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1. 发明申请

US20170158964A1 SYNTHETIC FUELS AND CHEMICALS PRODUCTION WITH IN-SITU CO2 CAPTURE 审中-公开
公开(公告)号：US20170158964A1
公开(公告)日：2017-06-08
申请号：US15376590
申请日：2016-12-12
申请人： THE OHIO STATE UNIVERSITY RESEARCH FOUNDATION
发明人： Liang-Shih FAN , Fanxing LI , Liang ZENG
IPC分类号： C10G1/02 , C10J3/72
CPC分类号： C10G1/02 , C01B3/344 , C01B2203/062 , C01B2203/148 , C01B2203/86 , C10G2/50 , C10G2300/1011 , C10G2300/807 , C10J3/466 , C10J3/725 , C10J3/86 , C10J2300/0916 , C10J2300/093 , C10J2300/0959 , C10J2300/1612 , C10J2300/1659 , C10J2300/1678 , C10J2300/1807 , C10K1/003 , C10K1/024 , Y02P20/145 , Y02P30/20 , Y02P30/30
摘要： Novel redox based systems for fuel and chemical production with in- situ CO2 capture are provided. A redox system using one or more chemical intermediates is utilized in conjunction with liquid fuel generation via indirect Fischer-Tropsch synthesis, direct hydro genation, or pyrolysis. The redox system is used to generate a hydrogen rich stream and/or CO2 and/or heat for liquid fuel and chemical production. A portion of the byproduct fuels and/or steam from liquid fuel and chemical synthesis is used as part of the feedstock for the redox system.

2. 发明申请

US20170015554A1 SYNGAS PRODUCTION VIA CYCLIC REDUCTION AND OXIDATION OF METAL OXIDES 有权
标题翻译：通过循环减少和氧化金属氧化物的生产
公开(公告)号：US20170015554A1
公开(公告)日：2017-01-19
申请号：US14799559
申请日：2015-07-14
申请人： The Babcock & Wilcox Company
发明人： Tritti Siengchum , Luis G. Velazquez-Vargas , Thomas J. Flynn , Douglas J. DeVault
IPC分类号： C01B3/36 , B01J8/00
CPC分类号： C01B3/36 , C01B3/061 , C01B3/08 , C01B3/344 , C01B2203/0216 , C01B2203/0811 , C01B2203/0838 , C01B2203/1241 , C10J3/725 , Y02E60/36
摘要： A chemical-looping system utilizes oxygen-carrier particles to produce syngas from carbonaceous fuels. The system provides a circuitous flow path for the oxygen-carrier particles, which are used to partially oxidize the fuel to produce syngas. The circuitous flow path can proceed through a plurality of unit operations, including a reducer, a conversion reactor, an oxidizer, and a combustor. The conversion reactor is designed to partially oxidize carbonaceous fuel in co-current flow with the oxygen-carrier particles to produce syngas. In embodiments including an oxidizer, the oxidizer is designed to at partially re-oxidize the carrier particles, yielding hydrogen that can be mixed with partially oxidized products from the conversion reactor to adjust syngas quality. The combustor can be used to fully oxidize the carrier particles traveling in a closed loop. Reactions carried out in the combustor are highly exothermic and yield thermal energy that is absorbed by the carrier particles. The absorbed energy is used at other parts of the process, including the conversion reactor, to drive endothermic reactions. In this manner the system can be operated autothermally or nearly so. Methods of producing syngas are also disclosed.
摘要翻译：化学循环系统利用氧载体颗粒从碳质燃料产生合成气。该系统为氧载体颗粒提供了迂回的流动路径，其用于部分氧化燃料以产生合成气。迂回的流动路径可以通过多个单元操作进行，包括减速器，转化反应器，氧化器和燃烧器。转化反应器设计成与氧载体颗粒同时流动地部分地氧化含碳燃料以产生合成气。在包括氧化剂的实施方案中，氧化剂被设计为部分地再次氧化载体颗粒，产生可与转化反应器的部分氧化产物混合以调节合成气质量的氢。燃烧器可用于完全氧化在闭环中行进的载体颗粒。在燃烧器中进行的反应是高度放热的并产生被载体颗粒吸收的热能。吸收的能量用于该方法的其它部分，包括转化反应器，以驱动吸热反应。以这种方式，系统可以自动或几乎这样操作。还公开了制备合成气的方法。

