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1. 发明授权

US5011944A Substituted .alpha.-pyrones 失效
标题翻译：取代的α-吡喃酮
公开(公告)号：US5011944A
公开(公告)日：1991-04-30
申请号：US356825
申请日：1989-05-24
申请人： Vratislav Kvita , Marcus Baumann , Walter Fischer , Carl W. Mayer , Thomas Allmendinger
发明人： Vratislav Kvita , Marcus Baumann , Walter Fischer , Carl W. Mayer , Thomas Allmendinger
IPC分类号： C07D309/30 , B05D1/20 , C07C45/00 , C07C50/24 , C07C67/00 , C07C69/95 , C07D309/38 , C07F7/08 , C07F7/18 , C08G61/12 , C09K9/02 , H01B1/12
CPC分类号： B05D1/202 , B82Y30/00 , B82Y40/00 , C07D309/38 , C08G61/123 , C09K9/02 , H01B1/121
摘要： .alpha.-Pyrones of the formula I ##STR1## in which R.sup.1 is --CF.sub.3 or --COOR.sup.3 and R.sup.3 is the radical of a C.sub.1 -C.sub.18 alcohol diminished by a hydroxyl group, and R.sup.2 is --F, --Br, --Cl, --CN, --CF.sub.3, C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.18 alkenyl, C.sub.2 -C.sub.18 alkynyl, C.sub.1 -C.sub.18 alkoxy, C.sub.1 -C.sub.18 alkylthio, C.sub.1 -C.sub.18 alkylsulfonyl, C.sub.6 -C.sub.16 aryl, C.sub.7 -C.sub.24 alkaryl, C.sub.7 -C.sub.12 aralkyl, C.sub.8 -C.sub.24 alkaralkyl, C.sub.6 -C.sub.16 aryloxy, C.sub.6 -C.sub.16 arylthio, C.sub.6 -C.sub.16 arylsulfonyl, C.sub.7 -C.sub.24 alkaryloxy, C.sub.7 -C.sub.24 alkarylthio, C.sub.7 -C.sub.24 alkarylsulfonyl, C.sub.7 -C.sub.12 aralkyloxy, C.sub.7 -C.sub.12 aralkylthio, C.sub.7 -C.sub.12 aralkylsulfonyl, C.sub.8 -C.sub.24 alkaralyloxy, C.sub.8 -C.sub.24 alkaralylthio, C.sub.8 -C.sub.24 alkaralylsulfonyl, secondary amine having 2 to 24 C atoms or trialkylsilyl or trialkoxysilyl each of which has 3 to 18 C atoms. They are suitable for the preparation of naphtho-1,4-quinones and anthra-1,4-quinones, from which tetrathiotetracenes or tetraselenotetracenes having electrochromic properties can be obtained.
摘要翻译：其中R 1为-CF 3或-COOR 3且R 3为被羟基减弱的C 1 -C 18醇基团的式I（I）的α-吡喃酮，R2为-F，-Br，-Cl ，-CN，-CF 3，C 1 -C 18烷基，C 2 -C 18烯基，C 2 -C 18炔基，C 1 -C 18烷氧基，C 1 -C 18烷硫基，C 1 -C 18烷基磺酰基，C 6 -C 16芳基，C 7 -C 24烷芳基，C 7 -C 12芳烷基，C 8 -C 24烷基烷基，C 6 -C 16芳氧基，C 6 -C 16芳硫基，C 6 -C 16芳基磺酰基，C 7 -C 24链烯氧基，C 7 -C 24烷芳硫基，C 7 -C 24烷芳基磺酰基，C 7 -C 12芳烷氧基，C 7 -C 12芳烷硫基，C 7 -C 12芳烷基磺酰基，C 8 -C 24链烷氧基，C 8 -C 24烷酰基硫代，C 8 -C 24烷酰基磺酰基， 24个C原子或三烷基甲硅烷基或三烷氧基甲硅烷基，各自具有3至18个C原子。它们适用于制备萘并-1,4-醌和蒽-1,4-醌，可从中得到具有电致变色特性的四硫代四烯或四硒代四烯。

