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    • 5. 发明申请
    • SYNTHESIS OF M41S MATERIALS
    • M41S材料的合成
    • WO1998006665A1
    • 1998-02-19
    • PCT/US1997013952
    • 1997-08-12
    • MOBIL OIL CORPORATION
    • MOBIL OIL CORPORATIONROTH, Wieslaw, Jerzy
    • C01B33/36
    • C01B37/00C01B37/02
    • M41S materials are synthesized from an aqueous reaction mixture comprising sources of an oxide of a tetravalent element Y, hydroxyl ions and an organic surfactant R', wherein R' comprises an ion of the formula R1R2R3R4Q , wherein Q is nitrogen or phosphorus and wherein at least one of R1, R2, R3 and R4 is aryl or alkyl of from 6 to about 36 carbon atoms or combinations thereof, the remainder of R1, R2, R3 and R4 being selected from the group consisting of hydrogen, alkyl of from 1 to 5 carbon atoms and combinations thereof, and wherein the OH/surfactant molar ratio is in the approximate range 0.9-1.2, more preferably 1.0-1.15. By controlling the surfactant level within the above ranges it is found that high quality M41S materials with excellent adsorption properties can be produced at surfactant utilization levels.
    • M41S材料由包含四价元素Y,羟基离子和有机表面活性剂R'的氧化物源的水性反应混合物合成,其中R'包含式R 1 R 2 R 3 R 4 Q +的离子,其中Q为氮或磷, 其中R 1,R 2,R 3和R 4中的至少一个为6至约36个碳原子的芳基或烷基或其组合,R 1,R 2,R 3和R 4的其余部分选自氢, 1至5个碳原子及其组合,并且其中OH /表面活性剂的摩尔比在约0.9-1.2,更优选1.0-1.15的范围内。 通过控制表面活性剂含量在上述范围内,可以发现在表面活性剂利用水平下可以生产具有优异吸附性能的高品质M41S材料。