3. 发明申请

US20120159841A1 SYNTHETIC FUELS AND CHEMICALS PRODUCTION WITH IN-SITU CO2 CAPTURE 审中-公开
标题翻译：合成燃料和化学品生产与现场二氧化碳捕获
公开(公告)号：US20120159841A1
公开(公告)日：2012-06-28
申请号：US13394396
申请日：2010-09-08
申请人： Liang-Shih Fan , Fanxing Li , Liang Zeng
发明人： Liang-Shih Fan , Fanxing Li , Liang Zeng
IPC分类号： C10L1/12 , C07C27/00
CPC分类号： C10G1/02 , C01B3/344 , C01B2203/062 , C01B2203/148 , C01B2203/86 , C10G2/50 , C10G2300/1011 , C10G2300/807 , C10J3/466 , C10J3/725 , C10J3/86 , C10J2300/0916 , C10J2300/093 , C10J2300/0959 , C10J2300/1612 , C10J2300/1659 , C10J2300/1678 , C10J2300/1807 , C10K1/003 , C10K1/024 , Y02P20/145 , Y02P30/20 , Y02P30/30
摘要： Novel redox based systems for fuel and chemical production with in-situ CO2 capture are provided. A redox system using one or more chemical intermediates is utilized in conjunction with liquid fuel generation via indirect Fischer-Tropsch synthesis, direct hydro genation, or pyrolysis. The redox system is used to generate a hydrogen rich stream and/or CO2 and/or heat for liquid fuel and chemical production. A portion of the byproduct fuels and/or steam from liquid fuel and chemical synthesis is used as part of the feedstock for the redox system.
摘要翻译：提供了用于燃料和化学生产的基于氧化还原的基于原位CO2捕获的系统。使用一种或多种化学中间体的氧化还原体系与通过间接费 - 托合成，直接氢化或热解的液体燃料结合使用。氧化还原系统用于产生富氢流和/或二氧化碳和/或热液体燃料和化学生产。来自液体燃料和化学合成的副产物燃料和/或蒸汽的一部分被用作氧化还原系统的原料的一部分。

4. 发明申请

US20110097673A1 CHEMICAL LOOPING METHOD FOR THE COMBUSTION OF HEAVY LIQUID HYDROCARBON FRACTIONS 有权
标题翻译：化学循环方法用于燃烧重质液相碳氢化合物
公开(公告)号：US20110097673A1
公开(公告)日：2011-04-28
申请号：US12990395
申请日：2009-04-28
申请人： Ann Forret , William Pelletant , Ali Hoteit
发明人： Ann Forret , William Pelletant , Ali Hoteit
IPC分类号： F23L7/00
CPC分类号： F23C10/00 , B01J8/22 , B01J19/0093 , B01J2208/00212 , B01J2208/00548 , B01J2208/00973 , B01J2219/00788 , B01J2219/00826 , B01J2219/00835 , B01J2219/00873 , B01J2219/00957 , B01J2219/00986 , C01B3/344 , C01B3/386 , C01B3/44 , C01B3/48 , C01B2203/0261 , C01B2203/0283 , C01B2203/062 , C01B2203/065 , C01B2203/08 , C01B2203/1058 , C01B2203/86 , F23C2900/99008 , Y02E20/346 , Y02P30/30
摘要： The invention relates to a method for upgrading heavy liquid fractions resulting from oil refining, by combustion in a fluidized-bed chemical looping process. The method according to the invention allows to produce energy by oxidizing totally the heavy liquid feeds while allowing direct capture of the CO2 emitted in the combustion fumes. The method according to the invention also allows a synthesis gas to be produced.
摘要翻译：本发明涉及一种通过在流化床化学循环过程中燃烧来提炼由炼油产生的重质液体馏分的方法。根据本发明的方法允许通过完全氧化重质液体进料同时允许直接捕获在燃烧烟气中排出的CO 2来产生能量。根据本发明的方法还允许产生合成气。

