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1. 发明申请

WO2011032875A1 PHOTO-LATENT TITANIUM CATALYSTS 审中-公开
标题翻译：钛酸钡催化剂
公开(公告)号：WO2011032875A1
公开(公告)日：2011-03-24
申请号：PCT/EP2010/063198
申请日：2010-09-09
申请人： BASF SE , HINTERMANN, Tobias , BAUER, Didier , CARROY, Antoine , LORDELOT, Caroline , KOHLI STECK, Rachel
发明人： HINTERMANN, Tobias , BAUER, Didier , CARROY, Antoine , LORDELOT, Caroline , KOHLI STECK, Rachel
IPC分类号： B01J31/02 , B01J31/22 , C08G18/22
CPC分类号： B01J31/2234 , B01J31/0208 , B01J31/2213 , B01J31/2226 , B01J2231/34 , B01J2531/46 , C08G18/222 , C08G18/6216 , C08G18/792 , C09D175/04
摘要： The present invention provides a photolatent Ti-chelate catalyst formulation, comprising (i) at least one compound of the formula (I) wherein R 1 is C 1 -C 20 alkyl or C 2 -C 20 alkyl which is interrupted by one or more non-consecutive O-atoms; Y is formula (II) or optionally substituted phenyl; Y 1 is formula (III) or optionally substituted phenyl; Y 2 is formula (IV) or optionally substituted phenyl; Y 3 is formula (V) or optionally substituted phenyl; R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 independently of each other are hydrogen, halogen, optionally substituted C 1 -C 20 alkyl, or R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 independently of each other are optionally substituted C 6 -C 14 aryl, provided that only one of R 2 , R 3 , R 4 is hydrogen and only one of R 5 , R 6 , R 7 is hydrogen and only one of R 8 , R 9 , R 10 is hydrogen and only one of R 11 , R 12 , R 13 is hydrogen; and (ii) at least one chelate ligand compound of the formula IIa, IIb or IIc, wherein Y' is formula (VI) or formula (VII); Y' 1 is formula (VIII) or formula (IX); R' 2 , R' 3 , R' 4 , R' 5 , R' 6 and R' 7 independently of each other have on of the meanings as given for R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 ; and R' 14 , R' 15 and R' 16 independently of each other have on of the meanings as given for R 14 , R 15 and R 16 .
摘要翻译：本发明提供了一种光催化剂钛螯合催化剂制剂，其包含（i）至少一种式（I）化合物，其中R 1是被一个或多个非连续O原子间隔的C 1 -C 20烷基或C 2 -C 20烷基; Y是式（II）或任选取代的苯基; Y1是式（III）或任选取代的苯基; Y2是式（IV）或任选取代的苯基; Y 3为式（Ⅴ）或任选取代的苯基; R2，R3，R4，R5，R6，R7，R8，R9，R10，R11，R12和R13彼此独立地是氢，卤素，任选取代的C 1 -C 20烷基，或者R 2，R 3，R 4，R 5，R 6，R 7 R 8，R 9，R 10，R 11，R 12和R 13彼此独立地是任选取代的C 6 -C 14芳基，条件是R 2，R 3，R 4中仅有一个是氢，并且R 5，R 6，R 7中只有一个是氢， R8，R9，R10为氢，R11，R12，R13中只有一个为氢; 和（ii）式IIa，IIb或IIc的至少一种螯合配体化合物，其中Y'为式（VI）或式（VII）; Y'1是式（VIII）或式（IX）; R'2，R'3，R'4，R'5，R'6和R'7彼此独立地具有对R2，R3，R4，R5，R6，R7，R8，R9给出的含义，R10，R11，R12和R13; 并且R 14，R'15和R 16彼此独立地具有对R 14，R 15和R 16给出的含义。

