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1. 发明申请

US20140127121A1 METHOD FOR THE PARALLEL PRODUCTION OF HYDROGEN AND CARBON-CONTAINING PRODUCTS 有权
标题翻译：平行生产含氢和含碳产品的方法
公开(公告)号：US20140127121A1
公开(公告)日：2014-05-08
申请号：US14131124
申请日：2012-07-06
申请人： Hans-Juergen Maass , Volker Goeke , Otto Machhammer , Marcus Guzmann , Christian Schneider , Wolfgang Alois Hormuth , Andreas Bode , Drik Klingler , Matthias Kern , Grigorios Kolios
发明人： Hans-Juergen Maass , Volker Goeke , Otto Machhammer , Marcus Guzmann , Christian Schneider , Wolfgang Alois Hormuth , Andreas Bode , Drik Klingler , Matthias Kern , Grigorios Kolios
IPC分类号： C01B3/24 , C01B31/02
CPC分类号： C01B3/24 , C01B3/28 , C01B3/30 , C01B32/05 , C01B2203/0272 , C01B2203/04 , C01B2203/0425 , C01B2203/0485 , C01B2203/049 , C01B2203/06 , C01B2203/0805 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0866 , C01B2203/1235 , C01B2203/1258 , C10B57/005 , Y02P20/128
摘要： The invention relates to a process for parallel preparation of hydrogen and one or more carbonaceous products, in which hydrocarbons are introduced into a reaction space (R) and decomposed thermally to carbon and hydrogen in the presence of carbon-rich pellets (W). It is a feature of the invention that at least a portion of the thermal energy required for the hydrocarbon decomposition is introduced into the reaction space (R) by means of a gaseous heat carrier.
摘要翻译：本发明涉及氢和一种或多种碳质产物的并行制备方法，其中在富含碳的颗粒（W）的存在下，将烃引入反应空间（R）并热分解成碳和氢。本发明的一个特征是烃分解所需的热能的至少一部分通过气态热载体引入反应空间（R）。

2. 发明授权

US09359200B2 Method for the parallel production of hydrogen and carbon-containing products 有权
标题翻译：并联生产氢和含碳产品的方法
公开(公告)号：US09359200B2
公开(公告)日：2016-06-07
申请号：US14131124
申请日：2012-07-05
申请人： Hans-Juergen Maass , Volker Goeke , Otto Machhammer , Marcus Guzmann , Christian Schneider , Wolfgang Alois Hormuth , Andreas Bode , Dirk Klingler , Matthias Kern , Grigorios Kolios
发明人： Hans-Juergen Maass , Volker Goeke , Otto Machhammer , Marcus Guzmann , Christian Schneider , Wolfgang Alois Hormuth , Andreas Bode , Dirk Klingler , Matthias Kern , Grigorios Kolios
IPC分类号： C01B3/24 , C01B31/02 , C01B3/28 , C01B3/30 , C10B57/00
CPC分类号： C01B3/24 , C01B3/28 , C01B3/30 , C01B32/05 , C01B2203/0272 , C01B2203/04 , C01B2203/0425 , C01B2203/0485 , C01B2203/049 , C01B2203/06 , C01B2203/0805 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0866 , C01B2203/1235 , C01B2203/1258 , C10B57/005 , Y02P20/128
摘要： The invention relates to a process for parallel preparation of hydrogen and one or more carbonaceous products, in which hydrocarbons are introduced into a reaction space (R) and decomposed thermally to carbon and hydrogen in the presence of carbon-rich pellets (W). It is a feature of the invention that at least a portion of the thermal energy required for the hydrocarbon decomposition is introduced into the reaction space (R) by means of a gaseous heat carrier.
摘要翻译：本发明涉及氢和一种或多种碳质产物的并行制备方法，其中在富含碳的颗粒（W）的存在下，将烃引入反应空间（R）并热分解成碳和氢。本发明的一个特征是烃分解所需的热能的至少一部分通过气态热载体引入反应空间（R）。

