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1. 发明授权

US06197872B1 Thin wall panels 失效
标题翻译：薄壁板
公开(公告)号：US06197872B1
公开(公告)日：2001-03-06
申请号：US09230348
申请日：1999-12-17
申请人： Herbert Naarmann , Graham Edmund McKee , Alfred Pirker , Hans-Josef Sterzel , Franz Brandstetter , Bernd-Steffen von Bernstorff , Bernhard Rosenau , Ulrich Endemann , Burkhard Straube
发明人： Herbert Naarmann , Graham Edmund McKee , Alfred Pirker , Hans-Josef Sterzel , Franz Brandstetter , Bernd-Steffen von Bernstorff , Bernhard Rosenau , Ulrich Endemann , Burkhard Straube
IPC分类号： C08L5100
CPC分类号： E04C2/20 , C08F255/02 , C08F265/04 , C08F283/12 , C08L25/12 , C08L51/003 , C08L51/04 , C08L2666/24 , C08L2666/02
摘要： The use of a thermoplastic molding composition differing from ABS and comprising, based on a total of 100% by weight of amounts of components A and B, and, if desired, C and/or D, a: as component A, from 1 to 99% by weight, preferably from 15 to 60% by weight, in particular from 25 to 50% by weight, of a particulate emulsion polymer with a glass transition temperature of below 0° C. and with a median particle size of from 50 to 1000 nm, preferably from 50 to 500 nm b: as component B, from 1 to 99% by weight, preferably from 40 to 85% by weight, in particular from 50 to 75% by weight, of at least one amorphous or partly crystalline polymer, c: as component C, from 0 to 50% by weight of polycarbonates, and d: as component D, from 0 to 50% by weight of fibrous or particulate fillers or mixtures of these for producing sheet-like wall elements and fastening parts therefor.
摘要翻译：使用不同于ABS的热塑性模塑组合物，并且基于总量为100重量％的组分A和B的量，以及如果需要，包括C和/或D，a：作为组分A，从1至 99重量％，优选15至60重量％，特别是25至50重量％的玻璃化转变温度低于0℃的颗粒状乳液聚合物，中值粒度为50至 1000nm，优选50-500nmb：作为组分B，1-99重量％，优选40-85重量％，特别是50-75重量％的至少一种无定形或部分结晶聚合物，c：作为组分C，0至50重量％的聚碳酸酯，和d：作为组分D，0至50重量％的纤维或颗粒填料或它们的混合物用于生产片状壁元件及其紧固部件。

2. 发明授权

US06103813A Covering grid plates for ventilation openings 失效
标题翻译：覆盖格栅板用于通风口
公开(公告)号：US06103813A
公开(公告)日：2000-08-15
申请号：US230349
申请日：1999-01-25
申请人： Herbert Naarmann , Graham Edmund Mc Kee , Alfred Pirker , Hans-Josef Sterzel , Franz Brandstetter , Bernd-Steffen von Bernstorff , Bernhard Rosenau , Ulrich Endemann , Burkhard Straube
发明人： Herbert Naarmann , Graham Edmund Mc Kee , Alfred Pirker , Hans-Josef Sterzel , Franz Brandstetter , Bernd-Steffen von Bernstorff , Bernhard Rosenau , Ulrich Endemann , Burkhard Straube
IPC分类号： C08L101/00 , C08F255/02 , C08F265/00 , C08F265/04 , C08F283/12 , C08L25/12 , C08L51/00 , C08L81/04 , F04D29/70 , F24F13/08 , C08L51/04
CPC分类号： F04D29/703 , C08F255/02 , C08F265/04 , C08F283/12 , C08L25/12 , C08L81/04 , C08L51/003 , F24F13/082
摘要： The use of a thermoplastic molding composition differing from ABS and comprising, based on a total of 100% by weight of amounts of components A and B, and, if desired, C and/or D,a: as component A, from 1 to 99% by weight, preferably from 15 to 60% by weight, in particular from 25 to 50% by weight, of a particulate emulsion polymer with a glass transition temperature of below 0.degree. C. and with a median particle size of from 50 to 1000 nm, preferably from 50 to 500 nm,b: as component B, from 1 to 99% by weight, preferably from 40 to 85% by weight, in particular from 50 to 75% by weight, of at least one amorphous or partly crystalline polymer,c: as component C, from 0 to 50% by weight of polycarbonates, andd: as component D, from 0 to 50% by weight of fibrous or particulate fillers or mixtures of thesefor producing covering grid plates for ventilator openings.
摘要翻译： PCT No.PCT / EP97 / 04032 Sec。 371日期1999年1月25日 102（e）日期1999年1月25日PCT提交1997年7月24日PCT公布。出版物WO98 / 04632 日期1998年2月5日使用不同于ABS的热塑性模塑组合物，其包含基于总量100重量份的组分A和B的量，以及如果需要，包括C和/或D，a：作为组分 A，1至99重量％，优选15至60重量％，特别是25至50重量％的玻璃化转变温度低于0℃的颗粒状乳液聚合物和中值粒子尺寸为50至1000nm，优选50至500nm，b：作为组分B，1至99重量％，优选40至85重量％，特别是50至75重量％的至少一种无定形或部分结晶聚合物，c：作为组分C，0至50重量％的聚碳酸酯，d：作为组分D，0至50重量％的纤维或颗粒填料或这些的混合物用于生产覆盖物格栅板用于呼吸机开口。

