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1. 发明授权

US5011944A Substituted .alpha.-pyrones 失效
标题翻译：取代的α-吡喃酮
公开(公告)号：US5011944A
公开(公告)日：1991-04-30
申请号：US356825
申请日：1989-05-24
申请人： Vratislav Kvita , Marcus Baumann , Walter Fischer , Carl W. Mayer , Thomas Allmendinger
发明人： Vratislav Kvita , Marcus Baumann , Walter Fischer , Carl W. Mayer , Thomas Allmendinger
IPC分类号： C07D309/30 , B05D1/20 , C07C45/00 , C07C50/24 , C07C67/00 , C07C69/95 , C07D309/38 , C07F7/08 , C07F7/18 , C08G61/12 , C09K9/02 , H01B1/12
CPC分类号： B05D1/202 , B82Y30/00 , B82Y40/00 , C07D309/38 , C08G61/123 , C09K9/02 , H01B1/121
摘要： .alpha.-Pyrones of the formula I ##STR1## in which R.sup.1 is --CF.sub.3 or --COOR.sup.3 and R.sup.3 is the radical of a C.sub.1 -C.sub.18 alcohol diminished by a hydroxyl group, and R.sup.2 is --F, --Br, --Cl, --CN, --CF.sub.3, C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.18 alkenyl, C.sub.2 -C.sub.18 alkynyl, C.sub.1 -C.sub.18 alkoxy, C.sub.1 -C.sub.18 alkylthio, C.sub.1 -C.sub.18 alkylsulfonyl, C.sub.6 -C.sub.16 aryl, C.sub.7 -C.sub.24 alkaryl, C.sub.7 -C.sub.12 aralkyl, C.sub.8 -C.sub.24 alkaralkyl, C.sub.6 -C.sub.16 aryloxy, C.sub.6 -C.sub.16 arylthio, C.sub.6 -C.sub.16 arylsulfonyl, C.sub.7 -C.sub.24 alkaryloxy, C.sub.7 -C.sub.24 alkarylthio, C.sub.7 -C.sub.24 alkarylsulfonyl, C.sub.7 -C.sub.12 aralkyloxy, C.sub.7 -C.sub.12 aralkylthio, C.sub.7 -C.sub.12 aralkylsulfonyl, C.sub.8 -C.sub.24 alkaralyloxy, C.sub.8 -C.sub.24 alkaralylthio, C.sub.8 -C.sub.24 alkaralylsulfonyl, secondary amine having 2 to 24 C atoms or trialkylsilyl or trialkoxysilyl each of which has 3 to 18 C atoms. They are suitable for the preparation of naphtho-1,4-quinones and anthra-1,4-quinones, from which tetrathiotetracenes or tetraselenotetracenes having electrochromic properties can be obtained.
摘要翻译：其中R 1为-CF 3或-COOR 3且R 3为被羟基减弱的C 1 -C 18醇基团的式I（I）的α-吡喃酮，R2为-F，-Br，-Cl ，-CN，-CF 3，C 1 -C 18烷基，C 2 -C 18烯基，C 2 -C 18炔基，C 1 -C 18烷氧基，C 1 -C 18烷硫基，C 1 -C 18烷基磺酰基，C 6 -C 16芳基，C 7 -C 24烷芳基，C 7 -C 12芳烷基，C 8 -C 24烷基烷基，C 6 -C 16芳氧基，C 6 -C 16芳硫基，C 6 -C 16芳基磺酰基，C 7 -C 24链烯氧基，C 7 -C 24烷芳硫基，C 7 -C 24烷芳基磺酰基，C 7 -C 12芳烷氧基，C 7 -C 12芳烷硫基，C 7 -C 12芳烷基磺酰基，C 8 -C 24链烷氧基，C 8 -C 24烷酰基硫代，C 8 -C 24烷酰基磺酰基， 24个C原子或三烷基甲硅烷基或三烷氧基甲硅烷基，各自具有3至18个C原子。它们适用于制备萘并-1,4-醌和蒽-1,4-醌，可从中得到具有电致变色特性的四硫代四烯或四硒代四烯。

