulas Z-(R-Z)-Z or Z-(R-U)-Z where R is an alkylene or arylene group; and Z and U are different and are O, S, N-H, or C-(=O)-O.
摘要翻译：用于烯烃聚合和共聚的催化剂组合物，其包含Ti，V，Zr或Hf与二齿配体或三齿配体的络合物和含有二烷基卤化铝和二烷基镁的助催化剂混合物。二齿配体由通式Z-R-Z或Z-R-W-R-Z描述，其中R是亚烷基，亚环烷基，亚芳基或烷基亚芳基; W是CH 2，O，S，N-R'或SiR'2，其中R'是烷基或芳基; Z为O，S，N-H或C（= O）-O。三齿配体由式Z-（R-Z）-Z或Z-（R-U）-Z表示，其中R是亚烷基或亚芳基; 且Z和U不同，为O，S，N-H或C - （= O）-O。

29. 发明申请

WO9113074A3 TRANSITION METAL CATALYST COMPOSITION FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的过渡金属催化剂组合物
公开(公告)号：WO9113074A3
公开(公告)日：1991-10-17
申请号：PCT/US9101377
申请日：1991-02-27
申请人： EXXON CHEMICAL PATENTS INC
发明人： DATTA SUDHIN
IPC分类号： C07F7/28 , B01J31/16 , B01J31/18 , B01J31/22 , C07F7/00 , C07F9/00 , C07F11/00 , C08F4/06 , C08F4/60 , C08F4/639 , C08F4/68 , C08F10/00 , C07F19/00 , C08F4/00
CPC分类号： B01J31/223 , B01J31/181 , B01J31/1825 , B01J2531/46 , B01J2531/56 , B01J2531/62 , C07F7/006 , C07F9/005 , C07F11/005 , C08F10/00 , C08F4/62 , C08F4/602 , C08F4/68198 , C08F4/64058
摘要： This invention relates to bidentate transition metal catalyst compositions useful for coordination polymerization of alpha olefin monomers. The novel catalyst compounds are prepared by: (1) reacting a transition trihalide, a transition metal trialkoxide or mixed tri(halide/alkoxide), or the adducts of these materials with Lewis bases, with two equivalents of a bidentate chelating ligand; or (2) reacting two equivalents of the same or different transition metal (+3) tris chelates with one equivalent of a transition metal trihalide or its adduct with Lewis bases. The invention chelating ligands are those which contain at least two, and preferably not more than two, hetero atoms such as O, N, P, or S, separated by a hydrocarbon radical providing sufficient chain length so as to allow both hetero atoms to chelate the same metal atom. The chelating ligand must have at least one easily removable positive ion which is lost on chelation to afford a uninegative, bidentate ligand.
摘要翻译：本发明涉及可用于α-烯烃单体配位聚合的二齿过渡金属催化剂组合物。新型催化剂化合物通过以下方法制备：（1）使三卤化过渡金属，三烷氧基过渡金属或三卤化物/醇盐混合物或这些物质与路易斯碱的加合物与两个当量的二齿螯合配体反应; 或（2）使两当量相同或不同的过渡金属（+3）三螯合物与一当量过渡金属三卤化物或其加合物与路易斯碱反应。本发明的螯合配体是含有至少两个，优选不多于两个杂原子如O，N，P或S的那些，被提供足够链长的烃基隔开，以使两个杂原子螯合相同的金属原子。螯合配体必须具有至少一个易于除去的阳离子，其在螯合作用时损失以提供单阴离子二齿配体。

30. 发明申请

WO2016012786A1 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2016012786A1
公开(公告)日：2016-01-28
申请号：PCT/GB2015/052115
申请日：2015-07-22
申请人： ECONIC TECHNOLOGIES LTD
发明人： KEYWORTH, Colin , CHAPMAN, Andy , CHARTOIRE, Anthony , HOLLIS, Emma , WILLIAMS, Charlotte , KEMBER, Michael
IPC分类号： B01J31/18 , B01J31/22 , C08G64/34
CPC分类号： C08G64/34 , B01J31/1835 , B01J31/2239 , B01J31/2243 , B01J31/226 , B01J2531/0216 , B01J2531/0252 , B01J2531/16 , B01J2531/22 , B01J2531/23 , B01J2531/26 , B01J2531/31 , B01J2531/46 , B01J2531/56 , B01J2531/62 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D257/02 , C07D285/00 , C07D487/08 , C08G63/823
摘要： The present invention relates to the field of polymerisation catalysts, and systems comprising these catalysts for polymerising carbon dioxide and an epoxide, a lactide and/or lactone, and/or an epoxide and an anhydride. The catalyst is of formula (I): (Formula (I)) wherein at least one of M 1 or M 2 is selected from Ni(II) and Ni(lll)-X. A process for the reaction of carbon dioxide with an epoxide; an epoxide and an anhydride; and/or a lactide and/or a lactone in the presence of the catalyst is also described.
摘要翻译：本发明涉及聚合催化剂领域，以及包含这些用于聚合二氧化碳和环氧化物，丙交酯和/或内酯，和/或环氧化物和酸酐的催化剂的体系。催化剂具有式（I）：（式（I）），其中M1或M2中的至少一个选自Ni（II）和Ni（III）-X。二氧化碳与环氧化物反应的方法; 环氧化物和酸酐; 和/或丙交酯和/或内酯在催化剂存在下也被描述。

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