3. 发明申请

US20140217327A1 PROCESS FOR PRODUCTION OF SYNTHESIS GAS 有权
标题翻译：生产合成气的方法
公开(公告)号：US20140217327A1
公开(公告)日：2014-08-07
申请号：US14130942
申请日：2012-07-05
申请人： Hans Jurgen Mass , Volker Goke , Otto Machhammer , Marcus Guzmann , Christian Schneider , Wolfgang Alois Hormuth , Andreas Bode , Dirk Klingler , Matthias Kern , Grigorios Kolios
发明人： Hans Jurgen Mass , Volker Goke , Otto Machhammer , Marcus Guzmann , Christian Schneider , Wolfgang Alois Hormuth , Andreas Bode , Dirk Klingler , Matthias Kern , Grigorios Kolios
IPC分类号： C01B3/34
CPC分类号： C01B3/344 , C01B32/40 , C01B2203/0222 , C01B2203/042 , C01B2203/0425 , C01B2203/049 , C01B2203/0822 , C01B2203/085 , C01B2203/0872 , C01B2203/1241 , Y02P20/128 , Y02P20/584
摘要： Process for the production of synthesis gas (3), in which methane and carbon dioxide (2) are introduced into a reaction space (R) and reacted in the presence of a solid (W) at elevated temperatures to give hydrogen and carbon monoxide. Methane and carbon dioxide are passed through a carbon-containing granular material (W) and reacted in a high-temperature zone (H).
摘要翻译：制备合成气（3）的方法，其中将甲烷和二氧化碳（2）引入反应空间（R）并在固体（W）存在下在升高的温度下反应，得到氢气和一氧化碳。甲烷和二氧化碳通过含碳颗粒材料（W）并在高温区（H）中反应。

4. 发明授权

US09266731B2 Process for production of synthesis gas 有权
标题翻译：合成气生产工艺
公开(公告)号：US09266731B2
公开(公告)日：2016-02-23
申请号：US14130942
申请日：2012-07-05
申请人： Hans-Jurgen Mass , Volker Goke , Otto Machhammer , Marcus Guzmann , Christian Schneider , Wolfgang Alois Hormuth , Andreas Bode , Dirk Klingler , Matthias Kern , Grigorios Kolios
发明人： Hans-Jurgen Mass , Volker Goke , Otto Machhammer , Marcus Guzmann , Christian Schneider , Wolfgang Alois Hormuth , Andreas Bode , Dirk Klingler , Matthias Kern , Grigorios Kolios
IPC分类号： C01B3/38 , C01B3/34 , C01B31/18
CPC分类号： C01B3/344 , C01B32/40 , C01B2203/0222 , C01B2203/042 , C01B2203/0425 , C01B2203/049 , C01B2203/0822 , C01B2203/085 , C01B2203/0872 , C01B2203/1241 , Y02P20/128 , Y02P20/584
摘要： Process for the production of synthesis gas (3), in which methane and carbon dioxide (2) are introduced into a reaction space (R) and reacted in the presence of a solid (W) at elevated temperatures to give hydrogen and carbon monoxide. Methane and carbon dioxide are passed through a carbon-containing granular material (W) and reacted in a high-temperature zone (H).
摘要翻译：制备合成气（3）的方法，其中将甲烷和二氧化碳（2）引入反应空间（R）并在固体（W）存在下在升高的温度下反应，得到氢气和一氧化碳。甲烷和二氧化碳通过含碳颗粒材料（W）并在高温区（H）中反应。