3. 发明授权

US5530087A Polyanils 失效
标题翻译：聚苯胺
公开(公告)号：US5530087A
公开(公告)日：1996-06-25
申请号：US347367
申请日：1994-12-02
申请人： Herbert Naarmann , Rudolf Gompper , Thomas Mueller
发明人： Herbert Naarmann , Rudolf Gompper , Thomas Mueller
IPC分类号： G02F1/35 , C08G73/00 , C08G73/02 , C08L101/00 , C09D179/02 , C09K3/00 , C09K9/02 , G02F1/355 , G02F1/361 , H01B1/12
CPC分类号： C08G73/00 , G02F1/3616
摘要： Polyanils of the general formula ##STR1## where R.sup.1 is C.sub.1 -C.sub.24 -alkyl, C.sub.1 -C.sub.24 -alkoxy, Cl, Br, CF.sub.3 or NO.sub.2,R.sup.2 is para-phenylene, a fused aromatic ring system of 10 to 30 carbon atoms or ##STR2## R.sup.3 is a chemical bond, S, O, NH, CH.sub.2, CH.dbd.CH, CO, SO or SS andn is an integer from 5 to 100,and their acid addition salts of the general formula II ##STR3## where X.sup.- is ClO.sub.4.sup.-, BF.sub.4.sup.-, AsF.sub.6.sup.- or ##STR4## and R.sub.4 is C.sub.1 --C.sub.8 -alkyl are disclosed. The polyanils are useful as electrically conductive materials and for nonlinear optical purposes.
摘要翻译： PCT No.PCT / EP93 / 01303 Sec。 371日期1994年12月2日第 102（e）日期1994年12月2日PCT提交1993年5月25日PCT公布。公开号WO93 / 25603 日本公报1993年12月23日。通式“IMAGE”I的聚苯胺，其中R 1为C 1 -C 24 - 烷基，C 1 -C 24 - 烷氧基，Cl，Br，CF 3或NO 2，R 2为对 - 亚苯基，稠合芳环系 10到30个碳原子或者是一个化学键，S，O，NH，CH 2，CH = CH，CO，SO或SS，n是5到100的整数，它们的一般酸加成盐公开了II式，其中X是ClO 4 - ，BF 4 - ，AsF 6 - 或者“IMA”，R 4是C 1 -C 8烷基。聚酰胺可用作导电材料和非线性光学目的。

4. 发明授权

US4927578A Method for producing uncrosslinked polyacetylene film 失效
标题翻译：未交联聚乙炔膜的制造方法
公开(公告)号：US4927578A
公开(公告)日：1990-05-22
申请号：US195663
申请日：1988-05-18
申请人： Herbert Naarmann , Nicolas Theophilou
发明人： Herbert Naarmann , Nicolas Theophilou
IPC分类号： C08F4/64 , C08F4/42 , C08F4/60 , C08F4/80 , C08F6/00 , C08F38/02 , D06M23/00 , H01B1/12
CPC分类号： H01B1/125 , C08F38/02 , D06M23/00
摘要： Virtually uncrosslinked polyacetylenes in film form are prepared by polymerization of acetylene using a liquid catalyst system consisting of an organicaluminum compound and a titanate in the form of a solution in a viscous inert liquid on a substrate to which the catalyst solution is applied, by a process in which, after the polymerization, the polymer is treated with a strong reducing agent which is inert to the organoaluminum catalyst component, the polymer is, if desired, oriented and is freed from residual catalyst and reducing agent by washing with a liquid, doped with a strong electron acceptor or electron donor in a conventional manner to increase the conductivity and dried, and the materials thus obtained are, if desired, covered with a layer or sheath of nonconductive material.
摘要翻译：膜形式的几乎未交联的聚乙炔通过使用由有机铝化合物和钛酸盐形成的液体催化剂体系的乙炔聚合制备，所述液体催化剂体系为溶液形式的溶液，所述液体催化剂体系是在施加有催化剂溶液的基材上的粘性惰性液体中，其中聚合后聚合物用对有机铝催化剂组分是惰性的强还原剂处理，如果需要，聚合物是取向的，并通过用液体洗涤而被除去残余的催化剂和还原剂，掺杂强电子受体或电子给体以常规方式增加导电性并干燥，如果需要，由此获得的材料被非导电材料层或鞘覆盖。