2. 发明申请

WO2011032837A1 PHOTO-LATENT TITANIUM-CHELATE CATALYSTS 审中-公开
标题翻译：钛酸钡催化剂
公开(公告)号：WO2011032837A1
公开(公告)日：2011-03-24
申请号：PCT/EP2010/062779
申请日：2010-09-01
申请人： BASF SE , HINTERMANN, Tobias , BAUER, Didier , CARROY, Antoine , LORDELOT, Caroline , KOHLI STECK, Rachel
发明人： HINTERMANN, Tobias , BAUER, Didier , CARROY, Antoine , LORDELOT, Caroline , KOHLI STECK, Rachel
IPC分类号： B01J31/02 , B01J31/22 , C08G18/22
CPC分类号： B01J31/2234 , B01J31/0214 , B01J31/223 , B01J2231/34 , B01J2531/46 , B33Y70/00 , C08G18/222 , C08G18/6229 , C08G18/792 , C09D175/04
摘要： The present invention provides photolatent Ti-chelate catalyst compounds of formula (I), wherein R 1 is for example C 6 -C 14 aryl which is substituted by one or more R' 2 , R' 3 or R' 4 ; or the two R 1 together are unsubstituted linear or branched C 1 -C 12 alkylene; R 2 , R 3 , R 4 , R' 2 , R' 3 , and R' 4 independently of each other are for example hydrogen, halogen or linear or branched C 1 -C 20 alkyl; R 5 , R 6 and R 7 independently of each other are hydrogen, linear or branched C 1 - C 20 alkyl, C 6 -C 14 aryl, Br or Cl, provided that not more than one of R 5 , R 6 and R 7 is hydrogen; as well as formulations comprising said compounds and defined 1,3-diketones.
摘要翻译：本发明提供式（I）的光催化钛螯合催化剂化合物，其中R 1为例如被一个或多个R'2，R'3或R'4取代的C6-C14芳基; 或两个R 1一起是未取代的直链或支链C 1 -C 12亚烷基; R 2，R 3，R 4，R'2，R'3和R 4彼此独立地是例如氢，卤素或直链或支链C 1 -C 20烷基; R 5，R 6和R 7彼此独立地是氢，直链或支链C 1 -C 20烷基，C 6 -C 14芳基，Br或Cl，条件是不多于一个R 5，R 6和R 7是氢; 以及包含所述化合物和所定义的1,3-二酮的制剂。

3. 发明申请

WO2012136606A1 PHOTO-LATENT TITANIUM-OXO-CHELATE CATALYSTS 审中-公开
标题翻译：紫外 - 钛 - 氧化钛催化剂
公开(公告)号：WO2012136606A1
公开(公告)日：2012-10-11
申请号：PCT/EP2012/055920
申请日：2012-04-02
申请人： BASF SE , HINTERMANN, Tobias , CARROY, Antoine , LORDELOT, Caroline , BAUER, Didier , KOHLI STECK, Rachel , FALLER, Marc
发明人： HINTERMANN, Tobias , CARROY, Antoine , LORDELOT, Caroline , BAUER, Didier , KOHLI STECK, Rachel , FALLER, Marc
IPC分类号： B01J31/02 , B01J31/22 , C08G18/22
CPC分类号： C09D175/16 , B01J31/0208 , B01J31/2234 , B01J2231/14 , B01J2231/48 , B01J2531/46 , C08G18/222 , C08G18/6229 , C08G18/68 , C08G18/792 , C09J175/04 , Y02P20/52
摘要： A titanium-oxo-chelate catalyst formulation, comprising: (i) at least one compound of the formula (I), wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 and R 12 independently of each other are for example hydrogen, halogen, C 1 -C 20 alkyl, C 6 -C 14 aryl which is unsubstituted or substituted; or R 1 , R 2 and R 3 and/or R 4 , R 5 and R 6 and/or R 7 , R 8 and R 9 and/or R 10 , R 11 and R 12 together with the C-atom to which they are attached each form a C 6 - C 14 aryl group which is unsubstituted or substituted; or R 1 and R 2 and/or R 4 and R 5 and/or R 7 and R 8 and/or R 10 and R 11 together with the C-atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate ligand compound of the formula (lla), (lIb) or (lIc), wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are defined as above for formula (I), is suitable as photolatent catalyst formulation for polymerizing compounds, which are capable to crosslink in the presence of a Lewis acid.
摘要翻译：一种钛 - 氧代 - 螯合催化剂制剂，其包含：（i）至少一种式（I）化合物，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10，R 11和R 12独立地彼此是例如氢，卤素，未取代或取代的C 1 -C 20烷基，C 6 -C 14芳基; 或R 1，R 2和R 3和/或R 4，R 5和R 6和/或R 7，R 8和R 9和/或R 10，R 11和R 12与它们所连接的C原子一起形成C 6 -C 14芳基，未取代或取代的; 或R 1和R 2和/或R 4和R 5和/或R 7和R 8和/或R 10和R 11与它们所连接的C原子一起形成5-至7-元碳环; 至少一种式（Ⅰla），（IIIb）或（IIIc）的螯合配体化合物，其中R 1，R 2，R 3，R 4，R 5和R 6如上文对式（I）所定义，适合作为用于聚合化合物，其能够在路易斯酸存在下交联。

