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    • 5. 发明申请
    • Polyimide Powder and Porous Polyimide Body Using the Same
    • 聚酰亚胺粉末和使用其的多孔聚酰亚胺体
    • US20140155508A1
    • 2014-06-05
    • US14122569
    • 2012-05-24
    • Fumio Aoki
    • Fumio Aoki
    • C08G73/10
    • C08G73/1082C08G73/1042C08G73/106C08J9/24C08J2379/08C08L79/08
    • A porous polyimide is obtained by pulverizing a foam product of a polyimide precursor. Particularly, the foam product of the polyimide precursor is a product of heating the polyimide precursor for foaming with microwave radiation and has the imidization ratio of 10 to 90%, and is preferably a foam product including a tetracarboxylic acid component, which contains 50 mol % or more of biphenyltetracarboxylic acids and is monoesterified and/or diesterified in parts with a lower aliphatic primary alcohol with the number of carbon atoms of 4 or less, and a diamine component containing 90 mol % or more of an aromatic diamine, and being a monomer salt of which the ratio of the tetracarboxylic acid component and the diamine component is approximately 2:1 and in a solid form dispersed at molecular level.
    • 通过粉碎聚酰亚胺前体的泡沫产物获得多孔聚酰亚胺。 特别地,聚酰亚胺前体的泡沫体是将微波辐射发泡的聚酰亚胺前体加热,酰亚胺化率为10〜90%的产物,优选含有四羧酸成分的泡沫体,其含有50摩尔% 或更多的联苯四羧酸,并且与碳原子数为4以下的低级脂肪族伯醇和含有90摩尔%以上的芳香族二胺的二胺成分部分酯化和/或二酯化,并且为单体 其中四羧酸组分和二胺组分的比例约为2:1,并以分子水平分散的固体形式存在。