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1. 发明授权

US5770755A Process to prepare polymeric metallocenes 失效
标题翻译：制备聚合金属茂的方法
公开(公告)号：US5770755A
公开(公告)日：1998-06-23
申请号：US339537
申请日：1994-11-15
申请人： Peter Schertl , Helmut G. Alt , Bernd Peifer , Syriac J. Palackal , M. Bruce Welch
发明人： Peter Schertl , Helmut G. Alt , Bernd Peifer , Syriac J. Palackal , M. Bruce Welch
IPC分类号： C07C13/00 , C07F17/00 , C08F4/44 , C08F4/639 , C08F4/64 , C08F4/649 , C08F4/6592 , C08F10/00 , C08F30/04 , C07F9/00 , C08G61/00 , C07F14/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/63912 , C08F4/65925 , Y10S526/943
摘要： Processes to prepare polymeric metallocene are provided. Said processes comprise reacting a polymeric ligand, an alkali metal compound, and a transition metal-containing compound to produce said polymeric metallocene. therefor.
摘要翻译：提供制备聚合金属茂的方法。所述方法包括使聚合物配体，碱金属化合物和含过渡金属的化合物反应以产生所述聚合金属茂。因此。

2. 发明授权

US06372930B1 Polymeric ligands, polymeric metallocenes, catalyst systems, preparation, and use 失效
标题翻译：聚合物配体，聚合金属茂，催化剂体系，制备和用途
公开(公告)号：US06372930B1
公开(公告)日：2002-04-16
申请号：US09501816
申请日：2000-02-10
申请人： Peter Schertl , Helmut G. Alt , M. Bruce Welch , Bernd Peifer , Syriac J. Palackal
发明人： Peter Schertl , Helmut G. Alt , M. Bruce Welch , Bernd Peifer , Syriac J. Palackal
IPC分类号： C07F1700
CPC分类号： C08F10/00 , C07F17/00 , C08F4/63912 , C08F4/65925 , Y10S526/943 , C08F4/63916 , C08F4/63922
摘要： Polymeric ligands, polymeric metallocenes, and processes for preparing same are provided. The process for preparing polymeric metallocenes comprises reacting a polymeric ligand, a transition metal compound, and an alkali metal compound. In one embodiment, a process for preparing polymeric ligands comprises reacting at least one bridged cyclopentadienyl-type monomer and an initiator under polymerization conditions. In another embodiment, a polymeric ligand is represented by the formula [Q′]n, wherein Q′ is a unit containing at least one bridged cyclopentadienyl-type group and wherein n is 1-5000. In another embodiment, a polymeric metallocene is represented by the formula [Q″MXm]n, wherein Q″ is a unit containing at least one fluorenyl-type group, M is a transition metal, each X is individually a hydrocarbyl group containing 1 to 20 carbon atoms, an alkoxy group containing 1 to 12 carbon atoms, an aryloxy group containing 6 to 20 carbon atoms, a halide, or hydride, m is 2 or 3, and wherein n is 1-5000. Other aspects of the present invention include a catalyst system comprising the polymeric metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.
摘要翻译：提供了聚合配体，聚合金属茂及其制备方法。制备聚合金属茂的方法包括使聚合物配体，过渡金属化合物和碱金属化合物反应。在一个实施方案中，制备聚合物配体的方法包括在聚合条件下使至少一种桥连环戊二烯基型单体与引发剂反应。在另一个实施方案中，聚合物配体由式[Q'] n表示，其中Q'是含有至少一个桥连环戊二烯基型基团并且其中n为1-5000的单元。在另一个实施方案中，聚合物茂金属由式[Q'MXm] n表示，其中Q“是含有至少一个芴基型基团的单元，M是过渡金属，每个X各自含有含烃基 1〜20个碳原子的烷氧基，碳原子数1〜12的烷氧基，碳原子数6〜20的芳氧基，卤化物或氢化物，m为2或3，n为1-5000。本发明的其它方面包括包含聚合金属茂和有机铝氧烷的催化剂体系，其制备方法和使用催化剂体系的聚合方法。