2. 发明授权

US4367324A Photocrosslinkable polymers with thioxanthone and imidyl groupings in side chains 失效
标题翻译：侧链中具有噻吨酮和亚氨基基团的可光交联聚合物
公开(公告)号：US4367324A
公开(公告)日：1983-01-04
申请号：US228817
申请日：1981-01-26
申请人： Hans Zweifel , Joseph Berger , Vratislav Kvita , Martin Roth
发明人： Hans Zweifel , Joseph Berger , Vratislav Kvita , Martin Roth
IPC分类号： C08F16/00 , C08F8/30 , C08F8/34 , C08F16/02 , C08F18/00 , C08F18/02 , C08F20/00 , C08F20/38 , C08F20/52 , C08F22/36 , C08F26/00 , C08F28/00 , C08F222/40 , C08F246/00 , C08F290/00 , C08F299/00 , G03F7/038 , C08F26/06 , C08F28/06
CPC分类号： G03F7/0388 , C08F222/40 , C08F246/00 , C08F8/30 , C08F8/34 , Y10S522/904
摘要： Photocrosslinkable polymers which have a mean molecular weight of not less than 5,000 and contain, in side chains, thioxanthone groupings of the formula ##STR1## and, in side chains, imidyl groupings of the formula ##STR2## in which X, Y, Z, n, G.sub.1 and G.sub.2 are as defined in the patent claim, are suitable for the production of highly light-sensitive image materials, for the production of printing plates for the offset printing process and in particular as so-called photoresists for the production of printed circuits. The thioxanthone groupings (I) act as sensitizers for the photocrosslinkable groups of the polymer, so that it is not necessary to add further sensitizers.
摘要翻译：平均分子量不小于5,000并且在侧链中含有式（I）的噻吨酮基团和在侧链中含有式（II）的亚氨基基团的光可交联聚合物，其中 X，Y，Z，n，G1和G2如专利权利要求中所定义，适用于生产高光敏图像材料，用于生产胶版印刷工艺的印版，特别是所谓的光刻胶生产印刷电路。噻吨酮组（I）作为聚合物的光致交联基团的敏化剂，因此不需要再添加敏化剂。

3. 发明授权

US4348530A Thioxanthonecarboxylic acids, esters, thioesters and amides with reactive functional groups 失效
标题翻译：具有反应性官能团的噻吨酮羧酸，酯，硫酯和酰胺
公开(公告)号：US4348530A
公开(公告)日：1982-09-07
申请号：US228533
申请日：1981-01-26
申请人： Vratislav Kvita , Hans Zweifel , Martin Roth , Louis Felder
发明人： Vratislav Kvita , Hans Zweifel , Martin Roth , Louis Felder
IPC分类号： C07D209/48 , C07D335/16 , C07D409/12 , C08F2/00 , C08F2/50 , C08F20/38 , C08G63/688 , C08G85/00 , C08K5/45 , C08L23/02 , C09D11/00 , C09D11/10 , G03F7/031 , G03F7/032 , G03F7/038
CPC分类号： C07D209/48 , C07C323/00 , C07D335/16 , C08F2/50 , C08F20/38 , C08G63/688 , C08G85/00 , C08G85/004 , C08K5/45 , C08L23/02 , G03F7/031 , G03F7/032 , G03F7/0388 , Y10S522/904
摘要： Thioxanthone carboxylic acid esters, thioesters and amides with reactive functional groups of the formula ##STR1## in which X, Y, Z, n and Q are as defined in the patent claim and Q is, for example, --OCH.dbd.CH.sub.2, --OCH.sub.2 CH.dbd.CH.sub.2, --SCH.sub.2 CH.dbd.CH.sub.2 or --NHCH.sub.2 CH.dbd.CH.sub.2 (n=1), --OH, --SH, --NH.sub.2, --COOH, --COCl or --OCO--C(R").dbd.CH.sub.2, in which R" is methyl or hydrogen (n=2), are suitable for the preparation of polymers with thioxanthone radicals in side chains. The compounds (I) and also the polymers which can be prepared therefrom can be employed as sensitisers for photocrosslinkable polymers or as initiators, if desired in a mixture with amines, for the photopolymerisation of ethylenically unsaturated compounds or for the photochemical crosslinking of polyolefines.
摘要翻译：具有式（I）的反应性官能团的噻吨酮羧酸酯，硫酯和酰胺，其中X，Y，Z，n和Q如专利权利要求和Q中所定义，是例如-OCH = CH 2 ，-OCH 2 CH = CH 2，-SCH 2 CH = CH 2或-NHCH 2 CH = CH 2（n = 1），-OH，-SH，-NH 2，-COOH，-COCl或-OCO-C（R“ R“是甲基或氢（n = 2），适用于在侧链中制备具有噻吨酮基团的聚合物。化合物（I）以及可由其制备的聚合物可以用作光可交联聚合物的敏化剂，或者如果需要，在与胺的混合物中用作烯键式不饱和化合物的光聚合或用于聚烯烃的光化学交联的引发剂。

