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1. 发明授权

US09819036B2 Method of plasma-catalyzed, thermally-integrated reforming 有权
公开(公告)号：US09819036B2
公开(公告)日：2017-11-14
申请号：US14948613
申请日：2015-11-23
申请人： Ceramatec, Inc.
发明人： Joseph J Hartvigsen , Singaravelu Elangovan , Piotr Czernichowski , Michele Hollist , Michael Boettcher
IPC分类号： H01M8/12 , C01B3/00 , H01M8/0612 , C01B3/34 , C01B3/38 , H01M8/086 , H01M8/14 , H01M8/124
CPC分类号： H01M8/0618 , C01B3/342 , C01B3/384 , C01B2203/0233 , C01B2203/0445 , C01B2203/062 , C01B2203/066 , C01B2203/0805 , C01B2203/0861 , C01B2203/0866 , H01M8/0643 , H01M8/086 , H01M8/12 , H01M8/145 , H01M2008/1293 , H01M2008/147 , H01M2250/405 , H01M2300/0051 , H01M2300/0074 , Y02B90/16 , Y02E60/50 , Y02P20/129
摘要： A reformer is disclosed in one embodiment of the invention as including a channel to convey a preheated plurality of reactants containing both a feedstock fuel and an oxidant. A plasma generator is provided to apply an electrical potential to the reactants sufficient to ionize one or more of the reactants. These ionized reactants are then conveyed to a reaction zone where they are chemically transformed into synthesis gas containing a mixture of hydrogen and carbon monoxide. A heat transfer mechanism is used to transfer heat from an external heat source to the reformer to provide the heat of reformation.

2. 发明申请

US20170197894A1 PROCESS FOR PRODUCTION OF METHANOL 审中-公开
公开(公告)号：US20170197894A1
公开(公告)日：2017-07-13
申请号：US15304891
申请日：2015-04-24
申请人： Haldor Topsøes A/S
发明人： Ib DYBKJÆR
IPC分类号： C07C29/151 , C01B3/12 , B01D53/26 , B01J19/00 , B01D53/22 , B01D53/047 , C07C29/152 , C01B3/56
CPC分类号： C07C29/1518 , B01D53/047 , B01D53/22 , B01D53/265 , B01D2256/16 , B01D2257/11 , B01D2257/40 , B01D2257/502 , B01D2257/504 , B01D2257/7025 , B01J19/0013 , B01J2219/00051 , C01B3/12 , C01B3/56 , C01B2203/0283 , C01B2203/04 , C01B2203/042 , C01B2203/061 , C01B2203/0805 , C01B2203/0872 , C07C29/152 , Y02P20/132 , C07C31/04
摘要： The present application relates to a process comprising the steps of—providing a purge stream from a synthesis section,—preheating at least part of said purge stream,—adding steam to the preheated purge stream to obtain a first mixed stream,—passing the first mixed stream through a shift conversion step thereby obtaining a conversion product stream,—passing at least part of the conversion product stream through a H2 separation step producing a H2 enriched stream and a H2 depleted waste stream, and —returning at least part of said H2 enriched stream to and/or upstream the synthesis section.

3. 发明授权

US09505617B2 Radiating wall catalytic reactor and process for carrying out a chemical reaction in this reactor 有权
标题翻译：辐射壁催化反应器和在该反应器中进行化学反应的方法
公开(公告)号：US09505617B2
公开(公告)日：2016-11-29
申请号：US14772619
申请日：2014-03-04
申请人： Alantum Europe GmbH
发明人： Stanislaw Tadeusz Kolaczkowski , Dirk Naumann , Shadi Saberi , Babak Saberi
IPC分类号： B01J8/04 , C01B3/38 , B01J8/06 , B01J8/00 , B01J19/24
CPC分类号： C01B3/384 , B01J8/008 , B01J8/0453 , B01J8/048 , B01J8/062 , B01J19/24 , B01J2208/00504 , B01J2208/00522 , B01J2208/00884 , B01J2208/025 , B01J2219/00024 , B01J2219/00087 , B01J2219/24 , C01B2203/0233 , C01B2203/0805 , C01B2203/1241 , C01B2203/143
摘要： Disclosed are a radiating wall catalytic reactor for providing heat from the inside wall surface 8 of a reaction chamber 1 by radiation 16 to support an overall endothermic gas phase chemical reaction taking place in the reaction chamber 1, and a process for carrying out a chemical reaction in the reactor. The reaction chamber 1 is provided with an entrance port 2 for introducing a gaseous reactant(s) in a continuous manner into the chamber 1 and an exit port 3 to enable the gaseous product(s) to leave the chamber 1 in a continuous manner. The reaction chamber 1 includes a plurality of catalyst segments (A)5, which has one void segment (B)6 on either side of it; and the reaction chamber 1 is made of a material(s) that is (are) suitable to resist a temperature of 700° C. or more.
摘要翻译：公开了一种用于通过辐射16从反应室1的内壁表面8提供热量以支持在反应室1中发生的总体吸热气相化学反应的辐射壁催化反应器，以及用于进行化学反应的方法在反应堆。反应室1设置有用于将气态反应物以连续方式引入室1的入口2和出口3，以使得气态产物能够以连续的方式离开室1。反应室1包括多个催化剂段（A）5，其在其两侧具有一个空隙段（B）6; 并且反应室1由适于抵抗700℃或更高温度的材料制成。