4. 发明申请

WO2009050115A1 PHOTOLATENT CATALYSTS BASED ON ORGANOMETALLIC COMPOUNDS 审中-公开
标题翻译：基于有机化合物的光催化剂催化剂
公开(公告)号：WO2009050115A1
公开(公告)日：2009-04-23
申请号：PCT/EP2008/063608
申请日：2008-10-10
申请人： CIBA HOLDING INC. , KOHLI STECK, Rachel , LORDELOT, Caroline , VOGEL, Thomas , BAUDIN, Gisèle , BROWN, Paul , DIETLIKER, Kurt , HÜSLER, Rinaldo , JUNG, Tunja , SIMMENDINGER, Peter , STUDER, Katia , CARROY, Antoine
发明人： KOHLI STECK, Rachel , LORDELOT, Caroline , VOGEL, Thomas , BAUDIN, Gisèle , BROWN, Paul , DIETLIKER, Kurt , HÜSLER, Rinaldo , JUNG, Tunja , SIMMENDINGER, Peter , STUDER, Katia , CARROY, Antoine
IPC分类号： C08G18/22 , C08G18/24 , C08G18/62 , C08G18/79 , C09D175/04 , C08G18/42 , C08G18/80
CPC分类号： C08G18/227 , B33Y70/00 , C08G18/222 , C08G18/24 , C08G18/42 , C08G18/6216 , C08G18/792 , C08G18/80 , C09D175/04
摘要： The present invention provides organometallic latent catalyst compounds, which aresuitable as catalysts in polyaddition or polycondensation reactions which are catalysed by a Lewis acid type catalyst, in particular for the crosslinking of a blocked or unblocked isocyanate or isothiocyanate component with a polyol or polythiolto form a polyurethane (PU).
摘要翻译：本发明提供了有机金属潜催化剂化合物，它们可作为催化剂在催化剂加成或缩聚反应中被路易斯酸型催化剂催化，特别是用于使多元醇或多硫醇与封端或未封端异氰酸酯或异硫氰酸酯组分交联形成聚氨酯（PU）。

