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1. 发明授权

US11555135B2 Cyanoacrylate compositions 有权
公开(公告)号：US11555135B2
公开(公告)日：2023-01-17
申请号：US16670074
申请日：2019-10-31
申请人： Henkel AG & Co. KGaA
发明人： Raymond P. Tully , Rory Barnes , Mark Loane , Deborah Coleman
IPC分类号： C09D4/06 , C09D11/08 , C09D11/00 , C09D133/14 , C09D133/04 , C08L33/04 , C08F263/04 , C08F265/06 , C09J4/06 , C09J5/00 , C09J11/08 , C09J133/14
摘要： Cyanoacrylate compositions, methods for forming same, and applications thereof are disclosed. The compositions demonstrate improved thermal ageing performance, including improved tensile strength performance after heat ageing in high humidity.

2. 发明申请

US20210130522A1 GRAFT COPOLYMER AND SOIL RESISTANT COMPOSITION 有权
公开(公告)号：US20210130522A1
公开(公告)日：2021-05-06
申请号：US17085544
申请日：2020-10-30
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Hisako NAKAMURA
IPC分类号： C08F263/04 , C09D151/00
摘要： Provided is a graft copolymer and a treatment method which give excellent antifouling property to a substrate, especially a carpet. The graft copolymer has a trunk polymer having a hydroxyl group; and a branch having a C7-40 hydrocarbon group bonded to the trunk polymer at a carbon atom substituted with the hydroxyl group, wherein the branch has a repeating unit formed from an acrylic monomer represented by the formula: CH2═C(—X)—C(═O)—Y—Z(—Y2—R)n. The treatment method include applying the graft copolymer to the substrate.

3. 发明授权

US09441123B2 Cationic water based polymers for ink, coating, and film applications 有权
标题翻译：用于油墨，涂料和薄膜应用的阳离子水基聚合物
公开(公告)号：US09441123B2
公开(公告)日：2016-09-13
申请号：US13586123
申请日：2012-08-15
申请人： Michael D. Spiegel , Charles B. Rybny
发明人： Michael D. Spiegel , Charles B. Rybny
IPC分类号： C08F255/00 , C08F259/04 , C08F261/04 , C08F263/04 , C08J3/03 , C09D11/00 , C09D11/10 , C09D11/30
CPC分类号： C08F261/04 , C08F259/04 , C08F263/04 , C09D11/10 , C09D11/107 , C09D11/30 , C09D151/003
摘要： The present invention provides a durable, external surfactant free, cationic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable amine-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.
摘要翻译：本发明提供了耐久的外部表面活性剂，阳离子型水基喷墨油墨聚合物，其在配制成喷墨油墨时形成与金属或塑料基材具有优异粘附性的印刷。这种喷墨油墨聚合物是目前商业上使用的溶剂可溶性聚合物的合适的性能替代品。杂化共聚物包含由聚硅氧烷聚合物，聚烯烃聚合物或官能聚乙烯基聚合物组成的疏水官能聚合物主链。杂化共聚物还包括连接到主链上的多个共聚侧链，包含可聚合的含胺不饱和单体和可聚合的不饱和单体。使用本发明的油墨增强了性能标准，例如打印头打开时间，油墨稳定性和对典型的水基清洁剂的耐受性。

