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1. 发明授权

US08008416B2 Curable alkoxycarbonylamino compositions, coatings, and methods 有权
标题翻译：可固化的烷氧基羰基氨基组合物，涂料和方法
公开(公告)号：US08008416B2
公开(公告)日：2011-08-30
申请号：US12345237
申请日：2008-12-29
申请人： Walter H. Ohrbom
发明人： Walter H. Ohrbom
IPC分类号： C08F26/02
CPC分类号： C07C271/16 , C07C271/64
摘要： A compound, oligomer, or polymer having a functional group of formula (I) wherein R is a group having 1 to 12 carbons and optionally including one or more heteroatoms selected from oxygen, nitrogen, and sulfur is useful in curable compositions having active hydrogen functional groups reactive with group (I). The functional groups of formula (I) and active hydrogen functional groups may be part of the same material or different materials. In some embodiments a filler is surface modified to have a functional group of formula (I). Also disclosed is a method of making a material having a functional group of formula (I).
摘要翻译：具有式（I）官能团的化合物，低聚物或聚合物可用于具有活性氢官能团的可固化组合物中，其中R是具有1至12个碳原子并且任选地包含一个或多个选自氧，氮和硫的杂原子的基团组与组（I）反应。式（I）和活性氢官能团的官能团可以是相同材料或不同材料的一部分。在一些实施方案中，填料被表面改性以具有式（I）的官能团。还公开了制备具有式（I）的官能团的材料的方法。

2. 发明授权

US07772304B2 Plasticizing component and a curable coating composition including the same 有权
标题翻译：增塑组分和包含其的可固化涂料组合物
公开(公告)号：US07772304B2
公开(公告)日：2010-08-10
申请号：US11560932
申请日：2006-11-17
申请人： Walter H. Ohrbom , John E. Boisseau
发明人： Walter H. Ohrbom , John E. Boisseau
IPC分类号： C08K5/3492 , C07D251/30
CPC分类号： C09D133/066 , C09D133/14
摘要： A curable coating composition includes a plasticizing component. The plasticizing component includes an isocyanurate core and at least one low surface tension group pending from the isocyanurate core. The low surface tension group may be a) a fatty chain includes at least 6 carbon atoms, b) a silicon-containing group having at least 1 silicon atom, c) a fluorocarbon, and combinations thereof. The low surface tension group may have cross-linkable functional groups pending therefrom. In addition to the plasticizing component, the curable coating composition further includes a resin component and a crosslinking agent that is reactive with the resin component. The curable coating composition including the plasticizing component is capable of forming a cured film that has resistance to both cracking and etching that, to date, has not been achieved with known plasticizing components.
摘要翻译：可固化涂料组合物包括增塑组分。增塑组分包括异氰脲酸酯芯和至少一种从异氰脲酸酯芯悬浮的低表面张力组。低表面张力基团可以是a）脂肪链包含至少6个碳原子，b）具有至少1个硅原子的含硅基团，c）碳氟化合物及其组合。低表面张力组可能具有可交联的官能团。除了增塑组分之外，可固化涂料组合物还包括树脂组分和与树脂组分反应的交联剂。包含增塑组分的可固化涂料组合物能够形成耐开裂和蚀刻的固化膜，迄今为止，已知的增塑组分尚未实现。

3. 发明申请

US20080119592A1 PLASTICIZING COMPONENT AND A CURABLE COATING COMPOSITION INCLUDING THE SAME 有权
标题翻译：塑化组分和可固化的涂料组合物，包括它们
公开(公告)号：US20080119592A1
公开(公告)日：2008-05-22
申请号：US11560932
申请日：2006-11-17
申请人： Walter H. Ohrbom , John E. Boisseau
发明人： Walter H. Ohrbom , John E. Boisseau
IPC分类号： C08K5/3492 , C07D251/30
CPC分类号： C09D133/066 , C09D133/14
摘要： A curable coating composition includes a plasticizing component. The plasticizing component includes an isocyanurate core and at least one low surface tension group pending from the isocyanurate core. The low surface tension group may be a) a fatty chain includes at least 6 carbon atoms, b) a silicon-containing group having at least 1 silicon atom, c) a fluorocarbon, and combinations thereof. The low surface tension group may have cross-linkable functional groups pending therefrom. In addition to the plasticizing component, the curable coating composition further includes a resin component and a crosslinking agent that is reactive with the resin component. The curable coating composition including the plasticizing component is capable of forming a cured film that has resistance to both cracking and etching that, to date, has not been achieved with known plasticizing components.
摘要翻译：可固化涂料组合物包括增塑组分。增塑组分包括异氰脲酸酯芯和至少一种从异氰脲酸酯芯悬浮的低表面张力组。低表面张力基团可以是a）脂肪链包含至少6个碳原子，b）具有至少1个硅原子的含硅基团，c）碳氟化合物及其组合。低表面张力组可能具有可交联的官能团。除了增塑组分之外，可固化涂料组合物还包括树脂组分和与树脂组分反应的交联剂。包含增塑组分的可固化涂料组合物能够形成耐开裂和蚀刻的固化膜，迄今为止，已知的增塑组分尚未实现。

