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1. 发明公开

US20230253199A1 TOROIDAL ION TRAP 审中-公开
公开(公告)号：US20230253199A1
公开(公告)日：2023-08-10
申请号：US18105308
申请日：2023-02-03
申请人： PerkinElmer Health Sciences, Inc.
发明人： Stephen D. Lammert , Atanu K. Mohanty , Shawn Johnson , Robert Jackson
IPC分类号： H01J49/42
CPC分类号： H01J49/424 , H01J49/423
摘要： Provided are improved toroidal ion traps and methods of design of such ion traps. Toroidal ion traps include an inner electrode comprising a first surface; an outer electrode at least partially circumferentially surrounding the inner electrode, the outer electrode comprising a second surface substantially facing the first surface, wherein the outer electrode is spaced apart from the first surface in a radial direction; a first end electrode comprising a third surface; a second end electrode comprising a fourth surface substantially facing the third surface; an axis of rotation extending through the inner electrode; and wherein: the first, second, third, and fourth surfaces define an ion confinement cavity and at least portions of each of the first, second, third, and fourth surfaces extend through or along iso-potential surfaces associated with a linear combination of toroidal multipoles to generate an electric field extending through slits in the first and second end electrodes.

2. 发明申请

US20170256389A1 Ion Beam Mass Pre-Separator 审中-公开
公开(公告)号：US20170256389A1
公开(公告)日：2017-09-07
申请号：US15060474
申请日：2016-03-03
申请人： Thermo Fisher Scientific (Bremen) GmbH , Thermo Finnigan LLC
发明人： Dmitry E. GRINFELD , Mikhail V. UGAROV , Viatcheslav V. KOVTOUN , Alexander A. MAKAROV
IPC分类号： H01J49/42 , H01J49/00
CPC分类号： H01J49/427 , H01J49/0031 , H01J49/423 , H01J49/4255
摘要： An apparatus for separating ions includes an electrode arrangement having a length extending between first and second ends. The first end is configured to introduce a beam of ions into an ion transmission space of the arrangement. An electronic controller applies an RF potential and a DC potential to an electrode of the electrode arrangement, for generating a ponderomotive RF electric field and a mass-independent DC electric field. The application of the potentials is controlled such that a ratio of the strength of the ponderomotive RF electric field to the strength of the mass-independent DC electric field varies along the length of the electrode arrangement. The generated electric field supports extraction of ions having different m/z values at respective different positions along the length of the electrode arrangement. Ions are extracted in one of increasing and decreasing sequential order of m/z ratio with increasing distance from the first end.

3. 发明授权

US09704696B2 High duty cycle ion spectrometer 有权
公开(公告)号：US09704696B2
公开(公告)日：2017-07-11
申请号：US15075082
申请日：2016-03-18
申请人： Thermo Fisher Scientific (Bremen) GmbH
发明人： Alexander Alekseevich Makarov
IPC分类号： H01J49/04 , H01J49/00 , H01J49/10 , H01J49/42 , H01J49/06 , H01J49/40 , G01N27/62
CPC分类号： H01J49/10 , G01N27/622 , H01J49/0027 , H01J49/0031 , H01J49/0481 , H01J49/06 , H01J49/063 , H01J49/401 , H01J49/4215 , H01J49/423 , H01J49/425 , H01J49/426 , H01J49/427 , H01J49/4295
摘要： An ion spectrometer is provided, comprising: an ion source, arranged to generate ions continuously with a first range of mass to charge ratios; and an ion trap, arranged to receive ions from the ion source along an axis, and to eject ions with a second range of mass to charge ratios orthogonally to that axis, the second range of mass to charge ratios being narrower than the first range of mass to charge ratios. In some embodiments, ions generated by the ion source continuously flow into the ion trap. Additionally or alternatively, ion optics receive ions ejected from the ion trap and cool the ions without substantial fragmentation. An ion analyser receives ions ejected from the ion trap or ion optics and separates the ions in accordance with at least one characteristic of the ions.