2. 发明授权

US5112977A Substituted naphthacene-5,12-diones 失效
标题翻译：取代的萘醌-5,12-二酮
公开(公告)号：US5112977A
公开(公告)日：1992-05-12
申请号：US356830
申请日：1989-05-24
申请人： Walter Fischer , Marcus Baumann , Jurgen Finter , Vratislav Kvita , Carl W. Mayer , Wolfgang Wernet
发明人： Walter Fischer , Marcus Baumann , Jurgen Finter , Vratislav Kvita , Carl W. Mayer , Wolfgang Wernet
IPC分类号： G03F7/028 , B05D1/20 , C07C45/00 , C07C50/24 , C07C50/36 , C07C66/00 , C07C67/00 , C07C69/00 , C07C69/738 , C07C201/00 , C07C205/46 , C07C205/48 , C07C211/61 , C07C225/32 , C07C235/40 , C07C255/40 , C07C255/41 , C07C255/56 , C07C255/57 , C07C317/24 , C07C323/20 , C07C323/22 , C07D295/10 , C07D295/116 , C07D307/12 , C07F7/08 , C08F2/50 , C08G61/12 , C08K5/08 , C08K5/10 , C08K5/13 , C08K5/36 , C09B3/58 , H01B1/12
CPC分类号： C07D295/116 , B05D1/202 , B82Y30/00 , B82Y40/00 , C07C205/48 , C07C225/32 , C07C255/40 , C07C255/41 , C07C255/56 , C07C323/20 , C07C323/22 , C07C50/24 , C07C50/36 , C07C69/00 , C07D307/12 , C07F7/0818 , C08F2/50 , C08G61/123 , H01B1/121 , C07C2101/02 , C07C2103/00 , C07C2103/44
摘要： Substituted naphthacenediones of the formula I ##STR1## in which R.sup.1 to R.sup.8 are H and at least one of R.sup.1 to R.sup.8, for example R.sup.2 and R.sup.3 or R.sup.2 and R.sup.6, are, for example, C.sub.1 -C.sub.20 alkoxy, C.sub.1 -C.sub.20 alkenoxy, C.sub.1 -C.sub.20 -alkylsulfinyl, --CN, --CF.sub.3, --NO.sub.2, --Si(CH.sub.3).sub.3 or --COO(C.sub.1 -C.sub.12 alkyl), are suitable, when incorporated into polymers having hydroxyalkyl groups, for currentless deposition of metals onto the polymer surface. They are in some cases suitable as photoinitiators.
摘要翻译：其中R 1至R 8为H并且R 1至R 8中的至少一个，例如R 2和R 3或R 2和R 6的取代的对映体萘并吖啶为例如C 1 -C 20烷氧基，C 1 -C 20链烯氧基，当C 1 -C 20烷基亚磺酰基，-CN，-CF 3，-NO 2，-Si（CH 3）3或-COO（C 1 -C 12烷基）掺入到具有羟烷基的聚合物中时，适用于金属在聚合物上无电沉积表面。在某些情况下，它们适合作为光引发剂。

