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1. 发明授权

US4482696A Avoiding an explosive gas phase in gas/liquid reactions 失效
标题翻译：在气/液反应中避免爆炸性气相
公开(公告)号：US4482696A
公开(公告)日：1984-11-13
申请号：US465760
申请日：1983-02-11
申请人： Hans H. Schuster , Hermann Dreher , Juergen Hambrecht
发明人： Hans H. Schuster , Hermann Dreher , Juergen Hambrecht
IPC分类号： B01J10/00 , B01J19/00 , B01J19/24 , B01J19/26 , C08G65/44
CPC分类号： C08G65/44 , B01J19/002 , B01J19/2465 , B01J19/26 , B01J2219/00103 , B01J2219/0011 , B01J2219/00263 , Y10S585/951
摘要： A coherent explosive gas phase in a gas/liquid reactor comprising a tubular body which is closed at the top and into which one or more jets of liquid which are fed from a liquid circulation and are directed downward, emerge from one or more nozzles located at the highest point of the reactor, and entrain a gas phase which is to be dispersed, introduce it into the liquid and finally produce complete dispersion of the gas, is avoided by a method wherein, before start-up of the liquid circulation, the inactive reactor is charged with an amount of liquid reactant such that a gas space corresponding to the subsequent gas hold-up of dispersed bubbles under operating conditions remains at the top of the reactor, this gas space is filled with a gas, at a pressure p.sub.1, which is inert under the reaction conditions, and the gaseous reactant is fed to the reactor only when, under the action of the liquid jet or jets, the inert gas has been dispersed into a hold-up of dispersed bubbles so that a coherent gas phase no longer exists.
摘要翻译：在气/液反应器中的相干爆炸性气相，包括管状主体，该管状体在顶部封闭，并且从液体循环进给并被向下引导的一个或多个液体射流从该管状体中的一个或多个喷嘴出射反应器的最高点，并且夹带待分散的气相，将其引入液体中并最终产生气体的完全分散，通过其中在液体循环启动之前的非活性的方法避免了反应器装有一定量的液体反应物，使得在操作条件下与分散气泡的随后气体保持相对应的气体空间保持在反应器的顶部，该气体空间以压力p1填充气体，其在反应条件下是惰性的，并且气体反应物仅在液体射流或喷射作用下被输送到反应器中时，惰性气体已经分散到分散的气泡的滞留物中，使得coh 气相不再存在。

2. 发明授权

US4460764A Removal of the catalyst from polyphenylene ethers 失效
标题翻译：从聚苯醚中除去催化剂
公开(公告)号：US4460764A
公开(公告)日：1984-07-17
申请号：US516383
申请日：1983-07-21
申请人： Rudi W. Reffert , Juergen Hambrecht , Adolf Echte , Hans H. Schuster , Hermann Dreher
发明人： Rudi W. Reffert , Juergen Hambrecht , Adolf Echte , Hans H. Schuster , Hermann Dreher
IPC分类号： C08G65/46 , C08G65/44
CPC分类号： C08G65/46
摘要： In the preparation of a high molecular weight polyphenylene ether from a monohydric phenol by an oxidative coupling reaction with oxygen in the presence of a catalyst complex obtained from a metal salt and an organic amine and in the presence of a solvent, and isolation of the metal ion component of the catalyst from the polyphenylene ether solution by means of a complex-forming or chelate-forming compound, the catalyst is removed by a method wherein complex formation and isolation of the metal ion component of the catalyst are carried out in an aqueous medium in the presence of from 0.1 to 5,000 mg of an anionic or non-ionic surfactant.
摘要翻译：在由金属盐和有机胺获得的催化剂配合物的存在下和在溶剂的存在下，通过与氧的氧化偶联反应从一元酚制备高分子量聚苯醚，并分离金属通过复合物形成或螯合形成化合物从聚苯醚溶液中除去催化剂的离子组分，通过催化剂的金属离子组分的复合形成和分离在水性介质中进行的方法除去催化剂在0.1至5,000mg阴离子或非离子表面活性剂的存在下。