5. 发明授权

US08497394B2 Sodium diformate production and use 有权
公开(公告)号：US08497394B2
公开(公告)日：2013-07-30
申请号：US13566376
申请日：2012-08-03
申请人： Robert Heinz , Otto Machhammer , Stefan Gropp , Alexander Hauk , Gerd Diebold , Anna Valeska Lohmann , Dieter Feuerstein , Robert Rühle , Rüdiger Schmitt
发明人： Robert Heinz , Otto Machhammer , Stefan Gropp , Alexander Hauk , Gerd Diebold , Anna Valeska Lohmann , Dieter Feuerstein , Robert Rühle , Rüdiger Schmitt
IPC分类号： C07C53/00
CPC分类号： C07C53/06 , A23K20/105 , A23K20/22 , A23K30/00 , A23K30/15 , A23K50/00 , A23K50/30 , A23K50/75 , A23V2002/00 , C05F11/00 , C07C51/02 , C07C51/412 , Y02P20/582 , A23V2200/06
摘要： The invention relates to a method for producing and using a solid sodium diformate having a high formic acid content, to the use thereof in animal foods in the form of an acidifier, preservatives, ensilage auxiliary agents, fertilizers, and a growth and productivity-stimulating agent and the inventive animal food additives containing sodium diformate.

6. 发明申请

US20130005925A1 AQUEOUS SOLUTION COMPRISING ACRYLIC ACID AND THE CONJUGATE BASE THEREOF 有权
标题翻译：包含丙烯酸及其结合基的水溶液
公开(公告)号：US20130005925A1
公开(公告)日：2013-01-03
申请号：US13483705
申请日：2012-05-30
申请人： Frank Hütten , Otto Machhammer , Thomas Daniel , Markus Ottenbacher , Daniel Pfeiffer , Stefanie Herzog , Manfred Heilig , Klaus Joachim Muller-Engel
发明人： Frank Hütten , Otto Machhammer , Thomas Daniel , Markus Ottenbacher , Daniel Pfeiffer , Stefanie Herzog , Manfred Heilig , Klaus Joachim Muller-Engel
IPC分类号： C08F222/02 , C08G16/02 , C08F216/34
CPC分类号： C08G63/81 , C07C51/252 , C07C51/42 , C07C51/47 , C07C57/04 , Y02P20/582
摘要： An aqueous solution containing 10% by weight of acrylic acid and its conjugate base. The solution further contains, based on the amount of acrylic acid and its conjugate base: at least 50 ppm of propionic acid and its conjugate base; at least 200 ppm of formic acid and its conjugate base; at least 3000 ppm of acetic acid and it conjugate base; at most 10 ppm of benzoic acid and its conjugate base; at most 10 ppm of maleic anhydride, maleic acid, and their conjugate bases; at most 10 ppm of phthalic anhydride, phthalic acid, and their conjugate bases; at most 50 ppm of acrolein; at most 50 ppm of benzaldehyde; at most 50 ppm of 2-furaldehyde; and at least 20 mol % of at least one alkali metal cation. A process for preparing this solution and the use of this solution for preparation of a polymer by free-radical polymerization.
摘要翻译：含有10重量％丙烯酸及其共轭碱的水溶液。该溶液还包含基于丙烯酸及其共轭碱的量：至少50ppm丙酸及其共轭碱; 至少200ppm的甲酸及其共轭碱; 至少3000ppm的乙酸及其共轭碱; 至多10ppm的苯甲酸及其共轭碱; 至多10ppm的马来酸酐，马来酸及其共轭碱; 至多10ppm的邻苯二甲酸酐，邻苯二甲酸及其共轭碱; 至多50ppm的丙烯醛; 至多50ppm的苯甲醛; 至多50ppm的2-糠醛; 和至少20摩尔％的至少一种碱金属阳离子。制备该溶液的方法以及通过自由基聚合制备聚合物的该溶液的用途。

