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    • 1. 发明授权
    • Method of forming a nitride or carbonitride layer
    • 形成氮化物或碳氮化物层的方法
    • US5443662A
    • 1995-08-22
    • US84322
    • 1993-06-30
    • Tohru AraiKazuyuki NakanishiHiromasa TakedaHideo Tachikawa
    • Tohru AraiKazuyuki NakanishiHiromasa TakedaHideo Tachikawa
    • C23C8/06C23C8/24C23C8/30C23C16/442C23C16/44B05D1/22
    • C23C16/442
    • A nitride or carbonitride layer is formed on the surface of a metal material as follows: A treating agent composed of a refractory powder of alumina or the like and a powder of a metal for forming a nitride or a carbide or an alloy thereof is disposed in a fluidized bed furnace; the treating agent is fluidized to form a fluidized bed by introducing an inert gas; the fluidized bed furnace is heated to a temperature of not higher than 700.degree. C.; an activator of a halogenated ammonium salt is intermittently supplied into the fluidized bed at a rate of 0.001 to 5 wt %/hour based on the total amount of the treating agent; and the metal material to be treated is disposed in the fluidized bed during or after any of the above steps. For example, a nitride layer composed of only a metal for forming a nitride which contains almost no Fe--N is formed on the surface of iron steel even at a temperature as low as not higher than 700.degree. C. The layer is very hard and efficient in wear resistance, and the toughness of the base metal is hardly lowered.
    • 在金属材料的表面上如下形成氮化物或碳氮化物层:由氧化铝等的耐火材料粉末和用于形成氮化物的金属粉末或其合金构成的处理剂设置在 流化床炉; 通过引入惰性气体使处理剂流化形成流化床; 将流化床炉加热至不高于700℃的温度; 基于处理剂的总量,以0.001至5重量%/小时的速率将卤化铵盐的活化剂间歇地供给到流化床中; 并且在任何上述步骤期间或之后将要处理的金属材料设置在流化床中。 例如,即使在700℃以下的温度下,也在铁钢的表面上形成仅由形成几乎不含Fe-N的氮化物的金属构成的氮化物层。该层非常硬, 耐磨损性高,贱金属的韧性几乎不降低。