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1. 发明授权

US4727128A Diisocyanates containing urethane groups, a process for their preparation and their use as binders or binder component in polyurethane lacquers 失效
标题翻译：含有氨基甲酸酯基团的二异氰酸酯，其制备方法以及它们在聚氨酯漆中作为粘合剂或粘合剂组分的用途
公开(公告)号：US4727128A
公开(公告)日：1988-02-23
申请号：US820057
申请日：1986-01-21
申请人： Josef Pedain , Bernd Riberi , Michael Sonntag , Klaus Konig , Jurg Frohlich
发明人： Josef Pedain , Bernd Riberi , Michael Sonntag , Klaus Konig , Jurg Frohlich
IPC分类号： C08G18/00 , C07C67/00 , C07C239/00 , C07C269/02 , C07C271/06 , C07C271/20 , C08G18/10 , C08G18/32 , C08G18/73 , C08G18/80 , C09D175/00 , C09D175/04 , C07C125/07 , C08G18/78
CPC分类号： C08G18/8009
摘要： The present invention is directed to a process for the preparation of a diisocyanate by reacting a diisocyanate with 2,2,4-trimethyl-pentanediol-(1,3) or reaction products of this diol which contain either ether or ester groups and optionally other diols or triols. The present invention is additionally directed to the diisocyanates produced by this process and to their use in one-component and two-component coating compositions.
摘要翻译：本发明涉及通过使二异氰酸酯与2,2,4-三甲基戊二醇 - （1,3）或该二醇的含有醚基或酯基的任意其它的二醇的反应产物进行反应来制备二异氰酸酯的方法二醇或三醇。本发明另外涉及通过该方法制备的二异氰酸酯及其在单组分和双组分涂料组合物中的用途。

2. 发明授权

US4639499A Cross-linkable polymer resins and use thereof as binders for coating agents 失效
标题翻译：可交联聚合物树脂及其作为涂布剂的粘合剂的用途
公开(公告)号：US4639499A
公开(公告)日：1987-01-27
申请号：US756483
申请日：1985-07-18
申请人： Peter Hohlein , Manfred Schmidt , Josef Pedain , Bernd Riberi , Michael Sonntag
发明人： Peter Hohlein , Manfred Schmidt , Josef Pedain , Bernd Riberi , Michael Sonntag
IPC分类号： C09D201/06 , C08F216/00 , C08F246/00 , C09D133/04 , C09D157/04 , C09D175/00 , C08F238/00 , C08F220/04
CPC分类号： C08F246/00 , C08F216/00 , C09D157/04
摘要： The present invention is directed to cross-linkable, hydroxyl group-containing polymer resins which are obtained by copolymerizing olefinically-unsaturated monomers and are suitable as binder components for lacquers, the polymer resins having a hydroxyl number of about 20 to 400, an average osmometrically-determined molecular weight of about 500 to 30,000 and a molecular inhomogeneity U of about 0.5 to 15, characterized in that they contain about 0.2 to 80% by weight, preferably about 10 to 70% by weight, based on the total weight of the copolymers, of incorporated monomers selected from olefinically- and acetylenically-unsaturated aliphatic diols having 4 carbon atoms, the ether group-containing alkoxylation products thereof with a hydroxyl number of about 50 to 900, the reaction products of these diols with .epsilon.-caprolactone in a mol ratio of diol:-caprolactone of about 1:0.2 to 1:10 and any mixtures of these components.The present invention is also directed to the use of the above polymer resins as binders for coating compositions.
摘要翻译：本发明涉及可交联的含羟基的聚合物树脂，其通过使烯属不饱和单体共聚合而获得，并且适合作为漆的粘合剂组分，聚合物树脂的羟值为约20至400，平均渗透压约500至30,000的测定分子量和约0.5至15的分子不均匀性U，其特征在于它们含有约0.2至80重量％，优选约10至70重量％，基于共聚物的总重量包含选自具有4个碳原子的烯属和炔属不饱和脂族二醇的单体，其含醚基的烷氧基化产物的羟值为约50至900，这些二醇与ε-己内酯的摩尔比为摩尔二醇：己内酯的比例为约1:0.2至1:10，以及这些组分的任何混合物。本发明还涉及上述聚合物树脂作为涂料组合物的粘合剂的用途。