5. 发明申请

WO2010128062A1 O-IMINO-ISO-UREA COMPOUNDS AND POLYMERIZABLE COMPOSITIONS THEREOF 审中-公开
标题翻译： O-IMINO-ISO-UREA化合物及其可聚合组合物
公开(公告)号：WO2010128062A1
公开(公告)日：2010-11-11
申请号：PCT/EP2010/056063
申请日：2010-05-05
申请人： BASF SE , NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine , FALLER, Marc , SPONY, Bruno
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine , FALLER, Marc , SPONY, Bruno
IPC分类号： C07C275/70 , C08F4/00
CPC分类号： C08F120/18 , C07C251/58 , C07C275/70 , C07C2601/14 , C07C2601/20 , C08F4/00 , C08F8/32 , C09D135/02
摘要： The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds. The O-lmino-isoureas compounds are compounds of the Formula (I), wherein n is 1, 2, 3 or 4, R 100 and R 101 are independently H, C 1-18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl, C 1 -C 14 heteroaryl, C 7 -C 15 aralkyl, C 2 -C 14 heteroaralkyl, Cyano, or R 100 and R 101 form together with the carbon to which they are attached a mono or polycyclic C 3 -C 18 carbocyclic or C 1 -C 18 heterocyclic ring; R 102 and R 103 are independently C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl, C 6 -C 14 aryl once or more than once substituted by C 1 -C 18 alkyl; C 7 -C 15 aralkyl, (CH 3 ) 3 Si-; or R 102 and R 103 are C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl, C 7 -C 15 aralkyl or R 102 and R 103 are C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl which are interrupted or substituted by O or by N containing groups selected from C 1 -C 18 alkylamino, bis(C 1 -C 18 alkyl)amino or tris(C 1 -C 1t alkyl)ammonium; R 104 if n is 1 is is H, C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 7 -C 14 aralkyl, C 6 -C 14 aryl or acyl selected from the group consisting of the following acyls -C(=O)-H, -C(=O)-C 1 -C 18 alkyl, -C(=O)-C 2 -d 18 alkenyl, -C(=O)-C 6 -C 14 aryl, -C(=O)-C 2 -C 18 alkenyl-C 6 -C 14 aryl, -C(=O)-O-C 1 C 18 alkyl, -C(=O)-O-C 6 -C 14 aryl, -C(=O)-NH-C 1 -C 18 alkyl, -C(=O)-NH-C 6 -C 14 aryl and -C(=O)-N(C 1 C 18 alkyl) 2 ; or R 102 and R 104 if n is 1 form together with the nitrogen atom to which they are attached a 5 to 12 membered ring which may contain additional heteroatoms, R 104 if n is more than 1 is di-, tri-, tetra-C 1 -C 18 alkylidene, diacyls, triacyls or tetraacyls and salts thereof.
摘要翻译：本发明涉及O-亚氨基 - 异脲化合物作为自由基源的用途，其包含这些O-亚氨基 - 异脲和包含新的O-亚氨基 - 异脲化合物的可聚合组合物。 O - 异喹啉化合物是式（I）化合物，其中n为1,2,3或4，R 101和R 101独立地为H，C 1-18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 1 -C 14杂芳基， C 1 -C 15芳烷基，C 2 -C 14杂芳烷基，氰基或R 100和R 101与它们所连接的碳一起形成单或多环C 3 -C 18碳环或C 1 -C 18杂环; R 102和R 103独立地是C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 1 -C 14芳基，其一次或多于一个被C 1 -C 18烷基取代; C 7 -C 15芳烷基，（CH 3）3 Si- 或R 102和R 103为C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 7 -C 15芳烷基或R 102和R 103为C 1 -C 18烷基，C 3 -C 12环烷基，其被O或含N的基团所取代或被取代，所述基团选自C 1 -C 18烷基氨基，双（C1-C18烷基）氨基或三（C1-C1烷基）铵; 如果n为1，R 104为H，C 1 -C 18烷基，C 3 -C 12环烷基，C 7 -C 14芳烷基，C 6 -C 14芳基或选自以下酰基-C（= O）-H，-C（= O） -C（= O）-C 2 -C 18芳基，-C（= O）-C 6 -C 14芳基，-C（= O）-C 2 -C 18烯基-C 6 -C 14芳基，-C（= O）-O C 1 -C 18烷基，-C（= O）-O-C 6 -C 14芳基，-C（= O）-NH-C 1 -C 18烷基，-C（= O）-NH-C 6 -C 14芳基和-C（= O）-N （C1C18alkyl）2; 如果n为1，则与R 102和R 104一起形成与它们所连接的氮原子一起形成可含有其它杂原子的5至12元环，如果n大于1，则R104是二 - ，三 - ，四-C1-C18亚烷基，二酰基，三酰基或四酰基及其盐。