4. 发明授权

US09029469B2 Wood protection paints 有权
标题翻译：木保护油漆
公开(公告)号：US09029469B2
公开(公告)日：2015-05-12
申请号：US13906547
申请日：2013-05-31
申请人： Celanese Emulsions GmbH
发明人： Lizandra Belmonte Rodrigues de Castro , Thomas Fichtner , Petra Klingel , Stephan Krieger
IPC分类号： C09D5/00 , C08F263/04 , C09D151/00 , C09D151/06 , C08F210/02 , C08F218/08 , C08F220/14 , C08F230/08
CPC分类号： C09D5/00 , C08F210/02 , C08F218/08 , C08F220/14 , C08F263/04 , C08F2230/085 , C09D151/003 , C09D151/06
摘要： A wood protection paint comprises a copolymer emulsion prepared by an emulsion polymerization process, in which a first monomer composition comprising from 60 weight percent to 95 weight percent of at least one vinyl ester, and from 5 weight percent to 40 weight percent ethylene is polymerized in a first stage under ethylene pressure to produce a first stage product having a Tg of less than 25° C. Then, in a second stage, a second monomer composition selected such that the polymer produced by the second monomer composition has a Tg of at least 95° C.
摘要翻译：木材防护漆包括通过乳液聚合方法制备的共聚物乳液，其中包含60重量％至95重量％的至少一种乙烯基酯和5重量％至40重量％乙烯的第一单体组合物聚合在在乙烯压力下的第一阶段以产生Tg小于25℃的第一阶段产物。然后，在第二阶段中，选择第二单体组合物，使得由第二单体组合物制备的聚合物的Tg至少为 95℃

5. 发明授权

US08962705B2 Material for removing cauxin in cat urine 有权
标题翻译：在猫尿中去除cauxin的物质
公开(公告)号：US08962705B2
公开(公告)日：2015-02-24
申请号：US13579897
申请日：2011-02-17
申请人： Shinya Matsuno , Kyoichi Saito , Tetsuro Yamashita , Ayako Ito , Yasuyuki Suzuta
发明人： Shinya Matsuno , Kyoichi Saito , Tetsuro Yamashita , Ayako Ito , Yasuyuki Suzuta
IPC分类号： C08F255/02 , C08F257/02 , C08F259/00 , C08F263/04 , C08F283/04 , C08J9/36 , G01N33/68 , C12Q1/44
CPC分类号： G01N33/6893 , C12Q1/44 , G01N2333/918 , G01N2800/347
摘要： A method for removing cauxin in cat urine and a material for removing cauxin are provided. The material for removing cauxin in cat urine comprises a polymer substrate on which surface a trifluoroketone derivative is immobilized via dithiol.
摘要翻译：提供了一种去除猫尿中的cauxin的方法和用于去除cauxin的材料。用于除去猫尿中的cauxin的材料包括通过二硫醇固定有三氟酮衍生物的表面的聚合物基材。

6. 发明授权

US08952096B2 Graft copolymers and use thereof as low-profile additives 有权
标题翻译：接枝共聚物及其作为低轮廓添加剂的用途
公开(公告)号：US08952096B2
公开(公告)日：2015-02-10
申请号：US13133862
申请日：2009-12-09
申请人： Florian Bauers , Michael Tobias Zarka
发明人： Florian Bauers , Michael Tobias Zarka
IPC分类号： C08F263/02 , C08F263/04 , C08L51/00 , C08L51/08 , C09D151/00 , C09D151/08 , C08F290/06 , C08F290/08 , C08F283/01 , C08F263/00 , C08F289/00
CPC分类号： C08F263/04 , C08F263/00 , C08F283/01 , C08F289/00 , C08F290/06 , C08L51/003 , C08L51/08 , C09D151/003 , C09D151/08 , C08L2666/02
摘要： The invention provides graft copolymers obtainable by A) free-radically initiated polymerization of one or more vinyl esters a), one or more further ethylenically unsaturated monomers b) comprising at least one further functional group, B) subsequent polymer-analogous reaction of the copolymers from stage A) by joining the monomer units b) thereof to one or more further monomers b) such that at least one free-radically polymerizable group is introduced into the copolymers from stage A), characterized in that C) one or more ethylenically unsaturated monomers are polymerized onto the products from stage B) by free-radically initiated polymerization.
摘要翻译：本发明提供了可通过以下方式获得的接枝共聚物：A）一种或多种乙烯基酯a），一种或多种其它烯属不饱和单体的自由基引发聚合，b）包含至少一个其它官能团，B）随后的共聚物的聚合物 - 类似反应通过将单体单元b）连接到一种或多种另外的单体b）使得至少一种可自由基聚合的基团从阶段A）引入到共聚物中，其特征在于C）一个或多个烯属不饱和的通过自由基引发的聚合将单体聚合到来自阶段B）的产物上。