5. 发明申请

US20100129276A1 GAS MIXING DEVICE AND SYNTHESIS GAS PRODUCING DEVICE 审中-公开
标题翻译：气体混合装置和合成气生产装置
公开(公告)号：US20100129276A1
公开(公告)日：2010-05-27
申请号：US12451719
申请日：2008-07-29
申请人： Takeshi Oohara , Shuichi Oguro , Yoshiyuki Watanabe
发明人： Takeshi Oohara , Shuichi Oguro , Yoshiyuki Watanabe
IPC分类号： B01J8/00
CPC分类号： B01F5/0696 , B01F3/02 , B01F5/0451 , B01F5/0453 , B01F5/0456 , B01F5/0604 , B01F5/0606 , B01F5/0608 , B01F5/0695 , B01J8/025 , B01J8/0278 , B01J2208/00902 , B01J2208/00929 , B01J2208/00938 , C01B3/344 , C01B3/382 , C01B3/386 , C01B2203/0244 , C01B2203/0261 , C01B2203/1241 , C01B2203/1282 , F23C99/006 , F23C2900/9901 , F23D14/62 , Y10T29/49826
摘要： To provide a gas mixing device capable of safely mixing flammable gas containing, for example, methane or the like and combustion supporting gas such as oxygen-containing gas, and a synthesis gas producing device using this gas mixing device.Flammable gas containing methane or the like and combustion supporting gas such as oxygen-containing gas are supplied into a mixing vessel 20 via a first gas supplying section 22a and a second gas supplying section 22b respectively, and these gases are mixed within a combustion range in the vessel 20 to be discharged via a discharge section 24. In the mixing vessel 20, packings 31 to 33 for forming a large number of narrow gas flow passages in the vessel 20 are packed so that velocity of the mixed gas flowing in the vessel 20 becomes higher than burning velocity of the flammable gas and the combustion supporting gas.
摘要翻译：提供一种能够安全地混合含有例如甲烷等的可燃性气体和燃烧负载气体如含氧气体的气体混合装置，以及使用该气体混合装置的合成气制造装置。通过第一气体供给部22a和第二气体供给部22b将含有甲烷等的可燃性气体和含氧气体等燃烧辅助气体分别供给到混合容器20中，这些气体在燃烧范围内容器20经由排出部分24排出。在混合容器20中，填充容器20中形成大量窄气体流动通道的填料31至33，以便在容器20中流动的混合气体的速度变得高于可燃气体和燃烧支持气体的燃烧速度。

6. 发明授权

US07033570B2 Solar-thermal fluid-wall reaction processing 失效
公开(公告)号：US07033570B2
公开(公告)日：2006-04-25
申请号：US10383875
申请日：2003-03-07
申请人： Alan W. Weimer , Jaimee K. Dahl , Allan A. Lewandowski , Carl Bingham , Karen J. Raska Buechler , Willy Grothe
发明人： Alan W. Weimer , Jaimee K. Dahl , Allan A. Lewandowski , Carl Bingham , Karen J. Raska Buechler , Willy Grothe
IPC分类号： C01B3/26
CPC分类号： B01J8/0045 , B01J8/025 , B01J8/087 , B01J10/002 , B01J19/127 , B01J2208/00212 , B01J2208/0038 , B01J2208/00451 , B01J2208/00513 , B01J2208/00522 , B01J2208/00752 , B01J2219/00006 , B01J2219/0272 , B01J2219/0883 , C01B3/04 , C01B3/24 , C01B3/34 , C01B3/344 , C01B17/0495 , C01B2203/0216 , C01B2203/0222 , C01B2203/0272 , C01B2203/04 , C01B2203/049 , C01B2203/0805 , C01B2203/0833 , C01B2203/085 , C01B2203/0866 , C01P2006/80 , C09C1/48 , F24S20/20 , F28C3/12 , Y02E10/41 , Y02E60/364 , Y02P20/134
摘要： The present invention provides a method for carrying out high temperature thermal dissociation reactions requiring rapid-heating and short residence times using solar energy. In particular, the present invention provides a method for carrying out high temperature thermal reactions such as dissociation of hydrocarbon containing gases and hydrogen sulfide to produce hydrogen and dry reforming of hydrocarbon containing gases with carbon dioxide. In the methods of the invention where hydrocarbon containing gases are dissociated, fine carbon black particles are also produced. The present invention also provides solar-thermal reactors and solar-thermal reactor systems.