4. 发明授权

US09472385B2 RF power supply for a mass spectrometer 有权
公开(公告)号：US09472385B2
公开(公告)日：2016-10-18
申请号：US14677857
申请日：2015-04-02
申请人： Thermo Finnigan LLC
发明人： Alexander A. Makarov , Eduard V. Denisov , Alexander Kholomeev
IPC分类号： H01J49/42 , H01J49/26 , B01D59/44 , H01J49/00 , H01J49/36 , H01J49/02
CPC分类号： H01J49/0031 , H01J49/022 , H01J49/36 , H01J49/423 , H01J49/427
摘要： The present invention provides a radio frequency (RF) power supply in a mass spectrometer. The power supply provides an RF signal to electrodes of a storage device to create a trapping field. The RF field is usually collapsed prior to ion ejection. In an illustrative embodiment the RF power supply includes a RF signal supply; a coil arranged to receive the signal provided by the RF signal supply and to provide an output RF signal for supply to electrodes of an ion storage device; and a shunt including a switch operative to switch between a first open position and a second closed position in which the shunt shorts the coil output.

5. 发明授权

US09406495B2 Linear ion beam bonding apparatus and array structure thereof 有权
标题翻译：线性离子束接合装置及其阵列结构
公开(公告)号：US09406495B2
公开(公告)日：2016-08-02
申请号：US14389642
申请日：2013-02-26
申请人： SHIMADZU RESEARCH LABORATORY (SHANGHAI) CO. LTD.
发明人： Gongyu Jiang , Wenjian Sun
IPC分类号： H01J49/42 , H01J49/06 , H01J49/00
CPC分类号： H01J49/423 , H01J49/0027 , H01J49/063 , H01J49/4255 , H01J49/427
摘要： A linear ion beam bonding apparatus and an array structure thereof, comprising a pair of primary radiofrequency electrodes (501 and 502) extending along the axial direction and oppositely arranged on two sides of the central axis of the linear ion beam bonding apparatus. Section patterns on different section planes of each of the primary radiofrequency electrodes (501 and 502) and perpendicular to the central axis are all kept symmetric via a primary symmetric plane (506) of the central axis. Radiofrequency voltages attached to the primary radiofrequency electrodes (501 and 502) are of identical phases. An ion extraction groove (84) is arranged on at least one of the primary radiofrequency electrodes (501 and 502), while at least one pair of auxiliary electrodes (503 and 505) are arranged on two sides of the pair of primary radiofrequency electrodes (501 and 502). The auxiliary electrodes (503 and 505) are arranged in duality to the primary symmetric plane (506). At least one of the auxiliary electrodes (503 and 505) is provided with a finite number of symmetric planes (507), while a minimal angle greater than 0 degrees and less than 90 degrees is provided between each symmetric plane (507) and the symmetric plane (506) of the primary radiofrequency electrodes (501 and 502). By means of this, a quadrupole field component of an ion beam bonding radiofrequency electric field within the ion beam bonding apparatus is strengthened.
摘要翻译：一种线性离子束接合装置及其阵列结构，包括沿着轴向延伸并且相对设置在线性离子束接合装置的中心轴线的两侧的一对初级射频电极（501和502）。主要射频电极（501和502）的每一个并且垂直于中心轴的不同截面的截面图案都通过中心轴的主对称平面（506）保持对称。附加到主射频电极（501和502）的射频电压具有相同的相位。离子提取槽（84）布置在主射频电极（501和502）中的至少一个上，而至少一对辅助电极（503和505）布置在一对主射频电极 501和502）。辅助电极（503和505）与主对称平面（506）的对置布置。至少一个辅助电极（503和505）设置有有限数量的对称平面（507），而在每个对称平面（507）和对称平面（507）之间提供大于0度且小于90度的最小角度平面（506）的主射频电极（501和502）。由此，离子束接合装置内的离子束结合射频电场的四极场成分被加强。

