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    • 4. 发明申请
    • SYNTHESIS METHOD OF POLYMER COMPLEX CRYSTAL
    • 聚合物复合晶体的合成方法
    • US20100105901A1
    • 2010-04-29
    • US12530240
    • 2009-03-07
    • Makoto FujitaMasaki KawanoTsuyoshi HanedaKiyoshi NakanishiTakahiro Kojima
    • Makoto FujitaMasaki KawanoTsuyoshi HanedaKiyoshi NakanishiTakahiro Kojima
    • C07F3/06
    • C07D401/14C09K19/3475C09K19/40
    • Disclosed is a synthesis method for synthesizing in a short time and selectively a microcrystal of a polymer complex having three three-dimensionally and regularly arranged channels.Specifically disclosed is a synthesis method of a polymer complex crystal wherein (1) a metallic solution, which is a mixture of zinc halide(II) and a solvent A that can dissolve the zinc halide, is mixed with (2) a ligand solution, which is a mixture of a tridentate ligand that has three coordination sites coordinated to zinc of the zinc halide and a solvent B that can dissolve the tridentate ligand, to be a single-phase solution, thereby synthesizing a microcrystal of a polymer complex having a three-dimensional coordination network formed by coordinating the tridentate ligand to the zinc and having channels that are three-dimensionally and regularly arranged in the three-dimensional coordination network.
    • 公开了一种用于在短时间内合成具有三个三维和规则排列的通道的聚合物复合物的微晶体的合成方法。 具体公开了一种聚合物络合物晶体的合成方法,其中(1)将卤化锌(II)和可溶解卤化锌的溶剂A的混合物的金属溶液与(2)配体溶液混合, 其是具有与卤化锌的锌配位的三个配位点和能够溶解三齿配体的溶剂B的三齿配体的混合物,作为单相溶液,由此合成具有三元组分的聚合物配合物的微晶体 通过将三齿配体与锌配位并且具有三维和规则地排列在三维协调网络中的通道形成的三维配位网络。
    • 6. 发明申请
    • Method for producing coated steel sheet
    • 涂层钢板的制造方法
    • US20050064107A1
    • 2005-03-24
    • US10502670
    • 2003-01-24
    • Yuka KomoriMasaki KawanoKazumichi SashiAkio Fujita
    • Yuka KomoriMasaki KawanoKazumichi SashiAkio Fujita
    • B05D3/02B05D7/14C21D8/02C21D8/04C21D8/12C23C22/74H01F1/147H01F1/18
    • C23C22/74B05D3/0209B05D7/14B05D2202/10C21D8/0284C21D8/0484C21D8/1233C21D8/1283H01F1/14725H01F1/18
    • In a process for manufacturing a coated steel sheet such as a coated electromagnetic steel sheet using a water-based coating liquid containing an organic resin, to perform steps subsequent to an annealing step continuously at high speed without causing appearance defects such as coating unevenness; to provide an electromagnetic steel sheet having an insulating film thereon, in which properties of the film are satisfactory, superior weldability and punchability can be obtained without deteriorating the space factor, and the satisfactory film properties can be maintained even if the electromagnetic steel sheet having the insulating film thereon is temper-rolled. A coating liquid is applied onto an untreated steel sheet. The applied liquid is heated on the side close to the steel sheet in such a manner that the time elapsed until the steel sheet temperature is increased to 100° C. after the application is completed is 10 seconds or less, thereby drying the coating liquid. The steel sheet temperature is further increased to a predetermined temperature, thereby forming a coating film. When insulating films for electromagnetic steel sheets are formed, the coating liquid preferably further contains a water based inorganic component.
    • 在使用含有有机树脂的水性涂布液的涂布电磁钢板的涂布钢板的制造方法中,高速连续地进行退火工序后的工序,不会引起涂布不均匀等的外观缺陷; 为了提供一种其上具有绝缘膜的电磁钢板,其中膜的性能令人满意,可以获得优异的焊接性和冲压性,而不会使空间因素变差,并且即使具有 对其上的绝缘膜进行回火。 将涂布液施加到未处理的钢板上。 所施加的液体在靠近钢板的一侧被加热,使得在施加完成之后直到钢板温度升高到100℃的时间为10秒以下,从而使涂布液干燥。 钢板温度进一步提高到预定温度,从而形成涂膜。 当形成用于电磁钢板的绝缘膜时,涂布液优选还含有水基无机组分。
    • 8. 发明申请
    • Polymer Complex
    • 聚合物复合物
    • US20110098414A1
    • 2011-04-28
    • US12224805
    • 2007-03-02
    • Makoto FujitaMasaki KawanoTakehide ChouTakahiro Kojima
    • Makoto FujitaMasaki KawanoTakehide ChouTakahiro Kojima
    • C08F26/06
    • C07D401/14A61K47/6949B01J31/1691B01J31/1815B01J2531/26B82Y5/00C07C29/76C07C205/06C07C211/61C07C2603/42C08G83/00C07C31/10
    • The invention provides a polymer complex having two or more kinds of channel groups through which specific compounds ranging from gaseous small molecules to large molecules such as proteins and other biomolecules can be selectively incorporated and/or released and/or transported. The polymer complex comprises an aromatic compound having two or more coordinating sites as a ligand, a metal ion as a central metal, and an uncoordinating aromatic compound, wherein the polymer complex has a three-dimensional lattice-like structure containing a stack structure comprising the uncoordinating aromatic compound intercalated between aromatic compound ligands in a three-dimensional coordination network formed by coordinating the aromatic compound ligands to the central metal ion, the three-dimensional lattice-like structure is provided with two or more kinds of channel groups each composed of channels identical with one another and having inherent affinity for guest components, the uncoordinating aromatic compound has a specific substituent A at a specific position on the aromatic ring thereof, and the uncoordinating aromatic compound is arranged regularly such that the substituent A is directed to the inside of a specific channel group B out of the two or more kinds of channel groups.
    • 本发明提供了一种具有两种或更多种通道基团的聚合物络合物,通过其可以选择性地并入和/或释放和/或输送从气态小分子到大分子(例如蛋白质和其它生物分子)的特定化合物。 聚合物配合物包括具有两个或更多个配体位点作为配体,金属离子作为中心金属的芳族化合物和不协调的芳族化合物,其中所述聚合物配合物具有包含堆叠结构的三维格子状结构, 通过将芳香族化合物配体与中心金属离子配位而形成的三维配位网络中的芳香族化合物配位体之间嵌入的不协调的芳香族化合物,三维格子状结构具有两个以上的通道,每个通道由通道 彼此相同并且对客体成分具有固有的亲和性,所述非配位芳香族化合物在其芳香环上的特定位置具有特定的取代基A,并且所述不协调的芳香族化合物规则地排列,使得取代基A指向 一个特定的渠道B组出来两种以上的cha nnel组。