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    • 6. 发明授权
    • Coating composition, a process of producing a coating composition, a coated article, and a method of forming such articles
    • US10065778B2
    • 2018-09-04
    • US14950070
    • 2015-11-24
    • Dow Global Technologies LLC
    • Jouko VyorykkaDavid L. MalotkyRonald Wevers
    • B65D65/42C09D151/08C08J3/05C08F255/00C08F255/02C08F285/00C08F289/00C09D151/00C09D151/06C09D123/00C09D7/61C09D7/40C09D7/80C08K3/26
    • The instant invention provides a coating composition, a process of making a coating composition, a coated article, and a method of forming such articles.The coating composition according to the present invention comprises a dispersion comprising: (a) a core comprising a base polymer; (b) a shell at least partially surrounding said core, wherein said shell comprising a polar polymeric stabilizing agent; and (c) one or more hydrophobic particulate fillers embedded at least partially in said shell.The process for making a coating composition according to the present invention comprises the steps of: (1) selecting a base polymer; (2) selecting a polar polymeric stabilizing agent; (3) selecting one or more hydrophobic particulate fillers; (4) melt-blending said base polymer, said polar polymeric stabilizing agent, and said one or more hydrophobic particulate fillers; (4) contacting said melt-blended base polymer, polar polymeric stabilizing agent and one or more hydrophobic particulate fillers with water and optionally in the presence of a neutralizing agent; (5) thereby forming said dispersion comprising: (a) a core comprising said base polymer; (b) a shell at least partially surrounding said core, wherein said shell comprising said polar polymeric stabilizing agent; and (c) said one or more hydrophobic particulate fillers embedded at least partially in said shell.The coated article according to the present invention comprises: a substrate comprising cellulose base material; and a dispersion on at least one surface of said substrate, wherein said dispersion comprises: (a) a core comprising a base polymer; (b) a shell at least partially surrounding said core, wherein said shell comprising a polar polymeric stabilizing agent; and (c) one or more hydrophobic particulate fillers embedded at least partially in said shell.The method of making a coated article according to the present invention comprises the steps of: (1) providing a substrate comprising cellulose base material (2) providing a coating composition comprising a dispersion comprising: (a) a core comprising a base polymer; (b) a shell at least partially surrounding said core, wherein said shell comprising a polar polymeric stabilizing agent; and (c) one or more hydrophobic particulate fillers embedded at least partially in said shell; (3) applying said coating composition to at least one surface of said substrate; and (4) thereby making said coated article.
    • 9. 发明授权
    • Cationic water based polymers for ink, coating, and film applications
    • 用于油墨,涂料和薄膜应用的阳离子水基聚合物
    • US09441123B2
    • 2016-09-13
    • US13586123
    • 2012-08-15
    • Michael D. SpiegelCharles B. Rybny
    • Michael D. SpiegelCharles B. Rybny
    • C08F255/00C08F259/04C08F261/04C08F263/04C08J3/03C09D11/00C09D11/10C09D11/30
    • C08F261/04C08F259/04C08F263/04C09D11/10C09D11/107C09D11/30C09D151/003
    • The present invention provides a durable, external surfactant free, cationic, water based jet ink polymer which when formulated into an ink jet ink results in a printing that has an excellent adhesion to metal or plastic substrates. Such a jet ink polymer is suitable performance replacement of solvent soluble polymers currently in commercial use. The hybridized copolymer comprises a hydrophobic functional polymeric backbone comprised of a polysiloxane polymer, a polyolefin polymer, or a functional polyvinyl polymer. The hybridized copolymer also comprises a plurality of copolymeric side chains attached to the backbone, comprising a polymerizable amine-containing unsaturated monomer, and a polymerizable unsaturated monomer. The use of the inks of the present invention enhances performance criteria such as print-head open time, ink stability, and resistance to typical water based cleaners.
    • 本发明提供了耐久的外部表面活性剂,阳离子型水基喷墨油墨聚合物,其在配制成喷墨油墨时形成与金属或塑料基材具有优异粘附性的印刷。 这种喷墨油墨聚合物是目前商业上使用的溶剂可溶性聚合物的合适的性能替代品。 杂化共聚物包含由聚硅氧烷聚合物,聚烯烃聚合物或官能聚乙烯基聚合物组成的疏水官能聚合物主链。 杂化共聚物还包括连接到主链上的多个共聚侧链,包含可聚合的含胺不饱和单体和可聚合的不饱和单体。 使用本发明的油墨增强了性能标准,例如打印头打开时间,油墨稳定性和对典型的水基清洁剂的耐受性。