6. 发明授权

US09330894B1 Ion transfer method and device 有权
标题翻译：离子转移方法和装置
公开(公告)号：US09330894B1
公开(公告)日：2016-05-03
申请号：US14613168
申请日：2015-02-03
申请人： Thermo Finnigan LLC
发明人： Viatcheslav V. Kovtoun
IPC分类号： H01J49/06 , G01N27/62 , H01J49/02 , H01J49/00
CPC分类号： H01J49/063 , H01J49/0045 , H01J49/062 , H01J49/423
摘要： An ion transport device can include a plurality of pole rod pairs arranged in parallel, and a controller. The controller can be configured to apply voltages in a repeating voltage pattern to the pole rod pairs thereby creating a plurality of potential wells capable of capturing ions, and move the repeating voltage pattern along the pole rod pairs to move captured ions along the ion transport device. The ion transport device can be incorporated into a mass spectrometer.
摘要翻译：离子传输装置可以包括并联布置的多个极杆对和控制器。控制器可以被配置为以重复的电压模式将电压施加到极杆对，从而产生能够捕获离子的多个势阱，并沿着极杆对移动重复的电压模式，以沿着离子传输装置移动捕获的离子。离子迁移装置可以并入质谱仪中。

7. 发明申请

US20150170898A1 LINER ION BEAM BONDING APPARATUS AND ARRAY STRUCTURE THEREOF 有权
标题翻译：内置离子束结合装置及其阵列结构
公开(公告)号：US20150170898A1
公开(公告)日：2015-06-18
申请号：US14389642
申请日：2013-02-26
申请人： SHIMADZU RESEARCH LABORATORY (SHANGHAI) CO. LTD.
发明人： Gongyu Jiang , Wenjian Sun
IPC分类号： H01J49/42 , H01J49/00
CPC分类号： H01J49/423 , H01J49/0027 , H01J49/063 , H01J49/4255 , H01J49/427
摘要： A linear ion beam bonding apparatus and an array structure thereof, comprising a pair of primary radiofrequency electrodes (501 and 502) extending along the axial direction and oppositely arranged on two sides of the central axis of the linear ion beam bonding apparatus. Section patterns on different section planes of each of the primary radiofrequency electrodes (501 and 502) and perpendicular to the central axis are all kept symmetric via a primary symmetric plane (506) of the central axis. Radiofrequency voltages attached to the primary radiofrequency electrodes (501 and 502) are of identical phases. An ion extraction groove (84) is arranged on at least one of the primary radiofrequency electrodes (501 and 502), while at least one pair of auxiliary electrodes (503 and 505) are arranged on two sides of the pair of primary radiofrequency electrodes (501 and 502). The auxiliary electrodes (503 and 505) are arranged in duality to the primary symmetric plane (506). At least one of the auxiliary electrodes (503 and 505) is provided with a finite number of symmetric planes (507), while a minimal angle greater than 0 degrees and less than 90 degrees is provided between each symmetric plane (507) and the symmetric plane (506) of the primary radiofrequency electrodes (501 and 502). By means of this, a quadrupole field component of an ion beam bonding radiofrequency electric field within the ion beam bonding apparatus is strengthened.
摘要翻译：一种线性离子束接合装置及其阵列结构，包括沿着轴向延伸并且相对设置在线性离子束接合装置的中心轴线的两侧的一对初级射频电极（501和502）。主要射频电极（501和502）的每一个并且垂直于中心轴的不同截面的截面图案都通过中心轴的主对称平面（506）保持对称。附加到主射频电极（501和502）的射频电压具有相同的相位。离子提取槽（84）布置在主射频电极（501和502）中的至少一个上，而至少一对辅助电极（503和505）布置在一对主射频电极 501和502）。辅助电极（503和505）与主对称平面（506）的对置布置。至少一个辅助电极（503和505）设置有有限数量的对称平面（507），而在每个对称平面（507）和对称平面（507）之间提供大于0度且小于90度的最小角度平面（506）的主射频电极（501和502）。由此，离子束接合装置内的离子束结合射频电场的四极场成分被加强。