7. 发明申请

US20050175533A1 Combustion looping using composite oxygen carriers 有权
标题翻译：使用复合氧载体的燃烧循环
公开(公告)号：US20050175533A1
公开(公告)日：2005-08-11
申请号：US11010648
申请日：2004-12-13
申请人： Theodore Thomas , Liang-Shih Fan , Puneet Gupta , Luis Velazquez-Vargas
发明人： Theodore Thomas , Liang-Shih Fan , Puneet Gupta , Luis Velazquez-Vargas
IPC分类号： C01B3/06 , C01B3/08 , C01B3/10 , C10J3/46 , C21B13/00 , C21B13/14 , C22B5/10 , C22B5/12 , C22B5/18
CPC分类号： C01B3/344 , C01B3/063 , C01B3/08 , C01B3/105 , C01B3/50 , C01B2203/04 , C01B2203/0405 , C01B2203/047 , C01B2203/0485 , C01B2203/066 , C01B2203/86 , C10J3/463 , C10J3/725 , C10J2300/0916 , C10J2300/093 , C10J2300/0983 , C21B13/0073 , C21B13/14 , C21B2100/282 , C21B2100/42 , C22B5/10 , C22B5/12 , C22B5/18 , F23C2900/99008 , Y02E20/346 , Y02E60/36 , Y02P10/136 , Y02P10/34 , Y02P20/145 , Y02P30/30
摘要： A method for producing hydrogen gas is provided and comprises reducing a metal oxide in a reduction reaction between a carbon-based fuel and a metal oxide to provide a reduced metal or metal oxide having a lower oxidation state, and oxidizing the reduced metal or metal oxide to produce hydrogen and a metal oxide having a higher oxidation state. The metal or metal oxide is provided in the form of a porous composite of a ceramic material containing the metal or metal oxide. The porous composite may comprise either a monolith, pellets, or particles.
摘要翻译：提供了一种生产氢气的方法，包括在碳系燃料和金属氧化物之间的还原反应中还原金属氧化物，以提供具有较低氧化态的还原金属或金属氧化物，并且还原的金属或金属氧化物以产生具有较高氧化态的氢和金属氧化物。金属或金属氧化物以包含金属或金属氧化物的陶瓷材料的多孔复合材料的形式提供。多孔复合材料可以包括整料，丸粒或颗粒。

8. 发明申请

US20030182861A1 Solar-thermal fluid-wall reaction processing 失效
标题翻译：太阳能热流体壁反应处理
公开(公告)号：US20030182861A1
公开(公告)日：2003-10-02
申请号：US10383875
申请日：2003-03-07
发明人： Alan W. Weimer , Jaimee K. Dahl , Allan A. Lewandowski , Carl Bingham , Karen J. Raska Buechler , Willy Grothe
IPC分类号： C01B003/24
CPC分类号： B01J8/0045 , B01J8/025 , B01J8/087 , B01J10/002 , B01J19/127 , B01J2208/00212 , B01J2208/0038 , B01J2208/00451 , B01J2208/00513 , B01J2208/00522 , B01J2208/00752 , B01J2219/00006 , B01J2219/0272 , B01J2219/0883 , C01B3/04 , C01B3/24 , C01B3/34 , C01B3/344 , C01B17/0495 , C01B2203/0216 , C01B2203/0222 , C01B2203/0272 , C01B2203/04 , C01B2203/049 , C01B2203/0805 , C01B2203/0833 , C01B2203/085 , C01B2203/0866 , C01P2006/80 , C09C1/48 , F24S20/20 , F28C3/12 , Y02E10/41 , Y02E60/364 , Y02P20/134
摘要： The present invention provides a method for carrying out high temperature thermal dissociation reactions requiring rapid-heating and short residence times using solar energy. In particular, the present invention provides a method for carrying out high temperature thermal reactions such as dissociation of hydrocarbon containing gases and hydrogen sulfide to produce hydrogen and dry reforming of hydrocarbon containing gases with carbon dioxide. In the methods of the invention where hydrocarbon containing gases are dissociated, fine carbon black particles are also produced. The present invention also provides solar-thermal reactors and solar-thermal reactor systems.
摘要翻译：本发明提供一种使用太阳能进行需要快速加热和停留时间短的高温热解离反应的方法。特别地，本发明提供了一种用于进行高温热反应的方法，例如含烃气体和硫化氢的解离以产生氢气，并且用含二氧化碳的含烃气体进行干重整。在含烃气体解离的本发明的方法中，也生产细小的炭黑颗粒。本发明还提供太阳能热反应堆和太阳能热反应堆系统。

