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    • 5. 发明申请
    • Polymerizable Spherical Transition Metal Complex, Spherical Transition Metal Complex, and Production Method Thereof
    • 可聚合球形过渡金属络合物,球形过渡金属络合物及其制备方法
    • US20090318663A1
    • 2009-12-24
    • US12224831
    • 2007-03-06
    • Makoto FujitaSota SatoTakashi MuraseTetsuya IidaTakanobu HiguchiSatoru Tanaka
    • Makoto FujitaSota SatoTakashi MuraseTetsuya IidaTakanobu HiguchiSatoru Tanaka
    • C08G69/26
    • C07D401/10C07F15/0066
    • A polymerizable spherical transition metal complex is provided which has a hollow shell which is formed from transition metal atoms and bidentate organic ligands, the bidentate organic ligands having a substituent having a polymerizable group moiety at an end thereof, and the substituents being oriented towards the interior of the hollow shell. A spherical transition metal complex in which, in the hollow shell of the polymerizable spherical transition metal complex, the polymerizable groups are polymerized, and a production method thereof are also provided. The polymerizable spherical transition metal complex which is a spherical transition metal complex having a hollow shell, is characterized in that the hollow shell is formed from a transition metal atoms (wherein a represents an integer of 6 to 60), and 2a bidentate organic ligands, the bidentate organic ligands have a substituent having at least one or more polymerizable group moieties at an end thereof, and the substituents are oriented towards an interior of the hollow shell. The spherical transition metal complex is characterized in that the polymerizable groups are polymerized in the hollow shell of the polymerizable spherical transition metal complex. The production method thereof is also provided.
    • 提供了一种可聚合的球状过渡金属络合物,其具有由过渡金属原子和二齿有机配体形成的中空壳,二齿有机配位体在其末端具有可聚合基团部分的取代基,并且取代基朝向内部 的空心壳。 在聚合性球状过渡金属络合物的中空壳中使聚合性基团聚合的球状过渡金属络合物及其制造方法。 作为具有中空壳的球形过渡金属络合物的聚合性球状过渡金属络合物的特征在于,中空壳由过渡金属原子(其中a表示6〜60的整数)和2a二齿有机配体形成, 双齿有机配体具有在其末端具有至少一个或多个可聚合基团部分的取代基,并且取代基朝向空心壳体的内部。 球形过渡金属络合物的特征在于可聚合的基团在可聚合的球状过渡金属络合物的中空壳中聚合。 还提供了其制备方法。