3. 发明授权

US4981962A Substituted tetrathiotetracenes and tetraselenotetracenes 失效
公开(公告)号：US4981962A
公开(公告)日：1991-01-01
申请号：US356824
申请日：1989-05-24
申请人： Marcus Baumann , Walter Fischer , Vratislav Kvita , Carl W. Mayer , Wolfgang Wernet
发明人： Marcus Baumann , Walter Fischer , Vratislav Kvita , Carl W. Mayer , Wolfgang Wernet
IPC分类号： B05D1/20 , C07D495/06 , C07D517/06 , C07D517/16 , C08G61/12 , C09K9/02 , H01B1/12
CPC分类号： C07D495/06 , B05D1/202 , B82Y30/00 , B82Y40/00 , C07D517/06 , C07D517/08 , C08G61/123 , C09K9/02 , H01B1/121
摘要： Substituted tetrathiotetracenes and tetraselenotetracenes of the formula I ##STR1## in which Z is --S-- or --Se-- and (a) R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are H and R.sup.5 to R.sup.8 are each H and at least one of the radicals R.sup.5 to R.sup.8 independently of one another is a substituent belonging to the group comprising C.sub.1 -C.sub.20 alkyl--X--.sub.p which is unsubstituted or substituted by halogen, --CN, --CONR.sup.9 R.sup.10, --OR.sup.9, --SR.sup.9 or --COOR.sup.9, with the exception of C.sub.1 -C.sub.4 alkyl and methoxy, C.sub.2 -C.sub.18 alkenyl--X--.sub.p, C.sub.2 -C.sub.18 -alkynyl--X--.sub.p, C.sub.3 -C.sub.8 cycloalkyl--X--.sub.p, (C.sub.1 -C.sub.12 alkyl)--C.sub.3 -C.sub.8 cycloalkyl--X--.sub.p, C.sub.3 -C.sub.8 cycloalkyl-C.sub.r H.sub.2r --X--.sub.p, (C.sub.1 -C.sub.12 alkyl)-C.sub.3 -C.sub.8 -cyclo alkyl-C.sub.r H.sub.2r --X--.sub.p, phenyl--X--.sub.p, (C.sub.1 -C.sub.12)alkyl)-phenyl--X--, phenyl-C.sub.r H.sub. 2r --X--.sub.p and (C.sub.1 -C.sub.12 alkyl)-phenyl-C.sub.r H.sub.2r --X--.sub.p, r is 1 or 2 and p is 0 or 1 and X is --O--, --S--, --SO-- or --SO.sub.2 --, or R.sup.5 to R.sup.8 independently are a substituent belonging to the group comprising --Br, --CF.sub.3, --CN, --Si(C.sub.1 -C.sub.4 alkyl).sub.3, --S--(C.sub.m H.sub.2m O)--.sub.n R.sup.11 or --O--C.sub.m H.sub.2m --O--R.sup.11, or each one of R.sup.5 to R.sup.8 is --F or --Cl and at least one further member of R.sup.5 to R.sup.8 is a substituent of the groups defined above, including C.sub.1 -C.sub.4 alkyl and methoxy, R.sup.9 and R.sup.10 independently of one another are H, C.sub.1 -C.sub.12 alkyl, phenyl or --C.sub.m H.sub.2m --O--.sub.q R.sup.11, or R.sup.9 and R.sup.10 together are tetramethylene, pentamethylene, 3-oxapentylene or --CH.sub.2 CH.sub.2 NR.sup.9 CH.sub.2 CH.sub.2 --, R.sup.11 is H or C.sub.1 -C.sub.12 -alkyl, m is a number from 2 to 4, n is a number from 2 to 20 and q is a number from 1 to 20, orb) R.sup.1 to R.sup.8 independently of one another are H or one of the substituents defined above, including C.sub.1 -C.sub.4 alkyl and methoxy, or --COOR.sup.9 or --CONR.sup.9 R.sup.10 or two pairs of adjacent radicals of R.sup.1 to R.sup.8 are --CO--O--CO-- or --CO--NR.sup.9 --CO--, and at least one of R.sup.1 to R.sup.4 and also R.sup.5 to R.sup.8 is a substituent, with the exception of R.sup.2, R.sup.3, R.sup.6 and R.sup.7 when these are --F and methyl, and where R.sup.9 and R.sup.10 are as defined above.With electron acceptors they form charge-transfer complexes which can be used as organic electrical conductors, displays, optical switches and sensors.

