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1. 发明授权

US5576356A Cationically co-curable polysiloxane release coatings 失效
标题翻译：阳离子共可聚合的聚硅氧烷脱模涂层
公开(公告)号：US5576356A
公开(公告)日：1996-11-19
申请号：US333354
申请日：1994-11-02
申请人： Charles M. Leir , William R. Berggren , William R. Bronn , David J. Kinning , Olester Benson, Jr.
发明人： Charles M. Leir , William R. Berggren , William R. Bronn , David J. Kinning , Olester Benson, Jr.
IPC分类号： C08L83/06 , C08F2/50 , C08L83/04 , C08L83/07 , C09D4/06 , C09D183/04 , C09D183/06 , C09D183/08 , C09D183/10 , C09J7/02 , C08L83/10
CPC分类号： C09J7/0228 , C09D183/06 , C09D183/08 , C09D183/10 , C09D4/06 , C09J7/0232 , C09J2205/31 , C09J2483/005 , Y10T428/24388 , Y10T428/24446 , Y10T428/31598 , Y10T428/31601 , Y10T428/31663 , Y10T428/31667 , Y10T442/2098 , Y10T442/2107
摘要： The invention provides a radiation curable release coating composition comprising:(a) about 1 to about 50 percent by weight of a cationically reactive polydiorganosiloxane liquid rubber having the following formula: ##STR1## wherein R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl wherein at least about 50% of the total number of silicon atoms have two methyl groups bonded thereto;E is an organic monovalent functional group comprising from about 1 to about 20 carbon atoms having at least one cationically co-reactive functional group;a and b both represent integers, wherein the sum of a plus b is an integer of about 10 to about 1200;b has a value ranging from about 0 to about 0.2a;a is an integer of about 10 to about 1000; andM is a silyl group which must contain at least one cationically co-reactive functional group when b=0 and may contain at least one cationically co-reactive group when b is greater than 0;(b) about 50 to about 99 percent by weight of at least one cationically co-reactive monomer copolymerizable with said cationically co-reactive functional group of said polydiorganosiloxane liquid rubber;wherein the percentages of (a) and (b) are based on the total weight of (a) plus (b); and(c) about 0.5 to about 4 parts by weight of a photoactive radiation activatable cationically reactive catalyst based on the weight of (a) plus (b).The invention also provides release coatings and methods of making release coatings.
摘要翻译：本发明提供了一种可辐射固化的脱模涂料组合物，其包含：（a）约1至约50重量％的具有下式的阳离子反应性聚二有机硅氧烷液体橡胶：其中R是可以相同的一价部分，选自烷基，取代的烷基，芳基和取代的芳基的不同，其中硅原子总数的至少约50％具有与其键合的两个甲基; E是包含具有至少一个阳离子共反应性官能团的约1至约20个碳原子的有机单价官能团; a和b均表示整数，其中加号b的和为约10至约1200的整数; b的值为约0至约0.2a; a为约10至约1000的整数; 当b = 0时，M是甲硅烷基，其必须含有至少一个阳离子共反应性官能团，当b大于0时可以含有至少一个阳离子共反应基团; （b）约50至约99重量％的至少一种可与所述聚二有机硅氧烷液体橡胶的所述阳离子共反应性官能团共聚的阳离子共反应性单体; 其中（a）和（b）的百分比基于（a）加（b）的总重量; 和（c）基于（a）加（b）的重量，约0.5至约4重量份的光活性辐射可激活阳离子反应催化剂。本发明还提供了剥离涂层和制备剥离涂层的方法。

