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    • 2. 发明申请
    • OPTICAL RECORDING MATERIALS HAVING HIGH STORAGE DENSITY
    • 具有高存储密度的光学记录材料
    • WO2006015960A1
    • 2006-02-16
    • PCT/EP2005/053782
    • 2005-08-03
    • CIBA SPECIALTY CHEMICALS HOLDING INC.KUNIMOTO, KazuhikoNISHIMAE, YuichiTAKAHASHI, RyuichiDUBAS, Henri
    • KUNIMOTO, KazuhikoNISHIMAE, YuichiTAKAHASHI, RyuichiDUBAS, Henri
    • C09B57/10
    • C09B57/10G11B7/246G11B7/2467G11B7/247G11B7/2472G11B7/2475G11B7/2478G11B7/249G11B7/2531G11B7/2533G11B7/2534G11B7/2535G11B7/2575G11B2007/25706G11B2007/2571G11B2007/25713G11B2007/25715G11B2007/25716
    • The invention relates to new compounds of formula (I), (II), (III) or (IV) and their use in the recording layer of an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers. The instant compounds are of formula (I), (II), (III) or (IV) or tautomers thereof, wherein G1 and G2 are each independently of the other formula (V), (VI), (VII), (VIII), (IX), (X), (XI), X 1 and X 2 are each independently from the other a direct bond or a chain consisting of from 1 to 8 members each selected independently from the group consisting of CR 12 =CR 13 , C=CR 12 R 13 , CR 12 R 13 , C=O, C=S, C=N(R 14 ), N(R 14 ), O or S, preferably a direct bond or a chain consisting of 1, 2, 3 or 4 members, most preferred a direct bond or a chain CR 12 R 13 , C=O, C=S, C=N(R 14 ), N(R 14 ), O or S; A 1 , A 2 and A 3 are CR 15 R 16 , formula (a) , N(R 14 ), O, S, Se, N=C(R 18 ) or CR 19 =CR 20 , and A 4 is O, S or Se; M 1 is a transition metal of groups 9 to 12, preferably Co, Cu, Ni, Pd or Zn, especially Co, Cu or Ni, or is SiR 21 R 22 , GeR 21 R 2 2, PR 21 R 22 or AIR 21 ; and Q 1 and Q 2 are each independently of the other C(R 23 ) , N or P. For the detailed definitions of the further substituents, see the description. Recording and playback are effected especially at a wavelength of from 350 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density.
    • 本发明涉及新的式(I),(II),(III)或(IV)化合物及其在包含基底,记录层和任选的一个或多个反射层的光学记录介质的记录层中的用途。 本发明化合物具有式(I),(II),(III)或(IV)或其互变异构体,其中G1和G2各自独立地为其他式(V),(VI),(VII) ),(IX),(X),(XI),X 1和X 2各自独立地为直接键或由1〜 8个成员各自独立地选自CR 12,CR 13,C = CR 12 R 13, ,C 12,R 13,C = O,C = S,C = N(R 14),N(R 14) O或S,优选直接键或由1,2,3或4个成员组成的链,最优选直接键或链CR 12 R 13 C = O,C = S,C = N(R 14),N(R 14),O或S; A 1,A 2和A 3是CR 15 R 16,式 (a),N(R 14),O,S,Se,N = C(R 18)或CR 19 = CR < SUB> 20 ,A 4是O,S或Se; M 1是基团9至12的过渡金属,优选Co,Cu,Ni,Pd或Zn,特别是Co,Cu或Ni,或者是SiR 21 R, 21> 22,GeR 21 R 2 2,PR 21 21或AIR 21 ; 和Q 1和Q 2各自独立地为C(R 23),N或P。另外,另外的C(R 23),N或P。 取代基,参见说明书。 记录和回放特别是在350至500nm的波长下进行,例如使用蓝色激光。 录制和播放质量非常好,可以保持较高的存储密度。