4. 发明申请

US20160340184A1 SYSTEMS AND METHODS FOR PRODUCING HYDROGEN GAS 审中-公开
标题翻译：用于生产氢气的系统和方法
公开(公告)号：US20160340184A1
公开(公告)日：2016-11-24
申请号：US15227826
申请日：2016-08-03
申请人： Elwha LLC
发明人： Roderick A. Hyde , Lowell L. Wood, JR.
IPC分类号： C01B3/24 , B01J7/00
CPC分类号： C01B3/24 , B01J7/00 , C01B2203/0272 , C01B2203/0277 , C01B2203/0805 , C01B2203/0833 , C01B2203/1235 , C01B2203/1241 , C01B2203/1247
摘要： Systems and methods for thermally decomposing hydrocarbon feedstock may comprise a hydrocarbon feedstock, a non-oxidizing carrier gas, one or more heat exchangers, and a reaction chamber. The carrier gas may be used to transfer heat to the hydrocarbon feedstock. The heat exchanger(s) may be configured to heat the carrier gas. And the reaction chamber may be configured to receive hydrocarbon feedstock and heated carrier gas. Inside the reaction chamber, the hydrocarbon feedstock and the heated carrier gas may mix with one another causing the thermal decomposition reaction. The thermal decomposition reaction occurs in a substantially oxidant-free environment thereby eliminating or greatly reducing the production of carbon oxide byproducts. Hydrogen gas may be separated from a gaseous product stream that is thereafter collected from the reaction chamber. A portion of the gaseous product stream may be thermally coupled to the carrier gas and may thereafter be recycled through the system.
摘要翻译：用于热分解烃原料的系统和方法可以包括烃原料，非氧化载体气体，一个或多个热交换器和反应室。载气可用于将热量转移到烃原料。热交换器可以被配置为加热载气。并且反应室可以被配置成接收烃原料和加热的载气。在反应室内，烃原料和加热的载气可能彼此混合引起热分解反应。热分解反应发生在基本上无氧化剂的环境中，从而消除或大大降低了碳氧化物副产物的产生。氢气可以与之后从反应室收集的气态产物流分离。气体产物流的一部分可以与载气热耦合，然后可以通过系统再循环。

5. 发明授权

US09406957B2 Hydrogen extraction 有权
标题翻译：氢萃取
公开(公告)号：US09406957B2
公开(公告)日：2016-08-02
申请号：US12508032
申请日：2009-07-23
申请人： Gerald Peter Jackson , Jason Ryan Babcock , Joseph Matthew Zlotnicki
发明人： Gerald Peter Jackson , Jason Ryan Babcock , Joseph Matthew Zlotnicki
IPC分类号： B01D46/22 , C01B3/24 , C01B31/02 , F02B43/08 , F02M25/12 , H01M8/06 , B01D46/00 , H01M8/04
CPC分类号： H01M8/0612 , B01D46/0079 , B01D46/22 , C01B3/24 , C01B32/05 , C01B2203/0266 , C01B2203/04 , C01B2203/049 , C01B2203/0805 , C01B2203/085 , C01B2203/1235 , C01B2203/1247 , C01B2203/84 , F02B43/08 , F02M25/12 , H01M8/04022 , H01M8/0631 , Y02P20/128 , Y02T10/121 , Y02T10/166 , Y02T10/32
摘要： Representatively, a method of separating carbon from hydrocarbon molecules, the method including: heating hydrocarbon molecules beyond their boiling point; decomposing the heated hydrocarbon molecules to generate elemental or molecular carbon and hydrogen gas; separating at least some of the elemental or molecular carbon from the hydrogen gas; chemically reacting the hydrogen gas to produce heat; and applying some of the heat in carrying out said heating.
摘要翻译：代表性地是从烃分子中分离碳的方法，该方法包括：将烃分子加热超过其沸点; 分解加热的烃分子以产生元素或分子碳和氢气; 从氢气中分离出至少一些元素或分子碳; 使氢气化学反应产生热量; 并且在进行所述加热时施加一些热量。