3. 发明授权

US6124414A Fluorenyl-containing polymeric metallocene catalyst systems 失效
标题翻译：含芴基聚合金属茂催化剂体系
公开(公告)号：US6124414A
公开(公告)日：2000-09-26
申请号：US48395
申请日：1998-03-26
申请人： Bernd Peifer , Syriac J. Palackal , M. Bruce Welch , Helmut G. Alt , Peter Schertl
发明人： Bernd Peifer , Syriac J. Palackal , M. Bruce Welch , Helmut G. Alt , Peter Schertl
IPC分类号： C07C13/00 , C07F17/00 , C08F4/44 , C08F4/639 , C08F4/64 , C08F4/649 , C08F4/6592 , C08F10/00 , C08F30/04
CPC分类号： C08F10/00 , C07F17/00 , C08F4/63912 , C08F4/65925 , Y10S526/943
摘要： A catalyst system comprising an organoaluminoxane cocatalyst and a polymeric fluorenyl-containing metallocene prepared from a polymer resulting from the polymerization of a 2-vinylfluorene compound or the alkylation of a fluorene compound.
摘要翻译：一种包含有机铝氧烷助催化剂和由由2-乙烯基芴化合物聚合得到的聚合物或芴化合物的烷基化制备的聚合芴基茂金属的催化剂体系。

4. 发明授权

US6057410A Polymeric ligands, polymeric metallocenes, catalyst systems, preparation, and use 失效
公开(公告)号：US6057410A
公开(公告)日：2000-05-02
申请号：US48392
申请日：1998-03-26
申请人： Helmut G. Alt , Peter Schertl , Bernd Peifer , Syriac J. Palackal , M. Bruce Welch
发明人： Helmut G. Alt , Peter Schertl , Bernd Peifer , Syriac J. Palackal , M. Bruce Welch
IPC分类号： C07C13/00 , C07F17/00 , C08F4/44 , C08F4/639 , C08F4/64 , C08F4/649 , C08F4/6592 , C08F10/00 , C08F30/04 , C08F32/08 , C08F30/08 , C08F30/10
CPC分类号： C08F10/00 , C07F17/00 , C08F4/63912 , C08F4/65925 , Y10S526/943
摘要： Polymeric ligands, polymeric metallocenes, and processes for preparing same are provided. The process for preparing polymeric metallocenes comprises reacting a polymeric ligand, a transition metal compound, and an alkali metal compound. In one embodiment, a process for preparing polymeric ligands comprises reacting at least one bridged cyclopentadienyl-type monomer and an initiator under polymerization conditions. In another embodiment, a polymeric ligand is represented by the formula [Q'].sub.n, wherein Q' is a unit containing at least one bridged cyclopentadienyl-type group and wherein n is 1-5000. In another embodiment, a polymeric metallocene is represented by the formula [Q"MX.sub.m ].sub.n, wherein Q" is a unit containing at least one fluorenyl-type group, M is a transition metal, each X is individually a hydrocarbyl group containing 1 to 20 carbon atoms, an alkoxy group containing 1 to 12 carbon atoms, an aryloxy group containing 6 to 20 carbon atoms, a halide, or hydride, m is 2 or 3, and wherein n is 1-5000. Other aspects of the present invention include a catalyst system comprising the polymeric metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.

5. 发明授权

US6040402A Polymeric ligands, polymeric metallocenes, catalyst systems, preparation, and use 失效
标题翻译：聚合物配体，聚合金属茂，催化剂体系，制备和用途
公开(公告)号：US6040402A
公开(公告)日：2000-03-21
申请号：US48390
申请日：1998-03-26
申请人： Bernd Peifer , Syriac J. Palackal , M. Bruce Welch , Helmut G. Alt , Peter Schertl
发明人： Bernd Peifer , Syriac J. Palackal , M. Bruce Welch , Helmut G. Alt , Peter Schertl
IPC分类号： C07C13/00 , C07F17/00 , C08F4/44 , C08F4/639 , C08F4/64 , C08F4/649 , C08F4/6592 , C08F10/00 , C08F30/04 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F10/00 , C07F17/00 , C08F4/63912 , C08F4/65925 , Y10S526/943
摘要： A polymerization process comprising contacting at least one olefin under polymerization conditions with a catalyst composition produced by combining an organoaluminoxane cocatalyst and a polymeric metallocene catalyst prepared by (1) forming a fluorine-containing polymer by (a) polymerizing a 2-vinyl fluorenyl compound or (b) polymerizing a fluorenyl compound by reacting it with chloro methyl methyl ether in the presence of zinc dichloride or aluminum trichloride; (2) reacting the fluorenyl-containing polymer with an alkali metal compound; and (3) reacting the product of step (2) with a transition metal-containing compound.
摘要翻译：一种聚合方法，包括使聚合条件下的至少一种烯烃与通过组合有机铝氧烷助催化剂和通过（1）通过（a）聚合2-乙烯基芴基化合物或（a）形成含氟聚合物而制备的聚合金属茂催化剂制备的催化剂组合物接触，（b）在二氯化锌或三氯化铝的存在下使芴基化合物与氯甲基甲基醚反应; （2）使含芴基的聚合物与碱金属化合物反应; 和（3）使步骤（2）的产物与含过渡金属的化合物反应。