6. 发明申请

WO2010112410A1 POLYMERIZABLE COMPOSITIONS 审中-公开
标题翻译：可聚合组合物
公开(公告)号：WO2010112410A1
公开(公告)日：2010-10-07
申请号：PCT/EP2010/053969
申请日：2010-03-26
申请人： BASF SE , NESVADBA, Peter , BUGNON FOLGER, Lucienne , BIRBAUM, Jean-Luc , FALLER, Marc , CARROY, Antoine
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , BIRBAUM, Jean-Luc , FALLER, Marc , CARROY, Antoine
IPC分类号： C07C245/24 , C08F2/50 , C08F8/50
CPC分类号： C08F4/04 , C07D211/98 , C08F2/46 , C09D175/14
摘要： The invention relates to the use of triazenes of formula (I) wherein Q is a direct bond or a bivalent radical -(CR 8 R 9 )-, Z 1 is -O-, -NR 10 -, -CH 2 -,-(CR 11 R 12 )- or -C(=O)- and R 1 to R 12 are optionally substituted hydrocarbon residues, as precursors for radicals useful in reactions triggered by free radicals, such as polymerization of unsaturated monomers and degradation of polyolefins. Most of the triazenes of formula (I) are novel and claimed, too, as well as the preparation of triazenes of formula (I) and polymerisable compositions comprising them.
摘要翻译：本发明涉及其中Q是直接键或二价基 - （CR 8 R 9） - ，Z 1是-O-，-NR 10 - ， - CH 2 - ， - （CR 11 R 12） - 或 - C（= O） - 和R 1至R 12是任选取代的烃残基，作为可用于由自由基引发的反应的基团的前体，例如不饱和单体的聚合和聚烯烃的降解。式（I）的大多数三氮烯也是新型的，并且还要求制备式（I）的三氮烯和包含它们的可聚合组合物。

7. 发明申请

WO2009049780A1 ACRYLIERTE POLYAMINOAMIDE (III) 审中-公开
标题翻译：丙烯酸酯化的聚氨基酰胺（III）
公开(公告)号：WO2009049780A1
公开(公告)日：2009-04-23
申请号：PCT/EP2008/008404
申请日：2008-10-04
申请人： COGNIS IP MANAGEMENT GMBH , CARROY, Antoine , BALLIN, Jean-Marc , DRUENE, Laurence , GARINET, Morgan , RHUBRIGHT, Douglas
发明人： CARROY, Antoine , BALLIN, Jean-Marc , DRUENE, Laurence , GARINET, Morgan , RHUBRIGHT, Douglas
IPC分类号： C08F283/04 , C09D11/10 , C09D151/08
CPC分类号： C08F290/06 , C08F283/04 , C08F290/061 , C09D11/101
摘要： Strahlungshärtbare acrylierte Polyaminoamide, erhältlich durch Michael-Addition von Polyaminoamiden mit endständigen Amingruppen (A) und Polyolesteracrylaten (B), wobei das molare Verhältnis der Acrylatgruppen in den Polyolesteracrylaten (B) zu den Amino-Wasserstoffgruppen in den Polyaminoamiden (A) mindestens 1 : 1 beträgt, dadurch gekennzeichnet, dass es sich bei den Polyolesteracrylaten (B) um acrylierte Anlagerungsprodukte von Propylenoxid an Trimethylolpropan handelt, eignen sich als strahlungshärtbare Verbindungen zur Herstellung von Beschichtungen.
摘要翻译： 1：通过迈克尔加成具有末端胺基的（A）和多元醇酯（B），其中摩尔丙烯酸酯基团中的多元醇酯（B）与氨基 - 氢基团的聚氨基酰胺的比例（A）至少为1的聚氨基酰胺的可获得的可辐射固化的丙烯酸酯化的聚氨基酰胺的特征在于，（B）是在多元醇酯与三羟甲基丙烷环氧丙烷的丙烯酸酯化的加成产物，如用于生产涂料的辐射固化性化合物是有用的。

