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    • 1. 发明授权
    • Method for producing expandable granulates containing polylactic acid
    • 用于生产含有聚乳酸的可膨胀颗粒的方法
    • US09212270B2
    • 2015-12-15
    • US13522031
    • 2011-01-06
    • Andreas FüβlBangaru SampathMaximilian HofmannIngo BellinSameer NalawadeKlaus HahnAndreas KünkelRobert Loos
    • Andreas FüβlBangaru SampathMaximilian HofmannIngo BellinSameer NalawadeKlaus HahnAndreas KünkelRobert Loos
    • C08J9/16C08J9/18C08L67/02C08J9/00C08L67/04C08L33/06
    • C08J9/127C08J9/0061C08J9/16C08J9/18C08J2333/14C08J2367/02C08J2367/04C08J2463/00C08J2467/02C08L33/068C08L67/02C08L67/04C08L2666/02
    • The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of the following components: i) from 50 to 99.9% by weight, based on the total weight of components i to iii), of polylactic acid, ii) from 0 to 49.9% by weight, based on the total weight of components i to iii), of one or more further polymers, iii) from 0.1 to 2% by weight, based on the total weight of components i to iii), of a diepoxide or polyepoxide, and iv) from 0 to 10% by weight of one or more additives, b) incorporation by mixing of v) from 3 to 7% by weight, based on the total weight of components i to iv), of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.5 mm, and d) pelletizing the melt comprising blowing agent directly downstream of the die plate, and under water, at a pressure in the range from 1 to 20 bar. The invention further relates to expandable pelletized material which comprises polylactic acid and which is obtainable by said process, and also to specific expandable pelletized material which comprises polylactic acid and which has a proportion of from 3 to 7% by weight of an organic blowing agent, preferably n-pentane and particularly preferably isopentane. The invention further relates to a preferred process for producing expandable pelletized material which comprises blowing agent and which comprises polylactic acid, and which has low bulk density.
    • 本发明涉及一种生产可膨胀颗粒材料的方法,其包括聚乳酸,其包括以下步骤:a)通过混合以下组分熔融和掺入:i)基于组分的总重量为50至99.9重量% ii)0至49.9重量%,基于组分i至iii的总重量),一种或多种其它聚合物,iii)基于以下物质的0.1至2重量%,基于 组分i至iii),二环氧化物或聚环氧化物的总重量,和iv)0至10重量%的一种或多种添加剂,b)通过混合v)3至7重量%,基于 通过静态或动态混合器在至少140℃的温度下将有机发泡剂的总成分重量分配到聚合物熔体中,c)通过具有孔的模板排出,直径 其中在模具的出口处至多为1.5mm,以及d)将熔体造粒, 直接在模板的下游,并在水下,在1至20巴的压力范围内。 本发明还涉及包含聚乳酸并且可通过所述方法获得的可膨胀颗粒材料,还涉及包含聚乳酸并且具有3-7重量%的有机发泡剂的比例的特定的可膨胀颗粒状材料, 优选正戊烷,特别优选异戊烷。 本发明还涉及一种用于生产可膨胀颗粒材料的优选方法,其包括发泡剂,其包含聚乳酸,并且其堆积密度低。
    • 3. 发明申请
    • METHOD FOR PRODUCING EXPANDABLE GRANULATES CONTAINING POLYLACTIC ACID
    • 生产含有聚氨酯的可膨胀颗粒的方法
    • US20130150468A1
    • 2013-06-13
    • US13522031
    • 2011-01-06
    • Andreas FüssiBangaru SampathMaximilian HofmannIngo BellinSameer NalawadeKlaus HahnAndreas KünkelRobert Loos
    • Andreas FüssiBangaru SampathMaximilian HofmannIngo BellinSameer NalawadeKlaus HahnAndreas KünkelRobert Loos
    • C08J9/18
    • C08J9/127C08J9/0061C08J9/16C08J9/18C08J2333/14C08J2367/02C08J2367/04C08J2463/00C08J2467/02C08L33/068C08L67/02C08L67/04C08L2666/02
    • The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of the following components: i) from 50 to 99.9% by weight, based on the total weight of components i to iii), of polylactic acid, ii) from 0 to 49.9% by weight, based on the total weight of components i to iii), of one or more further polymers, iii) from 0.1 to 2% by weight, based on the total weight of components i to iii), of a diepoxide or polyepoxide, and iv) from 0 to 10% by weight of one or more additives, b) incorporation by mixing of v) from 3 to 7% by weight, based on the total weight of components i to iv), of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.5 mm, and d) pelletizing the melt comprising blowing agent directly downstream of the die plate, and under water, at a pressure in the range from 1 to 20 bar. The invention further relates to expandable pelletized material which comprises polylactic acid and which is obtainable by said process, and also to specific expandable pelletized material which comprises polylactic acid and which has a proportion of from 3 to 7% by weight of an organic blowing agent, preferably n-pentane and particularly preferably isopentane. The invention further relates to a preferred process for producing expandable pelletized material which comprises blowing agent and which comprises polylactic acid, and which has low bulk density.
    • 本发明涉及一种生产可膨胀颗粒材料的方法,其包括聚乳酸,其包括以下步骤:a)通过混合以下组分熔融和掺入:i)基于组分的总重量为50至99.9重量% ii)0至49.9重量%,基于组分i至iii的总重量),一种或多种其它聚合物,iii)基于以下物质的0.1至2重量%,基于 组分i至iii),二环氧化物或聚环氧化物的总重量,和iv)0至10重量%的一种或多种添加剂,b)通过混合v)3至7重量%,基于 通过静态或动态混合器在至少140℃的温度下将有机发泡剂的总成分重量分配到聚合物熔体中,c)通过具有孔的模板排出,直径 其中在模具的出口处至多为1.5mm,以及d)将熔体造粒, 直接在模板的下游,并在水下,在1至20巴的压力范围内。 本发明还涉及包含聚乳酸并且可通过所述方法获得的可膨胀颗粒材料,还涉及包含聚乳酸并且具有3-7重量%的有机发泡剂的比例的特定的可膨胀颗粒状材料, 优选正戊烷,特别优选异戊烷。 本发明还涉及一种用于生产可膨胀颗粒材料的优选方法,其包括发泡剂,其包含聚乳酸,并且其堆积密度低。