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1. 发明授权

US4914167A Polymeric organic acids, their preparation and their use in detergents and cleansers 失效
标题翻译：聚合有机酸，它们的制备及其在洗涤剂和清洁剂中的应用
公开(公告)号：US4914167A
公开(公告)日：1990-04-03
申请号：US752013
申请日：1985-07-08
申请人： Juergen Hambrecht , Heinrich Hartmann , Walter Denzinger , Albert Hettche , Wolfgang Trieselt , Rolf Schneider
发明人： Juergen Hambrecht , Heinrich Hartmann , Walter Denzinger , Albert Hettche , Wolfgang Trieselt , Rolf Schneider
IPC分类号： C08F2/02 , C08F220/04 , C11D3/37
CPC分类号： C11D3/3761 , C08F220/04
摘要： Organic polyacids are prepared from monomeric monofunctional acids, such as acrylic acid or methacrylic acid and monomers without an acid group, with or without dicarboxylic acids or their anhydrides, by continuous free radical mass copolymerization under superatmospheric pressure at from 200.degree. to 400.degree. C., followed, if desired, by neutralization of the polyacids obtained. The polyacids obtained by the novel process are useful as phosphate substitutes and scale inhibitors in detergents and cleansers.
摘要翻译：有机多元酸通过在200-400℃的超大气压下连续自由基基团共聚，由单体单官能酸例如丙烯酸或甲基丙烯酸和无酸基的单体制备，含或不含二羧酸或其酸酐。，如果需要，通过中和获得的多元酸。通过该方法获得的多酸可用作洗涤剂和清洁剂中的磷酸盐替代物和防垢剂。

2. 发明授权

US5175361A Preparation of copolymers of monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids 失效
标题翻译：单烯属不饱和一元羧酸和二羧酸的共聚物的制备
公开(公告)号：US5175361A
公开(公告)日：1992-12-29
申请号：US625621
申请日：1990-11-30
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
IPC分类号： C08F220/04 , C08F222/02
CPC分类号： C08F222/02 , C08F220/04
摘要： A process for the preparation of copolymers which contain monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids as copolymerized monomer units, which comprises copolymerizinga) 10 to 60% by weight, based on the sum of the monomers, of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, -or an alkali metal salt thereof or, an anhydride thereof,b) 90 to 40% by weight of a monoethylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms or an alkali metal salt thereof andc) 0 to 20% by weight of another monoethylenically unsaturated monomer, not having carboxyl groups and which is copolymerizable with a) and b);in an aqueous medium in the presence of from 0.5 to 5% by weight, based on monomers, of a water-soluble initiator.
摘要翻译：一种制备包含单烯属不饱和一元羧酸和二羧酸作为共聚单体单元的共聚物的方法，其包括将基于单体总量的10-60重量％的单烯属不饱和二羧酸与4- 6个碳原子，或其碱金属盐或其酸酐，b）90〜40重量％的3〜10个碳原子的单烯属不饱和一元羧酸或其碱金属盐，c）0〜20重量％重量的不具有羧基且可与a）和b）共聚的另一单烯属不饱和单体; 在水介质中，以0.5至5重量％的单体为基础，存在水溶性引发剂。

3. 发明授权

US4725655A Preparation of copolymers of monoethylenically unsaturated mono- and dicarboxylic acids and anhydrides 失效
公开(公告)号：US4725655A
公开(公告)日：1988-02-16
申请号：US919583
申请日：1986-10-16
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
IPC分类号： C08F2/00 , C08F2/10 , C08F8/00 , C08F8/12 , C08F8/44 , C08F20/00 , C08F20/02 , C08F120/04 , C08F220/04 , C08F222/02 , C08F220/06 , C08F222/04
CPC分类号： C08F220/04 , C08F222/02
摘要： Copolymers which contain, as copolymerized monomer units, monoethylenically unsaturated mono- and dicarboxylic acids are prepared by a process in which(a) from 10 to 60% by weight of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, its salt and/or, if appropriate, its anhydride,(b) from 90 to 40% by weight of a monothylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms and/or its salt and(c) from 0 to 20% by weight of another, carboxyl-free monoethylenically unsaturated monomer which is copolymerizable with (a) and (b),the percentages being based on the sum of the monomers, are polymerized in the presence of from 0.5 to 5% by weight of a water-soluble free-radical-forming initiator in an aqueous medium at from 60.degree. to 150.degree. C., and, if appropriate, their anhydride groups are hydrolyzed, the monomers (a) and (b) being employed in a form such that from 20 to 80% of their amount is neutralized during the polymerization reaction, wherein the copolymerization is carried out continuously in a reactor cascade comprising several reactors, and an aqueous solution of a pre-prepared copolymer of (a), (b) and, if appropriate, (c) is initially introduced into all the reactors and heated to the required reaction temperature, the total amount of unneutralized or partially neutralized (a), not less than 40% by weight of unneutralized or partially neutralized (b), where relevant, all or some of (c), and some or all of the amount of initiator required for polymerization, with or without the amount of neutralizing agent required for the neutralization according to the definition, are metered into the first reactor, the remaining amount of unneutralized or neutralized (b) and, where relevant, (c), and any remaining amount of initiator and neutralizing agent which may be required are introduced into the second reactor or are distributed over the second reactor and the downstream reactors, and the reactants are allowed to react together during a residence time of from 0.5 to 8 hours. The above copolymers can be used as incrustation inhibitors or for scaling inhibition.