4. 发明授权

US07297749B2 Asymmetric polyisocyanate monomers in urethane polymers and oligomers to reduce crystallinity 失效
标题翻译：聚氨酯聚合物和低聚物中的不对称多异氰酸酯单体，以降低结晶度
公开(公告)号：US07297749B2
公开(公告)日：2007-11-20
申请号：US10965346
申请日：2004-10-14
申请人： Craig S. Schang , Walter H. Ohrbom , Joanne Casale , Thaddeus J. Lepkowski
发明人： Craig S. Schang , Walter H. Ohrbom , Joanne Casale , Thaddeus J. Lepkowski
IPC分类号： C08G18/70
CPC分类号： C09D175/04 , C08G18/8016 , C08G18/8058 , C08L2666/16
摘要： Compositions comprising a reaction product of a) an asymmetrical, saturated polyisocyanate that is non-cyclic, non-aromatic, and has at least 3 carbon atoms in the polyisocyanate per isocyanate group, b) a material that is at least one of i) a primary carbamate material having at least one functional group reactive with an isocyanate and at least one primary carbamate group or a group convertible to a primary carbamate group and ii) a reaction product of the primary carbamate material and an extending agent, and c) optionally, a chain extension agent that has at least difunctional reactivity with an isocyanate. Also, methods of making these compositions.
摘要翻译：包含a）不对称饱和多异氰酸酯的反应产物的组合物，其是非环状的，非芳族的，并且在每个异氰酸酯基团的多异氰酸酯中具有至少3个碳原子，b）至少一种i）具有至少一个与异氰酸酯和至少一个伯氨基甲酸酯基团或可转换成伯氨基甲酸酯基团的基团反应的官能团的主要氨基甲酸酯材料和ii）主要氨基甲酸酯材料和延伸剂的反应产物，和c）任选地，与异氰酸酯具有至少双官能反应性的扩链剂。而且，制备这些组合物的方法。

5. 发明授权

US07030263B2 Method of preparing a carbamate- or urea-functional compound 有权
公开(公告)号：US07030263B2
公开(公告)日：2006-04-18
申请号：US10280619
申请日：2002-10-25
申请人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
发明人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
IPC分类号： C08G63/64
CPC分类号： C09D175/02 , C07C269/04 , C07C269/06 , C07C273/1809 , C07C273/1854 , C08G18/4615 , C09D175/06 , Y10T428/31551 , C08L2666/16
摘要： A method of preparing a carbamate or urea-functional compound is described comprising the step of reacting a lactone or hydroxy carboxylic acid with a compound (A) comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group capable of reacting with the hydroxy carboxylic acid or in a ring-opening reaction with a lactone. The compound thus prepared is useful in curable compositions.

6. 发明授权

US06962730B2 Coating composition containing crosslinkable monomeric difunctional compounds having at least thirty carbon atoms 有权
标题翻译：包含具有至少30个碳原子的可交联单体双官能化合物的涂料组合物
公开(公告)号：US06962730B2
公开(公告)日：2005-11-08
申请号：US10351079
申请日：2003-01-23
申请人： Walter H. Ohrbom , John A. Gilbert , Patricia A. Herrel , Marvin L. Green , Joanne Casale , Thomas G. Savino
发明人： Walter H. Ohrbom , John A. Gilbert , Patricia A. Herrel , Marvin L. Green , Joanne Casale , Thomas G. Savino
IPC分类号： C09D5/02 , C09D133/14 , C09D201/00 , C09D201/02 , B05D3/00
CPC分类号： C09D5/02 , C09D133/14 , C09D201/00 , C09D201/02 , C09D201/025
摘要： The invention provides coating compositions comprising a reactive component (a) which is substantially free of any heteratoms and is a not a crystalline solid at room temperature and which comprises from (i) 12 to 72 carbon atoms, and (ii) at least two functional groups, and (b) a crosslinking agent comprising a plurality of functional groups (iii) reactive with the functional groups (ii) of compound (a), wherein functional groups (ii) and (iii) are selected such that reaction there between produces a thermally irreversible chemical linkage. The coating compositions of the invention provide improved solids, chip resistance, flexibility and/or scratch & mar resistance while maintaining desirable and/or improved performance characteristics with regard to environmental etch, relative humidity, QCT, chip resistance, thermoshock resistance, cold crack resistance, adhesion and the like.
摘要翻译：本发明提供涂料组合物，其包含基本上不含任何杂原子的反应性组分（a），并且在室温下不是结晶固体，并且其包含（i）12至72个碳原子，和（ii）至少两个官能基团，和（b）包含与化合物（a）的官能团（ⅱ）反应的多个官能团（ⅲ）的交联剂，其中选择官能团（ⅱ）和（ⅲ），使得其中的反应产生热不可逆化学键。本发明的涂料组合物在环境蚀刻，相对湿度，QCT，芯片电阻，耐热裂纹性，耐寒裂纹性方面保持理想和/或改进的性能特征，提供了改进的固体，耐芯片性，柔性和/ ，粘合等。