8. 发明授权

US08581185B2 Ion storage device with direction-selective radial ejection 有权
标题翻译：具有方向选择性径向喷射的离子存储装置
公开(公告)号：US08581185B2
公开(公告)日：2013-11-12
申请号：US13226390
申请日：2011-09-06
申请人： Alexander A. Makarov , Eduard V. Denisov , Alexander Kholomeev
发明人： Alexander A. Makarov , Eduard V. Denisov , Alexander Kholomeev
IPC分类号： H01J49/42 , H01J49/26 , B01D59/44
CPC分类号： H01J49/0031 , H01J49/022 , H01J49/36 , H01J49/423 , H01J49/427
摘要： The present invention provides a radio frequency (RF) power supply in a mass spectrometer. The power supply provides an RF signal to electrodes of a storage device to create a trapping field. The RF field is usually collapsed prior to ion ejection. In an illustrative embodiment the RF power supply includes a RF signal supply; a coil arranged to receive the signal provided by the RF signal supply and to provide an output RF signal for supply to electrodes of an ion storage device; and a shunt including a switch operative to switch between a first open position and a second closed position in which the shunt shorts the coil output.
摘要翻译：本发明提供质谱仪中的射频（RF）电源。电源向存储设备的电极提供RF信号以产生捕获场。射频场通常在离子喷射之前倒塌。在说明性实施例中，RF电源包括RF信号电源; 布置成接收由RF信号电源提供的信号并提供用于向离子存储装置的电极供应的输出RF信号的线圈; 以及分流器，其包括可操作以在第一打开位置和第二关闭位置之间切换的开关，其中分流器使线圈输出短路。

9. 发明授权

US08519331B2 Mass spectrometer 有权
标题翻译：质谱仪
公开(公告)号：US08519331B2
公开(公告)日：2013-08-27
申请号：US12528173
申请日：2008-02-21
申请人： Robert Harold Bateman , Martin Green , Jason Lee Wildgoose
发明人： Robert Harold Bateman , Martin Green , Jason Lee Wildgoose
IPC分类号： H01J49/42 , H01J49/00
CPC分类号： H01J49/0095 , H01J49/423 , H01J49/424
摘要： A mass spectrometer is disclosed comprising a 2D or 3D ion trap. The 2D ion trap comprises a quadrupole rod set ion trap wherein a slot is provided in each of the rods to allow ions to be ejected radially from the ion trap. The 3D ion trap comprises a central ring electrode which is radially segmented and wherein a slot is provided in each radial segment to allow ions to be ejected radially from the ion trap. Ions having different mass to charge ratios and/or opposite polarities may be simultaneously ejected from the ion trap via different exit pathways.
摘要翻译：公开了包括2D或3D离子阱的质谱仪。 2D离子阱包括四极杆组离子阱，其中在每个棒中设置有槽，以允许离子从离子阱径向喷射。 3D离子阱包括径向分段的中心环电极，并且其中在每个径向段中设置狭槽以允许离子从离子阱径向喷射。具有不同质荷比和/或相反极性的离子可以通过不同的出口通道从离子阱同时喷出。

10. 发明授权

US08288714B2 Ion trapping 有权
标题翻译：离子捕获
公开(公告)号：US08288714B2
公开(公告)日：2012-10-16
申请号：US12944357
申请日：2010-11-11
申请人： Alexander A. Makarov , Eduard V. Denisov , Gerhard Jung , Robert Malek , Oliver Lange
发明人： Alexander A. Makarov , Eduard V. Denisov , Gerhard Jung , Robert Malek , Oliver Lange
IPC分类号： H01J49/00
CPC分类号： H01J49/423 , H01J49/004 , H01J49/425 , H01J49/4295
摘要： This invention relates to a method of trapping ions and to an ion trapping assembly. In particular, the present invention has application in gas-assisted trapping of ions in an ion trap prior to a mass analysis of the ions in a mass spectrometer. The invention provides a method of trapping ions in a target ion trap of an ion trapping assembly that comprises a series of volumes arranged such that ions can traverse from one volume to the next, the volumes including the target ion trap, whereby ions are allowed to pass repeatedly through the volumes such that they also pass into and out from the target ion trap without being trapped. Potentials may be used to reflect the ions from respective ends of the ion trapping assembly. Optionally, a potential well and/or gas-assisted cooling may be used to cause the ions to settle in the target ion trap.
摘要翻译：本发明涉及一种捕获离子和离子捕获组件的方法。特别地，本发明在质谱仪中对离子的质量分析之前，已经将其应用于离子阱中的气体辅助捕获。本发明提供了一种捕获离子捕获组件的靶离子阱中的离子的方法，该方法包括一系列体积排列使得离子可以从一个体积向下一个体积横越，该体积包括目标离子阱，从而使离子被允许反复通过体积，使得它们也被进入和离开目标离子阱而不被捕获。电位可用于从离子捕获组件的相应末端反射离子。任选地，潜在的井和/或气体辅助冷却可用于使离子沉淀在目标离子阱中。

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