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1. 发明申请

WO2003004471A1 MULTIFUNCTIONAL ALKOXYAMINES BASED ON POLYALKYLPIPERIDINES, POLYALKYLPIPERAZINONES AND POLYALKYLMORPHOLINONES AND THEIR USE AS POLYMERIZATION REGULATORS/INITIATORS 审中-公开
标题翻译：多官能烷基胺基聚对苯二胺，聚丙烯腈和聚甲基吗啉及其作为聚合稳定剂/引发剂的用途
公开(公告)号：WO2003004471A1
公开(公告)日：2003-01-16
申请号：PCT/EP2002/007131
申请日：2002-06-27
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , KRAMER, Andreas , MÜHLEBACH, Andreas , NESVADBA, Peter , ZINK, Marie-Odile , HINTERMANN, Tobias
发明人： KRAMER, Andreas , MÜHLEBACH, Andreas , NESVADBA, Peter , ZINK, Marie-Odile , HINTERMANN, Tobias
IPC分类号： C07D211/94
CPC分类号： C08F4/00 , C07D211/94
摘要： The instant invention relates to multifunctional alkoxyamines based on polyalkylpiperidines, polyalkylpiperazinones and polyalkylmorpholinones and their use as polymerization regulatros/initiators. Further subjects of the invention are a polymerizable composition comprising an ethylenically unsaturated monomer or oligomer and the alkoxyamine compound as well as a process for polymerization and a process for preparation of the compounds.
摘要翻译：本发明涉及基于聚烷基哌啶，聚烷基哌嗪酮和聚烷基吗啉酮的多官能烷氧基胺及其作为聚合调节剂/引发剂的用途。本发明的其它主题是包含烯键式不饱和单体或低聚物和烷氧基胺化合物的可聚合组合物以及聚合方法和化合物的制备方法。

2. 发明申请

WO2002100831A1 4-IMINO-N-ALKOXY OR OXY-POLYALKYL-PIPERIDINE COMPOUNDS AND THEIR USE AS POLYMERIZATION REGULATORS 审中-公开
标题翻译： 4-亚氨基-N-烷基或氧代 - 聚亚烷基 - 哌啶化合物及其作为聚合调节剂的用途
公开(公告)号：WO2002100831A1
公开(公告)日：2002-12-19
申请号：PCT/EP2002/006108
申请日：2002-06-04
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , NESVADBA, Peter , HINTERMANN, Tobias , KRAMER, Andreas , ZINK, Marie-Odile , BUGNON, Lucienne
发明人： NESVADBA, Peter , HINTERMANN, Tobias , KRAMER, Andreas , ZINK, Marie-Odile , BUGNON, Lucienne
IPC分类号： C07D211/94
CPC分类号： C07D211/94
摘要： The present invention relates to selected 4-imino-N-alkoxy-polyalkyl-peperidine compounds preparation, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a 4-imino-N-alkoxy-polyalkyl-piperidine compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 4-imino-N-alkoxy-polyalkyl-piperidine compounds for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.
摘要翻译：本发明涉及选择的4-亚氨基-N-烷氧基 - 多烷基 - 哌啶化合物，其可聚合组合物包含a）至少一种烯属不饱和单体和b）4-亚氨基-N-烷氧基 - 多烷基 - 哌啶化合物。本发明的其它方面是用于聚合烯属不饱和单体的方法，以及4-亚氨基-N-烷氧基 - 聚烷基 - 哌啶化合物用于受控聚合的方法。中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。

3. 发明申请

WO2003074572A1 OPEN-CHAIN ALKOXYAMINES AND THEIR CORRESPONDING NITROXIDES FOR CONTROLLED LOW TEMPERATURE RADICAL POLYMERIZATION 审中-公开
标题翻译：开链烷氧基胺及其与对照的硝基过氧化物用于控制低温放射性聚合
公开(公告)号：WO2003074572A1
公开(公告)日：2003-09-12
申请号：PCT/EP2003/001895
申请日：2003-02-25
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , HINTERMANN, Tobias , NESVADBA, Peter , KRAMER, Andreas , FINK, Jochen
发明人： HINTERMANN, Tobias , NESVADBA, Peter , KRAMER, Andreas , FINK, Jochen
IPC分类号： C08F4/00
CPC分类号： C08F4/00
摘要： The present invention relates to open chain alkoxyamine compounds, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) at least one open chain alkoxyamine compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of open chain alkoxyamine compounds for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X, as well as a process and their use for polymerization are also subjects of the present invention.
摘要翻译：本发明涉及开链烷氧基胺化合物，可聚合组合物，其包含a）至少一种烯键式不饱和单体和b）至少一种开链烷氧基胺化合物。本发明的另外的方面是用于聚合烯键式不饱和单体的方法，以及使用开链烷氧基胺化合物用于受控聚合。中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂X的组合物以及其聚合的方法和用途也是本发明的主题。