8. 发明申请

WO2009049781A3 ACRYLIERTE POLYAMINOAMIDE (II) 审中-公开
公开(公告)号：WO2009049781A3
公开(公告)日：2009-04-23
申请号：PCT/EP2008/008405
申请日：2008-10-04
申请人： COGNIS IP MANAGEMENT GMBH , CARROY, Antoine , BALLIN, Jean-Marc , DRUENE, Laurence , GARINET, Morgan , RHUBRIGHT, Douglas , BUSCH, Stefan
发明人： CARROY, Antoine , BALLIN, Jean-Marc , DRUENE, Laurence , GARINET, Morgan , RHUBRIGHT, Douglas , BUSCH, Stefan
IPC分类号： C08G73/00 , C08G73/06 , C08G81/00 , B32B15/00 , B32B15/08 , C08F283/00 , C08F299/00 , C08G69/00 , C08G69/26 , C08G69/48 , C08J3/00 , C08K5/00 , C09D11/10 , C09D151/08 , C09J177/00
摘要： Strahlungshärtbare acrylierte Polyaminoamide, erhältlich durch Michael-Addition von Polyaminoamiden mit endständigen Amingruppen (A) und Polyolesteracrylaten (B), wobei das molare Verhältnis der Acrylatgruppen in den Polyolesteracrylaten (B) zu den Amino-Wasserstoffgruppen in den Polyaminoamiden (A) mindestens 1 : 1 beträgt, dadurch gekennzeichnet, dass die Polyaminoamide (A) eine Aminzahl oberhalb von 115 aufweisen, eignen sich als strahlungshärtbare Verbindungen zur Herstellung von Beschichtungen.

9. 发明申请

WO2016034963A1 POLYCYCLIC PHOTOINITIATORS 审中-公开
标题翻译：多晶型光电元件
公开(公告)号：WO2016034963A1
公开(公告)日：2016-03-10
申请号：PCT/IB2015/056178
申请日：2015-08-13
申请人： BASF SE , BASF (CHINA) COMPANY LIMITED
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine
IPC分类号： C08F2/50 , C07D307/00 , C07D309/00 , C07D327/02 , C07D339/08
CPC分类号： C09D11/101 , C07D307/91 , C07D311/82 , C07D327/08 , C07D339/08 , C08L33/14 , C09D11/107 , C09D133/14
摘要： Compounds of the formula (I) (I), wherein X is O, S, a direct bond or CR 16 R 17 ; Y is O or S; R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 for example are hydrogen, halogen, C 1 -C 4 alkyl, or a group of formula (II) or (III) (II) (III) provided that either (i) one of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 or R 8 is a group of formula (II) or (III); or (ii) one of R 1 , R 2 , R 3 or R 4 is a group of formula (II) or (III) and one of R 5 , R 6 , R 7 or R 8 is a group of formula (II) or (III); R 9 and R 10 independently of each other are C 1 -C 4 alkyl or together with the C atom to which they are attached form a 5-membered, 6-membered or 7-membered carbocyclic ring; R 11 is hydrogen, C 1 -C 4 alkyl, C 5 -C 7 cycloalkyl, 2-tetrahydropyranyl or Si(C 1 -C 4 alkyl) 3 ; R 12 and R 13 for example are C 1 -C 4 alkyl, C 2 -C 12 alkenyl, phenyl-C 1 -C 4 alkyl, phenyl-C 1 - C 4 alkyl which is substituted by C 1 -C 4 alkyl, R 14 and R 15 independently of each other are C 1 -C 4 alkyl, C 5 -C 7 cycloalkyl, or together with the N atom to which they are attached form a 5-membered, 6-membered or 7- membered ring, which may contain additional heteroatoms O, S or N; R 16 and R 17 for example are hydrogen, C 1 -C 8 alkyl, C 5 -C 7 cycloalkyl, phenyl-C 1 -C 4 alkyl, phenyl; are effective photoinitiators.
摘要翻译：式（I）（I）的化合物，其中X是O，S，直接键或CR 16 R 17; Y为O或S; R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8例如是氢，卤素，C 1 -C 4烷基或式（II）或（III）（II）（III） R1，R2，R3，R4，R5，R6，R7或R8中的一个是式（II）或（III）的基团; 或（ii）R 1，R 2，R 3或R 4中的一个为式（II）或（III）的基团，R 5，R 6，R 7或R 8中的一个为式（II）或（III）的基团。 R 9和R 10彼此独立地是C 1 -C 4烷基或与它们所连接的C原子一起形成5元，6元或7元碳环; R11是氢，C1-C4烷基，C5-C7环烷基，2-四氢吡喃基或Si（C1-C4烷基）3; R 12和R 13例如是C 1 -C 4烷基，C 2 -C 12烯基，苯基-C 1 -C 4烷基，被C 1 -C 4烷基取代的苯基-C 1 -C 4烷基，R 14和R 15彼此独立地是C 1 -C 4烷基，C 5 -C 7环烷基或与它们所连接的N原子一起形成5元，6元或7元环，其可以含有额外的杂原子O，S或N; R 16和R 17例如是氢，C 1 -C 8烷基，C 5 -C 7环烷基，苯基-C 1 -C 4烷基，苯基; 是有效的光引发剂。