4. 发明授权

US4233220A Imidyl-benzene-dicarboxylic and -tricarboxylic acid derivatives 失效
标题翻译：苯偶姻 - 苯二羧酸和三羧酸衍生物
公开(公告)号：US4233220A
公开(公告)日：1980-11-11
申请号：US951432
申请日：1978-10-16
申请人： Vratislav Kvita , Roland Darms , Gerd Greber
发明人： Vratislav Kvita , Roland Darms , Gerd Greber
IPC分类号： C07D209/48 , C07D207/44 , C07D207/452 , C07D209/76 , C07D307/89 , C07D405/04 , C07D405/14 , C07D491/18 , C07D493/08 , C07D493/18 , C08G59/00 , C08G59/40 , C08G59/42 , C08G59/48 , C08G73/12 , C07D403/02 , C07D405/02
CPC分类号： C07D207/452 , C07D307/89 , C08G59/4042 , C08G59/4223 , C08G73/12
摘要： New imidyl-benzene-dicarboxylic and -tricarboxylic acid derivatives, in particular 5-maleimidyl-trimellitic acid derivatives and 3,5-bis-(maleimidyl)-phthalic acid derivatives, and a process for their manufacture are described. These imidylbenzene-dicarboxylic and -tricarboxylic acid derivatives are suitable for the manufacture of crosslinkable polymers, above all polycondensation and polymerization products, which are distinguished by good processability and good solubility in customary organic solvents. Imidyl compounds, according to the definition, which have anhydride groups can also be used as curing agents for optionally modified epoxide resins.
摘要翻译：描述了新的亚氨基 - 苯 - 二羧酸和三羧酸衍生物，特别是5-马来酰亚胺基偏苯三酸衍生物和3,5-双 - （马来酰亚胺基） - 邻苯二甲酸衍生物及其制备方法。这些亚氨基苯二羧酸和三羧酸衍生物适用于制造可交联聚合物，尤其是缩聚和聚合产物，其特征在于加工性良好，在常规有机溶剂中具有良好的溶解性。根据具有酸酐基团的定义的酰亚胺基化合物也可以用作任选改性的环氧树脂的固化剂。

5. 发明授权

US4197133A Photo-curable compositions of matter containing bis-azidophthalimidyl derivatives 失效
标题翻译：含有双叠氮基邻苯二甲酰亚胺基衍生物的光固化组合物
公开(公告)号：US4197133A
公开(公告)日：1980-04-08
申请号：US948856
申请日：1978-10-05
申请人： Hans Zweifel , Vratislav Kvita
发明人： Hans Zweifel , Vratislav Kvita
IPC分类号： C08K5/00 , C07D209/48 , C08K5/3412 , C08K5/3417 , C08L23/00 , C08L33/00 , C08L33/02 , C08L101/00 , G03F7/008 , G03G5/00 , G03C1/68 , G03C1/52
CPC分类号： C07D209/48 , C08K5/3417 , G03F7/008
摘要： The compositons of matter according to the invention consist of at least one polymeric compound and at least one compound of the formula I ##STR1## in which R is a divalent organic radical. The weight ratio of polymer to compound of the formula I is about 9:1 to 1:4.The compounds of the formula I and thus also the compositions of matter are photo-curable (-crosslinkable). They are superior to known systems in respect of heat stability and oxidation resistance, while possessing photosensitivity which is equally as good.
摘要翻译：根据本发明的物质组合物由至少一种聚合化合物和至少一种其中R是二价有机基团的式I（I）化合物组成。聚合物与式I化合物的重量比为约9:1至1:4。式I的化合物以及因此的物质组成是可光固化的（可交联的）。它们在热稳定性和抗氧化性方面优于已知的体系，同时具有同样好的光敏性。

