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1. 发明授权

US08530649B2 Polymer complex 有权
标题翻译：聚合物复合物
公开(公告)号：US08530649B2
公开(公告)日：2013-09-10
申请号：US12224805
申请日：2007-03-02
申请人： Makoto Fujita , Masaki Kawano , Takehide Chou , Takahiro Kojima
发明人： Makoto Fujita , Masaki Kawano , Takehide Chou , Takahiro Kojima
IPC分类号： C07F9/80
CPC分类号： C07D401/14 , A61K47/6949 , B01J31/1691 , B01J31/1815 , B01J2531/26 , B82Y5/00 , C07C29/76 , C07C205/06 , C07C211/61 , C07C2603/42 , C08G83/00 , C07C31/10
摘要： A polymer complex having two or more kinds of channel groups through which specific compounds ranging from gaseous small molecules to large molecules such as proteins and other biomolecules can be selectively incorporated and/or released and/or transported is provided. The polymer complex includes an aromatic compound ligand, a central metal ion, and an uncoordinating aromatic compound. In the polymer complex, the uncoordinating aromatic compound is intercalated between aromatic compound ligands in a three-dimensional coordination network. Each of two or more kinds of channel groups contains channels identical with one another and having inherent affinity for guest components. The uncoordinating aromatic compound has a specific substituent A at a specific position on the aromatic ring thereof, and the uncoordinating aromatic compound is arranged regularly such that the substituent A is directed to the inside of a specific channel group B out of the two or more kinds of channel groups.
摘要翻译：提供了具有两种或更多种通道基团的聚合物复合物，通过其可以选择性地并入和/或释放和/或输送从气态小分子到大分子（例如蛋白质和其它生物分子）的特定化合物。聚合物配合物包括芳香族化合物配体，中心金属离子和不协调的芳族化合物。在聚合物络合物中，不协调的芳族化合物插入在三维配位网络中的芳族化合物配体之间。两种或多种通道组中的每一个包含彼此相同的通道，并且对于客体组件具有固有的亲和性。不协调的芳香族化合物在其芳香环上的特定位置具有特定的取代基A，并且不均匀的芳香族化合物规则地排列，使得取代基A指向两种或更多种的特定通道群B的内部的频道组。

2. 发明申请

US20110098414A1 Polymer Complex 有权
标题翻译：聚合物复合物
公开(公告)号：US20110098414A1
公开(公告)日：2011-04-28
申请号：US12224805
申请日：2007-03-02
申请人： Makoto Fujita , Masaki Kawano , Takehide Chou , Takahiro Kojima
发明人： Makoto Fujita , Masaki Kawano , Takehide Chou , Takahiro Kojima
IPC分类号： C08F26/06
CPC分类号： C07D401/14 , A61K47/6949 , B01J31/1691 , B01J31/1815 , B01J2531/26 , B82Y5/00 , C07C29/76 , C07C205/06 , C07C211/61 , C07C2603/42 , C08G83/00 , C07C31/10
摘要： The invention provides a polymer complex having two or more kinds of channel groups through which specific compounds ranging from gaseous small molecules to large molecules such as proteins and other biomolecules can be selectively incorporated and/or released and/or transported. The polymer complex comprises an aromatic compound having two or more coordinating sites as a ligand, a metal ion as a central metal, and an uncoordinating aromatic compound, wherein the polymer complex has a three-dimensional lattice-like structure containing a stack structure comprising the uncoordinating aromatic compound intercalated between aromatic compound ligands in a three-dimensional coordination network formed by coordinating the aromatic compound ligands to the central metal ion, the three-dimensional lattice-like structure is provided with two or more kinds of channel groups each composed of channels identical with one another and having inherent affinity for guest components, the uncoordinating aromatic compound has a specific substituent A at a specific position on the aromatic ring thereof, and the uncoordinating aromatic compound is arranged regularly such that the substituent A is directed to the inside of a specific channel group B out of the two or more kinds of channel groups.
摘要翻译：本发明提供了一种具有两种或更多种通道基团的聚合物络合物，通过其可以选择性地并入和/或释放和/或输送从气态小分子到大分子（例如蛋白质和其它生物分子）的特定化合物。聚合物配合物包括具有两个或更多个配体位点作为配体，金属离子作为中心金属的芳族化合物和不协调的芳族化合物，其中所述聚合物配合物具有包含堆叠结构的三维格子状结构，通过将芳香族化合物配体与中心金属离子配位而形成的三维配位网络中的芳香族化合物配位体之间嵌入的不协调的芳香族化合物，三维格子状结构具有两个以上的通道，每个通道由通道彼此相同并且对客体成分具有固有的亲和性，所述非配位芳香族化合物在其芳香环上的特定位置具有特定的取代基A，并且所述不协调的芳香族化合物规则地排列，使得取代基A指向一个特定的渠道B组出来两种以上的cha nnel组。

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