    • 3. 发明申请
    • OXIME SULFONATES AND THE USE THEROF AS LATENT ACIDS
    • OXIME硫酸盐及其作为酸性物质的用途
    • WO2007147782A2
    • 2007-12-27
    • PCT/EP2007/055936
    • 2007-06-15
    • CIBA SPECIALTY CHEMICALS HOLDING INC.YAMATO, HitoshiASAKURA, ToshikageNISHIMAE, YuichiIWAI, TakeshiIRIE, MakikoNAKAYAMA, Kazuhiko
    • YAMATO, HitoshiASAKURA, ToshikageNISHIMAE, YuichiIWAI, TakeshiIRIE, MakikoNAKAYAMA, Kazuhiko
    • G03F7/039G03F7/027C07C309/00G03C1/73
    • G03F7/0045C07C309/00C07C2603/18C08F20/36G03F7/0046G03F7/0397
    • Compounds of the formula (I), (Il) or (III), wherein R 1 is for example C 1 -C 18 alkylsulfonyl, C 1 -C 10 haloalkylsulfonyl, camphorylsulfonyl, phenyl-C 1 -C 3 alkylsulfonyl, phenylsulfonyl, naphthylsulfonyl, anthrylsulfonyl, phenanthrylsulfonyl or heteroarylsulfonyl, R' 1 is for example phenylenedisulfonyl, R 2 is for example CN, C 1 -C 10 haloalkyl or C 1 -C 10 haloalkyl which is substituted by (IV); Ar 1 is for example phenyl optinally substituted by a group of formula (IV); Ar' 1 is for example phenylene which optionally is substituted by a group of formula (IV); A 1 , A 2 and A 3 independently of each other are for example hydrogen, halogen, CN, or C 1 -C 18 alkyl; D 2 is for example a direct bond, O, (CO)O, (CO)S, SO 2 , OSO 2 or C 1 -C 18 alkylene; or A 3 and D 2 together form C 3 -C 30 cycloalkenyl; or A 2 and D 2 together with the carbon of the ethylenically unsaturated double bond to which they are attached form C 3 -C 30 cycloalkyl; D 3 and D 4 for example independently of each other are a direct bond, O, S, C 1 -C 18 alkylene or C 3 -C 30 cycloalkylene provided that at least one of the radicals R 2 , Ar 1 or Ar 1 ' comprises a group of the formula (IV); are suitable as photolatent acid donors and for the preparation of corresponding polymers to be employed in chemically amplified photoresists.
    • 式(I),(II)或(III)的化合物,其中R 1是例如C 1 -C 18烷基磺酰基, C 1 -C 10卤代烷基磺酰基,樟脑磺酰基,苯基-C 1 -C 3烷基磺酰基,苯基磺酰基,萘基磺酰基, 蒽基磺酰基,菲基磺酰基或杂芳基磺酰基,R 1'是例如亚苯基二磺酰基,R 2是例如CN,C 1 -C 10 (IV)取代的卤代烷基或C 1 -C 10 - 卤代烷基; Ar 1是例如被式(IV)基团取代的苯基; Ar'1是例如任选被式(IV)的基团取代的亚苯基; 彼此独立的A 1,A 2,A 3和A 3是例如氢,卤素,CN或C 1〜 SUB> -C 18 烷基; D 2是例如直接键合O,(CO)O,(CO)S,SO 2,OSO 2或C < SUB> 1 -C 18 亚烷基; 或A 3和D 2一起形成C 3〜C 30环烯基; 或者它们所连接的烯属不饱和双键的碳一起形成C 3 -C 3亚烷基, 30 环烷基; D 3和D 4,例如彼此独立地是直接键,O,S,C 1 -C 18, / SUB>亚烷基或C 3 -C 30亚环烷基,条件是基团R 2,Ar 1中的至少一个, 或者是式(Ⅳ)所示的基团。 适合作为光潜酸供体,并用于制备用于化学放大光致抗蚀剂的相应聚合物。