3. 发明授权

US4654418A Continuous removal of the catalyst from polyphenylene ethers 失效
标题翻译：从聚苯醚连续除去催化剂
公开(公告)号：US4654418A
公开(公告)日：1987-03-31
申请号：US627984
申请日：1984-07-05
申请人： Rosemarie Berger , Hermann Dreher , Juergen Hambrecht , Eduard Heil , Rudi W. Reffert , Johann Swoboda , Adolf Echte , Peter Siebel
发明人： Rosemarie Berger , Hermann Dreher , Juergen Hambrecht , Eduard Heil , Rudi W. Reffert , Johann Swoboda , Adolf Echte , Peter Siebel
IPC分类号： C08G65/46 , C08G65/42
CPC分类号： C08G65/46
摘要： The catalyst is removed in the preparation of high molecular weight polyphenylene ethers from monohydric phenols, which are alkyl-substituted at the two ortho-positions but not at the para-position and may or may not be alkyl-substituted at the meta-position, by an oxidative coupling reaction with oxygen at from 15.degree. to 50.degree. C. in the presence of a catalyst complex obtained from a copper salt and an organic amine, in the presence of from 1 to 20 parts by weight of a solvent per part by weight of the monomeric phenol, and in the presence or absence of an activator, and removal of the metal component of the catalyst from the polyphenylene ether solution with a complex-forming or chelate-forming compound in aqueous solution, in the presence or absence of reducing and stabilizing substances and assistants for accelerating the interphase reactions and for phase separation, by a method in which the continuous removal of the copper catalyst is carried out in one or more mixer-settler stages at a phase volume ratio of the organic phase to the aqueous phase of from 1:0.1 to 1:1.0, preferably from 1:0.4 to 1:0.6.
摘要翻译：在从一元酚制备高分子量聚苯醚时除去催化剂，该二元酚在两个邻位进行烷基取代，而不是在对位，在间位可以是或不是烷基取代的，在由铜盐和有机胺获得的催化剂配合物的存在下，在15〜50℃下，与氧气进行氧化偶合反应，每份由1〜20份重量的溶剂单体苯酚的重量，并且在存在或不存在活化剂的情况下，在存在或不存在复合物形成或螯合形成化合物的情况下，在聚苯醚溶液中除去催化剂的金属组分减少和稳定物质和辅助剂，用于加速相间反应和相分离，方法是连续除去铜催化剂的方法是在一个或多个混合沉淀器以有机相与水相的相体积比为1:0.1至1:1.0，优选1:0.4至1:0.6。

4. 发明授权

US4696996A Preparation of polyphenylene ethers, and an apparatus for this purpose 失效
标题翻译：聚苯醚的制备及其用途
公开(公告)号：US4696996A
公开(公告)日：1987-09-29
申请号：US797884
申请日：1985-11-14
申请人： Hermann Brandt , Hermann Fischer , Hermann Dreher , Eduard Heil , Juergen Hambrecht , Herbert Naarmann , Adolf Echte , Hermann Gausepohl , Peter Siebel , Johann Swoboda , Gerd Schwoebel , Albert Nikles
发明人： Hermann Brandt , Hermann Fischer , Hermann Dreher , Eduard Heil , Juergen Hambrecht , Herbert Naarmann , Adolf Echte , Hermann Gausepohl , Peter Siebel , Johann Swoboda , Gerd Schwoebel , Albert Nikles
IPC分类号： B01J10/00 , B01J19/18 , C08G65/44 , C08G65/38
CPC分类号： C08G65/44 , B01J19/1862 , B01J19/1881 , B01J2219/00094 , B01J2219/00103 , B01J2219/0011
摘要： Polyphenylene ethers are prepared from monohydric phenols, which possess alkyl substituents in the two ortho-positions and, if desired, in the meta-position, but not in the para-position, by an oxidative coupling reaction with oxygen at from 15.degree. to 50.degree. C. and under from 1 to 10 bar in the presence of a catalyst complex, of a solvent and, if required, of an activator, by a method in which the conversion of the phenols is carried out in two more reaction zones, in which some or all of the solvent, the catalyst complex and the phenols and, where relevant, the activator is initially taken and is circulated by means of a conveying unit, and about 60-100% of the stoichiometric amount of oxygen required for the oxidative coupling is introduced into the first reaction zone and from 0 to about 40% of the said stoichiometric amount is introduced into the second reaction zone.
摘要翻译：聚苯醚由单羟基苯酚制得，它们在两个邻位具有烷基取代基，如果需要，在间位，而不是在对位，通过与15至50的氧的氧化偶联反应，在催化剂配合物存在下，在溶剂和如果需要的情况下，活化剂存在下，在1至10巴下，通过酚的转化在两个更多的反应区中进行，在其中一些或全部溶剂，催化剂络合物和酚，并且在相关的情况下，活化剂最初被摄取并通过输送单元循环，并且约60-100％的化学计量量的氧化所需的氧将偶联引入第一反应区，并将0至约40％的所述化学计量量引入第二反应区。