3. 发明授权

US4518761A Process for the preparation of mixed trimers from organic isocyanates, the mixed trimers obtained according to the process and the use thereof for the production of polyurethanes 失效
标题翻译：从有机异氰酸酯制备混合三聚物的方法，根据该方法获得的混合三聚物及其在生产聚氨酯中的用途
公开(公告)号：US4518761A
公开(公告)日：1985-05-21
申请号：US439086
申请日：1982-11-04
申请人： Roland Richter , Hanns P. Muller , Kuno Wagner , Bernd Riberi , Jurg Frohlich
发明人： Roland Richter , Hanns P. Muller , Kuno Wagner , Bernd Riberi , Jurg Frohlich
IPC分类号： C07D251/34 , C08G18/00 , C08G18/79 , C08G18/70
CPC分类号： C07D251/34 , C08G18/791 , Y10T428/22
摘要： The present invention is directed to a new process for the preparation of mixed trimers by at least partly trimerizing the isocyanate groups of at least two organic isocyanates of a reactivity which differs in the sense of the trimerization reaction, in the presence of trimerization catalysts and optionally interrupting the trimerization reaction at the respectively desired degree of trimerization, in which process the less reactive isocyanate component is introduced, polymerization is then commenced in the presence of the catalyst with the trimerization of at least 0.1% of the isocyanate groups and the more reactive isocyanate component is finally metered into the reaction mixture thus obtained; the mixed trimers obtained according to this process; and the use of the mixed trimers having free isocyanate groups obtained by this process, optionally in a form blocked by blocking agents for organic polyisocyanates, as a starting material for the production of polyurethane plastics materials.
摘要翻译：本发明涉及一种新的制备混合三聚体的方法，该方法是在三聚催化剂存在下，至少部分地将三聚反应意义上的至少两种有机异氰酸酯的反应性的异氰酸酯基团三聚，其反应性不同，在分别期望的三聚程度下中断三聚反应，其中引入反应活性较低的异氰酸酯组分较少，然后在催化剂存在下开始聚合，三聚化至少为0.1％的异氰酸酯基团，反应活性较高的异氰酸酯将组分最终计量加入由此获得的反应混合物中; 根据该方法得到的混合三聚物; 以及使用通过该方法获得的具有游离异氰酸酯基团的混合三聚体，任选地以用于有机聚异氰酸酯的封闭剂封闭的形式作为用于制备聚氨酯塑料材料的起始材料。

4. 发明授权

US4552946A Process for the production of polyisocyanates containing isocyanurate groups, the compounds which may be obtained according to this process, and the use thereof for the production of polyurethanes 失效
标题翻译：用于生产含有异氰脲酸酯基团的多异氰酸酯的方法，根据该方法得到的化合物及其用于生产聚氨酯的用途
公开(公告)号：US4552946A
公开(公告)日：1985-11-12
申请号：US571982
申请日：1984-01-19
申请人： Hans-Joachim Scholl , Josef Pedain , Bernd Riberi , Gerhard Mennicken
发明人： Hans-Joachim Scholl , Josef Pedain , Bernd Riberi , Gerhard Mennicken
IPC分类号： C07D251/34 , C07C265/12 , C08G18/00 , C08G18/02 , C08G18/76 , C08G18/79
CPC分类号： C07C265/12 , C08G18/794 , C08G18/795
摘要： This invention relates to a new process for the production of polyisocyanates containing isocyanurate groups by partial trimerization of the isocyanate groups of organic polyisocyanates comprising(a) compounds or mixtures of compounds corresponding to the formula ##STR1## wherein R represents a saturated, aliphatic hydrocarbon radical having from 8 to 15 carbon atoms, and optionally(b) up to about 95 NCO equivalent %, based on the total of (a)+(b), of other organic polyisocyantes.This invention also relates to the compounds which may be obtained according to this process and to the use thereof for the production of isocyanate-polyaddition products such as polyurethanes.
摘要翻译：本发明涉及通过有机多异氰酸酯的异氰酸酯基团的部分三聚制备含有异氰脲酸酯基团的多异氰酸酯的新方法，其包括（a）对应于式的化合物或混合物，其中R表示饱和脂族烃基具有8至15个碳原子，以及（b）至多约95NCO当量％，基于（a）+（b）的其它有机聚异氰酸酯的总量。本发明还涉及根据该方法获得的化合物及其用于生产异氰酸酯 - 加聚产物如聚氨酯的用途。