2. 发明授权

US5753346A Cationically co-curable polysiloxane release coatings 失效
标题翻译：阳离子共可聚合的聚硅氧烷脱模涂层
公开(公告)号：US5753346A
公开(公告)日：1998-05-19
申请号：US747475
申请日：1996-11-12
申请人： Charles M. Leir , William R. Berggren , William R. Bronn , David J. Kinning , Olester Benson, Jr.
发明人： Charles M. Leir , William R. Berggren , William R. Bronn , David J. Kinning , Olester Benson, Jr.
IPC分类号： C08L83/06 , C08F2/50 , C08L83/04 , C08L83/07 , C09D4/06 , C09D183/04 , C09D183/06 , C09D183/08 , C09D183/10 , C09J7/02 , B32B9/04 , C08J7/04
CPC分类号： C09J7/0228 , C09D183/06 , C09D183/08 , C09D183/10 , C09D4/06 , C09J7/0232 , C09J2205/31 , C09J2483/005 , Y10T428/24388 , Y10T428/24446 , Y10T428/31598 , Y10T428/31601 , Y10T428/31663 , Y10T428/31667 , Y10T442/2098 , Y10T442/2107
摘要： The invention provides a radiation curable release coating composition comprising: (a) about 1 to about 50 percent by weight of a cationically reactive polydiorganosiloxane liquid rubber having the following formula: ##STR1## wherein R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl wherein at least about 50% of the total number of silicon atoms have two methyl groups bonded thereto; E is an organic monovalent functional group comprising from about 1 to about 20 carbon atoms having at least one cationically co-reactive functional group; a and b both represent integers, wherein the sum of a plus b is an integer of about 10 to about 1200; b has a value ranging from about 0 to about 0.2 a; a is an integer of about 10 to about 1000; and M is a silyl group which must contain at least one cationically co-reactive functional group when b=0 and may contain at least one cationically co-reactive group when b is greater than 0; (b) about 50 to about 99 percent by weight of at least one cationically co-reactive monomer copolymerizable with said cationically co-reactive functional group of said polydiorganosiloxane liquid rubber; wherein the percentages of (a) and (b) are based on the total weight of (a) plus (b); and (c) about 0.5 to about 4 parts by weight of a photoactive radiation activatable cationically reactive catalyst based on the weight of (a) plus (b). The invention also provides release coatings and methods of making release coatings.
摘要翻译：本发明提供了一种可辐射固化的脱模涂料组合物，其包含：（a）约1至约50重量％的具有下式的阳离子反应性聚二有机硅氧烷液体橡胶：其中R是可以相同的一价部分，选自烷基，取代的烷基，芳基和取代的芳基的不同，其中硅原子总数的至少约50％具有与其键合的两个甲基; E是包含具有至少一个阳离子共反应性官能团的约1至约20个碳原子的有机单价官能团; a和b均表示整数，其中加号b的和为约10至约1200的整数; b的值为约0至约0.2a; a为约10至约1000的整数; 当b = 0时，M是甲硅烷基，其必须含有至少一个阳离子共反应性官能团，当b大于0时可以含有至少一个阳离子共反应基团; （b）约50至约99重量％的至少一种可与所述聚二有机硅氧烷液体橡胶的所述阳离子共反应性官能团共聚的阳离子共反应性单体; 其中（a）和（b）的百分比基于（a）加（b）的总重量; 和（c）基于（a）加（b）的重量，约0.5至约4重量份的光活性辐射可激活阳离子反应催化剂。本发明还提供了剥离涂层和制备剥离涂层的方法。