5. 发明授权

US4959415A Thermoplastic molding materials based on polyphenylene ethers, nylons and styrene copolymers 失效
标题翻译：基于聚苯醚，尼龙和苯乙烯共聚物的热塑性成型材料
公开(公告)号：US4959415A
公开(公告)日：1990-09-25
申请号：US179991
申请日：1988-04-11
申请人： Christof Taubitz , Erhard Seiler , Juergen Hambrecht , Konrad Mitulla , Klaus Boehlke
发明人： Christof Taubitz , Erhard Seiler , Juergen Hambrecht , Konrad Mitulla , Klaus Boehlke
IPC分类号： C08L53/02 , C08L67/00 , C08L71/12 , C08L77/00
CPC分类号： C08L53/02 , C08L71/123 , C08L77/00 , C08L67/00 , Y10S525/905
摘要： Thermoplastic molding materials containing(A) not less than 5% by weight of a polyphenylene ether and(B) not less than 5% by weight of a nylon furthermore contain(C) not less than 0.1% by weight of a copolymer composed of(C.sub.1) not less than 30% by weight of a styrene of the general formula I ##STR1## where R and R.sup.1 are alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1, 2 or 3,(C.sub.2) not less than 0.5% by weight of an epoxide-containing polymerizable monomer and/or(C.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer possessing a structural unit (II) ##STR2## where X is halogen, R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3, and/or(C.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups and(C.sub.5) from 0 to 20% by weight of acrylonitrile, methacrylonitrile and/or other nonionic comonomers, and(D) from 0 to 35% by weight of a toughened rubber, and possess particularly good impact strength.
摘要翻译：含有（A）不小于5重量％的聚苯醚的热塑性成型材料和（B）不小于5重量％的尼龙，还含有（C）不小于0.1重量％的由（ C1）不小于30重量％的通式I（I）的苯乙烯，其中R和R 1是1至8个碳原子的烷基，氢和/或卤素，n是0,1,2或 3，（C2）不小于0.5重量％的含环氧化物的可聚合单体和/或（C3）不少于0.05重量％的具有结构单元（II）的卤代苄基的可聚合单体（IMAGE） II）其中X是卤素，R2和R3各自为1-8个碳原子的烷基或氢，n为1,2或3，和/或（C4）不小于0.05重量％的含有恶唑啉基团的可聚合单体和（C5）0至20重量％的丙烯腈，甲基丙烯腈和/或其它非离子共聚单体，和（D）0至35重量％的增韧橡胶，并且具有特定的良好的冲击强度。