6. 发明授权

US09174199B2 Methanol steam reforming catalysts 有权
标题翻译：甲醇蒸汽重整催化剂
公开(公告)号：US09174199B2
公开(公告)日：2015-11-03
申请号：US12472104
申请日：2009-05-26
申请人： Qinglin Zhang , Robert J. Farrauto , Christopher R. Castellano
发明人： Qinglin Zhang , Robert J. Farrauto , Christopher R. Castellano
IPC分类号： C01B3/08 , B01J23/10 , B01J23/648 , B01J23/62 , B01J23/63 , B01J37/00 , B01J37/02 , C01B3/32 , B01J23/58 , B01J23/89
CPC分类号： B01J23/896 , B01J23/58 , B01J23/62 , B01J23/622 , B01J23/63 , B01J23/648 , B01J23/6482 , B01J23/894 , B01J23/8946 , B01J37/0036 , B01J37/0236 , B01J37/04 , B01J37/08 , C01B3/326 , C01B2203/0233 , C01B2203/066 , C01B2203/0805 , C01B2203/1041 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1094 , C01B2203/1223 , Y02E60/36 , Y02P20/52
摘要： Novel catalysts, substantially free of Cu and Zn, useful for the reformation of methanol and steam into H2 for use in hydrogen fuel cells and their use are described herein.
摘要翻译：本文描述了可用于将甲醇和蒸汽重整成用于氢燃料电池的H 2中的基本上不含Cu和Zn的新型催化剂及其用途。

7. 发明授权

US09156688B2 Systems and methods for producing hydrogen gas 有权
标题翻译：用于生产氢气的系统和方法
公开(公告)号：US09156688B2
公开(公告)日：2015-10-13
申请号：US13691543
申请日：2012-11-30
申请人： Elwha LLC
发明人： Roderick A. Hyde , Lowell L. Wood, Jr.
IPC分类号： C01B3/24
CPC分类号： C01B3/24 , C01B2203/0272 , C01B2203/0277 , C01B2203/0805 , C01B2203/1241 , C01B2203/1247
摘要： Systems and methods for thermally decomposing hydrocarbon feedstock may comprise a hydrocarbon feedstock, a non-oxidizing carrier gas, one or more heat exchangers, and a reaction chamber. The carrier gas may be used to transfer heat to the hydrocarbon feedstock. The heat exchanger(s) may be configured to heat the carrier gas. And the reaction chamber may be configured to receive hydrocarbon feedstock and heated carrier gas. Inside the reaction chamber, the hydrocarbon feedstock and the heated carrier gas may mix with one another causing the thermal decomposition reaction. The thermal decomposition reaction occurs in a substantially oxidant-free environment thereby eliminating or greatly reducing the production of carbon oxide byproducts. Hydrogen gas may be separated from a gaseous product stream that is thereafter collected from the reaction chamber. A portion of the gaseous product stream may be thermally coupled to the carrier gas and may thereafter be recycled through the system.
摘要翻译：用于热分解烃原料的系统和方法可以包括烃原料，非氧化载体气体，一个或多个热交换器和反应室。载气可用于将热量转移到烃原料。热交换器可以被配置为加热载气。并且反应室可以被配置成接收烃原料和加热的载气。在反应室内，烃原料和加热的载气可能彼此混合引起热分解反应。热分解反应发生在基本上无氧化剂的环境中，从而消除或大大降低了碳氧化物副产物的产生。氢气可以与之后从反应室收集的气态产物流分离。气体产物流的一部分可以与载气热耦合，然后可以通过系统再循环。

8. 发明申请

US20150276112A1 SATURATOR AND NATURAL GAS REFORMING SYSTEM PROVIDED WITH SAME 有权
标题翻译：饱和度和自然气体重整系统
公开(公告)号：US20150276112A1
公开(公告)日：2015-10-01
申请号：US14437076
申请日：2013-09-05
申请人： MITSUBISHI HEAVY INDUSTRIES, LTD.
发明人： Masaki Iijima , Masato Matsuzawa
IPC分类号： F16L53/00 , C01B3/34 , B01J19/24
CPC分类号： F16L53/002 , B01J19/24 , C01B3/34 , C01B3/384 , C01B2203/0233 , C01B2203/0805 , C01B2203/0811 , C01B2203/1058 , C01B2203/1241 , C01B2203/1276 , F16L53/32 , Y10T137/6579
摘要： A saturator includes: a flow path inside of which a first fluid flows; a first heat exchange unit that causes heat exchange between the first fluid and a second fluid; a second heat exchange unit that causes heat exchange between a third fluid and the first fluid after the first fluid has passed through the first heat exchange unit; a humidifying unit that adds water to the first fluid upstream from the first heat exchange unit and the second heat exchange unit; and a conveyance path that conveys the third fluid after heat exchange from the second heat exchange unit to the upstream side of the first heat exchange unit and causes said third fluid to flow into the flow path as the first fluid.
摘要翻译：饱和器包括：第一流体在其内流动的流路; 第一热交换单元，其引起第一流体和第二流体之间的热交换; 第二热交换单元，其在所述第一流体通过所述第一热交换单元之后，在第三流体和所述第一流体之间进行热交换; 加湿单元，其从第一热交换单元和第二热交换单元向上游的第一流体添加水; 以及输送路径，其将热交换后的第三流体从第二热交换单元输送到第一热交换单元的上游侧，并使所述第三流体作为第一流体流入流路。