3. 发明授权

US06824820B1 Polyurea-based adhesives, articles therefrom and methods of their preparation and use 有权
标题翻译：聚脲类粘合剂，制品及其制备和使用方法
公开(公告)号：US06824820B1
公开(公告)日：2004-11-30
申请号：US09355601
申请日：1999-07-30
申请人： David J. Kinning , Charles M. Leir , Audrey A. Sherman , Meherdil D. Dastur
发明人： David J. Kinning , Charles M. Leir , Audrey A. Sherman , Meherdil D. Dastur
IPC分类号： B05D510
CPC分类号： C08G18/5024 , C08G18/61 , C08G18/765 , C08G2170/40 , C09J7/22 , C09J7/35 , C09J7/38 , C09J2475/00 , C09J2475/006 , Y10T428/28 , Y10T428/2826
摘要： An adhesive composition comprising a silicone free polyurea-based polymer, comprising a segmented copolymer, wherein the copolymer comprises repeating units of Formula I: wherein: each B is independently a polyvalent radical selected form a group consisting of arylene, aralkylene, cycloalkylene, polyoxyalkylene, or mixtures thereof; each D is independently selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, a phenyl group, a group that completes a ring structure that includes B to form a heterocycle, and mixtures thereof; each Z is independently a polyvalent radical having about 1 to about 20 carbon atoms; each Y is independently a polyoxyalkylene; m is an integer greater than zero; and a is zero or an integer greater than zero; and wherein the composition comprises a tackifier in an amount sufficient to provide the adhesive composition as a pressure sensitive adhesive and in an amount less than about 45 parts by weight tackifier per hundred part by weight polyurea-based polymer.
摘要翻译：一种粘合剂组合物，其包含无硅氧烷聚脲基聚合物，其包含分段共聚物，其中所述共聚物包含式I的重复单元：其中：每个B独立地为选自亚芳基，亚芳基亚烷基，亚环烷基，聚氧化烯或每个D独立地选自氢，烷基，环烷基，苯基，完成包括B形成杂环的环结构的基团，及其混合物;每个Z独立地为具有约1至约20个碳原子的多价基团;每个Y独立地是聚氧化烯; m是大于零的整数; anda为零或大于零的整数; 并且其中组合物包含足以提供粘合剂组合物作为压敏粘合剂的量的增粘剂，其量为每100重量份聚脲基聚合物小于约45重量份的增粘剂。

4. 发明授权

US06896944B2 Imaged articles comprising a substrate having a primed surface 有权
公开(公告)号：US06896944B2
公开(公告)日：2005-05-24
申请号：US09896863
申请日：2001-06-29
申请人： Caroline M. Ylitalo , Bret W. Ludwig , David J. Kinning , Ernest M. Rinehart , Jennifer L. Lee , Oh Sang Woo , Richard L. Severance , Richard F. Theissen
发明人： Caroline M. Ylitalo , Bret W. Ludwig , David J. Kinning , Ernest M. Rinehart , Jennifer L. Lee , Oh Sang Woo , Richard L. Severance , Richard F. Theissen
IPC分类号： B41J2/01 , B41M5/00 , B41M5/50 , B41M5/52 , B44F1/02 , C09D5/00 , C09D133/00 , C09D133/06 , C09D157/00 , C09D183/06 , G09F7/00 , G09F13/16 , G09F17/00 , B32B33/00 , B32B9/00
CPC分类号： B41M5/52 , B41M5/0011 , B41M5/506 , B41M5/508 , B41M5/5254 , B41M5/5281 , B41M5/529 , B44F1/02 , G09F7/00 , G09F13/16 , G09F17/00 , Y10T428/1486 , Y10T428/24802 , Y10T428/2495 , Y10T428/26 , Y10T428/3154 , Y10T428/31786 , Y10T428/31855
摘要： The present invention relates to an imaged article comprising a substrate having a primed surface layer. The primed surface layer is comprised of a base polymer having a solubility parameter, molecular weight (Mw) and glass transition temperature within a specified range. The presence of the primer improves the overall image quality by improving at least one property including ink uptake, dot gain, color density and/or ink adhesion. Preferred primer compositions are soluble at least in part in the ink composition resulting in an increase in ink layer thickness that further improves the durability and/or day/night color balance. A variety of substrates may be primed including various sheeting for traffic control signage and commercial graphic films for advertising and promotional displays.

