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1. 发明授权

US06878841B2 Diethyloctandioldicarbamates and diethyloctandioldiallophanates, method for the production and use thereof 失效
标题翻译：二十二烷基二恶唑烷酸酯和二乙基辛二酸二乙酯，生产和使用方法
公开(公告)号：US06878841B2
公开(公告)日：2005-04-12
申请号：US10182528
申请日：2001-01-24
申请人： Heinz-Peter Rink , Jochem Henkelmann , Werner-Alfons Jung , Paul J. Harris , Swaminathan Ramesh
发明人： Heinz-Peter Rink , Jochem Henkelmann , Werner-Alfons Jung , Paul J. Harris , Swaminathan Ramesh
IPC分类号： C07C269/04 , C07C271/12 , C07C275/60 , C08K5/205 , C08K5/21 , C09D179/00 , C09D201/02 , C09J7/02 , C09J179/00 , C09J201/02 , C07C261/00
CPC分类号： C08K5/21 , C07C271/12 , C07C275/60 , C08K5/205
摘要： Positionally isomeric diethyloctanediol dicarbamates and diethyloctanediol diallophanates, processes for preparing them, and their use as synthesis building blocks and constituents of adhesives, sealing compounds, and coating materials.
摘要翻译：位置异构的二乙基辛二醇二氨基甲酸酯和二乙二醇二环戊二酸酯，它们的制备方法，以及它们作为粘合剂，密封化合物和涂料的合成结构单元和成分的用途。

2. 发明申请

US20080249250A1 Copolymers Containing Lateral Carbamate Groups And Groups Which Can Be Activated With Actinic Radiation, Processes For Preparing Them, And Their Use 审中-公开
标题翻译：含有侧链氨基甲酸酯基团和可以用光化学辐射活化的基团的共聚物，用于制备它们的方法及其用途
公开(公告)号：US20080249250A1
公开(公告)日：2008-10-09
申请号：US11995839
申请日：2006-07-18
申请人： Heinz-Peter Rink , Wilma Nimz , Ulrike Rockrath , Eva Wagner , Swaminathan Ramesh , Paul J. Harris
发明人： Heinz-Peter Rink , Wilma Nimz , Ulrike Rockrath , Eva Wagner , Swaminathan Ramesh , Paul J. Harris
IPC分类号： C08G69/08 , C08G12/00 , C08G18/00 , C08F226/00
CPC分类号： C08F8/14 , C08F220/14 , C08F220/28 , C08F220/32 , C08F220/36 , C08F2800/20 , C08F2810/30 , C08J3/243 , C08J2333/06 , C09D133/14 , C08F2220/325 , C08F2220/346 , C08F212/08 , C08F2220/1825 , C08F220/20
摘要： Copolymers (A) containing lateral, primary and/or secondary carbamate groups (a12) and groups (a31) which can be activated with actinic radiation, preparable byI. in a first process step copolymerizing (a1) a monomer containing (a11) a group of the general formula I: CH2═C(R)C(O)—O—, (I) in which the variable R is a hydrogen atom, a halogen atom, a nitrile group or an alkyl group having 1 to 10 carbon atoms, and (a12) a primary and/or secondary carbamate group, and (a2) a monomer containing (a21) a free-radically or ironically polymerizable, olefinically unsaturated double bond and (a22) a reactive functional group which is not reactive with the carbamate groups (a12) and is not polymerizable with the double bond (a21), to give the copolymer (a1/a2), and II. in a further process step, reacting the copolymer (a1/a2) with (a3) a compound containing (a31) a group which can be activated with actinic radiation and (a32) a reactive functional group complementary to the reactive functional group (a22), to give the copolymer (A); processes for preparing them, and their use.
摘要翻译：共聚物（A）含有侧链，伯胺和/或仲氨基甲酸酯基团（a12）和可以用光化辐射活化的基团（a31），其可由I制备，在第一工艺步骤中，共聚（a1）含（a11）通式I的基团：<？in-line-formula description =“In-line formula”end =“lead”？> CH 2 -C（R）C（O）-O- ，（I）<？in-line-formula description =“In-line formula”end =“tail”？>其中变量R是氢原子，卤素原子，腈基或具有1〜 10个碳原子和（a12）伯和/或仲氨基甲酸酯基团，和（a2）含有（a21）自由基或可讽刺可聚合的烯属不饱和双键的单体和（a22）不是与氨基甲酸酯基（a12）反应，与双键（a21）不可聚合，得到共聚物（a1 / a2），和II。在另一工艺步骤中，使共聚物（a1 / a2）与（a3）含有（a31）可以用光化辐射活化的基团的化合物和（a32）与反应性官能团（a22）互补的反应性官能团，得到共聚物（A）; 制备它们的过程及其用途。