6. 发明授权

US4605699A Thermoplastic molding compositions containing polycarbonate and an acrylate graft copolymer 失效
标题翻译：含有聚碳酸酯和丙烯酸酯接枝共聚物的热塑性成型组合物
公开(公告)号：US4605699A
公开(公告)日：1986-08-12
申请号：US722155
申请日：1985-04-11
申请人： Konrad Mitulla , Juergen Hambrecht , Adolf Echte , Johann Swoboda , Peter Siebel , Josef Schwaab , Herbert Frank
发明人： Konrad Mitulla , Juergen Hambrecht , Adolf Echte , Johann Swoboda , Peter Siebel , Josef Schwaab , Herbert Frank
IPC分类号： C08L51/00 , C08L69/00
CPC分类号： C08L51/003 , C08L69/00 , Y10S525/902
摘要： A thermoplastic molding material consists of from 10 to 90 parts by weight of a polycarbonate A and from 90 to 10 parts by weight of a graft copolymer B having a mean particle size of from 200 to 700 nm (d.sub.50 value of the integral mass distribution). The graft polymer B is formed from an elastomer (rubber) (b.sub.1), which accounts for from 10 to 80% by weight, and a grafted shell (b.sub.2), which accounts for from 90 to 20% by weight, the percentages in each case being based on (B).The elastomer (b.sub.1) is composed of from 50 to 99.9% by weight of an alkyl acrylate, where alkyl is of 1 to 8 carbon atoms, and from 0.1 to 5% by weight of a copolymerizable polyfunctional crosslinking monomer.The grafted shell (b.sub.2) is produced in three stages and contains, as graft monomers,(b.sub.2 a.sub.1) from 5 to 40% by weight of a monoethylenically unsaturated aromatic hydrocarbon of not more than 12 carbon atoms, in the first stage,(b.sub.2 a.sub.2) from 15 to 50% by weight of a mixture of a monoethylenically unsaturated aromatic hydrocarbon of not more than 12 carbon atoms and a copolymerizable ethylenically unsaturated monomer, in a weight ratio of from 90:10 to 60:40, in the second stage, and(b.sub.2 a.sub.3) from 10 to 85% by weight of an alkyl (meth)acrylate in the third stage, the percentages in each case being based on (b.sub.2).
摘要翻译：热塑性成型材料由10〜90重量份的聚碳酸酯A和90〜10重量份的平均粒径为200〜700nm的接枝共聚物B（整体质量分布的d50）组成，。接枝聚合物B由占总重量的10〜80重量％的弹性体（橡胶）（b1）和接枝壳（b2）的90〜20重量％构成。情况基于（B）。弹性体（b1）由50〜99.9重量％的丙烯酸烷基酯（其中烷基为1〜8个碳原子）和0.1〜5重量％的可共聚的多官能交联单体组成。接枝壳（b2）分三个阶段制成，在第一阶段，（b2a2）含有5-40重量％的不大于12个碳原子的单烯属不饱和芳族烃作为接枝单体，（b2a1） 15重量％至50重量％的不超过12个碳原子的单烯属不饱和芳族烃和可共聚烯属不饱和单体的混合物，其重量比为90:10至60:40，第二阶段为（b2a3）在第三阶段为10〜85重量％的（甲基）丙烯酸烷基酯，其各自的百分比基于（b2）。

7. 发明授权

US4536567A Removal of the catalyst from polyphenylene ethers 失效
标题翻译：从聚苯醚中除去催化剂
公开(公告)号：US4536567A
公开(公告)日：1985-08-20
申请号：US631948
申请日：1984-07-18
申请人： Juergen Hambrecht , Rudi W. Reffert , Peter Minges , Johann Swoboda
发明人： Juergen Hambrecht , Rudi W. Reffert , Peter Minges , Johann Swoboda
IPC分类号： C08G65/46 , C08G65/44
CPC分类号： C08G65/46
摘要： High molecular weight polyphenylene ethers are prepared from a monohydric phenol by an oxidative coupling reaction with oxygen in the presence of a catalyst complex obtained from a copper salt and an organic amine, and in the presence of a solvent, by a process in which the metal component of the catalyst is removed after the polymerization by adding one or more organic ammonium salts of the general formula ##STR1## where A.sup..crclbar. is an anion or polyanion of an organic carboxylic, sulfonic or phosphonic acid, R.sup.1 is hydrogen, R.sup.2 and R.sup.3 are each hydrogen, alkyl of 1 to 18 carbon atoms or aryl and R.sup.4 is alkyl of 1 to 18 carbon atoms or aryl.
摘要翻译：在由铜盐和有机胺得到的催化剂配合物存在下，通过与氧的氧化偶联反应，在溶剂存在下，通过一种方法制备高分子量聚苯醚，其中金属通过加入一种或多种通式为“IMAGE”的有机铵盐，其中A（ - ）是有机羧酸，磺酸或膦酸的阴离子或聚阴离子，R1是氢，R2和R2，并且 R3各自为氢，1至18个碳原子的烷基或芳基，R4为1至18个碳原子的烷基或芳基。