7. 发明授权

US07897812B2 Process for preparing acrolein or acrylic acid or a mixture thereof from propane 有权
标题翻译：从丙烷制备丙烯醛或丙烯酸或其混合物的方法
公开(公告)号：US07897812B2
公开(公告)日：2011-03-01
申请号：US11751202
申请日：2007-05-21
申请人： Otto Machhammer , Klaus Joachim Mueller-Engel , Martin Dieterle
发明人： Otto Machhammer , Klaus Joachim Mueller-Engel , Martin Dieterle
IPC分类号： C07C51/16 , C07B41/00
CPC分类号： C07C45/35 , C07C45/33 , C07C51/215 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for preparing acrolein or acrylic acid or a mixture thereof as the target product from propane, in which propane is partially dehydrogenated under heterogeneous catalysis in a reaction zone A, molecular hydrogen formed is at least partly combusted to water, any water present in the product gas A formed in reaction zone A is removed therefrom and product gas A is otherwise used to charge a reaction zone B in which propylene formed in reaction zone A is partially oxidized in the presence of remaining propane to give the target product. The target product is removed from the product gas B formed in reaction zone B and propane present in the remaining residual gas is absorbed therefrom into a solvent and, after release from the absorbate, recycled into reaction zone A.
摘要翻译：制备丙烯醛或丙烯酸或其混合物的方法作为丙烷的目标产物，其中丙烷在反应区A中在非均相催化下部分脱氢，形成的分子氢至少部分地燃烧到水中，存在于在反应区A中形成的产物气体A被除去，产物气体A另外用于给反应区B充电，其中反应区A中形成的丙烯在剩余的丙烷存在下被部分氧化，得到目标产物。将目标产物从反应区B中形成的产物气体B中除去，剩余的残余气体中存在的丙烷从其中吸收到溶剂中，并且在从吸收物质释放后再循环到反应区A中。

8. 发明申请

US20080207975A1 Method For The Production Of Propene From Propane 审中-公开
标题翻译：丙烷生产丙烯的方法
公开(公告)号：US20080207975A1
公开(公告)日：2008-08-28
申请号：US11722367
申请日：2005-12-20
申请人： Sven Crone , Otto Machhammer , Gotz-Peter Schindler
发明人： Sven Crone , Otto Machhammer , Gotz-Peter Schindler
IPC分类号： C07C5/00
CPC分类号： C07C5/3337 , C07C7/04 , C07C11/06
摘要： The invention relates to a process for preparing propene from propane, comprising the steps:A) a feed gas stream a comprising propane is provided;B) the feed gas stream a comprising propane and an oxygenous gas stream are fed into a dehydrogenation zone and propane is subjected to a nonoxidative catalytic, autothermal dehydrogenation to propene to obtain a product gas stream b comprising propane, propene, methane, ethane, ethene, nitrogen, carbon monoxide, carbon dioxide, steam and hydrogen;C) product gas stream b is cooled and steam is removed by condensation to obtain a steam-depleted product gas stream c;D) uncondensable or low-boiling gas constituents are removed by contacting product gas stream c with an inert absorbent and subsequently desorbing the gases dissolved in the inert absorbent to obtain a C3 hydrocarbon stream d1 and an offgas stream d2 comprising methane, ethane, ethene, nitrogen, carbon monoxide, carbon dioxide and hydrogen;E) the C3 hydrocarbon stream d1 is cooled and compressed to obtain a liquid C3 hydrocarbon stream e1;F) the liquid C3− hydrocarbon stream e1 is fed into a first distillation zone and separated distillatively into a stream f1 composed of propane and propene and a stream f2 comprising ethane and ethene;G) stream f1 is fed into a (second) distillation zone and separated distillatively into a product stream g1 composed of propene and a stream g2 composed of propane, and stream g2 is recycled at least partly into the dehydrogenation zone.
摘要翻译：本发明涉及一种从丙烷制备丙烯的方法，包括以下步骤：A）提供包含丙烷的原料气流a; B）将包含丙烷和含氧气流的原料气流a进料到脱氢区，丙烷经受非氧化催化，自热脱氢至丙烯以获得包含丙烷，丙烯，甲烷，乙烷，乙烯的产物气流b ，氮气，一氧化碳，二氧化碳，蒸气和氢气; C）产物气流b被冷却并通过冷凝除去蒸汽，得到蒸汽消耗产物气流c; D）通过使产物气流c与惰性吸收剂接触并随后将溶解在惰性吸收剂中的气体解吸，得到C 3 N 3烃流d 1和废气，除去不可冷凝或低沸点气体成分流d 2包含甲烷，乙烷，乙烯，氮气，一氧化碳，二氧化碳和氢气; E）将C 3 C 3烃流d 1冷却并压缩，得到液体C 3烃流e1; F）将液体C 3 - C 3 - 烃流e 1进料到第一蒸馏区并蒸馏分离成由丙烷和丙烯组成的料流f 1和包含乙烷和乙烯的料流f 2; G）流f 1进料到（第二）蒸馏区并蒸馏分离成由丙烯构成的产物流g 1和由丙烷组成的料流g 2，并且流g 2至少部分地再循环到脱氢区中。

