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    • 3. 发明申请
    • (METH)ALLYLSILANE COMPOUND, SILANE COUPLING AGENT THEREFOR, AND FUNCTIONAL MATERIAL USING SAME
    • (METH)全甲硅烷化合物,硅烷偶联剂及其功能材料
    • US20140142292A1
    • 2014-05-22
    • US14129416
    • 2012-06-28
    • Toyoshi Shimada
    • Toyoshi Shimada
    • C07F7/08C07H23/00
    • C07F7/0818C03C17/30C03C2217/75C07F7/081C07F7/0812C07H23/00C08B15/05C08B37/0012C08J3/126C08J3/128C08K9/06C08K9/08C09C3/12C09K3/18
    • A (meth)allylsilane compound chemically bonded to various alcohol derivatives including polyol derivatives such as saccharides, is raw material used to cause a substrate to express functionalities such as a defogging property and separation characteristics for column chromatography, can be easily prepared, is easily purified, and is stable and easy to handle, and a functional material in which those functionalities are expressed, while silyl group-containing groups are conveniently carried at a high density on the surface of the substrate, by using the (meth)allylsilane compound as a silane coupling agent for silane-coupling to the substrate. The (meth)allylsilane compound includes a (meth)allylsilyl group-containing alkyl group or a (meth)allylsilylalkyl group-containing aralkyl group that is bonded to an alcohol derivative. In the functional material, the silane coupling agent is ether-bonded to surface hydroxyl groups exposed on a substrate through the surface hydroxyl groups by silane coupling to have an ether bond on the functional material.
    • 化学键合到各种醇衍生物(包括多元醇衍生物如糖类)上的(甲基)烯丙基硅烷化合物可以容易地制备,用于引起底物表达诸如除雾性能和柱色谱分离特性等功能的原料 并且稳定且易于处理,并且通过使用(甲基)烯丙基硅烷化合物作为基质,通过在基材的表面上方便地以高密度方式携带含有甲硅烷基的基团,其中表达这些官能团的官能材料 用于硅烷耦合到基底的硅烷偶联剂。 (甲基)烯丙基硅烷化合物包含(甲基)烯丙基含烷基或与醇衍生物结合的(甲基)丙烯酰基烷基烷基。 在功能材料中,硅烷偶联剂通过硅烷偶联通过表面羟基与基体上露出的表面羟基醚键合,在功能材料上具有醚键。