7. 发明授权

US08207252B2 Moisture-curable silylated polymer resin composition 有权
标题翻译：水分固化型甲硅烷基化聚合物树脂组合物
公开(公告)号：US08207252B2
公开(公告)日：2012-06-26
申请号：US11715000
申请日：2007-03-07
申请人： Misty W. Huang , Jeries I. Nesheiwat
发明人： Misty W. Huang , Jeries I. Nesheiwat
IPC分类号： C08F255/02 , C08F263/04 , C08L51/00
CPC分类号： C08G18/10 , C08G18/6229 , C08G18/718 , C08G2190/00 , C08L75/04 , C08L2666/20 , C09J175/04 , C08G18/289
摘要： The present invention provides a moisture-curable composition containing silylated polyurethane prepolymer and silane acrylate polymer. The composition is flowable at room temperatures, and upon curing forms high modulus resins for use in adhesives, coatings and sealants for automotive and industrial applications.
摘要翻译：本发明提供含有甲硅烷基化聚氨酯预聚物和硅烷丙烯酸酯聚合物的湿气固化组合物。组合物在室温下是可流动的，并且在固化时形成用于汽车和工业应用的粘合剂，涂料和密封剂的高模量树脂。

8. 发明申请

US20050059775A1 Shelf-stable silane-modified aqueous dispersion polymers 有权
标题翻译：稳定的硅烷改性水分散体聚合物
公开(公告)号：US20050059775A1
公开(公告)日：2005-03-17
申请号：US10881450
申请日：2004-06-30
申请人： Weizhen Cai , William Herdle , Jeffrey Cooke , Bruce Waldman
发明人： Weizhen Cai , William Herdle , Jeffrey Cooke , Bruce Waldman
IPC分类号： C08F2/24 , C08F8/42 , C08F220/12 , C08F230/08 , C08F263/04 , C08F265/04 , C08F283/12 , C08F290/06 , C08L43/04 , C08L51/00 , C08L51/08 , C09D143/04 , C08K5/15
CPC分类号： C08L51/003 , C08F8/42 , C08F220/12 , C08F230/08 , C08F263/04 , C08F265/04 , C08F283/12 , C08F290/06 , C08L43/04 , C08L51/085 , C09D143/04
摘要： Disclosed herein is a process for preparing a shelf-stable, one-pack, silane modified (meth)acrylic latex interpolymer composition, wherein the process comprises continuously adding at least a portion of a mixture comprising at least 0.5 mole percent of a vinyl silane comprising hydrolyzable groups and up to 99.5 mole percent of a (meth)acrylic monomer to water and a surfactant in a reaction vessel, wherein said addition is carried out in the presence of a polymerization initiator and buffer sufficient to maintain the pH of the reaction at a level of at least 6 throughout the reaction, while simultaneously hydrolyzing from about 10 to about 60% of the hydrolyzable groups of the vinyl silane.
摘要翻译：本文公开了一种制备搁置稳定的单组分硅烷改性（甲基）丙烯酸乳胶互聚物组合物的方法，其中该方法包括连续加入至少一部分包含至少0.5摩尔％的乙烯基硅烷的混合物，所述乙烯基硅烷包含可水解基团和至多99.5摩尔％的（甲基）丙烯酸单体与水和反应容器中的表面活性剂，其中所述加入在聚合引发剂和缓冲液存在下进行，足以将反应的pH保持在水平在整个反应中至少为6，同时水解约10至约60％的乙烯基硅烷的可水解基团。

