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    • 4. 发明申请
    • BLOCKING AGENT FOR AN ISOCYANATE GROUP AND ISOCYANATE PROTECTED BY SAID BLOCKING AGENT
    • US20230062457A1
    • 2023-03-02
    • US17778905
    • 2020-11-19
    • Shin-Etsu Chemical Co., Ltd.
    • Fumihiro AsoKohei Masuda
    • C08G18/80C08G18/28C08G18/24C08G18/62C09D175/04
    • One of the purposes of the present invention is to provide a blocking agent for blocking an isocyanate group to thereby prepare an isocyanate compound which has excellent water resistance and is react with another polymerizable compound to be cured at a relatively low temperature; and another purpose is to provide a blocked isocyanate having an isocyanate group blocked with the blocking agent. The present invention provides a blocking agent for blocking an isocyanate group, wherein the blocking agent is an organic silicon alcohol having an organic group bonded to a silicon atom and said organic group is capable of forming a β-silyl cation together with the silicon atom. In a preferred embodiment, the present invention provides a blocking agent which is an organic silicon alcohol represented by the general formula (1). In the formula (1), R1 is an alkylene group having 3 to 5 carbon atoms and may have a substituent, provided that the number of carbon atoms of the substituent is not included in the number of the carbon atoms of the alkylene group, R2 is an alkyl group having 1 to 10 carbon atoms, Z is an organic group capable of forming a β-silyl cation together with the silicon atom to which Z bonds, and n is an integer of 1 to 3. The present invention further provides a blocked isocyanate having a structure in which the isocyanate group is blocked with the aforesaid blocking agent and a thermosetting composition comprising the blocked isocyanate.