9. 发明授权

US09067785B2 Integration of a closed loop supercritical carbon dioxide power cycle in a steam methane reformer 有权
标题翻译：在蒸汽甲烷重整器中集成闭环超临界二氧化碳动力循环
公开(公告)号：US09067785B2
公开(公告)日：2015-06-30
申请号：US14043290
申请日：2013-10-01
申请人： L'AIR LIQUIDE, SOCIÉTÉ ANONYME POUR L'ÉTUDE ET L'ÉXPLOITATION DES PROCÉDÉS GEORGES CLAUDE
发明人： Bruce Eng , Rahul Khandelwal
IPC分类号： C01B3/24 , C01B3/34 , C01B3/02
CPC分类号： C01B3/34 , C01B3/02 , C01B3/384 , C01B2203/0205 , C01B2203/0805 , C01B2203/0883 , C01B2203/0894 , C01B2203/142 , C01B2203/84 , F01K5/02 , F02C1/05 , F02C1/10 , F05D2210/12 , Y02P20/544
摘要： An integrated reforming and power generation process is provided. This process employs a steam methane reformer to provide a hot process gas stream and a flue gas stream, utilizes the hot process gas stream to provide heat to produce a total steam stream comprising a process steam stream and an excess steam stream, and utilizes the flue gas stream to provide heat to at least a pre-reformer mixture stream, a reformer feed stream, the process steam stream and a pre-reformer steam stream The flue gas stream also provides heat to an integrated power generation process, and the excess steam stream is less than 15% of the total steam stream.
摘要翻译：提供了一体化改造和发电过程。该方法采用蒸汽甲烷重整器来提供热过程气流和烟气流，利用热过程气流提供热量以产生包含工艺蒸汽流和过量蒸汽流的总蒸汽流，并利用烟道气流，以向至少一个预重整器混合物流，重整器进料流，工艺蒸汽流和预重整器蒸汽流提供热量。烟道气流还向集成的发电过程提供热量，并且过量蒸汽流小于总蒸汽流量的15％。

10. 发明授权

US09039795B2 Reforming process for synthesis gas production and related plant 有权
标题翻译：合成气生产及相关厂房改造工艺
公开(公告)号：US09039795B2
公开(公告)日：2015-05-26
申请号：US11817299
申请日：2006-02-20
申请人： Ermanno Filippi
发明人： Ermanno Filippi
IPC分类号： C01B3/36 , C01B3/38 , B01J8/04 , B01J8/06
CPC分类号： C01B3/382 , B01J8/0496 , B01J8/067 , B01J2208/00212 , B01J2208/00256 , B01J2208/00274 , B01J2208/0053 , B01J2219/00006 , C01B3/384 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0805 , C01B2203/142 , C01B2203/148 , Y02P20/129 , Y02P20/52
摘要： A reforming process for synthesis gas (12) production from a mixture of hydrocarbons (14) comprises a first step, or pre-reforming step, in which a process mixture 18), comprising said mixture of hydrocarbons :14: and steam (16), is subjected to a preliminary catalytic conversion reaction, obtaining a partial conversion product (22) comprising hydrogen, carbon oxides and hydrocarbons, and a second step, or main reforming step, in which said partial conversion product (22) is subjected to a conversion completion reaction, obtaining said synthesis gas (12), said pre-reforming step being carried out in pseudo-isothermal conditions.
摘要翻译：由烃（14）的混合物生产合成气（12）的重整方法包括第一步或预重整步骤，其中包含烃：14：和蒸汽（16）的混合物的工艺混合物18）进行预催化转化反应，得到包含氢，碳氧化物和烃的部分转化产物（22），第二步或主要重整步骤，其中所述部分转化产物（22）进行转化完成反应，获得所述合成气（12），所述预重整步骤在假等温条件下进行。

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