8. 发明授权

US4440906A Thermoplastic molding material 失效
标题翻译：热塑性成型材料
公开(公告)号：US4440906A
公开(公告)日：1984-04-03
申请号：US337404
申请日：1982-01-06
申请人： Franz Brandstetter , Juergen Hambrecht , Adolf Echte
发明人： Franz Brandstetter , Juergen Hambrecht , Adolf Echte
IPC分类号： C08L25/00 , C08L25/04 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , C08L51/06 , C08L71/00 , C08L71/12 , C08L61/04
CPC分类号： C08L25/00 , C08L51/003 , C08L71/123 , C08L51/04 , C08L71/12 , Y10S525/905
摘要： The use of tricyclodecenyl alcohol in place of other crosslinking agents for crosslinking the soft component of impact-resistant polystyrene based on a polystyrene-grafted poly(alkyl acrylate) improves the flow of mixtures of the said polystyrene with polyphenylene ethers.
摘要翻译：基于聚苯乙烯接枝的聚（丙烯酸烷基酯），使用三环癸烯醇代替用于交联耐冲击聚苯乙烯的软组分的其它交联剂改善了所述聚苯乙烯与聚苯醚的混合物的流动。

9. 发明授权

US4435541A Antistatic thermoplastic molding masses containing styrene-acrylonitrile grafted polyether 失效
标题翻译：含有苯乙烯 - 丙烯腈接枝聚醚的抗静电热塑性模塑料
公开(公告)号：US4435541A
公开(公告)日：1984-03-06
申请号：US361862
申请日：1982-03-25
申请人： Franz Brandstetter , Juergen Hambrecht , Bernhard Scharf , Gerhard Lindenschmidt , Josef Schwaab , Rudolf H. Jung
发明人： Franz Brandstetter , Juergen Hambrecht , Bernhard Scharf , Gerhard Lindenschmidt , Josef Schwaab , Rudolf H. Jung
IPC分类号： C08L25/12 , C08L51/08 , C08L55/02 , C08L71/02
CPC分类号： C08L25/12 , C08L51/08
摘要： Thermoplastic molding masses based on the copolymerization of styrene and/or .alpha.-methylstyrene and acrylonitrile, which may be modified to be impact resistant with rubberlike polymers, are made antistatic by adding 0.01 to 1.5 percent by weight of a graft polyol which is a polyhydroxy-polyalkylene polyether modified with styrene-acrylonitrile copolymers.
摘要翻译：基于苯乙烯和/或α-甲基苯乙烯和丙烯腈的共聚合的热塑性模塑料可以通过橡胶状聚合物改性成抗冲击性，通过加入0.01〜1.5重量％的作为多羟基 - 用苯乙烯 - 丙烯腈共聚物改性的聚亚烷基聚醚。

10. 发明授权

US4914167A Polymeric organic acids, their preparation and their use in detergents and cleansers 失效
标题翻译：聚合有机酸，它们的制备及其在洗涤剂和清洁剂中的应用
公开(公告)号：US4914167A
公开(公告)日：1990-04-03
申请号：US752013
申请日：1985-07-08
申请人： Juergen Hambrecht , Heinrich Hartmann , Walter Denzinger , Albert Hettche , Wolfgang Trieselt , Rolf Schneider
发明人： Juergen Hambrecht , Heinrich Hartmann , Walter Denzinger , Albert Hettche , Wolfgang Trieselt , Rolf Schneider
IPC分类号： C08F2/02 , C08F220/04 , C11D3/37
CPC分类号： C11D3/3761 , C08F220/04
摘要： Organic polyacids are prepared from monomeric monofunctional acids, such as acrylic acid or methacrylic acid and monomers without an acid group, with or without dicarboxylic acids or their anhydrides, by continuous free radical mass copolymerization under superatmospheric pressure at from 200.degree. to 400.degree. C., followed, if desired, by neutralization of the polyacids obtained. The polyacids obtained by the novel process are useful as phosphate substitutes and scale inhibitors in detergents and cleansers.
摘要翻译：有机多元酸通过在200-400℃的超大气压下连续自由基基团共聚，由单体单官能酸例如丙烯酸或甲基丙烯酸和无酸基的单体制备，含或不含二羧酸或其酸酐。，如果需要，通过中和获得的多元酸。通过该方法获得的多酸可用作洗涤剂和清洁剂中的磷酸盐替代物和防垢剂。

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