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    • 5. 发明授权
    • Thermosetting resin, composition including the same, and printed board fabricated using the same
    • 热固性树脂,包含其的组合物和使用其制造的印刷电路板
    • US08552123B2
    • 2013-10-08
    • US12859425
    • 2010-08-19
    • Jae-Jun LeeMyung-Sup Jung
    • Jae-Jun LeeMyung-Sup Jung
    • C08G63/00
    • C09K19/3809C08G61/02C08G65/38C08G65/44C08G2261/3424C08G2261/76C08J5/24C08J2300/24H05K1/0326H05K1/0366H05K1/0393Y10T428/31681
    • A thermosetting resin including at least one repeating unit represented by the following Chemical Formula 1: wherein, in Chemical Formula 1, A is derived from a phenolic moiety, an anilinic moiety, or a combination thereof, L is C(O)O, C(O)NR′ wherein R′ is hydrogen, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C30 aryl group, or a substituted or unsubstituted C6 to C30 aryloxy group, an aromatic ester, an aromatic ester-imide, an aromatic ester-amide, an aromatic amide, or a combination thereof, Z is a substituted or unsubstituted aliphatic group including a double bond or a triple bond, a substituted or unsubstituted alicyclic group including a double bond or a triple bond, a substituted or unsubstituted aryl group including a double bond or a triple bond, (iso)cyanate, a derivative thereof, or a combination thereof, and n is an integer ranging from 1 to about 4.
    • 一种热固性树脂,其包含至少一种由以下化学式1表示的重复单元:其中,在化学式1中,A衍生自酚部分,苯胺部分或其组合,L为C(O)O,C (O)NR',其中R'是氢,取代或未取代的C 1至C 20烷基,取代或未取代的C 6至C 30芳基,或取代或未取代的C 6至C 30芳氧基,芳族酯,芳族酯 - 酰亚胺,芳香族酯 - 酰胺,芳香族酰胺或其组合,Z为取代或未取代的包含双键或三键的脂族基团,取代或未取代的包含双键或三键的脂环族基团, 取代或未取代的包括双键或三键的芳基,(iso)氰酸酯,其衍生物或其组合,n是1至约4的整数。
    • 6. 发明授权
    • Polyphenylene ether resin composition having narrow molecular weight distribution
    • 具有窄分子量分布的聚苯醚树脂组合物
    • US08445573B2
    • 2013-05-21
    • US12990811
    • 2009-05-08
    • Tomohiro KondoToru YamaguchiKazunori Terada
    • Tomohiro KondoToru YamaguchiKazunori Terada
    • C08K5/17B60C3/00
    • C08L71/12C08G65/44C08G65/485C08K5/17
    • A polyphenylene ether resin composition obtainable by melt-mixing a polyphenylene ether (A) comprising a structural unit (a) represented by formula (1): (wherein R1 and R2 each independently represent a hydrogen atom, a halogen atom, an optionally substituted alkyl group, and the like), and/or a structural unit (b) represented by formula (2): (wherein R3 and R4 each independently represent a hydrogen atom, a halogen atom, an optionally substituted alkyl group, and the like), with a nitrogen compound (B) comprising at least one group selected from the group consisting of primary amino groups, secondary amino groups and tertiary amino groups in a single molecule thereof, wherein the polyphenylene ether (A) comprises 0.1% by mass or more and 1.5% by mass or less of at least one type of aromatic hydrocarbon (C) containing 7 or 8 carbon atoms.
    • 通过将包含由式(1)表示的结构单元(a)的聚苯醚(A)熔融混合而获得的聚苯醚树脂组合物:其中R 1和R 2各自独立地表示氢原子,卤素原子,任选取代的烷基 基团等)和/或由式(2)表示的结构单元(b):(其中R 3和R 4各自独立地表示氢原子,卤素原子,任选取代的烷基等), 与在单分子中含有选自伯氨基,仲氨基和叔氨基中的至少一个基团的氮化合物(B),其中聚苯醚(A)的含量为0.1质量%以上, 至少一种含有7或8个碳原子的芳族烃(C)的1.5质量%以下。
    • 8. 发明申请
    • NOVEL METHOD FOR PRODUCING POLYPHENYLENE ETHER
    • 用于生产聚苯乙烯的新方法
    • US20120149865A1
    • 2012-06-14
    • US13397304
    • 2012-02-15
    • Mutsumi MAEDAHiroaki FURUKAWA
    • Mutsumi MAEDAHiroaki FURUKAWA
    • C08G65/46
    • C08G65/44
    • Method for producing polyphenylene ether, comprising preparing a polymerization solution of 10-25 parts by mass of a phenolic compound (M) and 75-90 parts by mass of an aromatic solvent (A) with the total of the compound and the solvent being 100 parts by mass, and 0.1-10 parts by mass of a catalyst (C) containing a metal salt; performing oxidative polymerization of the phenolic compound (M) by passing oxygen-containing gas through polymerization solution; stopping polymerization by mixing aqueous chelating agent solution into polymerization solution; subjecting a diphenoquinone compound produced as a by-product to quinone binding process or removal by reduction; and obtaining polyphenylene ether by separating aqueous phase through liquid-liquid separation. In the method for producing a polyphenylene ether, 0.001-0.004 part by weight of an ion catalyst (D) is added into the polymerization solution before the liquid-liquid separation.
    • 制备聚苯醚的方法,包括制备10-25质量份酚类化合物(M)和75-90质量份芳族溶剂(A)的聚合溶液,其中化合物和溶剂的总量为100 质量份,和含有金属盐的催化剂(C)0.1-10质量份; 通过使含氧气体通过聚合溶液进行酚类化合物(M)的氧化聚合; 通过将水性螯合剂溶液混合到聚合溶液中停止聚合; 将作为副产物生产的联苯醌化合物经受醌结合过程或通过还原除去; 并通过液 - 液分离分离水相得到聚苯醚。 在聚苯醚的制造方法中,在液液分离前向聚合液中添加0.001-0.004重量份的离子催化剂(D)。