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    • 5. 发明授权
    • Aqueous compositions based on acid-functional acrylic silanol polymers
    • 基于酸官能的丙烯酸硅烷醇聚合物的水性组合物
    • US5162420A
    • 1992-11-10
    • US707250
    • 1991-05-22
    • Wen-Hsuan ChangEdward E. McEntireMarvin L. Kaufman
    • Wen-Hsuan ChangEdward E. McEntireMarvin L. Kaufman
    • C08F230/08C09D143/04
    • C09D143/04C08F230/08
    • Disclosed is an aqueous composition containing a vinyl-type polymer product having hydrolyzable silyl groups which aqueous composition is stable at relatively high solids for such a composition and yet cures at relatively low temperatures upon the evaporation of water. More particularly, disclosed is a stable, aqueous, colloidal silica-free, dispersion or solution containing a solution-polymerized vinyl-type polymer having acid functionality sufficient to provide an acid value of from 5 to 160 and having a hydroxyl value of less than or equal to 10 and sufficient hydrolyzable silyl groups to provide a Si content in the range of from 0.40 to 6.0 percent by weight based on the total weight of the vinyl-type polymer. The vinyl-type polymer is characterized in that a composition consisting of at least 25 percent by weight of the polymer in water remains stable in a closed container for at least 24 hours at a temperature of 48.9 degrees Celsius.Also disclosed is a stable, aqueous, colloidal silica-free, coating composition having a total organic resin solids content of greater than or equal to 25 percent by weight, at least 50 percent by weight of the total organic resin solids content consisting of the aforesaid solution-polymerized vinyl-type polymer.
    • 公开了一种水性组合物,其含有具有可水解甲硅烷基的乙烯基型聚合物产物,该水性组合物对于这种组合物在相对高的固含量下是稳定的,并且在水蒸发时在相对低的温度下固化。 更具体地,公开了一种稳定的含水胶态二氧化硅的分散体或溶液,其含有溶液聚合的乙烯基型聚合物,该聚合物的酸官能度足以提供5至160的酸值,并且其羟基值小于或等于 等于10和足够的可水解甲硅烷基,以提供基于乙烯基类聚合物总重量的0.40至6.0重量%的Si含量。 乙烯基型聚合物的特征在于由水中至少25重量%的聚合物组成的组合物在密封容器中在48.9摄氏度的温度下保持稳定至少24小时。 还公开了一种稳定的水性无胶体二氧化硅涂料组合物,其总有机树脂固体含量大于或等于25重量%,至少占总有机树脂固体含量的50重量%,由上述 溶液聚合的乙烯基型聚合物。