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    • 10. 发明授权
    • Method for modified aminoplast compounds, aminoplasts obtained thereby
and coatings containing the same
    • 修饰氨基塑料化合物的方法,由此获得的氨基塑料和含有它们的涂层
    • US5777048A
    • 1998-07-07
    • US667261
    • 1996-06-20
    • Walter H. OhrbomDonald H. CampbellDonald L. St. Aubin
    • Walter H. OhrbomDonald H. CampbellDonald L. St. Aubin
    • C08G12/40C08G18/80C09D161/20C09D201/00C09D201/02C08F8/30
    • C09D201/025C08G12/40C08G18/8077C09D161/20C09D201/02
    • A method for reducing the molecular weight of aminoplast compounds, the aminoplast compounds obtained thereby, and coating compositions containing said aminoplast compounds are provided. The reduced molecular weight aminoplasts are obtained by reacting (a) an aminoplast compound, having a total number (y) of reactive substituents on the amino nitrogens of the aminoplast, where y=(E.times.M) and E=equivalents per mole of aminoplast and M=total number of moles of aminoplast, wherein the reactive substituents are selected from the group consisting of --NH, alkylol, alkoxy, alkoxyalkyl, and mixtures thereof and(b) at least one carbamate compound selected from the group consisting of unsubstituted and substituted primary carbamate compounds, unsubstituted and substituted secondary carbamate compounds and mixtures thereof, in the presence of primary or secondary alcohols, at temperatures under 150.degree. C., and at pressures ranging between atmospheric pressure and 20 atm pressure, to form a functionalized aminoplast compound, wherein at least one and up to (y-1) of the amino substituents on the aminoplast are substituted with the carbamate functionality.
    • 提供了降低氨基塑料化合物的分子量,由此获得的氨基塑料化合物和含有所述氨基塑料化合物的涂料组合物的方法。 通过使(a)在氨基塑料的氨基氮上具有总数(y)的反应性取代基的氨基塑料化合物,其中y =(ExM)和E =每摩尔氨基塑料的当量和M =氨基塑料的总摩尔数,其中反应性取代基选自-NH,羟烷基,烷氧基,烷氧基烷基及其混合物,和(b)至少一种选自未取代和取代的伯 氨基甲酸酯化合物,未取代和取代的仲氨基甲酸酯化合物及其混合物,在初级醇或仲醇的存在下,在150℃的温度和在大气压和20atm压力之间的压力下形成官能化的氨基塑料化合物,其中 氨基塑料上氨基取代基的至少一个和至多(y-1)被氨基甲酸酯官能团取代。