4. 发明申请

WO2004000809A1 CATIONIC ALKOXYAMINES AND THEIR USE IN PRODUCING NANO PARTICLES FROM NATURAL OR SYNTHETIC CLAYS 审中-公开
标题翻译：阳离子烷氧基胺及其在天然或合成粘土生产纳米颗粒中的应用
公开(公告)号：WO2004000809A1
公开(公告)日：2003-12-31
申请号：PCT/EP2003/006370
申请日：2003-06-17
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , MÜHLEBACH, Andreas , NESVADBA, Peter , KRAMER, Andreas
发明人： MÜHLEBACH, Andreas , NESVADBA, Peter , KRAMER, Andreas
IPC分类号： C07D211/94
CPC分类号： C08F4/00 , C07D211/94 , C07D241/08 , C07F9/4006 , C07F9/591
摘要： The instant invention relates to cationic alkoxyamines, which are useful as polymerization initiators/regulators in a controlled stable free radical polymerization process to produce intercalated and/or exfoliated nanoparticles from natural or synthetic clays. The invention also relates to improved nanocomposites produced by this process and to the use of these nanocomposite compositions as, for example, coatings, sealants, caulks, adhesives and as plastic additives.
摘要翻译：本发明涉及阳离子烷氧基胺，其可用作控制稳定的自由基聚合方法中的聚合引发剂/调节剂，以从天然或合成粘土生产插层和/或剥离的纳米颗粒。本发明还涉及通过该方法生产的改进的纳米复合材料以及这些纳米复合材料组合物作为例如涂料，密封剂，填缝剂，粘合剂和塑料添加剂的用途。

5. 发明申请

WO2005118651A1 ALKOXYAMINES CONTAINING A RADICALLY POLYMERIZABLE GROUP 审中-公开
标题翻译：含有极性可聚合基团的烷氧基胺
公开(公告)号：WO2005118651A1
公开(公告)日：2005-12-15
申请号：PCT/EP2005/052260
申请日：2005-05-17
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , NESVADBA, Peter , KRAMER, Andreas , BUGNON, Lucienne
发明人： NESVADBA, Peter , KRAMER, Andreas , BUGNON, Lucienne
IPC分类号： C08F4/00
CPC分类号： C07D241/08 , C07D211/94
摘要： The instant invention relates to novel alkoxyamine initiators/regulators containing an ethylenically unsaturated, radically polymerizable group. The compounds are useful for the preparation of complex polymeric architectures. Further aspects of the invention are a polymerizable composition and a polymerization process comprising the alkoxyamine initiators/regulators, a macroinitiator obtainable by said polymerization process and a process for polymerizing with the macroinitiator.
摘要翻译：本发明涉及含有烯属不饱和的，可自由基聚合的基团的新的烷氧基胺引发剂/调节剂。该化合物可用于制备复合聚合物结构。本发明的其它方面是可聚合组合物和包含烷氧基胺引发剂/调节剂的聚合方法，通过所述聚合方法获得的大分子引发剂和与大分子引发剂聚合的方法。

6. 发明申请

WO2004044017A1 PROCESS FOR THE PREPARATION OF HYDROXY-VINYL-AROMATIC POLYMERS OR COPOLYMERS BY ANIONIC OR CONTROLLED RADICAL POLYMERIZATION 审中-公开
标题翻译：通过阴离子或控制的自由基聚合制备羟基 - 芳基芳族聚合物或共聚物的方法
公开(公告)号：WO2004044017A1
公开(公告)日：2004-05-27
申请号：PCT/EP2003/050793
申请日：2003-11-05
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , KUNIMOTO, Kazuhiko , NESVADBA, Peter , KRAMER, Andreas
发明人： KUNIMOTO, Kazuhiko , NESVADBA, Peter , KRAMER, Andreas
IPC分类号： C08F12/22
CPC分类号： C08F12/22
摘要： The instant invention relates to a process for the preparation of hydroxy-vinyl-aromatic polymers in particular 4-hydroxystyrene polymers or copolymers by anionic or controlled radical polymerization of the respective monomer, wherein the hydroxy functionality is blocked with a protective group which is subsequently removed by reacting it with a halosilane reagent. The resulting (co)polymers have a narrow polydispersity and are useful for manufacturing photoresists.
摘要翻译：本发明涉及通过相应单体的阴离子或受控自由基聚合制备羟基乙烯基芳族聚合物，特别是4-羟基苯乙烯聚合物或共聚物的方法，其中羟基官能团被保护基团封闭，随后被除去通过使其与卤代硅烷试剂反应。所得（共）聚合物具有窄的多分散性，并且可用于制造光致抗蚀剂。