3. 发明申请

US20060128901A1 Clearcoat paint composition 有权
标题翻译：清漆涂料组成
公开(公告)号：US20060128901A1
公开(公告)日：2006-06-15
申请号：US11227868
申请日：2005-09-15
申请人： Swaminathan Ramesh , Donald Campbell , Marvin Green , Heinz-Peter Rink
发明人： Swaminathan Ramesh , Donald Campbell , Marvin Green , Heinz-Peter Rink
IPC分类号： C08F120/08
CPC分类号： C09D133/06 , C08F8/14 , C08F220/06 , C08F220/18 , C08F220/32 , C08F220/36 , C09D4/00 , C09D133/062 , C09D201/025 , C08L2666/02
摘要： A coating composition including a copolymerization product of a mixture of monomers including one or more carbamate-functional monomers and (meth)acrylic monomers, some having carboxylic acid-functionality. The monomer mixture is essentially free of hydroxyl monomers. The coating composition may be a solvent-borne clearcoat coating composition, preferably an automotive clearcoat coating composition, that may be applied over a water-borne basecoat coating composition.
摘要翻译：一种涂料组合物，其包含包含一种或多种氨基甲酸酯官能单体和（甲基）丙烯酸单体的单体混合物的共聚产物，一些具有羧酸官能团。单体混合物基本上不含羟基单体。涂料组合物可以是可涂覆在水性底涂层组合物上的溶剂型透明涂料涂料组合物，优选汽车透明涂料涂料组合物。

4. 发明授权

US07342071B2 Clearcoat paint composition 有权
标题翻译：清漆涂料组成
公开(公告)号：US07342071B2
公开(公告)日：2008-03-11
申请号：US11227868
申请日：2005-09-15
申请人： Swaminathan Ramesh , Donald H. Campbell , Marvin L Green , Heinz-Peter Rink
发明人： Swaminathan Ramesh , Donald H. Campbell , Marvin L Green , Heinz-Peter Rink
IPC分类号： C08L29/02
CPC分类号： C09D133/06 , C08F8/14 , C08F220/06 , C08F220/18 , C08F220/32 , C08F220/36 , C09D4/00 , C09D133/062 , C09D201/025 , C08L2666/02
摘要： A coating composition including a copolymerization product of a mixture of monomers including one or more carbamate-functional monomers and (meth)acrylic monomers, some having carboxylic acid-functionality. The monomer mixture is essentially free of hydroxyl monomers. The coating composition may be a solvent-borne clearcoat coating composition, preferably an automotive clearcoat coating composition, that may be applied over a water-borne basecoat coating composition.
摘要翻译：一种涂料组合物，其包括包含一种或多种氨基甲酸酯官能单体和（甲基）丙烯酸单体的单体混合物的共聚产物，一些具有羧酸官能团。单体混合物基本上不含羟基单体。涂料组合物可以是可涂覆在水性底涂层组合物上的溶剂型透明涂料涂料组合物，优选汽车透明涂料涂料组合物。