4. 发明授权

US5391749A Substituted naphthacene-5,12-diones and their use 失效
标题翻译：取代的并四苯-5,12-二酮及其用途
公开(公告)号：US5391749A
公开(公告)日：1995-02-21
申请号：US843656
申请日：1992-02-28
申请人： Walter Fischer , Marcus Baumann , Jurgen Finter , Vratislav Kvita , Carl W. Mayer , Wolfgang Wernet
发明人： Walter Fischer , Marcus Baumann , Jurgen Finter , Vratislav Kvita , Carl W. Mayer , Wolfgang Wernet
IPC分类号： G03F7/028 , B05D1/20 , C07C45/00 , C07C50/24 , C07C50/36 , C07C66/00 , C07C67/00 , C07C69/00 , C07C69/738 , C07C201/00 , C07C205/46 , C07C205/48 , C07C211/61 , C07C225/32 , C07C235/40 , C07C255/40 , C07C255/41 , C07C255/56 , C07C255/57 , C07C317/24 , C07C323/20 , C07C323/22 , C07D295/10 , C07D295/116 , C07D307/12 , C07F7/08 , C08F2/50 , C08G61/12 , C08K5/08 , C08K5/10 , C08K5/13 , C08K5/36 , C09B3/58 , H01B1/12 , C07D211/06
CPC分类号： C07D295/116 , B05D1/202 , B82Y30/00 , B82Y40/00 , C07C205/48 , C07C225/32 , C07C255/40 , C07C255/41 , C07C255/56 , C07C323/20 , C07C323/22 , C07C50/24 , C07C50/36 , C07C69/00 , C07D307/12 , C07F7/0818 , C08F2/50 , C08G61/123 , H01B1/121 , C07C2101/02 , C07C2103/00 , C07C2103/44
摘要： Substituted naphthacenediones of the formula I ##STR1## in which R.sup.1 to R.sup.8 are H and at least one of R.sup.1 to R.sup.8, for example R.sup.2 and R.sup.3 or R.sup.2 and R.sup.6, are, for example, C.sub.1 -C.sub.20 alkoxy, C.sub.1 -C.sub.20 alkenoxy, C.sub.1 -C.sub.20 -alkylsulfinyl, --CN, --CF.sub.3, --NO.sub.2, --Si(CH.sub.3).sub.3 or --COO(C.sub.1 -C.sub.12 alkyl), are suitable, when incorporated into polymers having hydroxyalkyl groups, for currentless deposition of metals onto the polymer surface. They are in some cases suitable as photoinitiators.
摘要翻译：其中R 1至R 8为H并且R 1至R 8中的至少一个，例如R 2和R 3或R 2和R 6的取代的对映体萘并吖啶为例如C 1 -C 20烷氧基，C 1 -C 20链烯氧基，当C 1 -C 20烷基亚磺酰基，-CN，-CF 3，-NO 2，-Si（CH 3）3或-COO（C 1 -C 12烷基）掺入到具有羟烷基的聚合物中时，适用于金属在聚合物上无电沉积表面。在某些情况下，它们适合作为光引发剂。

5. 发明授权

US5001243A Substituted naphthacene-5, 12-diones 失效
标题翻译：取代的并四苯-5,12-二酮
公开(公告)号：US5001243A
公开(公告)日：1991-03-19
申请号：US356828
申请日：1989-05-24
申请人： Walter Fischer , Marcus Baumann , Jurgen Finter , Vratislav Kvita , Carl W. Mayer , Manfred Rembold , Martin Roth
发明人： Walter Fischer , Marcus Baumann , Jurgen Finter , Vratislav Kvita , Carl W. Mayer , Manfred Rembold , Martin Roth
IPC分类号： C09K3/00 , B05D1/20 , C07C323/22 , C07C323/25 , C07C323/52 , C08F2/50 , C08G61/12 , C09B3/58 , C09K9/02 , G03C1/73 , G03F7/031 , H01B1/12
CPC分类号： B05D1/202 , B82Y30/00 , B82Y40/00 , C07C323/22 , C07C323/25 , C07C323/52 , C08G61/123 , C09K9/02 , G03C1/73 , G03F7/031 , H01B1/121 , C07C2103/44
摘要： Naphthacene-5,12-diones which are substituted by at least one organic thio radical are not only photoinitiators for the photopolymerization but also sensitizers for the photodimerization of ethylenically unsaturated compounds. Compositions made of these naphthacene-5,12-diones and ethylenically unsaturated compounds are suitable for the preparation of printing inks, paints, printing plates, resist materials or as image recording material.
摘要翻译：被至少一个有机硫基取代的并用的5-萘二氢-5,12-二酮不仅是用于光聚合的光引发剂，而且也是用于烯属不饱和化合物的光二聚化的敏化剂。由这些并四烯-5,12-二酮和烯键式不饱和化合物制成的组合物适用于印刷油墨，油漆，印刷版，抗蚀剂材料或图像记录材料的制备。