4. 发明授权

US4698174A Additives for detergents and cleaning agents 失效
标题翻译：洗涤剂和清洁剂的添加剂
公开(公告)号：US4698174A
公开(公告)日：1987-10-06
申请号：US822610
申请日：1986-01-27
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
IPC分类号： C11D3/33 , C11D3/37
CPC分类号： C11D3/33 , C11D3/3761
摘要： Pulverulent and/or granular additives for pulverulent detergents and cleaning agents, consisting of(a) from 80 to 20% by weight of one or more copolymers comprising from 40 to 90% by weight of (meth)acrylic acid and from 60 to 10% by weight of maleic acid and/or one or more copolymers comprising from 10 to 45% by weight of (meth)acrylic acid, from 10 to 45% by weight of maleic acid and from 10 to 60% by weight of one or more hydroxyalkyl (meth)acrylates where hydroxyalkyl is of 2 to 6 carbon atoms, if appropriate in the form of a partially or completely neutralized water-soluble salt,(b) from 20 to 80% by weight of nitrilotriacetic acid or its mono-, di- or trisodium or mono-, di- or tripotassium salt and(c) from 0 to 20% by weight of one or more additives conventionally used for detergent and cleaning agent formulations, the use of these pulverulent and/or granular mixtures as additives for pulverulent and/or granular detergents and cleaning agents, and processes for the preparation of the said additives.
摘要翻译：用于粉状洗涤剂和清洁剂的粉末和/或颗粒添加剂由（a）80至20重量％的一种或多种共聚物组成，所述共聚物包含40至90重量％的（甲基）丙烯酸和60至10重量％的马来酸和/或一种或多种共聚物，其包含10至45重量％的（甲基）丙烯酸，10至45重量％的马来酸和10至60重量％的一种或多种羟烷基（甲基）丙烯酸酯，其中羟基烷基为2至6个碳原子，如果合适的话以部分或完全中和的水溶性盐的形式，（b）20至80重量％的次氮基三乙酸或其单 - 或三钠或单，二或三钾盐和（c）0至20重量％的常规用于洗涤剂和清洁剂配方的一种或多种添加剂，使用这些粉状和/或颗粒状混合物作为粉末状添加剂和/或颗粒状洗涤剂和清洁剂，以及制备方法 n的所述添加剂。

5. 发明授权

US4370454A Preparation of maleic anhydride copolymers 失效
标题翻译：马来酸酐共聚物的制备
公开(公告)号：US4370454A
公开(公告)日：1983-01-25
申请号：US350356
申请日：1982-02-19
申请人： Karlheinz Messmer , Hermann Fischer , Heinrich Hartmann , Walter Denzinger , Rolf Schneider , Klaus Wulz , Hans-Juergen Raubenheimer
发明人： Karlheinz Messmer , Hermann Fischer , Heinrich Hartmann , Walter Denzinger , Rolf Schneider , Klaus Wulz , Hans-Juergen Raubenheimer
IPC分类号： C08F20/00 , B01F17/52 , C08F20/02 , C08F210/00 , C08F222/06 , C11D3/37 , D21H17/43 , D21H19/58 , C08L37/00
CPC分类号： C11D3/3773 , C08F222/06 , C11D3/3757 , C11D3/3769 , D21H17/43 , D21H19/58
摘要： Maleic anhydride copolymer powders are prepared by a process wherein a solution or dispersion of maleic anhydride in an alkyl vinyl ether and/or an alkene, containing from 3 to 25 moles of the alkyl vinyl ether and/or alkene per mole of maleic anhydride, is brought into contact with a powder bed under polymerization conditions, and is polymerized in the bed while the reaction mass is circulated and the powder state is maintained, and the heat generated during polymerization is removed by evaporating excess monomer which boils lower than maleic anhydride.
摘要翻译：马来酸酐共聚物粉末通过以下方法制备：其中马来酸酐在烷基乙烯基醚和/或烯烃中的溶液或分散体含有3至25摩尔烷基乙烯基醚和/或烯烃/摩尔马来酸酐的方法是在聚合条件下与粉末床接触，并且在反应物料循环并保持粉末状态的同时在床中聚合，并且通过蒸发沸腾低于马来酸酐的过量单体来除去聚合期间产生的热量。