5. 发明申请

US20070059451A1 Clearcoat paint composition 审中-公开
标题翻译：清漆涂料组成
公开(公告)号：US20070059451A1
公开(公告)日：2007-03-15
申请号：US11227891
申请日：2005-09-15
申请人： Swaminathan Ramesh , Heinz-Peter Rink
发明人： Swaminathan Ramesh , Heinz-Peter Rink
IPC分类号： B05D7/00
CPC分类号： C09D201/025 , B05D7/577 , B05D2502/005 , C08J7/047 , C08J2369/00 , C08J2433/00 , C08L33/06 , C09D133/14 , C08L2666/04
摘要： A coating composition including an aqueous dispersion of a copolymerization product of a mixture of monomers including carbamate-functional and (meth)acrylic monomers, some having carboxylic acid-functionality. The monomer mixture is essentially free of hydroxyl monomer. The coating can be applied on a polycarbonate substrate. The coating composition may be a clearcoat coating composition, preferably an automotive clearcoat coating composition. The invention provides a method of producing such a coating and application on a substrate, particularly as a basecoat/clearcoat composite coating, with the coating composition of the invention preferably being at least the clearcoat of the composite coating. If the substrate is a polycarbonate, the clearcoat can be applied directly on the substrate without any primer or basecoat.
摘要翻译：一种涂料组合物，其包含包含氨基甲酸酯官能和（甲基）丙烯酸单体的单体混合物的共聚产物的水分散体，一些具有羧酸官能团。单体混合物基本上不含羟基单体。涂层可以涂在聚碳酸酯基材上。涂料组合物可以是透明涂料涂料组合物，优选汽车透明涂料涂料组合物。本发明提供了一种在基材上，特别是作为底涂/透明涂层复合涂层生产这种涂料和涂料的方法，本发明的涂料组合物优选至少为复合涂料的透明涂料。如果基材是聚碳酸酯，则可以将透明涂层直接涂布在基材上，而无需任何底漆或底漆。

6. 发明授权

US06849686B2 Polymeric pigment dispersant utilized as a grind resin for pigments and method of preparing the same 失效
标题翻译：用作颜料研磨树脂的聚合颜料分散剂及其制备方法
公开(公告)号：US06849686B2
公开(公告)日：2005-02-01
申请号：US09963951
申请日：2001-09-25
申请人： Joseph F. Michalec , Swaminathan Ramesh , Paul J. Harris
发明人： Joseph F. Michalec , Swaminathan Ramesh , Paul J. Harris
IPC分类号： B01F17/00 , B01F17/52 , C08F8/40 , C09B67/46 , C09C1/36 , C09C3/08 , C09C3/10 , C09D7/45 , C09D17/00 , C08L62/00
CPC分类号： B01F17/0028 , B01F17/005 , B01F17/0057 , B01F17/0064 , C01P2004/61 , C01P2006/22 , C08F8/40 , C09B67/009 , C09C1/3676 , C09C3/08 , C09C3/10 , C09D7/45 , C09D17/00 , C09D17/004
摘要： The present invention is directed to a polymeric pigment dispersant to be used as a grind resin to incorporate pigment into a pigment dispersion for a coating composition. The polymeric pigment dispersant is the reaction product of dipentaerylthritol, hexahydrophthalic anhydride, glycidylneodecanoate, dimethylethanolamine, and polyphosphoric acid. The present invention is also directed to a method of preparing the polymeric pigment dispersant. In this method, the dipentaerythritol and the hexahydrophthalic anhydride are polymerized to form an intermediate compound. Next, an epoxy group of the glycidylneodecanoate reacts with the intermediate compound, and then the dimethylethanolamine salts the intermediate compound. Finally, the polyphosphoric acid is added to form the completed polymeric pigment dispersant. The polymeric pigment dispersant has improved stability in the pigment dispersion and is utilized for efficient wetting and grinding of the pigment in the pigment dispersion.
摘要翻译：本发明涉及一种用作研磨树脂的聚合颜料分散剂，以将颜料掺入用于涂料组合物的颜料分散体中。聚合颜料分散剂是二戊二醇，六氢邻苯二甲酸酐，缩水甘油基癸酸癸酯，二甲基乙醇胺和多磷酸的反应产物。本发明还涉及制备聚合颜料分散剂的方法。在该方法中，将二季戊四醇和六氢邻苯二甲酸酐聚合形成中间体化合物。接着，缩水甘油基新癸酸酯的环氧基与中间体化合物反应，然后二甲基乙醇胺对中间体化合物进行盐化。最后，加入多磷酸以形成完成的聚合颜料分散剂。聚合颜料分散剂具有改善的颜料分散体的稳定性，并用于颜料分散体中颜料的有效润湿和研磨。