5. 发明授权

US5723564A Process for preparing isocyanurate group-containing polyisocyanates and their use in two-component coating compositions 失效
标题翻译：制备含异氰脲酸酯基的多异氰酸酯的方法及其在双组分涂料组合物中的用途
公开(公告)号：US5723564A
公开(公告)日：1998-03-03
申请号：US667568
申请日：1996-06-21
申请人： Lutz Schmalstieg , Carl-Gerd Dieris , Wolfgang Kremer , Bernd Riberi
发明人： Lutz Schmalstieg , Carl-Gerd Dieris , Wolfgang Kremer , Bernd Riberi
IPC分类号： C08G18/02 , C07D251/34 , C08G18/79 , C08G18/80 , C09D175/00 , C09D175/04
CPC分类号： C07D251/34 , C08G18/794 , C08G18/8064
摘要： A process for the preparation of isocyanurate group-containing polyisocyanates in solvents which are inert towards isocyanate groups by reacting 0.2 to 1.5% of the isocyanate groups of diisocyanatotoluene with an aliphatic monohydric alcohol having 6 to 22 carbon atoms and subsequently trimerizing at least a portion of the isocyanate groups of the urethanized diisocyanates in the form of 40 to 70 wt. % solutions in lacquer solvents which are inert towards isocyanate groups, and the use of these polyisocyanates in two-component polyurethane coating compositions.
摘要翻译：通过使0.2〜1.5％的二异氰酸基甲苯的异氰酸酯基与具有6〜22个碳原子的脂肪族一元醇反应，然后将至少一部分的三聚化来制备含异氰脲酸酯基的多异氰酸酯在对异氰酸酯基团呈惰性的溶剂中的方法氨基甲酸酯化二异氰酸酯的异氰酸酯基团为40至70wt。在对异氰酸酯基团是惰性的漆溶剂中的％溶液，以及这些多异氰酸酯在双组分聚氨酯涂料组合物中的用途。

6. 发明授权

US5459214A Olefinically unsaturated isocyanates 失效
标题翻译：烯属不饱和异氰酸酯
公开(公告)号：US5459214A
公开(公告)日：1995-10-17
申请号：US195726
申请日：1994-02-11
申请人： Martin Brahm , Eberhard Arning , Lutz Schmalstieg , Bernd Riberi
发明人： Martin Brahm , Eberhard Arning , Lutz Schmalstieg , Bernd Riberi
IPC分类号： C07C269/02 , C07C271/20 , C07C271/24 , C08G18/28 , C08G18/80 , C08G18/81 , C09D175/14 , C09D175/16 , C08F26/02
CPC分类号： C07C271/20 , C07C271/24 , C08G18/2825 , C08G18/8064 , C07C2101/14
摘要： The present invention relates to olefinically unsaturated, urethane group-containing isocyanates which are prepared by reacting at an NCO/OH equivalent ratio of 4 to 40a) an isocyanate component substantially containing urethane group-free cycloaliphatic diisocyanates withb) an unsaturated alcohol component substantially containing monohydric olefinically unsaturated alcoholsand subsequently removing distillable unreacted isocyanates by distillation. The present invention also relates to a process for the preparation of these isocyanates and to their use as a binder component in one-component, coating compositions which may be cured at room temperature.
摘要翻译：本发明涉及通过使NCO / OH当量比为4至40反应制备的烯属不饱和的含氨基甲酸酯基的异氰酸酯a）基本上含有不含氨基甲酸酯基的脂环族二异氰酸酯的异氰酸酯组分和b）不饱和醇组分基本上含有一元烯属不饱和醇，然后通过蒸馏除去可蒸馏的未反应的异氰酸酯。本发明还涉及一种制备这些异氰酸酯的方法以及它们在单组分涂料组合物中作为粘合剂组分的用途，其可以在室温下固化。