5. 发明授权

US5866222A Silicone copolymer modified release tapes 失效
标题翻译：硅氧烷共聚物改性释放胶带
公开(公告)号：US5866222A
公开(公告)日：1999-02-02
申请号：US896708
申请日：1997-07-18
申请人： Jayshree Seth , Stephen W. Bany , David J. Kinning
发明人： Jayshree Seth , Stephen W. Bany , David J. Kinning
IPC分类号： B32B27/00 , C08G18/61 , C09D151/08 , C09D153/00 , C09D175/04 , C09D183/10 , A61F13/02
CPC分类号： C09D153/00 , C08G18/61 , C09D151/08 , C09D183/10 , Y10T428/14 , Y10T428/1457 , Y10T442/223 , Y10T442/2328
摘要： There is provided a block, segmented or graft copolymer having polyorganosiloxane segments and self-associating hard segments, which copolymer is capable of forming a solid, generally non-tacky release coating without the requirement of curing. The release coating comprises the polyorganosiloxane copolymer admixed with an MQ resin wherein the amount of MQ resin is generally between 1 and 30 weight percent of the polyorganosiloxane content preferably 1 to 20 weight percent. The MQ resin modifies the copolymer release material to have a higher release than the copolymer itself, generally at least 10 percent and preferable at least 20 percent up to 50 percent or higher with the readhesion values decreasing by 50 percent or less, preferably 40 percent or less.
摘要翻译：提供了具有聚有机硅氧烷链段和自缔合硬链段的嵌段，分段或接枝共聚物，该共聚物能够形成固体，通常不粘性的脱模涂层，而不需要固化。脱模涂层包括与MQ树脂混合的聚有机硅氧烷共聚物，其中MQ树脂的量通常为聚有机硅氧烷含量的1至30重量％，优选为1至20重量％。 MQ树脂使共聚物释放材料改性为具有比共聚物本身更高的剥离性，通常至少10％，优选至少20％至多50％或更高，再附着值降低50％以下，优选40％减。

6. 发明授权

US5264278A Radiation-curable acrylate/silicone pressure-sensitive adhesive coated tapes adherable to paint coated substrates 失效
标题翻译：可涂覆涂料的可辐射固化的丙烯酸酯/硅氧烷压敏粘合剂涂层胶带
公开(公告)号：US5264278A
公开(公告)日：1993-11-23
申请号：US672356
申请日：1991-03-20
申请人： Mieczyslaw H. Mazurek , David J. Kinning , Steven S. Kantner
发明人： Mieczyslaw H. Mazurek , David J. Kinning , Steven S. Kantner
IPC分类号： C08F299/08 , C08F290/00 , C09J4/00 , C09J4/02 , C09J4/06 , C09J7/02 , C09J183/00 , C09J183/08 , C09J183/12
CPC分类号： C09J7/0289 , C09J4/06 , C09J7/0207 , Y10T428/249983 , Y10T428/249985 , Y10T428/2809 , Y10T428/2852 , Y10T428/2891
摘要： The present invention provides an acrylate/silicone pressure-sensitive adhesive tape having a foam backing having improved adhesion to painted surfaces and low temperature performance.
摘要翻译：本发明提供一种具有泡沫背衬的丙烯酸酯/硅氧烷压敏粘合带，其具有改进的与涂漆表面的粘附性和低温性能。

7. 发明申请

US20090262348A1 METHOD OF MODIFYING LIGHT WITH SILICONE (METH)ACRYLATE COPOLYMERS 有权
标题翻译：用（丙烯）丙烯酸酯共聚物修饰光的方法
公开(公告)号：US20090262348A1
公开(公告)日：2009-10-22
申请号：US11930549
申请日：2007-10-31
申请人： Mieczyslaw H. Mazurek , Robert L. Brott , David J. Kinning , Yufeng Liu , John E. Potts , Kevin R. Schaffer , Audrey A. Sherman , Wendi J. Winkler
发明人： Mieczyslaw H. Mazurek , Robert L. Brott , David J. Kinning , Yufeng Liu , John E. Potts , Kevin R. Schaffer , Audrey A. Sherman , Wendi J. Winkler
IPC分类号： G01J4/00 , G01N21/00 , G02F1/00 , G02B5/30 , G02B5/02
CPC分类号： G02B5/3041 , G01J1/04 , G01J1/0429 , G01J1/0474 , G02B1/04 , G02B5/0247 , G02B5/0257 , G02B5/0268 , G02B5/0278 , G02B5/0284 , G02B5/0294 , G02F1/0147 , Y10T428/24355 , Y10T428/24479 , Y10T428/31663 , C08L51/085
摘要： A method of modifying light is disclosed and includes: providing an optical element having an oriented polymer network of a silicone (meth)acrylate copolymer and exhibiting a first phase and a second phase, the first phase and the second phase being chemically connected and having different refractive indices, the first phase being continuous, and the second phase comprising a plurality of structures dispersed within the first phase; illuminating the optical element with light from a light source; and detecting polarized or directionally diffused light transmitted by the optical element. Optical elements including the polymer network and a variety of additional layers are also disclosed, as are optical devices such as prisms, display panels, lenses, and the like.
摘要翻译：公开了一种修改光的方法，包括：提供具有硅氧烷（甲基）丙烯酸酯共聚物的定向聚合物网络并呈现第一相和第二相的光学元件，第一相和第二相化学连接并具有不同的折射率，第一相是连续的，第二相包括分散在第一相内的多个结构; 用来自光源的光照射光学元件; 并且检测由光学元件透射的偏振或方向扩散的光。还公开了包括聚合物网络和各种附加层的光学元件，诸如棱镜，显示面板，透镜等的光学装置也是如此。

