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    • 11. 发明申请
    • PHOTO-LATENT TITANIUM CATALYSTS
    • 钛酸钡催化剂
    • WO2011032875A1
    • 2011-03-24
    • PCT/EP2010/063198
    • 2010-09-09
    • BASF SEHINTERMANN, TobiasBAUER, DidierCARROY, AntoineLORDELOT, CarolineKOHLI STECK, Rachel
    • HINTERMANN, TobiasBAUER, DidierCARROY, AntoineLORDELOT, CarolineKOHLI STECK, Rachel
    • B01J31/02B01J31/22C08G18/22
    • B01J31/2234B01J31/0208B01J31/2213B01J31/2226B01J2231/34B01J2531/46C08G18/222C08G18/6216C08G18/792C09D175/04
    • The present invention provides a photolatent Ti-chelate catalyst formulation, comprising (i) at least one compound of the formula (I) wherein R 1 is C 1 -C 20 alkyl or C 2 -C 20 alkyl which is interrupted by one or more non-consecutive O-atoms; Y is formula (II) or optionally substituted phenyl; Y 1 is formula (III) or optionally substituted phenyl; Y 2 is formula (IV) or optionally substituted phenyl; Y 3 is formula (V) or optionally substituted phenyl; R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 independently of each other are hydrogen, halogen, optionally substituted C 1 -C 20 alkyl, or R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 independently of each other are optionally substituted C 6 -C 14 aryl, provided that only one of R 2 , R 3 , R 4 is hydrogen and only one of R 5 , R 6 , R 7 is hydrogen and only one of R 8 , R 9 , R 10 is hydrogen and only one of R 11 , R 12 , R 13 is hydrogen; and (ii) at least one chelate ligand compound of the formula IIa, IIb or IIc, wherein Y' is formula (VI) or formula (VII); Y' 1 is formula (VIII) or formula (IX); R' 2 , R' 3 , R' 4 , R' 5 , R' 6 and R' 7 independently of each other have on of the meanings as given for R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 ; and R' 14 , R' 15 and R' 16 independently of each other have on of the meanings as given for R 14 , R 15 and R 16 .
    • 本发明提供了一种光催化剂钛螯合催化剂制剂,其包含(i)至少一种式(I)化合物,其中R 1是被一个或多个非连续O原子间隔的C 1 -C 20烷基或C 2 -C 20烷基; Y是式(II)或任选取代的苯基; Y1是式(III)或任选取代的苯基; Y2是式(IV)或任选取代的苯基; Y 3为式(Ⅴ)或任选取代的苯基; R2,R3,R4,R5,R6,R7,R8,R9,R10,R11,R12和R13彼此独立地是氢,卤素,任选取代的C 1 -C 20烷基,或者R 2,R 3,R 4,R 5,R 6,R 7 R 8,R 9,R 10,R 11,R 12和R 13彼此独立地是任选取代的C 6 -C 14芳基,条件是R 2,R 3,R 4中仅有一个是氢,并且R 5,R 6,R 7中只有一个是氢, R8,R9,R10为氢,R11,R12,R13中只有一个为氢; 和(ii)式IIa,IIb或IIc的至少一种螯合配体化合物,其中Y'为式(VI)或式(VII); Y'1是式(VIII)或式(IX); R'2,R'3,R'4,R'5,R'6和R'7彼此独立地具有对R2,R3,R4,R5,R6,R7,R8,R9给出的含义 ,R10,R11,R12和R13; 并且R 14,R'15和R 16彼此独立地具有对R 14,R 15和R 16给出的含义。