6. 发明授权

US5220048A Substituted benzocyclobutenes, a process for their preparation and their use 失效
标题翻译：取代的苯甲酸酯，其制备方法及其使用
公开(公告)号：US5220048A
公开(公告)日：1993-06-15
申请号：US356826
申请日：1989-05-24
申请人： Marcus Baumann , Walter Fischer , Vratislav Kvita , Carl W. Mayer
发明人： Marcus Baumann , Walter Fischer , Vratislav Kvita , Carl W. Mayer
IPC分类号： B05D1/20 , C07B37/10 , C07C17/00 , C07C17/23 , C07C23/18 , C07C25/22 , C07C41/00 , C07C43/225 , C07C43/29 , C07C63/68 , C07C65/26 , C07C67/00 , C07C69/76 , C07C201/00 , C07C205/11 , C07C205/12 , C07C205/46 , C07C233/65 , C07C235/46 , C07C255/52 , C07C323/09 , C07F7/08 , C08G61/12 , H01B1/12
CPC分类号： B05D1/202 , B82Y30/00 , B82Y40/00 , C07C205/11 , C07C205/46 , C07C25/22 , C07C43/225 , C07C69/76 , C07F7/0818 , C08G61/123 , H01B1/121 , C07C2102/06 , C07C2103/44
摘要： Benzocyclobutene-1,2-dichlorides, -bromides and -iodides which are substituted in the benzene ring are accessible in good yields and short reaction times by reacting substituted 1,2-(dichloromethyl or dibromomethyl)-benzenes with NaI in acetonitrile as the solvent. They can be used together with dienophils, for example 1,4-quinones, in Diels-Alder reactions.
摘要翻译：在苯环中被取代的苯并环丁烯-1,2-二氯化物， - 溴化物和 - 碘化物可通过使取代的1,2-（二氯甲基或二溴甲基） - 苯与NaI在乙腈中作为溶剂而以良好的收率和短的反应时间获得。它们可以与Dien-Alder反应中的双亲体例如1,4-醌配合使用。