10. 发明申请

WO2014064064A1 IMINOXYTRIAZINES AS RADICAL GENERATORS 审中-公开
标题翻译：作为辐射发生器的IMINOXYTRIAZINES
公开(公告)号：WO2014064064A1
公开(公告)日：2014-05-01
申请号：PCT/EP2013/072006
申请日：2013-10-22
申请人： BASF SE
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine , FALLER, Marc
IPC分类号： C07D251/30 , C07D251/42 , C07D403/14
CPC分类号： C09J133/14 , C07D251/30 , C07D251/42 , C07D403/14 , C09D11/107
摘要： Iminoxytriazine compounds of the formula (I), wherein n is 1 or 2; R 1 and R 2 independently of each other are hydrogen, NH 2 , NHR 5 , NR 5 R 6 , COR 5 , COOR 5 , CONH 2 , CONHR 5 , CONR 5 R 6 , CN, SR 5 , OR 5 , C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl or C 2 -C 14 heteroaryl, wherein said C 3 -C 12 cycloalkyl, C 6 -C 14 aryl or C 2 -C 14 heteroaryl is unsubstituted or substituted by one or more radicals selected from the group consisting of C 1 -C 12 alkyl, C 3 -C 12 -cycloalkyl, phenyl, halogen and C 1 -C 12 alkoxy, or R 1 and R 2 together with the C atom to which they are linked form a 4 to 12 membered carbocyclic or heterocyclic saturated or unsaturated ring which is unsubstituted or substituted by one or more radicals selected from the group consisting of C 1 -C 12 alkyl, C 3 -C 12 -cycloalkyl, phenyl, halogen and C 1 -C 12 alkoxy; R 3 is F, Cl, OH, OR, SH, SR 5 , NH 2 , NHR 5 , NR 5 R 6 or R 1 R 2 C=N-O-; wherein R 1 and R 2 in all groups R 1 R 2 C=N-O- in the compound of the formula I are identical or different; if n is 1, R 4 is F, Cl, OH, OR 5 , SH, SR 5 , NH 2 , NHR 5 , NR 5 R 6 or R 1 R 2 C=N-O-; wherein R 1 and R 2 in all groups R 1 R 2 C=N-O- in the compound of the formula I are identical or different; if n is 2, R 4 is a difunctional group derived from a diol, diamine, aminoalcohol or mercaptoalcohol; R 5 and R 6 independently of each other are C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl or C 2 -C 14 heteroaryl; are suitable as radical generating agents.
摘要翻译：式（I）的亚氨基三嗪化合物，其中n为1或2; R 1和R 2彼此独立地是氢，NH 2，NHR 5，NR 5 R 6，COR 5，COOR 5，CONH 2，CONHR 5，CONR 5 R 6，CN，SR 5，OR 5，C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基其中所述C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基是未取代的或被一个或多个选自C 1 -C 12烷基，C 3 -C 12 - 环烷基，苯基，卤素和C 1 -C 12烷氧基的基团取代或被R 1和 R2与它们所连接的C原子一起形成4-12元碳环或杂环饱和或不饱和环，其未被取代或被一个或多个选自C 1 -C 12烷基，C 3 -C 12环烷基，苯基，卤素和C 1 -C 12烷氧基; R3是F，Cl，OH，OR，SH，SR5，NH2，NHR5，NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n是1，R4是F，Cl，OH，OR5，SH，SR5，NH2，NHR5，NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n为2，则R4为衍生自二醇，二胺，氨基醇或巯基醇的双官能团; R 5和R 6彼此独立地是C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基; 适合作为自由基产生剂。

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