6. 发明申请

US20150321139A1 PROCESS FOR ABSORPTION OF CO2 FROM A GAS MIXTURE USING AN AQUEOUS SOLUTION OF A DIAMINE 审中-公开
标题翻译：使用氨水溶液从气体混合物中吸收二氧化碳的方法
公开(公告)号：US20150321139A1
公开(公告)日：2015-11-12
申请号：US14649068
申请日：2013-11-13
申请人： Alexander SCHRAVEN , Jochen NIEMEYER , Manfred NEUMANN , Stefanie RINKER , Rolf SCHNEIDER , Jörn ROLKER
发明人： Alexander Schraven , Jochen Niemeyer , Manfred Neumann , Stefanie Rinker , Rolf Schneider , Jörn Rolker
IPC分类号： B01D53/14
CPC分类号： B01D53/1475 , B01D53/1425 , B01D53/1493 , B01D53/62 , B01D2252/103 , B01D2252/2041 , B01D2252/20426 , B01D2252/20431 , B01D2257/504 , B01D2258/0283 , B01D2258/05 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： CO2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorption medium comprising water and at least one amine of formula (I) R1R2NCH2CH2CHR4NHR3, (I) where R1, R2 and R3 are, independently of one another, C1-C3-alkyl radicals, R4 is hydrogen, methyl or ethyl and the radicals R1, R2, R3 and R4 together comprise not more than 5 carbon atoms.
摘要翻译：通过使气体混合物与包含水和至少一种式（I）的胺R 1 R 2 NCH 2 CH 2 CHR 4 NHR 3（I）的吸收介质接触，从气体混合物中吸收CO 2，其中R 1，R 2和R 3彼此独立地为C1- C 3 - 烷基，R 4是氢，甲基或乙基，基团R 1，R 2，R 3和R 4一起包含不超过5个碳原子。

7. 发明授权

US08500892B2 CO2 absorption from gas mixtures using an aqueous solution of 4-amino-2,2,6,6-tetramethylpiperidine 有权
标题翻译：使用4-氨基-2,2,6,6-四甲基哌啶的水溶液从气体混合物中的CO 2吸收
公开(公告)号：US08500892B2
公开(公告)日：2013-08-06
申请号：US13147198
申请日：2010-01-29
申请人： Matthias Seiler , Jörn Rolker , Rolf Schneider , Bernd Glöckler , Axel Kobus , Wolfgang Benesch , Thomas Riethmann , Hermann Winkler , Jens Reich , Helmut Brüggemann
发明人： Matthias Seiler , Jörn Rolker , Rolf Schneider , Bernd Glöckler , Axel Kobus , Wolfgang Benesch , Thomas Riethmann , Hermann Winkler , Jens Reich , Helmut Brüggemann
IPC分类号： B01D47/00
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/103 , B01D2252/2041 , B01D2252/20426 , B01D2252/20442 , B01D2252/2056 , B01D2252/30 , B01D2257/504 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： CO2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorbent that comprises water and at least one amine of the formula (I), wherein R1 and R2, independently of each other, are hydrogen or an alkyl group. According to the invention, absorption media comprise sulfolane or an ionic liquid in addition to water and an amine of the formula (I). A device according to the invention for removing CO2 from a gas mixture comprises an absorption unit, a desorption unit, and an absorption medium according to the invention that is conducted in the circuit.
摘要翻译：通过使气体混合物与包含水和至少一种式（I）的胺的吸收剂接触，从气体混合物吸收CO 2，其中R 1和R 2彼此独立地为氢或烷基。根据本发明，除了水和式（I）的胺之外，吸收介质还包括环丁砜或离子液体。根据本发明的用于从气体混合物中除去CO 2的装置包括在电路中进行的根据本发明的吸收单元，解吸单元和吸收介质。