6. 发明授权

US4134895A Imidyl-benzenedicarboxylic acid derivatives 失效
标题翻译：亚氨基 - 苯二甲酸衍生物
公开(公告)号：US4134895A
公开(公告)日：1979-01-16
申请号：US696347
申请日：1976-06-15
申请人： Martin Roth , Vratislav Kvita , Gerd Greber
发明人： Martin Roth , Vratislav Kvita , Gerd Greber
IPC分类号： C07D209/48 , C07D207/44 , C07D207/452 , C07D207/456 , C07D209/76 , C07D491/18 , C08F20/00 , C08F20/52 , C08F22/40 , C08G59/40 , C08G59/42 , C08G59/48 , C08G63/685 , C08G69/02 , C08G69/26 , C08G69/32 , C08G69/44 , C08G73/00 , C08G73/10 , C08G73/12 , C07D403/02
CPC分类号： C07D207/452 , C07D209/76 , C08F22/40 , C08G63/6854 , C08G69/02 , C08G69/265 , C08G69/32 , C08G69/44 , C08G73/12
摘要： New imidyl-benzenedicarboxylic acid derivatives, in particular 5-maleimidyl-isophthalic acid derivatives and 5-(nadic acid-imidyl)-isophthalic acid derivatives, and a process for their manufacture are described. These imidyl-benzenedicarboxylic acid derivatives are suitable for the manufacture of crosslinkable polymers, above all polycondensation and polymerization products, which are distinguished by good processability and good solubility in the customary organic solvents.
摘要翻译：描述了新的亚氨基 - 苯二甲酸衍生物，特别是5-马来酰亚胺基间苯二酸衍生物和5-（萘二甲酸 - 亚氨基） - 间苯二甲酸衍生物及其制备方法。这些亚氨基 - 苯二甲酸衍生物适用于制造可交联聚合物，尤其是缩聚和聚合产物，其特征在于良好的加工性和在常规有机溶剂中的良好溶解性。

7. 发明授权

US4110188A Crosslinkable mixtures of bis-imidyl derivatives 失效
标题翻译：双嘧啶衍生物的交联混合物
公开(公告)号：US4110188A
公开(公告)日：1978-08-29
申请号：US748015
申请日：1976-12-06
申请人： Roland Darms , Vratislav Kvita , Gerd Greber
发明人： Roland Darms , Vratislav Kvita , Gerd Greber
IPC分类号： C08G73/00 , C08G73/10 , C08G73/12
CPC分类号： C08G73/12
摘要： Crosslinkable mixtures of bis-imidyl derivatives and diamines are described, for example of the bis-imide of 2 moles of 3-maleimidyl-phthalic acid anhydride and one mole of 4,4'-diaminodiphenylmethane and a diamine. These mixtures are characterized by their good solubility in a large number of organic solvents, and they can also be processed from the melt. The crosslinked products obtainable therefrom are distinguished in particular by their good thermooxidative stability.