8. 发明授权

US07411020B2 Water-based release coating containing fluorochemical 有权
标题翻译：含氟化合物的水性防粘涂层
公开(公告)号：US07411020B2
公开(公告)日：2008-08-12
申请号：US11027606
申请日：2004-12-28
申请人： James G. Carlson , John C. Clark , James P. DiZio , David J. Kinning , Ramesh C. Kumar , Chetan P. Jariwala
发明人： James G. Carlson , John C. Clark , James P. DiZio , David J. Kinning , Ramesh C. Kumar , Chetan P. Jariwala
IPC分类号： C09D133/00 , B32B33/00
CPC分类号： C09D133/02 , Y10S525/902 , Y10T428/14
摘要： In one aspect, the invention provides a water-based release coating composition comprising a mixture of: A. from 0.1 to about 5 wt % of a fluoro(meth)acrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —CF2)nCF3, wherein n is an integer from 1 to 3; B. from about 5 to about 99.9 wt % of a copolymer comprising the reaction product of a. from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, b. from about 3 to about 20 wt % of (meth)acrylic acid, c. from about 20 to about 40 wt % acrylonitrile, and d. from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of a. through d. equals 100%; and C. from 0 to about 94.9 wt % of an extender polymer, wherein the sum of A., B., and C. is 100% and wt % is based on the total amount of solids in the composition.
摘要翻译：一方面，本发明提供了一种水性防粘涂料组合物，其包含以下混合物：A.从0.1至约5wt％的氟（甲基）丙烯酸酯（共）聚合物或含有至少一个氟化基团的含氟氨基甲酸酯化合物具有式 - （CF 2）n CF 3，其中n为1至3的整数; B.约5至约99.9重量％的包含a的反应产物的共聚物。约40至约70重量％的（甲基）丙烯酸烷基酯，其中烷基含有16至22个碳原子，b。约3至约20重量％的（甲基）丙烯酸，c。约20至约40重量％的丙烯腈，以及d。 0至约15重量％的乙烯基单体，除了丙烯腈，其中a。通过d。等于100％; 和C.0至约94.9重量％的增量聚合物，其中A.，B.和C.的总和为100％，wt％基于组合物中固体的总量。

9. 发明授权

US07199197B2 Water- and oil-repellent fluoroacrylates 有权
标题翻译：拒水拒油氟代丙烯酸酯
公开(公告)号：US07199197B2
公开(公告)日：2007-04-03
申请号：US11027604
申请日：2004-12-28
申请人： Gregg A. Caldwell , John C. Clark , David J. Kinning , Alan R. Kirk , Thomas P. Klun , Ramesh C. Kumar , Roger A. Mader , George G. I. Moore , Zai-Ming Qiu , Richard B. Ross
发明人： Gregg A. Caldwell , John C. Clark , David J. Kinning , Alan R. Kirk , Thomas P. Klun , Ramesh C. Kumar , Roger A. Mader , George G. I. Moore , Zai-Ming Qiu , Richard B. Ross
IPC分类号： C08F12/20
CPC分类号： C08F220/38 , C07C271/20 , C07C271/28 , C07C311/09 , Y10T442/2287
摘要： Fluoroacrylates comprise the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoro acrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译：氟丙烯酸酯包含反应产物

