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    • 3. 发明申请
    • ELASTIC MOLDED FOAM BASED ON POLYOLEFIN/STYRENE POLYMER MIXTURES
    • 基于聚烯烃/苯乙烯聚合物混合物的弹性模制泡沫
    • US20110269858A1
    • 2011-11-03
    • US13143029
    • 2009-12-16
    • Carsten SchipsKlaus HahnKonrad KnollHolger RuckdäschelJens AssmannGeorg GrässelMaximilian Hofmann
    • Carsten SchipsKlaus HahnKonrad KnollHolger RuckdäschelJens AssmannGeorg GrässelMaximilian Hofmann
    • C08L53/02C08J9/18C08L23/02C08L25/04C08J9/12C08J9/224B82Y30/00
    • C08L25/06C08K5/01C08L23/06C08L23/0815C08L53/02C08L53/025C08L2205/02C08L2205/035C08L2666/06C08L2666/02
    • Expandable, thermoplastic polymer bead material, comprising A) from 45 to 97.8 percent by weight of a styrene polymer, B1) from 1 to 45 percent by weight of a polyolefin with a melting point in the range from 105 to 140° C., B2) from 0 to 25 percent by weight of a polyolefin with a melting point below 105° C., C1) from 0.1 to 25 percent by weight of a block or graft copolymer with weight-average molar mass Mw of at least 100,000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block or graft copolymer A, C2) from 0 to 20 percent by weight of a styrene-butadiene or styrene-isoprene block copolymer different from C1, C3) from 0.1 to 9.9 percent by weight of a styrene-ethylene-butylene block copolymer, D) from 1 to 15 percent by weight of a blowing agent, and E) from 0 to 5 percent by weight of a nucleating agent, where the entirety composed of A) to E) gives 100% by weight.
    • 可膨胀的热塑性聚合物珠粒材料,其包含A)45至97.8重量%的苯乙烯聚合物,B1)1至45重量%的熔点为105-140℃的聚烯烃,B2 )0至25重量%的熔点低于105℃的聚烯烃,C1)0.1至25重量%的重均摩尔质量Mw至少为100,000克/摩尔的嵌段或接枝共聚物 包括a)至少一种由95-100%重量的乙烯基芳族单体和0-5%重量二烯组成的嵌段S,和b)至少一种由63组成的共聚物嵌段(S / B)A 至80重量%的乙烯基芳族单体和20至37重量%的二烯,玻璃化转变温度TgA在5至30℃的范围内,其中全部块S的重量比为 基于嵌段或接枝共聚物A在50至70重量%的范围内,C2)0至20重量%的苯乙烯 - 丁 二烯或苯乙烯 - 异戊二烯嵌段共聚物,不同于C1,C3)0.1至9.9重量%的苯乙烯 - 乙烯 - 丁烯嵌段共聚物,D)1至15重量%的发泡剂,E)0至 5重量%的成核剂,其中由A)至E)组成的整体得到100重量%。
    • 8. 发明申请
    • FLAME RETARDANTS
    • 阻燃剂
    • US20110196052A1
    • 2011-08-11
    • US13022045
    • 2011-02-07
    • Klaus HahnOlaf KrihaIngo BellinPatrick SpiesSabine FuchsPeter DeglmannKlemens MassonneHartmut DeneckeChristoph FleckensteinGeert JanssensMaximilian Hofmann
    • Klaus HahnOlaf KrihaIngo BellinPatrick SpiesSabine FuchsPeter DeglmannKlemens MassonneHartmut DeneckeChristoph FleckensteinGeert JanssensMaximilian Hofmann
    • C08K5/5398C08L25/06C08J9/18C08J9/12
    • C08J9/0038C08J9/16C08J2325/04C08K5/5398C08L25/06
    • Phosphine sulfide derivatives of the formula (I), S═PR1R2R3  (I) are suitable as flame retardants, in particular for polymers, where the definitions of the symbols in the formula (I) are as follows: R1 and R2 are identical or different, being C1-C12-alkyl, C3-C8-cycloalkyl, which may have no substitution or may have one or more C1-C4-alkyl groups as substituents, C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C8-C10-aryl-C1-C4-alkyl; R3 is H, SH, SR4, OH, OR5 or a —(Y1)n—[P(═X1)R6—(Y2)n]m—P(═X2)R7R8 group; or two groups R1, R2, R3 form, together with the phosphorus atom bonded thereto, a ring system; X1 and X2 are identical or different, being O or S; Y1 and Y2 are identical or different, being O or S; R4, R5, R6, R7 and R8 are identical or different, being independently from one another C1-C12-alkyl, C3-C8-cycloalkyl, which may have no substitution or may have one or more C1-C4-alkyl groups as substituents, C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C6-C10-aryl-C1-C4-alkyl; n is 1 if Y1 and, respectively, Y2 is O, and is 1, 2, 3, 4, 5, 6, 7, or 8 if Y1 and, respectively, Y2 is S, and m is an integer from 0 to 100.