8. 发明授权

US5112977A Substituted naphthacene-5,12-diones 失效
标题翻译：取代的萘醌-5,12-二酮
公开(公告)号：US5112977A
公开(公告)日：1992-05-12
申请号：US356830
申请日：1989-05-24
申请人： Walter Fischer , Marcus Baumann , Jurgen Finter , Vratislav Kvita , Carl W. Mayer , Wolfgang Wernet
发明人： Walter Fischer , Marcus Baumann , Jurgen Finter , Vratislav Kvita , Carl W. Mayer , Wolfgang Wernet
IPC分类号： G03F7/028 , B05D1/20 , C07C45/00 , C07C50/24 , C07C50/36 , C07C66/00 , C07C67/00 , C07C69/00 , C07C69/738 , C07C201/00 , C07C205/46 , C07C205/48 , C07C211/61 , C07C225/32 , C07C235/40 , C07C255/40 , C07C255/41 , C07C255/56 , C07C255/57 , C07C317/24 , C07C323/20 , C07C323/22 , C07D295/10 , C07D295/116 , C07D307/12 , C07F7/08 , C08F2/50 , C08G61/12 , C08K5/08 , C08K5/10 , C08K5/13 , C08K5/36 , C09B3/58 , H01B1/12
CPC分类号： C07D295/116 , B05D1/202 , B82Y30/00 , B82Y40/00 , C07C205/48 , C07C225/32 , C07C255/40 , C07C255/41 , C07C255/56 , C07C323/20 , C07C323/22 , C07C50/24 , C07C50/36 , C07C69/00 , C07D307/12 , C07F7/0818 , C08F2/50 , C08G61/123 , H01B1/121 , C07C2101/02 , C07C2103/00 , C07C2103/44
摘要： Substituted naphthacenediones of the formula I ##STR1## in which R.sup.1 to R.sup.8 are H and at least one of R.sup.1 to R.sup.8, for example R.sup.2 and R.sup.3 or R.sup.2 and R.sup.6, are, for example, C.sub.1 -C.sub.20 alkoxy, C.sub.1 -C.sub.20 alkenoxy, C.sub.1 -C.sub.20 -alkylsulfinyl, --CN, --CF.sub.3, --NO.sub.2, --Si(CH.sub.3).sub.3 or --COO(C.sub.1 -C.sub.12 alkyl), are suitable, when incorporated into polymers having hydroxyalkyl groups, for currentless deposition of metals onto the polymer surface. They are in some cases suitable as photoinitiators.
摘要翻译：其中R 1至R 8为H并且R 1至R 8中的至少一个，例如R 2和R 3或R 2和R 6的取代的对映体萘并吖啶为例如C 1 -C 20烷氧基，C 1 -C 20链烯氧基，当C 1 -C 20烷基亚磺酰基，-CN，-CF 3，-NO 2，-Si（CH 3）3或-COO（C 1 -C 12烷基）掺入到具有羟烷基的聚合物中时，适用于金属在聚合物上无电沉积表面。在某些情况下，它们适合作为光引发剂。

9. 发明授权

US5004814A Substituted .alpha.-pyrones and process for their preparation 失效
标题翻译：取代的α-吡喃酮及其制备方法
公开(公告)号：US5004814A
公开(公告)日：1991-04-02
申请号：US421573
申请日：1989-10-16
申请人： Vratislav Kvita
发明人： Vratislav Kvita
IPC分类号： G03F7/028 , C07D309/38 , C08F2/50
CPC分类号： C07D309/38
摘要： The invention relates to .alpha.-pyrones of formula I ##STR1## wherein R.sup.1 is chloro or bromo and R.sup.2 is hydrogen, chloro or bromo. The halogen in 4-position can be replaced, for example, by alkoxy, alkylthio or secondary amino. The .alpha.-pyrones are suitable diene components for Diels-Alder reactions.
摘要翻译：本发明涉及式Ⅰ的α-吡喃酮（Ⅰ），其中R1是氯或溴，R2是氢，氯或溴。 4-位的卤素可以被例如烷氧基，烷硫基或仲氨基取代。 α-吡喃酮是Diels-Alder反应的合适的二烯成分。