7. 发明申请

WO2003075091A1 COLOUR PHOTOGRAPHIC RECORDING MATERIAL 审中-公开
标题翻译：彩色摄影记录材料
公开(公告)号：WO2003075091A1
公开(公告)日：2003-09-12
申请号：PCT/EP2003/001898
申请日：2003-02-25
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BIRY, Stéphane , FUSO, Francesco , KRAMER, Andreas
发明人： BIRY, Stéphane , FUSO, Francesco , KRAMER, Andreas
IPC分类号： G03C7/392
CPC分类号： C07D405/12 , C07D211/94 , C07D491/10 , G03C7/3005 , G03C7/39248 , G03C7/3928
摘要： A colour photographic material which contains on a support at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, together with customary non-light-sensitive layers, characterized in that at least one layer contains a compound of formula (I) or (II) wherein the R 1 -radicals and R 2 -radicals are preferably methyl; and wherein the compounds of formula (II) are preferably (III) R 3 is a radical -CH(CH 3 )-X-D, wherein X is phenylene, D is a group (IV) or a group -C(O)-C 1 -C 18 alkyl or a group -O-CH 2 -CH(OH)-CH 2 -NR 12 R 13 , with R 12 and R 13 being C 1 -C 18 alkyl or together form a 4 to 8 membered ring as defined in claim 1, or D is a group -O-CH 2 -CH(OH)-CH 2 -N(R 12 )-CH 2 -CHOH-CH 2 -O- or -O-CH 2 -CH(OH)-CH 2 -W-CH 2 -CHOH-CH 2 -O- with W being a divalent amino group (-N(C 1 -C 18 alkyl)-), a polyamine residue, a polyethyleneimine residue or a polyoxyalkyleneamine residue; Z and Z' are for example C 1 -C 12 alkyl, C 3 -C 12 alkenyl, C 3 -C 12 alkinyl, C 5 -C 8 cycloalkyl, or Z and Z' together bivalent groups such as -CH 2 -CH 2 - or -CH 2 -C(R 18 )(R 19 )-CH(R 20 )-.
摘要翻译：在载体上含有至少一种含有至少一种黄色成色剂的感蓝卤化银乳剂层，含有至少一种品红色成色剂的至少一种感绿卤化银乳剂层，至少一种红色敏感性银含有至少一种青色成色剂的卤化物乳剂层以及常规非感光层，其特征在于至少一层含有式（I）或（II）的化合物，其中R 1取代基和R“ 2个取代基优选为甲基; 并且其中式（II）化合物优选为（III）R 3为基团-CH（CH 3）-XD，其中X为亚苯基，D为基团（Ⅳ）或基团-C（ O）-C≡1<-C 18烷基或基团-O-CH 2，-CH =（OH）-CH 2，R 13，其中R 12和R > 13 18 <烷基或一起形成如权利要求1所定义的4至8元环，或D为基团-O-CH 2，-CH =（OH）-CH 2 <-N（R 12）-CH 2，-CH 2 -CH 2，-O-CH 2，-CH（OH）-CH 2，-W-CH 2，其中W为二价氨基（-N（C 1 -C 18）烷基） - ），多胺残基，聚乙烯亚胺残基或聚氧化烯胺残基; CHOH- Z和Z'是例如C 1 -C 12烷基，C 3 -C 12链烯基，C 3 -C 12炔基，C 5 -C 8环烷基，或Z和Z'二价基团如-CH 2，-CH 2或-CH 2，-C（R 18）（R 19）-CH（R 20） - 。

8. 发明申请

WO2006106048A1 PROCESS FOR THE PREPARATION OF STAR AND BLOCK-COPOLYMERS VIA EPOXY-FUNCTIONALIZED ALKOXYAMINES 审中-公开
标题翻译：通过环氧官能化的烷氧基胺制备星型和嵌段共聚物的方法
公开(公告)号：WO2006106048A1
公开(公告)日：2006-10-12
申请号：PCT/EP2006/061045
申请日：2006-03-27
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , FINK, Jochen , PFAENDNER, Rudolf , KRAMER, Andreas , FUSO, Francesco
发明人： FINK, Jochen , PFAENDNER, Rudolf , KRAMER, Andreas , FUSO, Francesco
IPC分类号： C08F2/38 , C08F112/08
CPC分类号： C08F12/08 , C08F283/124 , C08F293/005 , C08F2438/03 , C08G65/22 , C08G65/26 , C08G65/329 , C08L53/00 , C08L2666/02 , C09J153/00 , C08F2/38 , C08F4/00 , C08F220/60
摘要： The instant invention relates to a process for the preparation of star and block-copolymers, which are prepared by controlled free radical polymerization using epoxy-functionalized alkoxyamines and multifunctional compounds capable of reacting with the epoxy group.
摘要翻译：本发明涉及通过使用环氧官能化烷氧基胺和能与环氧基反应的多官能化合物的控制自由基聚合制备星形和嵌段共聚物的方法。