7. 发明授权

US4798859A Polyhydroxyl compounds containing ester and ether groups as reactive diluents 失效
标题翻译：含有酯和醚基团的多羟基化合物作为反应性稀释剂
公开(公告)号：US4798859A
公开(公告)日：1989-01-17
申请号：US95928
申请日：1987-09-14
申请人： Peter Hohlein , Eberhard Kreiss , Franz Mory , Bernd Riberi
发明人： Peter Hohlein , Eberhard Kreiss , Franz Mory , Bernd Riberi
IPC分类号： C08F299/04 , C08F283/01 , C08L67/06 , C09D167/00 , C09D167/02 , C09D167/08 , C08L67/02 , C08L67/08
CPC分类号： C09D167/00
摘要： An improved lacquer system composition based on alkyl resins and/or oil-free polyesters contains as a reactive diluent the esterification product of(A) polyols containing an average on average at least 3 hydroxyl groups per molecule and, per hydroxyl group, an average of 0.5 to 15, but in total no more than an average of 20 ether groups per molecule and(B) 0.05 to 1.0 equivalent, based on hydroxyl groups of A, of C.sub.2 -C.sub.30 monocarboxylic acids,with the proviso that the esterification products of A and B have an acid number of at most 5, a hydroxyl number of from 5 to 800 and, on average, from 0.1 to 5 hydroxyl groups per molecule.
摘要翻译：基于烷基树脂和/或无油聚酯的改进的漆系统组合物含有作为反应性稀释剂的（A）多元醇的酯化产物，其每分子平均含有至少3个羟基，每个羟基平均为 0.5〜15，但总共不超过每个分子20个醚基团，（B）基于A的C 2 -C 30单羧酸的羟基为0.05-1.0当量，条件是A的酯化产物 B的酸值最多为5，羟值为5〜800，平均每个分子为0.1〜5个羟基。

8. 发明授权

US5502148A Two-component polyurethane coating compositions and their use for coating or sealing floors 失效
标题翻译：双组分聚氨酯涂料组合物及其用于涂层或密封地板的用途
公开(公告)号：US5502148A
公开(公告)日：1996-03-26
申请号：US182871
申请日：1994-01-18
申请人： Karl-Heinz Hentschel , Ulrich Walter , Bernd Riberi
发明人： Karl-Heinz Hentschel , Ulrich Walter , Bernd Riberi
IPC分类号： C08G18/42 , C08G18/40 , C08G18/48 , C08G18/72 , C08G18/73 , C08G18/78 , C08G18/79 , C09D175/00 , C09D175/04 , C08G18/74
CPC分类号： C08G18/4009 , C08G18/725 , C08G18/78 , C08G18/79 , C09D175/04
摘要： Two-component polyurethane coating compositions essentially containing A) a polyisocyanate component containing A1) certain aliphatic polyisocyanates and A2) certain aromatic polyisocyanates, B) a polyol component containing B1) selected polycaprolactone polyols and/or selected polyether polyols, and optionally B2) other organic polyhydroxyl compounds, and C) known additives used in surface coating technology; and the application of such coating compositions for the manufacture of floor sealers or thin coatings.
摘要翻译：双组分聚氨酯涂料组合物，其基本上包含A）含有Al）某些脂族多异氰酸酯和A2）某些芳族多异氰酸酯的多异氰酸酯组分，B）含有B1）选择的聚己内酯多元醇和/或选择的聚醚多元醇，以及任选的B2）其它有机多羟基化合物和C）表面涂层技术中使用的已知添加剂; 以及这种用于制造地板密封剂或薄涂层的涂料组合物的应用。