7. 发明授权

US06812297B2 Coating systems containing modified crosslinkers 有权
标题翻译：包含改性交联剂的涂料体系
公开(公告)号：US06812297B2
公开(公告)日：2004-11-02
申请号：US10216351
申请日：2002-08-09
申请人： Swaminathan Ramesh , Paul Lessek , Paul J. Harris
发明人： Swaminathan Ramesh , Paul Lessek , Paul J. Harris
IPC分类号： C08L8304
CPC分类号： C09D167/00 , C08G12/40 , C08G12/427 , C08L61/20 , C08L83/04 , C09D161/20 , C09D161/32 , C08L2666/02
摘要： The present invention provides a crosslinker for organic coatings having an amino resin core with substituents including more than one olefin functional group, a silicon-containing group, and at least one alkoxyalkyl or alkylol group. Coating compositions containing the crosslinker can be cured with radiation, especially ultraviolet radiation. The crosslinker can be included in a coating composition with one or more curable resins, applied onto a substrate and cured to form the cured coating of the invention.
摘要翻译：本发明提供了一种用于有机涂层的交联剂，其具有具有包含多于一个烯属官能团，含硅基团和至少一个烷氧基烷基或羟烷基的取代基的氨基树脂核心。含有交联剂的涂料组合物可以用辐射，特别是紫外线辐射固化。交联剂可以包含在具有一种或多种可固化树脂的涂料组合物中，施加到基材上并固化以形成本发明的固化涂层。

8. 发明授权

US07342075B2 Carbamate functional addition polymers and method for their preparation 失效
标题翻译：氨基甲酸酯官能加成聚合物及其制备方法
公开(公告)号：US07342075B2
公开(公告)日：2008-03-11
申请号：US10957556
申请日：2004-10-01
申请人： Swaminathan Ramesh , Paul J. Harris , Walter H. Ohrbom , Donald H. Campbell , Donald L. St. Aubin , Ulrike Röckrath
发明人： Swaminathan Ramesh , Paul J. Harris , Walter H. Ohrbom , Donald H. Campbell , Donald L. St. Aubin , Ulrike Röckrath
IPC分类号： C08F8/28
CPC分类号： C08F220/06 , C08F8/00 , C08F8/14 , C08F220/08 , C08F222/20 , C08F222/22 , C08L2312/00 , C09D133/14 , C09D201/025 , C08F265/06
摘要： Disclosed is a method for making nongelled addition polymers, especially carbamate functional additional polymers from linear unsaturated anhydrides. The method comprises reacting an unsaturated linear anhydride with an active hydrogen compound to provide two monomers comprising polymerizable C═C bonds, at least one of said monomers comprising an acid functional group; polymerizing the polymerizable C═C bonds of the two monomers to provide an acid functional polymerization product; and reacting the acid functional polymerization product with an epoxy functional compound to provide a nongelled addition polymer, wherein the disclosed method does not include a step comprising the physical removal of any acid functional monomers or polymerization products. Also disclosed is a curable coating composition containing the resulting carbamate functional polymer, as well as a coated substrate comprising a cured film resulting from the application and curing of the disclosed curable coating composition.
摘要翻译：公开了一种用于制备非线性加成聚合物，特别是来自线性不饱和酸酐的氨基甲酸酯官能的另外的聚合物的方法。该方法包括使不饱和直链酸酐与活性氢化合物反应以提供包含可聚合C-C键的两种单体，至少一种所述单体包含酸官能团; 聚合两种单体的可聚合C-C键以提供酸官能聚合产物; 并使酸官能聚合产物与环氧官能化合物反应以提供不通电的加成聚合物，其中所公开的方法不包括物理除去任何酸官能单体或聚合产物的步骤。还公开了含有所得氨基甲酸酯官能聚合物的可固化涂料组合物，以及包含由所公开的可固化涂料组合物的施用和固化产生的固化膜的涂布基材。