6. 发明授权

US5616752A Metallocenes and processes therefor and therewith 失效
标题翻译：金属茂及其处理方法及其
公开(公告)号：US5616752A
公开(公告)日：1997-04-01
申请号：US462328
申请日：1995-06-05
申请人： Konstantinos Patsidis , Bernd Peifer , Helmut G. Alt , Rolf L. Geerts , Darryl R. Fahey , M. Bruce Welch , Syriac J. Palackal , Harold R. Deck
发明人： Konstantinos Patsidis , Bernd Peifer , Helmut G. Alt , Rolf L. Geerts , Darryl R. Fahey , M. Bruce Welch , Syriac J. Palackal , Harold R. Deck
IPC分类号： B01J31/16 , B01J31/22 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F7/08 , C07F7/12 , C07F7/22 , C07F7/30 , C07F17/00 , C08F4/619 , C08F4/6192 , C08F4/639 , C08F4/6392 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C07F7/00
CPC分类号： C07F17/00 , B01J31/143 , B01J31/1616 , B01J31/1633 , B01J31/2295 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F7/0809 , C07F7/0818 , C07F7/0827 , C07F7/12 , C07F7/2212 , C07F7/2216 , C07F7/30 , C08F10/00 , B01J21/08 , B01J2231/12 , B01J2231/52 , B01J2231/643 , B01J2231/72 , B01J2531/35 , B01J2531/36 , B01J2531/37 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , C07B2200/11 , C07C2101/10 , C07C2103/18 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61927 , C08F4/63912 , C08F4/63922 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A method is provided for forming a supported cyclopentadiene-type compound comprising contacting a cyclopentadiene-type compound containing an active halogen with an inorganic support having surface hydroxyl group. Also there is provided a method of preparing a supported metallocene comprising reacting the supported cyclopentadiene-type compound with a transition metal compound under suitable conditions. There is also provided a process for producing bridged cyclopentadiene-type ligands having a bridge having branch that has a terminal vinyl group. Also metallocenes of these ligands are provided. Still further there is provided a process for producing bridged cyclopentadiene-type ligands having a bridge having a branch that has a terminal active halogen. The resulting new ligands and supported metallocenes produced therefrom are also provided. There is further provided supported metallocene catalysts wherein at least two metallocenes of differing effectiveness are both bonded to an inorganic support having surface hydroxy groups. Olefin polymerization employing the inventive bridged supported metallocenes is also provided, as well the resulting polymer products.
摘要翻译：提供用于形成负载的环戊二烯型化合物的方法，包括使含有活性卤素的环戊二烯型化合物与具有表面羟基的无机载体接触。还提供了一种制备负载型茂金属的方法，包括在合适的条件下使负载的环戊二烯型化合物与过渡金属化合物反应。还提供了一种制备桥连环戊二烯型配体的方法，其具有具有末端乙烯基的分支的桥。还提供了这些配体的金属茂。还提供了一种制备桥连环戊二烯型配体的方法，其具有具有末端活性卤素的分支的桥。还提供了由此产生的新配体和负载的金属茂。进一步提供负载型金属茂催化剂，其中至少两种不同效力的金属茂都与具有表面羟基的无机载体结合。还提供了使用本发明桥连的负载金属茂的烯烃聚合，以及所得的聚合物产物。