9. 发明授权

US4726913A Conversion process 失效
标题翻译：转换过程
公开(公告)号：US4726913A
公开(公告)日：1988-02-23
申请号：US70081
申请日：1987-07-06
申请人： John H. Brophy , Richard P. Manning
发明人： John H. Brophy , Richard P. Manning
IPC分类号： C07C2/82 , B01J8/24 , C01B3/34 , C07C1/00 , C07C11/04 , C07C11/24 , C07C67/00 , C01B3/28 , C01B3/30
CPC分类号： B01J8/245 , C01B3/344
摘要： Process for the production of synthesis gas and hydrocarbons in which a saturated hydrocarbon and an oxygen containing gas having a ratio of hydrocarbon to oxygen of greater than the stoichiometric ratio for complete combustion are introduced together with hydrogen into a bed of particulate material. The upward flow rate of the gases is sufficiently large to fluidize or to cause a spouting action of the bed material. The hydrocarbon, oxygen containing gas and hydrogen are ignited and reacted together and the products of the reaction are withdrawn.
摘要翻译：用于生产合成气和烃的方法，其中将饱和烃和具有大于全部燃烧的化学计量比的烃与氧的含氧气体一起引入到颗粒材料床中。气体的向上流速足够大以流化或引起床料的喷射作用。烃，含氧气体和氢气被点燃并一起反应，反应产物被排出。

10. 发明申请

US20180273380A1 METHOD FOR PRODUCING SYNTHESIS GAS 审中-公开
公开(公告)号：US20180273380A1
公开(公告)日：2018-09-27
申请号：US15779596
申请日：2016-11-28
申请人： THYSSENKRUPP INDUSTRIAL SOLUTIONS AG , thyssenkrupp AG
发明人： Hans-Jürgen MAASS , Volker GÖKE , Otto MACHHAMMER , Andreas BODE , Grigorios KOLIOS , Karsten BÜKER
IPC分类号： C01B3/34
CPC分类号： C01B3/344 , C01B3/30 , C01B2203/0216 , C01B2203/0255 , C01B2203/0272 , C01B2203/0485 , C01B2203/0822 , C01B2203/0844 , C01B2203/085 , C01B2203/1241 , C01B2203/1247 , C01B2203/1252 , C01B2203/1258 , C01B2203/142 , C01B2203/82 , C10G2/32 , C10K3/02
摘要： A method for producing synthesis gas may involve introducing a hydrocarbon-containing coke-oven gas and a carbon dioxide-containing converter gas into a first reaction zone where hydrogen present in the hydrocarbon-containing coke-oven gas reacts at least partly with carbon dioxide to form water, which reacts thermally with hydrocarbon to form synthesis gas containing carbon monoxide and hydrogen. The method may further involve introducing an oxygen-containing gas in a second reaction zone, and using the oxygen-containing gas and some hydrogen from the first reaction zone to produce thermal energy. Still further, the method may involve supplying the thermal energy produced in the second reaction zone to the first reaction zone.

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