9. 发明授权

US5874498A Vinyl acetate emulsions for high scrub paints 失效
标题翻译：乙酸乙烯酯乳液用于高擦洗涂料
公开(公告)号：US5874498A
公开(公告)日：1999-02-23
申请号：US610785
申请日：1996-03-11
申请人： Christian Leonard Daniels , Leon Edward Newman
发明人： Christian Leonard Daniels , Leon Edward Newman
IPC分类号： C08F263/04 , C09D151/00 , C08L29/04
CPC分类号： C09D151/00 , C08F263/04
摘要： This invention relates to improved vinyl acetate-ethylene emulsions for use in formulating high performance paints without the need for coalescing solvents. These latexes are based on copolymers of vinyl acetate and ethylene optionally containing a comonomer such as an alkyl acrylate or methacrylate. Paints formulated from these latexes, without coalescing solvents, are characterized as having substantially no insolubles, the resin particles in the emulsion are characterized as having a particle size of from 0.2 to 0.35 microns measured as weight average by capillary hydrodynamic fractionation. In other words, the copolymer particles are characterized in that a small percentage, up to about 5% of the total number of particles in the latex, have an average size greater than 0.35 microns, and a small percentage have a size smaller than about 0.2 microns. Further the resin particles are essentially monodisperse. Ethylene in place of the conventional acrylate as the low Tg monomer wit the resulting resin particles having a Tg of from minus -5.degree. to 8.degree. C.The improved process for producing the emulsion or latex includes as an important component the formation of a seed latex and then polymerizing the monomers in the presence of the seed, the monomers being introduced over a period of time.
摘要翻译：本发明涉及用于配制高性能涂料而不需要聚结溶剂的改进的乙酸乙烯酯 - 乙烯乳液。这些胶乳基于乙酸乙烯酯和任选含有共聚单体如丙烯酸烷基酯或甲基丙烯酸酯的乙烯的共聚物。由这些胶乳配制的没有聚结溶剂的油漆的特征在于基本上不存在不溶物，乳液中的树脂颗粒的特征在于通过毛细管流体力学分馏作为重均分子测量的粒度为0.2至0.35微米。换句话说，共聚物颗粒的特征在于，胶乳中颗粒总数的高达约5％的小百分比具有大于0.35微米的平均尺寸，并且小百分比具有小于约0.2的尺寸微米。此外，树脂颗粒基本上是单分散的。乙烯代替常规丙烯酸酯作为低Tg单体，所得树脂颗粒的Tg为-5℃至8℃。生产乳液或胶乳的改进方法包括作为重要组分的种子形成胶乳，然后在种子存在下使单体聚合，单体在一段时间内被引入。

10. 发明授权

US5399621A Process for the preparation of a graft copolymer latex of core/shell dispersion particles having improved phase binding between core and shell 失效
标题翻译：制备核/壳分散体颗粒的接枝共聚物胶乳的方法，其具有改善的核和壳之间的相结合
公开(公告)号：US5399621A
公开(公告)日：1995-03-21
申请号：US160620
申请日：1993-12-02
申请人： Klaus Kohlhammer
发明人： Klaus Kohlhammer
IPC分类号： C08F2/22 , C08F4/30 , C08F4/32 , C08F4/40 , C08F255/00 , C08F255/02 , C08F263/00 , C08F263/04 , C08F265/00 , C08F265/04 , C08F291/00 , C08L67/00 , C08L67/06 , C09D151/00 , C09D151/06 , C08F257/00 , C08F259/00 , C08F261/06 , C08F263/02
CPC分类号： C08F255/023 , C08F291/00 , Y10S525/902
摘要： The invention relates to the preparation of a graft copolymer latex of core/shell dispersion particles having improved phase binding between core and shell in a two-stage emulsion polymerization process, hydroperoxide groups being produced at the particle surface of the grafting base prior to grafting by hydrogen peroxide treatment.
摘要翻译：本发明涉及在两阶段乳液聚合方法中具有改进的核和壳相互结合的核/壳分散体颗粒的接枝共聚物胶乳的制备，氢过氧化物基团是在接枝基体的颗粒表面上在接枝前通过过氧化氢处理。

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