9. 发明授权

US4442145A Process for coating substrates with polyisocyanates and polyhydroxy polyacrylates 失效
标题翻译：用多异氰酸酯和多羟基聚丙烯酸酯涂覆基材的方法
公开(公告)号：US4442145A
公开(公告)日：1984-04-10
申请号：US393224
申请日：1982-06-28
申请人： Joachim Probst , Bernd Riberi , Gunter Kolb, deceased , Peter Hohlein
发明人： Joachim Probst , Bernd Riberi , Gunter Kolb, deceased , Peter Hohlein
IPC分类号： C08G18/00 , B05D7/24 , C08G18/62 , B05D3/02
CPC分类号： C08G18/6229
摘要： The invention relates to a process for the production of coatings using a coating composition containing as binder optionally blocked lacquer-grade polyisocyanates in combination with polyhydroxy polyacrylate resins based on copolymers of certain hydroxy alkyl(meth)acrylates, methyl methacrylate, 2-ethylhexyl acrylate and, optionally, (meth)acrylic acid, wherein the molecular weight is in the range from about 30,000 to 80,000, the content of low molecular weight constituents having molecular weights of at most about 3000 amounts to between 3 and 15% by weight, the molecular heterogeneity factor amounts to between about 1.0 and 10.0, and the parameter for the chemical heterogeneity of the copolymer is between 0 and about 0.06.
摘要翻译：本发明涉及一种使用涂料组合物制备涂料的方法，所述涂料组合物含有作为粘合剂的任选封闭的漆级多异氰酸酯与多羟基聚丙烯酸酯树脂的组合，所述聚羟基聚异氰酸酯基于某些羟基烷基（甲基）丙烯酸酯，甲基丙烯酸甲酯，丙烯酸2-乙基己酯和，任选地，（甲基）丙烯酸，其中分子量在约30,000至80,000的范围内，分子量至多约3000的低分子量组分的含量为3至15重量％，分子量异质因子在约1.0和10.0之间，共聚物的化学异质性参数在0和约0.06之间。

10. 发明授权

US5747628A Polyisocyanates containing ether and urethane groups, a process for their preparation and their use in the production of polyurethane lacquers 失效
标题翻译：含有醚和氨基甲酸酯基团的聚异氰酸酯，其制备方法及其在生产聚氨酯漆中的应用
公开(公告)号：US5747628A
公开(公告)日：1998-05-05
申请号：US984596
申请日：1992-12-02
申请人： Lutz Schmalstieg , Hermann Gruber , Bernd Riberi , Klaus Nachtkamp
发明人： Lutz Schmalstieg , Hermann Gruber , Bernd Riberi , Klaus Nachtkamp
IPC分类号： C08G18/32 , C07C271/28 , C08G18/10 , C08G18/73 , C08G18/80 , C09D175/00 , C09D175/04 , C09D175/06 , C09D175/08 , C07C269/02 , C07C271/26 , C08G18/76
CPC分类号： C07C271/28 , C08G18/10 , C08G18/8029 , C09D175/06
摘要： Polyisocyanates based on polyhydroxy polyethers and tolylene diisocyanate containing ether and urethane groups and having an isocyanate group content of from 11.8 to 14.4% by weight, an average isocyanate functionality of from 3.1 to 4.0 and a free tolylene diisocyanate content of less than 0.1% by weight are produced by reacting a polyhydroxy polyether having a molecular weight in the range of from about 350 to about 500 with excess quantities of tolylene diisocyanate and subsequently distilling the mixture to remove unreacted excess of the starting diisocyanate. These polyisocyanates are particularly useful in the production of polyurethane lacquers.
摘要翻译：基于多羟基聚醚的多异氰酸酯和含有醚和氨基甲酸酯基团的甲苯二异氰酸酯，异氰酸酯基含量为11.8至14.4重量％，平均异氰酸酯官能度为3.1至4.0，游离甲苯二异氰酸酯含量小于0.1重量％通过使分子量为约350至约500的多羟基聚醚与过量的甲苯二异氰酸酯反应制备，随后蒸馏混合物以除去未反应的过量的起始二异氰酸酯。这些多异氰酸酯特别可用于生产聚氨酯漆。

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