7. 发明授权

US5338863A Process for the preparation of tetrathiotetracenes 失效
标题翻译：四硫代四烯的制备方法
公开(公告)号：US5338863A
公开(公告)日：1994-08-16
申请号：US3067
申请日：1993-01-11
申请人： Marcus Baumann , Carl W. Mayer , Wolfgang Wernet , Walter Fischer
发明人： Marcus Baumann , Carl W. Mayer , Wolfgang Wernet , Walter Fischer
IPC分类号： B05D1/20 , C07C69/00 , C07C69/16 , C07C69/18 , C07C69/732 , C07C69/94 , C07C255/13 , C07C255/15 , C07C255/46 , C07C317/22 , C07C323/21 , C07D495/06 , C07F7/08 , C08G61/12 , C09K9/02 , H01B1/12
CPC分类号： C07D495/06 , B05D1/202 , B82Y30/00 , B82Y40/00 , C07C317/22 , C07C323/21 , C07C69/00 , C07F7/0818 , C08G61/123 , H01B1/121 , C07C2103/00 , C07C2103/44
摘要： Compounds of the formula I ##STR1## in which R.sup.1 to R.sup.8 independently of one another are H and at least one of R.sup.1 and R.sup.8 is a substituent belonging to the group --F, --Si(C.sub.1 -C.sub.4 alkyl).sub.3 or --COOR.sup.10 ; or each pair of adjacent radicals of R.sup.1 to R.sup.8 is --CO--O--CO--; or at least one of R.sup.1 to R.sup.8 is C.sub.1 -C.sub.20 alkyl-(X).sub.p --, C.sub.2 -C.sub.20 alkenyl-(X).sub.p --, C.sub.2 -C.sub.20 -alkynyl-(X).sub.p --, C.sub.3 -C.sub.8 cycloalkyl-(X).sub.p --, (C.sub.1 -C.sub.12 alkyl-C.sub.3 -C.sub.8 cycloalkyl-(X).sub.p --, C.sub.3 -C.sub.8 -cycloalkyl-CH.sub.2 --(X).sub.p --, C.sub.1 -C.sub.12 alkyl-C.sub.3 -C.sub.8 cycloalkyl-CH.sub.2 --(X).sub.p --, C.sub.6 -C.sub.10 aryl-X--, C.sub.7 -C.sub.20 alkaryl-X--, C.sub.7 -C.sub.12 aralkyl-(X).sub.p -- or C.sub.8 -C.sub.20 -alkaralkyl-(X).sub.p -- or --Y-- (C.sub.m H.sub.2m --O)--.sub.n R.sup.10 each of which is unsubstituted or substituted by --F, --OH, --CN, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 acyloxy or --COOR.sup.10 ; R.sup.10 is H or C.sub.1 -C.sub.18 alkyl, X is --O--, --S--, --SO-- or --SO.sub.2 -- and Y is --O-- or --S--, and p is 0 or 1, m is a number from 2 to 6 and n is a number from 2 to 20; and R.sup.9 is C.sub.1 -C.sub.4 acyl which is unsubstituted or substituted by --F.The compounds of the formula I can be reacted directly with sulfur in the presence of catalytic amounts of a sulfonic acid to give 5,6,11,12-tetrathiotetracenes which form electrically conducting charge-transfer complexes with electron donors.
摘要翻译：其中R 1至R 8彼此独立地为H并且R 1和R 8中的至少一个为属于基团-F，-Si（C 1 -C 4烷基）3或 - COOR10; 或R 1至R 8的每对相邻基团是-CO-O-CO-; 或者R 1至R 8中的至少一个为C 1 -C 20烷基 - （X）对，C 2 -C 20烯基 - （X）对，C 2 -C 20炔基 - （X）对 - ，C 3 -C 8环烷基 - （X），（C 1 -C 12烷基-C 3 -C 8环烷基 - （X）对 - ，C 3 -C 8 - 环烷基-CH 2 - （X）对，C 1 -C 12烷基-C 3 -C 8环烷基-CH 2 - （X） X，C7-C20烷芳基 - （X）对或C8-C20-烷基烷基 - （X）对 - 或-Y-（CmH2m-O）-n10，其各自未被取代或被 -F，-OH，-CN，C 1 -C 12烷氧基，C 1 -C 12酰氧基或-COOR 10; R 10是H或C 1 -C 18烷基，X是-O - ， - S - ， - SO-或-SO 2 - ，Y是-O - 或-S-，p为0或1，m为2至6的数，n为2至20的数; R 9为未被取代或被-F取代的C 1 -C 4酰基，在催化量的磺酸存在下，式I可以直接与硫反应，得到5,6,11,12-四硫代四烯，其与电子给体形成导电电荷转移络合物。