    • 5. 发明申请
    • SULFONIUM DERIVATIVES AND THE USE THEREOF AS LATENT ACIDS
    • 磺胺衍生物及其作为有效酸的用途
    • WO2009150074A1
    • 2009-12-17
    • PCT/EP2009/056703
    • 2009-06-02
    • BASF SENISHIMAE, YuichiASAKURA, ToshikageYAMATO, Hitoshi
    • NISHIMAE, YuichiASAKURA, ToshikageYAMATO, Hitoshi
    • C07D327/08C07D339/08G03F7/00
    • C07D339/08C07D327/08
    • Compounds of the formula (I), wherein R 1 , R 2 and R 3 for example are hydrogen, halogen, CN, C 1 -C 18 alkyl, C 1 -C 10 haloalkyl, (CO)R 8 , (CO)OR 4 , or (CO)NR 5 R 6 ; Y is O, S or CO; D 2 , D 3 and D 4 for example are a direct bond, O, S, NR 7 , CO, O(CO), (CO)O, S(CO), (CO)S, NR 7 (CO), (CO)NR 7 , SO, SO 2 , or OSO 2 , C 1 -C 18 alkylene, C 3 -C 30 cycloalkylene, C 2 -C 12 alkenylene, C 4 -C 30 cycloalkenylene, Ar 1 ; Ar 1 , Ar 2 and Ar 3 are for example phenylene, R 4 , R 5 , R 6 , R 7 and R 8 are for example hydrogen, C 3 -C 30 cycloalkyl, C 1 -C 18 alkyl, C 1 -C 10 haloalkyl, C 2 -C 12 alkenyl, C 4 -C 30 cycloalkenyl, phenyl-C 1 C 3 -alkyl; X - is Formulae (IA), (IB) or (IC); R 10 is for example C 1 -C 18 alkyl, C 1 -C 10 haloalkyl, camphoryl, phenyl-C 1 -C 3 alkyl, C 3 -C 30 cycloalkyl; and R 11 , R 12 , R 13 , R 14 and R 15 are for example C 1 -C 10 haloalkyl; are useful as polymerizable photolatent acids.
    • 式(I)化合物,其中R1,R2和R3例如是氢,卤素,CN,C1-C18烷基,C1-C10卤代烷基,(CO)R8,(CO)OR4或(CO)NR5R6; Y为O,S或CO; D2,D3和D4例如是直接键合,O,S,NR7,CO,O(CO),(CO)O,S(CO),(CO)S,NR7(CO) SO,SO 2或OSO 2,C 1 -C 18亚烷基,C 3 -C 30亚环烷基,C 2 -C 12亚烯基,C 4 -C 30环亚烯基,Ar 1; Ar 1,Ar 2和Ar 3是例如亚苯基,R 4,R 5,R 6,R 7和R 8是例如氢,C 3 -C 30环烷基,C 1 -C 18烷基,C 1 -C 10卤代烷基,C 2 -C 12烯基,C 4 -C 30环烯基,苯基-C 1 -C 3烷基; X-是式(IA),(IB)或(IC); R 10例如为C 1 -C 18烷基,C 1 -C 10卤代烷基,樟脑基,苯基-C 1 -C 3烷基,C 3 -C 30环烷基; R 11,R 12,R 13,R 14和R 15例如为C 1 -C 10卤代烷基; 可用作可聚合的光潜酸。
    • 7. 发明申请
    • LATENT ACIDS AND THEIR USE
    • 专利酸及其使用
    • WO2011104127A1
    • 2011-09-01
    • PCT/EP2011/051995
    • 2011-02-10
    • BASF SEYAMATO, HitoshiASAKURA, ToshikageMATSUMOTO, AkiraTANAKA, KeitaNISHIMAE, Yuichi
    • YAMATO, HitoshiASAKURA, ToshikageMATSUMOTO, AkiraTANAKA, KeitaNISHIMAE, Yuichi
    • C07C309/08C07C309/12C07C311/53C07C333/06C07C381/12C07C25/18G03F7/004G03F7/039C07D209/00C07D241/00C07D265/00C07D311/00C07D235/00
    • C07C381/12C07C25/18C07C309/08C07C309/12C07C311/53C07C333/06C07C2601/14C07C2602/42C07C2603/74C07D207/28C07D233/38C07D241/08C07D295/205C07D295/215C07D493/08G03F7/0045G03F7/0046G03F7/0382G03F7/0392