9. 发明申请

WO2004029156A1 THERMOPLASTIC COMPOSITIONS WITH ENHANCED MELT FLOW AND COMPATIBILITY 审中-公开
标题翻译：具有增强的熔体流动性和兼容性的热塑性组合物
公开(公告)号：WO2004029156A1
公开(公告)日：2004-04-08
申请号：PCT/EP2003/010393
申请日：2003-09-18
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , PFAENDNER, Rudolf , FINK, Jochen , WUNDERLICH, Wiebke , KRAMER, Andreas
发明人： PFAENDNER, Rudolf , FINK, Jochen , WUNDERLICH, Wiebke , KRAMER, Andreas
IPC分类号： C08L83/10
CPC分类号： C08L51/00 , C07D211/94 , C08L23/02 , C08L27/06 , C08L33/06 , C08L53/00 , C08L67/00 , C08L71/12 , C08L77/00 , C08L2666/02
摘要： The instant invention relates to a composition of a thermoplastic polymer and a triblock-copolymer or grafted comb copolymer, with enhanced melt flow during processing. Further aspects of the invention are the triblock-copolymers or grafted comb polymers itself, a method for their production and their use as compatibilizers and meltflow enhancing additives. Yet another aspect of the invention are functional alkoxyamines, which are useful for the preparation of the triblock-copolymers or grafted comb polymers.
摘要翻译：本发明涉及热塑性聚合物和三嵌段共聚物或接枝梳状共聚物的组合物，其在加工过程中具有增强的熔体流动性。本发明的另外的方面是三嵌段共聚物或接枝的梳状聚合物本身，它们的生产方法以及它们作为增容剂和熔融流动增强添加剂的用途。本发明的另一方面是功能性烷氧基胺，其可用于制备三嵌段共聚物或接枝梳状聚合物。

10. 发明申请

WO2004014999A1 BETA-NUCLEATING, LIGHT STABILIZING AGENTS FOR POLYPROPYLENE 审中-公开
标题翻译： BETA-NUCLEATING，光稳定剂用于聚丙烯
公开(公告)号：WO2004014999A1
公开(公告)日：2004-02-19
申请号：PCT/EP2003/008353
申请日：2003-07-29
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , MÄDER, Dietmar , DUBS, Paul , HOFFMANN, Kurt , KRAMER, Andreas
发明人： MÄDER, Dietmar , DUBS, Paul , HOFFMANN, Kurt , KRAMER, Andreas
IPC分类号： C08K5/3435
CPC分类号： C08K5/0083 , C08K5/3435 , C08L23/10
摘要： The compounds of the formula (I) wherein R 1 is hydrogen, C 1 -C 8 alkyl, -O, -OH, -CH 2 CN, C 1 -C 18 alkoxy, C 2 -C 18 alkoxy substituted by -OH; . C 5 -C 12 cycloalkoxy, C 3 -C 6 alkenyl, C 7 -C 9 phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C 1 -C 4 alkyl; or C 1 -C 8 acyl; R 2 is hydrogen or methyl; R 3 and R 4 are hydrogen or methyl; X is C 2 -C 10 ,alkylene or a group of the formula (II-a-1) (II-a-2) (II-a-3) (II-b-1) (II-b-2) or (II-b-3)and Y is C 5 -C 12 cycloalkyl, C 5 -C 12 cycloalkyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; or a group of the formula (III) wherein R 1 R 2 , R 3 and R 4 are as defined above, are suitable as ß-nucleating, light stabilizing agents for polypropylene resins.
摘要翻译：式（I）的化合物，其中R 1是氢，C 1 -C 8烷基，-O，-OH，-CH 2 CN，C 1 -C 18烷氧基，被-OH取代的C 2 -C 18烷氧基; 。 C 5 -C 12环烷氧基，C 3 -C 6链烯基，未被取代或未取代或被1,2或3个C 1 -C 4烷基取代的C 7 -C 9苯基烷基; 或C 1 -C 8酰基; R2是氢或甲基; R3和R4是氢或甲基; X是C 2 -C 10，亚烷基或式（II-a-1）（II-a-2）（II-a-3）（II-b-1）（II-b-2）或 II-b-3），Y是C 5 -C 12环烷基，被1,2或3个C 1 -C 4烷基取代的C 5 -C 12环烷基; 或其中R 1 R 2，R 3和R 4如上所定义的式（III）的基团适用作聚丙烯树脂的β-成核光稳定剂。

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