7. 发明授权

US5565592A Vinly-substituted bridged metallocenes 失效
标题翻译：连续取代的桥连金属茂
公开(公告)号：US5565592A
公开(公告)日：1996-10-15
申请号：US402244
申请日：1995-03-10
申请人： Konstantinos Patsidis , Bernd Peifer , Syriac J. Palackal , Helmut G. Alt , M. Bruce Welch , Rolf L. Geerts , Darryl R. Fahey , Harold R. Deck
发明人： Konstantinos Patsidis , Bernd Peifer , Syriac J. Palackal , Helmut G. Alt , M. Bruce Welch , Rolf L. Geerts , Darryl R. Fahey , Harold R. Deck
IPC分类号： B01J31/16 , B01J31/22 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F7/08 , C07F7/12 , C07F7/22 , C07F7/30 , C07F17/00 , C08F4/619 , C08F4/6192 , C08F4/639 , C08F4/6392 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/642
CPC分类号： C07F17/00 , B01J31/143 , B01J31/1616 , B01J31/1633 , B01J31/2295 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F7/0809 , C07F7/0818 , C07F7/0827 , C07F7/12 , C07F7/2212 , C07F7/2216 , C07F7/30 , C08F10/00 , B01J21/08 , B01J2231/12 , B01J2231/52 , B01J2231/643 , B01J2231/72 , B01J2531/35 , B01J2531/36 , B01J2531/37 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , C07B2200/11 , C07C2101/10 , C07C2103/18 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61927 , C08F4/63912 , C08F4/63922 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A method is provided for forming a supported cyclopentadiene-type compound comprising contacting a cyclopentadiene-type compound containing an active halogen with an inorganic support having surface hydroxyl group. Also there is provided a method of preparing a supported metallocene comprising reacting the supported cyclopentadiene-type compound with a transition metal compound under suitable conditions. There is also provided a process for producing bridged cyclopentadiene-type ligands having a bridge having branch that has a terminal vinyl group. Also metallocenes of these ligands are provided. Still further there is provided a process for producing bridged cyclopentadiene-type ligands having a bridge having a branch that has a terminal active halogen. The resulting new ligands and supported metallocenes produced therefrom are also provided. There is further provided supported metallocene catalysts wherein at least two metallocenes of differing effectiveness are both bonded to an inorganic support having surface hydroxy groups. Olefin polymerization employing the inventive bridged supported metallocenes is also provided, as well the resulting polymer products.
摘要翻译：提供用于形成负载的环戊二烯型化合物的方法，包括使含有活性卤素的环戊二烯型化合物与具有表面羟基的无机载体接触。还提供了一种制备负载型茂金属的方法，包括在合适的条件下使负载的环戊二烯型化合物与过渡金属化合物反应。还提供了一种制备桥连环戊二烯型配体的方法，其具有具有末端乙烯基的分支的桥。还提供了这些配体的金属茂。还提供了一种制备桥连环戊二烯型配体的方法，其具有具有末端活性卤素的分支的桥。还提供了由此产生的新配体和负载的金属茂。进一步提供负载型金属茂催化剂，其中至少两种不同效力的金属茂都与具有表面羟基的无机载体结合。还提供了使用本发明桥连的负载金属茂的烯烃聚合，以及所得的聚合物产物。

8. 发明授权

US5498581A Method for making and using a supported metallocene catalyst system 失效
标题翻译：制备和使用负载型金属茂催化剂体系的方法
公开(公告)号：US5498581A
公开(公告)日：1996-03-12
申请号：US252611
申请日：1994-06-01
申请人： M. Bruce Welch , Helmut G. Alt , Bernd Peifer , Syriac J. Palackal , Gary L. Glass , Ted M. Pettijohn , Gil R. Hawley , Darryl R. Fahey
发明人： M. Bruce Welch , Helmut G. Alt , Bernd Peifer , Syriac J. Palackal , Gary L. Glass , Ted M. Pettijohn , Gil R. Hawley , Darryl R. Fahey
IPC分类号： B01J31/38 , C07F17/00 , C08F4/60 , C08F4/642 , C08F4/651 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08J5/18 , B01J31/00
CPC分类号： C08J5/18 , C07F17/00 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F4/65927 , C08J2323/04
摘要： Methods are disclosed for preparing a highly active solid metallocene-containing catalyst system and its use in the polymerization of olefins. The catalyst system is prepared by creating a catalyst system solution by combining an aluminoxane with a metallocene having a substituent which has olefinic unsaturation in a suitable liquid to form a liquid catalyst system, conducting prepolymerization of an olefin in the liquid catalyst system, and separating the resulting solid metallocene-containing catalyst system from the reaction mixture. Also polymerization of olefins using the inventive solid catalyst system is disclosed.
摘要翻译：公开了用于制备高活性固体茂金属催化剂体系及其在烯烃聚合中的应用的方法。催化剂体系是通过在合适的液体中将铝氧烷与具有烯属不饱和键的取代基的茂金属组合形成液体催化剂体系，在液体催化剂体系中进行烯烃预聚合，并分离从反应混合物中得到固体茂金属的催化剂体系。还公开了使用本发明的固体催化剂体系的烯烃的聚合。