10. 发明授权

US4981962A Substituted tetrathiotetracenes and tetraselenotetracenes 失效
公开(公告)号：US4981962A
公开(公告)日：1991-01-01
申请号：US356824
申请日：1989-05-24
申请人： Marcus Baumann , Walter Fischer , Vratislav Kvita , Carl W. Mayer , Wolfgang Wernet
发明人： Marcus Baumann , Walter Fischer , Vratislav Kvita , Carl W. Mayer , Wolfgang Wernet
IPC分类号： B05D1/20 , C07D495/06 , C07D517/06 , C07D517/16 , C08G61/12 , C09K9/02 , H01B1/12
CPC分类号： C07D495/06 , B05D1/202 , B82Y30/00 , B82Y40/00 , C07D517/06 , C07D517/08 , C08G61/123 , C09K9/02 , H01B1/121
摘要： Substituted tetrathiotetracenes and tetraselenotetracenes of the formula I ##STR1## in which Z is --S-- or --Se-- and (a) R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are H and R.sup.5 to R.sup.8 are each H and at least one of the radicals R.sup.5 to R.sup.8 independently of one another is a substituent belonging to the group comprising C.sub.1 -C.sub.20 alkyl--X--.sub.p which is unsubstituted or substituted by halogen, --CN, --CONR.sup.9 R.sup.10, --OR.sup.9, --SR.sup.9 or --COOR.sup.9, with the exception of C.sub.1 -C.sub.4 alkyl and methoxy, C.sub.2 -C.sub.18 alkenyl--X--.sub.p, C.sub.2 -C.sub.18 -alkynyl--X--.sub.p, C.sub.3 -C.sub.8 cycloalkyl--X--.sub.p, (C.sub.1 -C.sub.12 alkyl)--C.sub.3 -C.sub.8 cycloalkyl--X--.sub.p, C.sub.3 -C.sub.8 cycloalkyl-C.sub.r H.sub.2r --X--.sub.p, (C.sub.1 -C.sub.12 alkyl)-C.sub.3 -C.sub.8 -cyclo alkyl-C.sub.r H.sub.2r --X--.sub.p, phenyl--X--.sub.p, (C.sub.1 -C.sub.12)alkyl)-phenyl--X--, phenyl-C.sub.r H.sub. 2r --X--.sub.p and (C.sub.1 -C.sub.12 alkyl)-phenyl-C.sub.r H.sub.2r --X--.sub.p, r is 1 or 2 and p is 0 or 1 and X is --O--, --S--, --SO-- or --SO.sub.2 --, or R.sup.5 to R.sup.8 independently are a substituent belonging to the group comprising --Br, --CF.sub.3, --CN, --Si(C.sub.1 -C.sub.4 alkyl).sub.3, --S--(C.sub.m H.sub.2m O)--.sub.n R.sup.11 or --O--C.sub.m H.sub.2m --O--R.sup.11, or each one of R.sup.5 to R.sup.8 is --F or --Cl and at least one further member of R.sup.5 to R.sup.8 is a substituent of the groups defined above, including C.sub.1 -C.sub.4 alkyl and methoxy, R.sup.9 and R.sup.10 independently of one another are H, C.sub.1 -C.sub.12 alkyl, phenyl or --C.sub.m H.sub.2m --O--.sub.q R.sup.11, or R.sup.9 and R.sup.10 together are tetramethylene, pentamethylene, 3-oxapentylene or --CH.sub.2 CH.sub.2 NR.sup.9 CH.sub.2 CH.sub.2 --, R.sup.11 is H or C.sub.1 -C.sub.12 -alkyl, m is a number from 2 to 4, n is a number from 2 to 20 and q is a number from 1 to 20, orb) R.sup.1 to R.sup.8 independently of one another are H or one of the substituents defined above, including C.sub.1 -C.sub.4 alkyl and methoxy, or --COOR.sup.9 or --CONR.sup.9 R.sup.10 or two pairs of adjacent radicals of R.sup.1 to R.sup.8 are --CO--O--CO-- or --CO--NR.sup.9 --CO--, and at least one of R.sup.1 to R.sup.4 and also R.sup.5 to R.sup.8 is a substituent, with the exception of R.sup.2, R.sup.3, R.sup.6 and R.sup.7 when these are --F and methyl, and where R.sup.9 and R.sup.10 are as defined above.With electron acceptors they form charge-transfer complexes which can be used as organic electrical conductors, displays, optical switches and sensors.

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