9. 发明申请

US20080182001A1 Sodium Diformate Production and Use 审中-公开
标题翻译：钠形态生产和使用
公开(公告)号：US20080182001A1
公开(公告)日：2008-07-31
申请号：US11911292
申请日：2006-04-12
申请人： Robert Heinz , Otto Machhammer , Stefan Gropp , Alexander Hauk , Gerd Diebold , Anna Valeska Lohmann , Dieter Feuerstein , Robert Ruhle , Rudiger Schmitt
发明人： Robert Heinz , Otto Machhammer , Stefan Gropp , Alexander Hauk , Gerd Diebold , Anna Valeska Lohmann , Dieter Feuerstein , Robert Ruhle , Rudiger Schmitt
IPC分类号： A23K1/00 , C07C53/06
CPC分类号： C07C53/06 , A23K20/105 , A23K20/22 , A23K30/00 , A23K30/15 , A23K50/00 , A23K50/30 , A23K50/75 , A23V2002/00 , C05F11/00 , C07C51/02 , C07C51/412 , Y02P20/582 , A23V2200/06
摘要： The invention relates to a method for producing and using a solid sodium diformate having a high formic acid content, to the use thereof in animal foods in the form of an acidifier, preservatives, ensilage auxiliary agents, fertilizers, and a growth and productivity-stimulating agent and the inventive animal food additives containing sodium diformate.
摘要翻译：本发明涉及一种用于生产和使用具有高甲酸含量的固体二甲酸钠的方法，其用于在酸化剂，防腐剂，青贮助剂，肥料和生长和生产力刺激的形式的动物食品中的用途药剂和含有二甲酸钠的本发明动物食品添加剂。

10. 发明授权

US07345167B2 Method for the production of maleic anhydride 失效
标题翻译：马来酸酐生产方法
公开(公告)号：US07345167B2
公开(公告)日：2008-03-18
申请号：US10565889
申请日：2004-07-06
申请人： Mark Duda , Otto Machhammer , Alexander Weck
发明人： Mark Duda , Otto Machhammer , Alexander Weck
IPC分类号： C07D307/60
CPC分类号： C07C51/215 , C07C57/145
摘要： A process for preparing maleic anhydride by oxidizing n-butane in the gas phase under heterogeneous catalysis with oxygen-containing gases over a vanadium-, phosphorus- and oxygen-containing catalyst in a reactor unit at a temperature in the range from 350 to 500° C., removing the maleic anhydride formed to form a gas stream which comprises unconverted n-butane and water and recycling at least a portion of the unconverted n-butane to the reactor unit, by feeding to the reactor unit an inlet stream having an n-butane concentration of from 0.5 to 1.5% by volume and an oxygen concentration of from 5 to 21% by volume, establishing a pressure at the inlet to the reactor unit of from 0.4 to 2 MPa abs, and converting from 40 to 100% of the n-butane from the inlet stream per reactor pass.
摘要翻译：在反应器单元中的含钒，含磷和氧的催化剂中，在350〜500℃的温度范围内，用含氧气体在非均相催化下，在气相中氧化正丁烷，制备马来酸酐的方法 C.去除形成的马来酸酐以形成包含未转化的正丁烷和水的气流，并将未转化的正丁烷的至少一部分再循环到反应器单元，通过向反应器单元供给具有n - 丁烷浓度为0.5至1.5体积％，氧浓度为5至21体积％，在反应器单元入口处建立压力为0.4至2MPa abs，并将40至100％来自每个反应器的入口流的正丁烷通过。

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