    • 式(I)的硫化膦衍生物,S = PR1R2R3(I)适用作阻燃剂,特别是用于聚合物的阻燃剂,其中式(I)中符号的定义如下:R1和R2相同或不同 可以不具有取代基或可以具有一个或多个C 1 -C 4烷基作为取代基的C 1 -C 12 - 烷基,C 3 -C 8 - 环烷基,C 2 -C 12 - 烯基,C 2 -C 12炔基,C 6 -C 10 - 芳基或C 8 -C 10 - 芳基-C 1 -C 4 - 烷基; R3是H,SH,SR4,OH,OR5或 - (Y1)n- [P(= X1)R6-(Y2)n] m-P(= X2)R7R8组; 或两个基团R 1,R 2,R 3与键合的磷原子一起形成环系; X1和X2相同或不同,为O或S; Y1和Y2相同或不同,为O或S; R 4,R 5,R 6,R 7和R 8相同或不同,彼此独立地为可以不具有取代基或可以具有一个或多个C 1 -C 4 - 烷基作为取代基的C 1 -C 12 - 烷基,C 3 -C 8 - 环烷基 ,C 2 -C 12 - 烯基,C 2 -C 12 - 炔基,C 6 -C 10 - 芳基或C 6 -C 10 - 芳基-C 1 -C 4 - 烷基; 如果Y1和Y1分别为0,则n为1,如果Y1分别为Y2,并且分别为1,2,3,4,5,6,7或8,并且m分别为0至100的整数。 。
    • 10. 发明授权
    • Flame retardant
    • 不易燃的
    • US09115312B2
    • 2015-08-25
    • US13075518
    • 2011-03-30
    • Klaus HahnSabine FuchsIngo BellinPatrick SpiesMaximilian HofmannPeter DeglmannKlemens MassonneHartmut DeneckeChristoph FleckensteinGeert JanssensManfred DöringMichael CiesielskiJochen Wagner
    • Klaus HahnSabine FuchsIngo BellinPatrick SpiesMaximilian HofmannPeter DeglmannKlemens MassonneHartmut DeneckeChristoph FleckensteinGeert JanssensManfred DöringMichael CiesielskiJochen Wagner
    • C08J9/00C08K5/36C09K21/12C08K5/49
    • C09K21/12C08J9/0033C08J2325/06C08K5/36C08K5/49
    • A flame retardant comprising a) at least one sulfur compound of the formula (I) A1-(Z1)m—(S)n—(Z2)p-A2  (I) where the definitions of the symbols and indices are as follows: A1 and A2 are identical or different, being C6-C12-aryl, cyclohexyl, Si(ORa)3, a saturated, partially unsaturated, or aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S, where the system is unsubstituted or has substitution by one or more substituents of the group of O, OH, S, SH, COORb, CONRcRd, C1-C18-alkyl, C1-C18-alkoxy, C1-C18-thioalkyl, C6-C12-aryl, C6-C12-aryloxy, C2-C18-alkenyl, C2-C18-alkenoxy, C2-C18-alkynyl, and C2-C18-alkinoxy; Z1 and Z2 are identical or different, being —CO— or —CS—; Ra is C1-C18-alkyl; Rb, Rc, and Rd are identical or different, being H, C1-C18-alkyl, C6-C12-aryl, or an aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S; m and p are identical or different, being 0 or 1, and n is a natural number from 2 to 10, and b) at least one halogen-free organophosphorus compound having phosphorus content in the range from 5 to 80% by weight, based on the phosphorus compound, is particularly suitable for protecting foams based on styrene polymers.
    • 一种阻燃剂,其包含a)至少一种式(I)A1-(Z1)m-(S)n-(Z2)p-A2(I)的硫化合物,其中符号和指数的定义如下: A1和A2相同或不同,为具有3至12个环成员且包含一个或多个杂原子的饱和,部分不饱和或芳族单环或双环的C 6 -C 12 - 芳基,环己基,Si(OR a)3 由N,O和S的基团组成,其中体系未被取代或被一个或多个O,OH,S,SH,COORb,CONRcRd,C 1 -C 18烷基,C 1 -C 18 - 烷氧基,C 1 -C 18 - 硫代烷基,C 6 -C 12 - 芳基,C 6 -C 12 - 芳氧基,C 2 -C 18烯基,C 2 -C 18 - 烯氧基,C 2 -C 18炔基和C 2 -C 18 - 烷氧基; Z 1和Z 2相同或不同,为-CO-或-CS-; R a是C 1 -C 18 - 烷基; R b,R c和R d相同或不同,为H,C 1 -C 18 - 烷基,C 6 -C 12 - 芳基或具有3至12个环成员并且包含一个或多个来自 N,O,S组; m和p相同或不同,为0或1,n为2至10的自然数,b)至少一种磷含量为5-80重量%的无卤素有机磷化合物,基于 在磷化合物上,特别适用于保护基于苯乙烯聚合物的泡沫体。