10. 发明授权

US5907018A Radiation-curable acrylate/silicone pressure-sensitive adhesive coated tapes adherable to paint coated substrates 失效
标题翻译：可涂覆涂料的可辐射固化的丙烯酸酯/硅氧烷压敏粘合剂涂层胶带
公开(公告)号：US5907018A
公开(公告)日：1999-05-25
申请号：US155476
申请日：1993-11-19
申请人： Mieczyslaw H. Mazurek , David J. Kinning , Steven S. Kantner
发明人： Mieczyslaw H. Mazurek , David J. Kinning , Steven S. Kantner
IPC分类号： C08F299/08 , C08F290/00 , C09J4/00 , C09J4/02 , C09J4/06 , C09J7/02 , C09J183/00 , C09J183/08 , C09J183/12
CPC分类号： C09J7/0289 , C09J4/06 , C09J7/0207 , Y10T428/249983 , Y10T428/249985 , Y10T428/2809 , Y10T428/2852 , Y10T428/2891
摘要： The present invention provides an acrylate/silicone pressure-sensitive adhesive tape having improved adhesion to painted surfaces and low temperature performance. The pressure-sensitive adhesive tape comprises:(a) a pressure-sensitive adhesive layer comprising a polymerized pressure sensitive adhesive composition wherein said pressure sensitive adhesive composition comprises:(I) about 25 to about 99 weight percent of polymer of the formula ##STR1## wherein: X, Y, D, R, R.sup.1, R.sup.2, R.sup.3, R.sup.4, and n are defined in the specification;(II) about 1 to about 75 weight percent free radically polymerizable vinyl monomer which is capable of copolymerizing with the polymer wherein said free radically polymerizable monomer comprises:(i) about 5 to about 100 parts by weight of an acidic monomer selected from the group consisting of methacrylic acid, acrylic acid, and mixtures thereof;(ii) about 0 to about 95 parts by weight of an acrylate monomer selected from the group consisting of esters of acrylic acid comprising 4 to 21 carbon atoms and esters of methacrylic acid comprising 5 to 21 carbon atoms and mixtures thereof; based upon 100 parts total by weight of said free radically polymerizable monomer; wherein the weight percentages set forth in elements,(I) and (II) are based upon the total weight of the polymer of element (I) plus the monomer of element (II); and(III) a sufficient amount of a silicate MQ tackifying resin to impart a degree of adhesive tack to the cured composition at the use temperature; and(b) a foam layer which is coated on at least one side with the adhesive layer.The present invention also provides the pressure sensitive adhesive composition and pressure sensitive adhesive.
摘要翻译：本发明提供了具有改进的涂漆表面粘附性和低温性能的丙烯酸酯/硅氧烷压敏粘合带。压敏粘合带包括：（a）包含聚合压敏粘合剂组合物的压敏粘合剂层，其中所述压敏粘合剂组合物包含：（I）约25至约99重量％的下式聚合物其中：X 在说明书中定义了Y，D，R，R1，R2，R3，R4和n。（II）约1至约75重量％的可自由基聚合的可自由基聚合的乙烯基单体，其能够与聚合物共聚，其中所述可自由基聚合的单体包含：（i）约5至约100重量份的选自由甲基丙烯酸，丙烯酸及其混合物组成; （ii）约0至约95重量份的选自包含4至21个碳原子的丙烯酸的酯和包含5至21个碳原子的甲基丙烯酸的酯的丙烯酸酯单体及其混合物; 基于100份重量的所述可自由基聚合单体; 其中元素（I）和（II）中列出的重量百分比是基于元素（I）的聚合物与元素（II）的单体的总重量; 和（III）足量的硅酸酯MQ增粘树脂，以在使用温度下赋予固化组合物一定程度的粘合粘合性; 和（b）在至少一侧用粘合剂层涂覆的泡沫层。本发明还提供了压敏粘合剂组合物和压敏粘合剂。

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