9. 发明授权

US07267845B2 Coating systems containing modified crosslinkers 有权
标题翻译：包含改性交联剂的涂料体系
公开(公告)号：US07267845B2
公开(公告)日：2007-09-11
申请号：US09747716
申请日：2000-12-22
申请人： Swaminathan Ramesh , Paul Lessek , Paul J. Harris
发明人： Swaminathan Ramesh , Paul Lessek , Paul J. Harris
IPC分类号： B05D3/02 , B05D3/06
CPC分类号： C09D167/00 , C08G12/40 , C08G12/427 , C08L61/20 , C08L83/04 , C09D161/20 , C09D161/32 , C08L2666/02
摘要： The present invention provides a crosslinker for organic coatings having an amino resin core with substituents including more than one olefin functional group, a silicon-containing group, and at least one alkoxyalkyl or alkylol group. Coating compositions containing the crosslinker can be cured with radiation, especially ultraviolet radiation. The crosslinker can be included in a coating composition with one or more curable resins, applied onto a substrate and cured to form the cured coating of the invention.
摘要翻译：本发明提供了一种用于有机涂层的交联剂，其具有具有包含多于一个烯属官能团，含硅基团和至少一个烷氧基烷基或羟烷基的取代基的氨基树脂核心。含有交联剂的涂料组合物可以用辐射，特别是紫外线辐射固化。交联剂可以包含在具有一种或多种可固化树脂的涂料组合物中，施加到基材上并固化以形成本发明的固化涂层。

10. 发明授权

US06642338B2 Water-based acrylic emulsion dispersants utilized as grind resins for pigments and method of preparing the same 失效
公开(公告)号：US06642338B2
公开(公告)日：2003-11-04
申请号：US09747472
申请日：2000-12-22
申请人： Swaminathan Ramesh , JoAnn Lanza , Paul J. Harris
发明人： Swaminathan Ramesh , JoAnn Lanza , Paul J. Harris
IPC分类号： C08F12010
CPC分类号： B01F17/0028 , B01F17/0057 , B01F17/0064 , C01P2004/61 , C01P2006/22 , C08F8/40 , C09D7/45 , C09D17/004
摘要： The present invention is directed to a water-based acrylic emulsion dispersant to be used as a grind resin to incorporate inorganic pigment into a pigment dispersion for a coating composition. The acrylic emulsion dispersant is the reaction product of butyl methacrylate, butyl acrylate, styrene, methyl ether polyethylene glycol methacrylate, polyethylene glycol methacrylate, and polyphosphoric acid. The present invention is also directed to a method of preparing the acrylic emulsion dispersant. In this method, the butyl methacrylate, butyl acrylate, and styrene are combined with water to establish a first reaction blend. Similarly, the methyl ether polyethylene glycol methacrylate and the polyethylene glycol methacrylate are combined with water to establish a second reaction blend. Next, the first and second reaction blends are polymerized to form an intermediate emulsion polymer containing a hydroxyl group from the functionality of the polyethylene glycol methacrylate. Finally, the hydroxyl group from the polyethylene glycol methacrylate is reacted with polyphosphoric acid to form the acrylic emulsion dispersant which is utilized for efficient wetting and grinding of the pigment.

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