5. 发明授权

US4566955A Preparation of finely divided electrically conductive pyrrole polymers 失效
标题翻译：精细分散的导电吡咯聚合物的制备
公开(公告)号：US4566955A
公开(公告)日：1986-01-28
申请号：US631946
申请日：1984-07-18
申请人： Herbert Naarmann
发明人： Herbert Naarmann
IPC分类号： C08G61/00 , C08G61/10 , C08G61/12 , C08G73/06 , H01B1/12 , H01M4/60 , C25D9/02
CPC分类号： C08G61/124 , C08G73/06 , H01B1/127 , H01M4/60
摘要： Finely divided electrically conductive pyrrole polymers are prepared by a process in which a finely divided pyrrole polymer, obtained by polymerization of pyrroles in solution with an oxygen-containing oxidizing agent, is electrochemically charged in the presence of a conductive salt. The finely divided electrically conductive pyrrole polymers can be used for the production of moldings.
摘要翻译：精细分散的导电吡咯聚合物通过以下方法制备，其中通过在含有氧的氧化剂溶液中聚合吡咯而获得的细碎的吡咯聚合物在导电盐存在下进行电化学充电。精细分散的导电吡咯聚合物可用于制造模制品。

6. 发明授权

US4532188A Electrically conductive pyrrole copolymer article 失效
标题翻译：导电吡咯共聚物制品
公开(公告)号：US4532188A
公开(公告)日：1985-07-30
申请号：US504723
申请日：1983-06-16
申请人： Herbert Naarmann , Gernot Koehler , Johannes Schlag
发明人： Herbert Naarmann , Gernot Koehler , Johannes Schlag
IPC分类号： H01M4/60 , C08F38/00 , C08G61/00 , C08G61/10 , C08G61/12 , C08J7/02 , C08L65/00 , H01B1/12 , H01L21/331 , H01L29/73 , H01L51/05 , H01L51/30 , H01L51/40 , B32B27/00 , C25B11/00
CPC分类号： H01B1/127 , C08G61/124 , Y10T428/31855 , Y10T428/8305
摘要： Highly electrically conductive copolymers of pyrroles and alkynes and/or aromatics, which possess good mechanical properties coupled with a well-balanced spectrum of properties, are prepared by anodic polymerization of the pyrroles and alkynes and/or aromatics in a polar solvent in the presence of a suitable conductive salt.
摘要翻译：通过吡咯和炔和/或芳族化合物在极性溶剂中的存在下阳极聚合，制备具有良好机械性能与良好平衡的性质光谱的吡咯和炔和/或芳族化合物的高度导电的共聚物合适的导电盐。

7. 发明授权

US4436854A Self-extinguishing thermoplastic molding material 失效
标题翻译：自熄性热塑性成型材料
公开(公告)号：US4436854A
公开(公告)日：1984-03-13
申请号：US344015
申请日：1982-01-29
申请人： Franz Brandstetter , Volker Muench , Herbert Naarmann , Edmund Priebe
发明人： Franz Brandstetter , Volker Muench , Herbert Naarmann , Edmund Priebe
IPC分类号： C08L25/00 , C08K5/00 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L51/04 , C08L71/00 , C08L71/12 , C08K5/52 , C08K5/53 , C08L71/04
CPC分类号： C08L51/04 , C08K5/0066 , C08L71/123
摘要： Self-extinguishing molding materials, comprising (A) a polymer of a vinyl-aromatic compound, especially a styrene polymer, which has been made impact-resistant (B) a polyphenylene ether and (C) a flameproofing additive, with or without (D) conventional additives, wherein one part of the soft component of the impact-resistant polymer of the vinyl-aromatic compound has a mean particle size of .ltoreq.1.5 .mu.m and the other part has a mean particle size of .ltoreq.3 .mu.m. Such molding materials not only have good self-extinguishing properties but also give moldings having a particularly uniform matt surface.
摘要翻译：自动灭火成型材料，包括（A）已经制成抗冲击性的乙烯基芳族化合物，特别是苯乙烯聚合物的聚合物（B）聚苯醚和（C）具有或不具有（D）的（C）阻燃添加剂）常规添加剂，其中乙烯基芳族化合物的耐冲击聚合物的一部分软组分的平均粒度为<1.5μm，另一部分的平均粒度为<3μm m。这种成型材料不仅具有良好的自熄性，而且还具有特别均匀的无光泽表面的模制品。