9. 发明授权

US5492974A Process for preparing polymer bound metallocenes 失效
标题翻译：制备聚合物结合金属茂的方法
公开(公告)号：US5492974A
公开(公告)日：1996-02-20
申请号：US455380
申请日：1995-05-31
申请人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
发明人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
IPC分类号： C08F4/642 , C07F17/00 , C08F4/58 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/656 , C08F4/657 , C08F4/685 , C08F8/00 , C08F8/42 , C08F10/00
CPC分类号： C08F8/42 , C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61922
摘要： A polymer bound ligand represented by the formula QM(R).sub.m and process for preparing same are provided, wherein Q is a polystyrene, M is Si, C, Ge, Sn, P, or N, each R is a that at least one R is a cyclopentadienyl-type compound, and m is 2 or 3, said process comprising reacting a metallated polystyrene and an organohalide compound, wherein the polystyrene is metallated with an alkali metal, and wherein said organohalide compound is represented by the formula XM(R).sub.m wherein X is a halide. Other aspects of the present invention include a polymer bound metallocene represented by the formula QM(R).sub.m ZY.sub.n and a process for preparing same, wherein Z is a transition metal, Y is a halide, methyl, hydrogen, or a cyclopentadienyl-type group, and n is 2 or 3. Other aspects of the present invention include a catalyst system comprising the polymer bound metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.
摘要翻译：提供由式QM（R）m表示的聚合物结合配体及其制备方法，其中Q是聚苯乙烯，M是Si，C，Ge，Sn，P或N，每个R是至少一个 R是环戊二烯基型化合物，m为2或3，所述方法包括使金属化聚苯乙烯和有机卤化物化合物反应，其中聚苯乙烯用碱金属进行金属化，其中所述有机卤化物由式XM（R ）m，其中X是卤化物。本发明的其它方面包括由式QM（R）mZYn表示的聚合物结合金属茂及其制备方法，其中Z为过渡金属，Y为卤化物，甲基，氢或环戊二烯基型基团，并且n为2或3.本发明的其它方面包括包含聚合物结合的茂金属和有机铝氧烷的催化剂体系，其制备方法和使用该催化剂体系的聚合方法。

10. 发明授权

US5473020A Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use 失效
标题翻译：聚合物结合的配体，聚合物结合的金属茂，催化剂体系，制备和用途
公开(公告)号：US5473020A
公开(公告)日：1995-12-05
申请号：US268425
申请日：1994-06-30
申请人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
发明人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
IPC分类号： C08F4/642 , C07F17/00 , C08F4/58 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/656 , C08F4/657 , C08F4/685 , C08F8/00 , C08F8/42 , C08F10/00 , C08F8/40
CPC分类号： C08F8/42 , C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61922
摘要： A polymer bound ligand represented by the formula QM(R).sub.m and process for preparing same are provided, wherein Q is a polystyrene, M is Si, C, Ge, Sn, P, or N, each R is a that at least one R is a cyclopentadienyl-type compound, and m is 2 or 3, said process comprising reacting a metallated polystyrene and an organohalide compound, wherein the polystyrene is metallated with an alkali metal, and wherein said organohalide compound is represented by the formula XM(R).sub.m wherein X is a halide. Other aspects of the present invention include a polymer bound metallocene represented by the formula QM(R).sub.m ZY.sub.n and a process for preparing same, wherein Z is a transition metal, Y is a halide, methyl, hydrogen, or a cyclopentadienyl-type group, and n is 2 or 3. Other aspects of the present invention include a catalyst system comprising the polymer bound metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.
摘要翻译：提供由式QM（R）m表示的聚合物结合配体及其制备方法，其中Q是聚苯乙烯，M是Si，C，Ge，Sn，P或N，每个R是至少一个 R是环戊二烯基型化合物，m为2或3，所述方法包括使金属化聚苯乙烯和有机卤化物化合物反应，其中聚苯乙烯用碱金属进行金属化，其中所述有机卤化物由式XM（R ）m，其中X是卤化物。本发明的其它方面包括由式QM（R）mZYn表示的聚合物结合金属茂及其制备方法，其中Z为过渡金属，Y为卤化物，甲基，氢或环戊二烯基型基团，并且n为2或3.本发明的其它方面包括包含聚合物结合的茂金属和有机铝氧烷的催化剂体系，其制备方法和使用该催化剂体系的聚合方法。

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