7. 发明授权

US06858674B2 Carbamate functional materials, a method of making said materials, and curable coating compositions containing said materials 失效
标题翻译：氨基甲酸酯官能材料，制备所述材料的方法和含有所述材料的可固化涂料组合物
公开(公告)号：US06858674B2
公开(公告)日：2005-02-22
申请号：US10285594
申请日：2002-10-31
申请人： Walter H. Ohrbom , Craig S. Schang
发明人： Walter H. Ohrbom , Craig S. Schang
IPC分类号： C07C217/12 , C08G18/28 , C08G18/38 , C09D201/02 , C08F8/32
CPC分类号： C08G18/3831 , C07C217/12 , C08G18/285 , C09D201/025 , Y10T428/31529 , Y10T428/31663
摘要： The invention provides a primary carbamate functional material of the formula: a method of making said materials and curable coating compositions comprising the primary carbamate functional material of the invention. The primary carbamate functional material comprises the reaction product of (1) at least one material P comprising one or more functional groups (i) which are reactive with a functional group Z but which are substantially nonreactive with a primary carbamate group X of monomeric reactive compound (2), and (2) a monomeric reactive compound comprising one or more structures of a particular formula.
摘要翻译：本发明提供下式的主要氨基甲酸酯官能材料：制备所述材料的方法和包含本发明的主要氨基甲酸酯官能材料的可固化涂料组合物。主要的氨基甲酸酯官能材料包括（1）至少一种包含一个或多个官能团（i）的材料P的反应产物，其与官能团Z反应，但是与单体反应性化合物的伯氨基甲酸酯基团X基本上不反应（2）和（2）包含一种或多种特定结构的单体反应性化合物。

8. 发明授权

US06841619B2 Compound and coating compositions for adhesion to olefinic substrates 失效
标题翻译：用于粘附到烯烃底物的化合物和涂料组合物
公开(公告)号：US06841619B2
公开(公告)日：2005-01-11
申请号：US09907207
申请日：2001-07-17
申请人： John D. McGee , Daniel Blickberndt , Craig Schang , Walter H. Ohrbom , Keri Krueger
发明人： John D. McGee , Daniel Blickberndt , Craig Schang , Walter H. Ohrbom , Keri Krueger
IPC分类号： C08J7/04 , C08G63/00 , C08G63/08 , C08G65/26 , C08L53/00 , C08L71/02 , C09D5/00 , C09D7/12 , C09D153/00 , C09D161/28 , C09D201/00 , C09J5/02 , C08J3/00 , C08K3/04 , C08L67/02 , B32B31/20
CPC分类号： C08L71/02 , C08G63/00 , C08L53/005 , C09D5/002 , C09D7/65 , C09D201/00 , Y10T428/31909 , Y10T428/31913 , Y10T428/31917 , C08L2666/04 , C08L2666/24
摘要： The present invention provides an olefin-based block copolymer that has an olefin block that is substantially saturated and at least one (poly)ester or (poly)ether block. The olefin-based block copolymer of the invention can be prepared by reacting a liquid hydroxyl-functional, saturated or substantially saturated olefin polymer with a chain-extension reagent that is reactive with hydroxyl groups and will polymerize in a head-to-tail arrangement of monomer units. The olefin-based block copolymer of the invention can be used to prepare an adhesion promoter that provides excellent adhesion of subsequent coating layers to olefinic substrates like TPO and superior properties as compared to previously used adhesion promoters containing chlorinated polyolefins. Alternatively, the olefin-based copolymers of the invention can be used as an additive in a curable coating composition to provide excellent adhesion to olefinic substrates like TPO, even when used in very minor amounts compared to the amounts required for previously known agents.
摘要翻译：本发明提供一种具有基本上饱和的烯烃嵌段和至少一种（多）酯或（聚）醚嵌段的烯烃基嵌段共聚物。本发明的烯烃基嵌段共聚物可以通过使液体羟基官能的饱和或基本上饱和的烯烃聚合物与与羟基反应的链延长试剂反应来制备，并且将以头 - 尾排列的方式聚合单体单元。与先前使用的含有氯化聚烯烃的粘合促进剂相比，本发明的烯烃基嵌段共聚物可用于制备粘合促进剂，其对随后的涂层提供与TPO等烯烃基材的优异粘附性和优异的性能。或者，本发明的烯烃基共聚物可用作可固化涂料组合物中的添加剂，以提供与诸如TPO的烯烃基材的优异粘合性，即使以与先前已知的试剂所需量相比非常小的量使用。