    • The invention pertains to a compound generating an acid of the formula (I) or (II), for instance corresponding sulfonium and iodonium salts, as well as corresponding sulfonyloximes, Formula (I) and Formula (II), wherein X is CH 2 or CO; Y is O, NR 4 , S, O(CO), O(CO)O, O(CO)NR 4 , OSO 2 , O(CS), or O(CS)NR 4 ; R 1 is for example C 1 -C 18 alkyl, C 1 -C 10 haloalkyl, C 2 -C 12 alkenyl, C 4 -C 30 cycloalkenyl, phenyl-C 1 -C 3 -alkyl, C 3 -C 30 cycloalkyl, C 3 -C 30 cycloalkyl-C 1 -C 18 alkyl, interrupted C 2 -C 18 alkyl, interrupted C 3 -C 30 cycloalkyl, interrupted C 3 -C 30 cycloalkyl-C 1 -C 18 alkyl, interrupted C 4 -C 30 cycloalkenyl, phenyl, naphthyl, anthracyl, phenanthryl, biphenylyl, fluorenyl or heteroaryl, all unsubstituted or are substituted; or R 1 is NR 12 R 13 ; R 2 and R 3 are for example C 3 -C 30 cycloalkylene, C 3 -C 30 cycloalkyl-C 1 -C 18 alkylene, C 1 -C 18 alkylene, C 1 -C 10 haloalkylene, C 2 -C 12 alkenylene, C 4 -C 30 cycloalkenylene, phenylene, naphthylene, anthracylene, phenanthrylene, biphenylene or heteroarylene; all unsubstituted or substituted; R 4 is for example C 3 -C 30 cycloalkyl, C 3 -C 30 cycloalkyl-C 1 -C 18 alkyl, C 1 -C 18 alkyl, C 1 -C 10 haloalkyl, C 2 -C 12 alkenyl, C 4 -C 30 cycloalkenyl, phenyl-C 1 -C 3 -alkyl; R 12 and R 13 are for example C 3 -C 30 cycloalkyl, C 3 -C 30 cycloalkyl-C 1 -C 18 alkyl, C 1 -C 18 alkyl, C 1 -C 10 haloalkyl, C 2 -C 12 alkenyl, C 4 -C 30 cycloalkenyl, phenyl-C 1 -C 3 -alkyl, Ar, (CO)R 15 , (CO)OR 15 or SO 2 R 15 ; and Ar is phenyl, biphenylyl, fluorenyl, naphthyl, anthracyl, phenanthryl or heteroaryl, all unsubstituted or substituted.
    • 本发明涉及产生式(I)或(II)的酸的化合物,例如相应的锍盐和碘鎓盐,以及相应的磺酰肟,式(I)和式(II),其中X是CH 2或CO ; Y是O,NR4,S,O(CO),O(CO)O,O(CO)NR4,OSO2,O(CS)或O(CS)NR4; R 1是例如C 1 -C 18烷基,C 1 -C 10卤代烷基,C 2 -C 12烯基,C 4 -C 30环烯基,苯基-C 1 -C 3烷基,C 3 -C 30环烷基,C 3 -C 30环烷基-C 1 -C 18烷基,间断的C 2 -C 18烷基,间断的C 3 -C 30环烷基, 间断的C 3 -C 30环烷基-C 1 -C 18烷基,间断的C 4 -C 30环烯基,苯基,萘基,蒽基,菲基,联苯基,芴基或杂芳基,全部未取代或被取代; 或R1是NR12R13; R2和R3是例如C 3 -C 30亚环烷基,C 3 -C 30环烷基-C 1 -C 18亚烷基,C 1 -C 18亚烷基,C 1 -C 10卤代亚烷基,C 2 -C 12亚烯基,C 4 -C 30环亚烯基,亚苯基,亚萘基,亚蒽基,亚菲基,亚联苯基或亚杂芳基。 全部未取代或取代; R4是例如C 3 -C 30环烷基,C 3 -C 30环烷基-C 1 -C 18烷基,C 1 -C 18烷基,C 1 -C 10卤代烷基,C 2 -C 12链烯基,C 4 -C 30环烯基,苯基-C 1 -C 3烷基; R 12和R 13例如为C 3 -C 30环烷基,C 3 -C 30环烷基-C 1 -C 18烷基,C 1 -C 18烷基,C 1 -C 10卤代烷基,C 2 -C 12烯基,C 4 -C 30环烯基,苯基-C 1 -C 3烷基,Ar,(CO)R 15 CO)OR15或SO2R15; 并且Ar是苯基,联苯基,芴基,萘基,蒽基,菲基或杂芳基,全部是未取代或取代的。