8. 发明授权

US5206390A Substituted bisacyloxynaphthacenes 失效
标题翻译：取代的双官能团
公开(公告)号：US5206390A
公开(公告)日：1993-04-27
申请号：US356827
申请日：1989-05-24
申请人： Marcus Baumann , Carl W. Mayer , Wolfgang Wernet , Walter Fischer
发明人： Marcus Baumann , Carl W. Mayer , Wolfgang Wernet , Walter Fischer
IPC分类号： B05D1/20 , C07C69/00 , C07C69/16 , C07C69/18 , C07C69/732 , C07C69/94 , C07C255/13 , C07C255/15 , C07C255/46 , C07C317/22 , C07C323/21 , C07D495/06 , C07F7/08 , C08G61/12 , C09K9/02 , H01B1/12
CPC分类号： C07D495/06 , B05D1/202 , B82Y30/00 , B82Y40/00 , C07C317/22 , C07C323/21 , C07C69/00 , C07F7/0818 , C08G61/123 , H01B1/121 , C07C2103/00 , C07C2103/44
摘要： Compounds of the formula I ##STR1## in which R.sup.1 to R.sup.8 independently of one another are H and at least one of R.sup.1 to R.sup.8 is a substituent belonging to the group --F, --Si(C.sub.1 -C.sub.4 alkyl).sub.3 or --COOR.sup.10 ; or each pair of adjacent radicals of R.sup.1 to R.sup.8 is --CO--O--CO--; or at least one of R.sup.1 to R.sup.8 is C.sub.1 -C.sub.20 alkyl--(X).sub.p --, C.sub.2 -C.sub.20 alkenyl--(X).sub.p --, C.sub.2 -C.sub.20 -alkynyl--(X).sub.p --, C.sub.3 -C.sub.8 cycloalkyl--(X).sub.p --, (C.sub.1 -C.sub.12 alkyl--C.sub.3 -C.sub.8 cycloalkyl--(X).sub.p --, C.sub.3 -C.sub.8 -cycloalkyl--CH.sub.2 --(X).sub.p --, C.sub.1 -C.sub.12 alkyl--C.sub.3 -C.sub.8 cycloalkyl--CH.sub.2 --(X).sub.p --, C.sub.6 -C.sub.10 aryl--X--, C.sub.7 -C.sub.20 alkaryl--X--, C.sub.7 -C.sub.12 aralkyl--(X).sub.p -- or C.sub.8 -C.sub.20 --alkaralkyl--(X).sub.p -- or --Y--(C.sub.m H.sub.2m --O)--.sub.n R.sup.10 each of which is unsubstituted or substituted by --F, --OH, --CN, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 acyloxy or --COOR.sup.10 ; R.sup.10 is H or C.sub.1 -C.sub.18 alkyl, X is --O--, --S--, --SO-- or --SO.sub.2 -- and Y is --O-- or --S--, and p is 0 or 1, m is a number from 2 to 6 and n is a number from 2 to 20; and R.sup.9 is C.sub.1 -C.sub.4 acyl which is unsubstituted or substituted by --F. The compounds are intermediates for the preparation of 5,6,11,12-tetrathiotetracenes which form electrically conducting charge-transfer complexes with electron donors.
摘要翻译：其中R 1至R 8彼此独立地为H并且R 1至R 8中的至少一个为属于-F，-Si（C 1 -C 4烷基）3或 - 的基团的式I的化合物（I） COOR10; 或R 1至R 8的每对相邻基团是-CO-O-CO-; 或者R 1至R 8中的至少一个为C 1 -C 20烷基 - （X）对，C 2 -C 20烯基 - （X）对，C 2 -C 20炔基 - （X）对 - ，C 3 -C 8环烷基 - （X），（C 1 -C 12烷基-C 3 -C 8环烷基 - （X）对 - ，C 3 -C 8 - 环烷基-CH 2 - （X）对，C 1 -C 12烷基-C 3 -C 8环烷基-CH 2 - （X） X，C7-C20烷芳基 - （X）对或C8-C20-烷基烷基 - （X）对 - 或-Y-（CmH2m-O）-n10，其各自未被取代或被 -F，-OH，-CN，C 1 -C 12烷氧基，C 1 -C 12酰氧基或-COOR 10; R 10是H或C 1 -C 18烷基，X是-O - ， - S - ， - SO-或-SO 2 - ，Y是-O - 或-S-，p为0或1，m为2至6的数，n为2至20的数; R9为未被取代或被-F取代的C1-C4酰基，化合物为中间体用于制备与电子给体形成导电电荷转移复合物的5,6,11,12-四硫代四烯。