9. 发明授权

US06838530B2 Method of preparing various multifunctional materials using limited starting reactants 失效
标题翻译：使用有限起始反应物制备各种多功能材料的方法
公开(公告)号：US06838530B2
公开(公告)日：2005-01-04
申请号：US10325328
申请日：2002-12-20
申请人： Walter H. Ohrbom , Patricia A. Herrel
发明人： Walter H. Ohrbom , Patricia A. Herrel
IPC分类号： C08F2/00 , C08F8/30 , C08F8/32
CPC分类号： C08F8/30 , C08F8/32
摘要： The invention provides a method of making a number of different multifunctional acrylic materials from a limited number of starting materials. The method of the invention requires the product of a masterbatch of an acrylic oligomer or polymer having two or more cyclic carbonate functional groups. A first portion of the masterbatch is then reacted with ammonia and a grafting material (c) in either successive or simultaneous reactions to provide a first multifunctional acrylic oligomer or polymer. Additional portions of the masterbatch may be reacted with ammonia and other grafting materials (c), different from the first grafting material (c), in either successive or simultaneous reactions to provide different multifunctional acrylic oligomers or polymers.
摘要翻译：本发明提供从有限数量的原料制备许多不同的多官能丙烯酸类材料的方法。本发明的方法需要具有两个或更多个环状碳酸酯官能团的丙烯酸类低聚物或聚合物的母料的产品。然后在连续或同时反应中将母料的第一部分与氨和接枝材料（c）反应以提供第一多官能丙烯酸低聚物或聚合物。在连续或同时反应中，母料的另外部分可与氨和不同于第一接枝材料（c）的其它接枝材料（c）反应以提供不同的多官能丙烯酸低聚物或聚合物。

10. 发明授权

US06710138B2 Carbamate functional polymers and oligomers 有权
标题翻译：氨基甲酸酯官能聚合物和低聚物
公开(公告)号：US06710138B2
公开(公告)日：2004-03-23
申请号：US10342897
申请日：2003-01-15
申请人： Walter H Ohrbom , John W. Rehfuss
发明人： Walter H Ohrbom , John W. Rehfuss
IPC分类号： C08F830
CPC分类号： C08G18/285 , C09D201/025
摘要： The instant invention provides carbamate functional polymers and/or oligomers and coating compositions containing such which have improved levels of nonvolatile solids yet demonstrate good sprayability and etch resistance. The carbamate functional polymers and/or oligomers of the invention comprise the polymerization reaction product of (a) a polymer or oligomer comprising a plurality of functional groups reactive with an active hydrogen group, and (b) a monomeric compound of the formula: wherein at least one of Y and Z is an active hydrogen containing group and the other is a primary carbamate group, and R is of the formula: —(L)n—R′ wherein L is a linking group of one or more carbons containing heteratoms selected from the group consisting of O, N, and mixtures thereof, R′ is an alkyl group free of heteratoms and selected from the group consisting of branched alkyl groups having from 5 to 30 carbons, straight chain alkyl groups of more than 2 carbons, and mixtures thereof, and n is a number from 0 to 1.
摘要翻译：本发明提供了含有这样的氨基甲酸酯官能聚合物和/或低聚物和涂料组合物，其具有改进的非挥发性固体含量，但表现出良好的喷涂性和耐蚀刻性。本发明的氨基甲酸酯官能聚合物和/或低聚物包含（a）包含多个与活性氢基团反应的官能团的聚合物或低聚物的聚合反应产物，和（b）下式的单体化合物：其中在 Y和Z中的至少一个是含氢活性基团，另一个是伯氨基甲酸酯基，R是下式的化合物： - （L）nR'其中L是一个或多个含有杂原子的碳的连接基团，选自由O，N及其混合物组成的基团，R'是不含杂原子的烷基，选自碳原子数5〜30的支链烷基，碳原子数2以上的直链烷基及其混合物，n为0〜1的数。

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