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    • 4. 发明授权
    • Water-based acrylic emulsion dispersants utilized as grind resins for pigments and method of preparing the same
    • 用作颜料研磨树脂的水性丙烯酸乳液分散剂及其制备方法
    • US06777519B2
    • 2004-08-17
    • US10619772
    • 2003-07-15
    • Swaminathan RameshJoAnn LanzaPaul J. Harris
    • Swaminathan RameshJoAnn LanzaPaul J. Harris
    • C08F12010
    • B01F17/0028B01F17/0057B01F17/0064C01P2004/61C01P2006/22C08F8/40C09D7/45C09D17/004
    • The present invention is directed to a water-based acrylic emulsion dispersant to be used as a grind resin to incorporate inorganic pigment into a pigment dispersion for a coating composition. The acrylic emulsion dispersant is the reaction product of butyl methacrylate, butyl acrylate, styrene, methyl ether polyethylene glycol methacrylate, polyethylene glycol methacrylate, and polyphosphoric acid. The present invention is also directed to a method of preparing the acrylic emulsion dispersant. In this method, the butyl methacrylate, butyl acrylate, and styrene are combined with water to establish a first reaction blend. Similarly, the methyl ether polyethylene glycol methacrylate and the polyethylene glycol methacrylate are combined with water to establish a second reaction blend. Next, the first and second reaction blends are polymerized to form an intermediate emulsion polymer containing a hydroxyl group from the functionality of the polyethylene glycol methacrylate. Finally, the hydroxyl group from the polyethylene glycol methacrylate is reacted with polyphosphoric acid to form the acrylic emulsion dispersant which is utilized for efficient wetting and grinding of the pigment.
    • 本发明涉及一种水性丙烯酸乳液分散剂,用作研磨树脂,以将无机颜料掺入用于涂料组合物的颜料分散体中。 丙烯酸乳液分散剂是甲基丙烯酸丁酯,丙烯酸丁酯,苯乙烯,甲基醚聚乙二醇甲基丙烯酸酯,聚乙二醇甲基丙烯酸酯和多磷酸的反应产物。 本发明还涉及一种制备丙烯酸乳液分散剂的方法。 在该方法中,将甲基丙烯酸丁酯,丙烯酸丁酯和苯乙烯与水混合以形成第一反应混合物。 类似地,将甲基醚聚乙二醇甲基丙烯酸酯和聚乙二醇甲基丙烯酸酯与水混合以形成第二反应混合物。 接下来,将第一和第二反应混合物聚合以形成从聚乙二醇甲基丙烯酸酯的官能团含有羟基的中间乳液聚合物。 最后,将来自聚乙二醇甲基丙烯酸酯的羟基与多磷酸反应形成用于有效润湿和研磨颜料的丙烯酸乳液分散剂。