9. 发明授权

US4385182A Thioxanthonecarboxylic acids and thioxanthonecarboxylic acid derivatives 失效
标题翻译：噻吨酮羧酸和噻吨酮衍生物
公开(公告)号：US4385182A
公开(公告)日：1983-05-24
申请号：US258267
申请日：1981-04-28
申请人： Walter Fischer , Vratislav Kvita , Hans Zweifel , Louis Felder
发明人： Walter Fischer , Vratislav Kvita , Hans Zweifel , Louis Felder
IPC分类号： C07D335/06 , C07D335/16 , C07D409/04 , C08F2/00 , C08F2/48 , C08F2/50 , C08F4/32 , C08K5/45 , G03F7/031
CPC分类号： G03F7/031 , C07D335/16 , C08F2/50 , C08K5/45 , Y10S430/116
摘要： Novel thioxanthonecarboxylic acids and thioxanthonecarboxylic acid derivatives of the formula I ##STR1## in which Y is --COOH, --CO-halogen, --CN or a carboxylic acid ester, thioester or amide group and X, Z and W are as defined in the patent claim, are described. The compounds of the formula I in which Y is other than --CO--halogen are suitable as sensitizers for photo-crosslinkable polymers or as initiators for photo-polymerization of ethylenically unsaturated compounds or for photo-chemical crosslinking of polyolefins. The acid halides of the formula I are starting materials for the preparation of the corresponding nitriles and carboxylic acid esters, thioesters and amides.
摘要翻译：其中Y是-COOH，-CO-卤素，-CN或羧酸酯，硫酯或酰胺基，X，Z和W的式I的噻吨酮羧酸和噻吨酮羧酸衍生物（I）如上所定义在专利权利要求中描述。其中Y不是-CO-卤素的式I化合物适合作为光可交联聚合物的敏化剂或作为烯属不饱和化合物光聚合的引发剂或聚烯烃的光化学交联。式I的酰卤为制备相应的腈和羧酸酯，硫酯和酰胺的起始原料。

10. 发明授权

US4480105A 3,5-Disubstituted phthalic acids and phthalic anhydrides 失效
标题翻译： 3,5-二取代邻苯二甲酸和邻苯二甲酸酐
公开(公告)号：US4480105A
公开(公告)日：1984-10-30
申请号：US373573
申请日：1982-04-30
申请人： Walter Fischer , Vratislav Kvita , Hans Zweifel
发明人： Walter Fischer , Vratislav Kvita , Hans Zweifel
IPC分类号： C07C67/00 , C07C313/00 , C07C323/62 , C07C323/65 , C07C323/66 , C07D209/48 , C07D307/89 , C07D335/16 , C08F2/00 , C08F2/48 , C08F2/50 , C08F4/00 , C08F4/32 , C08F10/00 , C08J3/24 , C08J3/28 , C08K5/37 , G03F7/031 , G03F7/038
CPC分类号： C07D209/48 , C07C323/00 , C07D307/89 , C08F10/00 , G03F7/031
摘要： Novel compounds of the formula II ##STR1## are described, in which M.sub.1 and M.sub.2 individually are --OH or together are --O--, X is --NO.sub.2, --OR', --SR' or SO.sub.2 R' and the (R')s independently of one another are C.sub.1-20 -alkyl, C.sub.3-5 -alkenyl, C.sub.3-5 -alkynyl, C.sub.2-4 -monohydroxyalkyl, C.sub.1-12 -halogenoalkyl, benzyl, C.sub.5-12 -cycloalkyl, phenyl, carboxyphenyl, halogenophenyl, nitrophenyl, alkyl- or alkoxy-phenyl each having 1-4 C atoms in the alkyl or alkoxy moieties, or acetylaminophenyl, such as for example 3-n-butylthio-5-nitrophthalic anhydride. The compounds (II) in which M.sub.1 and M.sub.2 together are --O-- are suitable as sensitizers for photo-crosslinkable polymers or as initiators for the photopolymerization of ethylenically unsaturated compounds or for the photochemical crosslinking of polyolefins, and those where M.sub.1 and M.sub.2 are --OH are useful intermediates for those wherein M.sub.1 and M.sub.2 together are --O--.
摘要翻译：描述了式II（II）的新型化合物，其中M1和M2各自为-OH或一起为-O-，X为-NO 2，-OR'，-SR'或SO 2 R'，（R C 1-6烷基，C 5-8 - 烯基，C 3-8 - 炔基，C 2-4 - 单羟基烷基，C 1-12 - 卤代烷基，苄基，C 5-12 - 环烷基，苯基，羧基苯基，卤代苯基，硝基苯基，烷基或烷氧基 - 苯基，各自在烷基或烷氧基部分具有1-4个C原子，或乙酰氨基苯基，如3-正丁硫基-5-硝基邻苯二甲酸酐。其中M1和M2一起为-O-的化合物（II）适用作光可交联聚合物的敏化剂或作为烯属不饱和化合物的光聚合引发剂或聚烯烃的光化学交联的引发剂，以及M1和M2为 - OH是其中M1和M2一起为-O-的那些的有用的中间体。

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