8. 发明申请

US20120308458A1 CO2 ABSORPTION FROM GAS MIXTURES USING AN AQUEOUS SOLUTION OF 4-AMINO-2,2,6,6-TETRAMETHYLPIPERIDINE 有权
标题翻译：使用4-氨基-2,2,6,6-四甲基哌啶的水溶液从气体混合物中吸收二氧化碳
公开(公告)号：US20120308458A1
公开(公告)日：2012-12-06
申请号：US13589169
申请日：2012-08-19
申请人： Matthias Seiler , Jörn Rolker , Rolf Schneider , Bernd Glöckler , Axel Kobus , Wolfgang Benesch , Thomas Riethmann , Hermann Winkler , Jens Reich , Helmut Brüggemann
发明人： Matthias Seiler , Jörn Rolker , Rolf Schneider , Bernd Glöckler , Axel Kobus , Wolfgang Benesch , Thomas Riethmann , Hermann Winkler , Jens Reich , Helmut Brüggemann
IPC分类号： B01D53/62 , C09K3/00
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/103 , B01D2252/2041 , B01D2252/20426 , B01D2252/20442 , B01D2252/2056 , B01D2252/30 , B01D2257/504 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： CO2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorbent that comprises water and at least one amine of the formula (I), wherein R1 and R2, independently of each other, are hydrogen or an alkyl group. According to the invention, absorption media comprise sulfolane or an ionic liquid in addition to water and an amine of the formula (1). A device according to the invention for removing CO2 from a gas mixture comprises an absorption unit, a desorption unit, and an absorption medium according to the invention that is conducted in the circuit.
摘要翻译：通过使气体混合物与包含水和至少一种式（I）的胺的吸收剂接触，从气体混合物吸收CO 2，其中R 1和R 2彼此独立地为氢或烷基。根据本发明，除了水和式（1）的胺之外，吸收介质还包括环丁砜或离子液体。根据本发明的用于从气体混合物中除去CO 2的装置包括在电路中进行的根据本发明的吸收单元，解吸单元和吸收介质。

9. 发明授权

US08167983B2 Gas separation membranes 有权
标题翻译：气体分离膜
公开(公告)号：US08167983B2
公开(公告)日：2012-05-01
申请号：US12517372
申请日：2007-12-17
申请人： Matthias Seiler , Stefan Bernhardt , Rolf Schneider , Roland Wursche , Franz-Erich Baumann
发明人： Matthias Seiler , Stefan Bernhardt , Rolf Schneider , Roland Wursche , Franz-Erich Baumann
IPC分类号： B01D53/22 , B01D39/16
CPC分类号： B01D53/228 , B01D67/0011 , B01D71/64 , B01D2256/10 , B01D2256/12 , B01D2323/12 , B01D2325/20 , B01D2325/34
摘要： The present invention relates to compositions for producing membranes, the compositions comprising at least 0.1% by weight of highly branched polymer, at least 0.5% by weight of linear polymer and at least 30% by weight of solvent. The present invention additionally describes membranes obtainable from the compositions, and methods of producing these membranes.
摘要翻译：本发明涉及用于生产膜的组合物，该组合物包含至少0.1重量％的高支化聚合物，至少0.5重量％的线性聚合物和至少30重量％的溶剂。本发明另外描述了可从组合物获得的膜以及制备这些膜的方法。

10. 发明申请

US20060058797A1 Device for osteosynthesis 有权
标题翻译：骨接合装置
公开(公告)号：US20060058797A1
公开(公告)日：2006-03-16
申请号：US11147140
申请日：2005-06-06
申请人： Claude Mathieu , Robert Frigg , Rolf Schneider , R. Appenzeller
发明人： Claude Mathieu , Robert Frigg , Rolf Schneider , R. Appenzeller
IPC分类号： A61B17/56
CPC分类号： A61B17/8047
摘要： A device of performing osteosynthesis includes an osteosynthesis element, e.g., a bone plate, having an upper face, a lower face and an opening with a central axis linking the upper and lower faces. The opening receives a multi-axial pivotable insert for a longitudinal bone fixing element, such as a bone screw. The insert has a central passage with a longitudinal axis for housing the bone fixing element. The insert may be configured as a helical spring with an external sheath surface and an internal sheath surface that defines the central passage. When placed in the through hole, the insert is rotationally fixed relative to its longitudinal axis, but remains pivotally adjustable within the through hole relative to the osteosynthesis element.
摘要翻译：进行骨接合术的装置包括具有上表面，下表面和具有连接上下表面的中心轴线的开口的骨接合元件，例如骨板。该开口接收用于纵向骨固定元件（例如骨螺钉）的多轴可枢转插入件。插入件具有中心通道，纵向轴线用于容纳骨固定元件。插入件可以被配置为具有外护套表面和限定中心通道的内护套表面的螺旋弹簧。当放置在通孔中时，插入物相对于其纵向轴线旋转地固定，但是相对于骨接合元件在通孔内保持可枢转地调节。

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