8. 发明授权

US4412037A Thermoplastic molding materials 失效
标题翻译：热塑性成型材料
公开(公告)号：US4412037A
公开(公告)日：1983-10-25
申请号：US302040
申请日：1981-09-14
申请人： Franz Brandstetter , Adolf Echte , Hermann Gausepohl , Herbert Naarmann
发明人： Franz Brandstetter , Adolf Echte , Hermann Gausepohl , Herbert Naarmann
IPC分类号： C08L25/00 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L51/04 , C08L71/00 , C08L71/12 , C08L61/04
CPC分类号： C08L51/04 , C08L71/123
摘要： Thermoplastic molding materials based on styrene polymers which have been made impact-resistant and on polyphenylene ethers, wherein the particles of the soft component of the styrene polymer which has been made impact-resistant have a mean diameter of more than 1 micron, and wherein the proportion of particles which have a diameter of less than 0.6 micron is not less than 40% by weight and the proportion of particles which have a diameter of from 0.6 to 3 microns is less than 3% by weight.
摘要翻译：基于已经制成抗冲击性的苯乙烯聚合物和聚苯醚的热塑性成型材料，其中已经制成抗冲击性的苯乙烯聚合物的软组分的颗粒具有大于1微米的平均直径，并且其中直径小于0.6微米的颗粒的比例不小于40重量％，直径为0.6至3微米的颗粒的比例小于3重量％。

9. 发明授权

US4404359A Preparation of polyphenylene ethers 失效
标题翻译：聚苯醚的制备
公开(公告)号：US4404359A
公开(公告)日：1983-09-13
申请号：US399211
申请日：1982-07-19
申请人： Herbert Naarmann , Juergen Hambrecht , Norbert Rieber
发明人： Herbert Naarmann , Juergen Hambrecht , Norbert Rieber
IPC分类号： C08G65/00 , C08G65/38 , C08G65/44
CPC分类号： C08G65/44
摘要： A process for the preparation of high molecular weight polyphenylene ethers from monohydric phenols which have alkyl substituents in both ortho-positions and may additionally have an alkyl substituent in one meta-position but not in the para-position, by an oxidative coupling reaction, employing oxygen, at from 10.degree. to 25.degree. C., in the presence of a catalyst complex comprising a copper salt and an N-substituted imidazole, in the presence of an aromatic C.sub.8 -C.sub.10 -hydrocarbon solvent.N-Methylimidazole, N-ethylimidazole, N-isopropylimidazole, N-n-butylimidazole, N-cyclohexylimidazole, N-octylimidazole and N-phenylimidazole are preferably used as the imidazole, advantageously in amounts of from 0.5 to 5 percent by weight.
摘要翻译：一种从一元酚制备高分子量聚苯醚的方法，其在两个邻位具有烷基取代基，并且可以通过氧化偶联反应另外在一个间位而不是在对位具有烷基取代基，采用在含有铜盐和N-取代的咪唑的催化剂络合物存在下，在芳族C 8 -C 10 - 烃溶剂存在下，在10〜25℃下进行。 N-甲基咪唑，N-乙基咪唑，N-异丙基咪唑，N-正丁基咪唑，N-环己基咪唑，N-辛基咪唑，N-苯基咪唑优选用作咪唑，有利地为0.5〜5重量％。

10. 发明授权

US4387189A Thermoplastic molding materials containing polymers with polyphenylene ether groups and styrene polymers 失效
标题翻译：含聚苯醚聚合物和苯乙烯聚合物的热塑性成型材料
公开(公告)号：US4387189A
公开(公告)日：1983-06-07
申请号：US297948
申请日：1981-08-31
申请人： Franz Brandstetter , Juergen Hambrecht , Herbert Naarmann , Hans Schuster
发明人： Franz Brandstetter , Juergen Hambrecht , Herbert Naarmann , Hans Schuster
IPC分类号： C08G81/00 , C08G81/02 , C08F8/00 , C08L71/04
CPC分类号： C08G81/025
摘要： Thermosplastic molding materials which contain styrene polymers and polyphenylene ethers whose phenolic hydroxyl groups have been reacted with reactive copolymers.
摘要翻译：含有酚羟基与反应性共聚物反应的苯乙烯聚合物和聚苯醚的热塑性成型材料。

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