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    • 9. 发明授权
    • Water-based release coating containing fluorochemical
    • 含氟化合物的水性防粘涂层
    • US07411020B2
    • 2008-08-12
    • US11027606
    • 2004-12-28
    • James G. CarlsonJohn C. ClarkJames P. DiZioDavid J. KinningRamesh C. KumarChetan P. Jariwala
    • James G. CarlsonJohn C. ClarkJames P. DiZioDavid J. KinningRamesh C. KumarChetan P. Jariwala
    • C09D133/00B32B33/00
    • C09D133/02Y10S525/902Y10T428/14
    • In one aspect, the invention provides a water-based release coating composition comprising a mixture of: A. from 0.1 to about 5 wt % of a fluoro(meth)acrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —CF2)nCF3, wherein n is an integer from 1 to 3; B. from about 5 to about 99.9 wt % of a copolymer comprising the reaction product of a. from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, b. from about 3 to about 20 wt % of (meth)acrylic acid, c. from about 20 to about 40 wt % acrylonitrile, and d. from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of a. through d. equals 100%; and C. from 0 to about 94.9 wt % of an extender polymer, wherein the sum of A., B., and C. is 100% and wt % is based on the total amount of solids in the composition.
    • 一方面,本发明提供了一种水性防粘涂料组合物,其包含以下混合物:A.从0.1至约5wt%的氟(甲基)丙烯酸酯(共)聚合物或含有至少一个氟化基团的含氟氨基甲酸酯化合物 具有式 - (CF 2)n CF 3,其中n为1至3的整数; B.约5至约99.9重量%的包含a的反应产物的共聚物。 约40至约70重量%的(甲基)丙烯酸烷基酯,其中烷基含有16至22个碳原子,b。 约3至约20重量%的(甲基)丙烯酸,c。 约20至约40重量%的丙烯腈,以及d。 0至约15重量%的乙烯基单体,除了丙烯腈,其中a。 通过d。 等于100%; 和C.0至约94.9重量%的增量聚合物,其中A.,B.和C.的总和为100%,wt%基于组合物中固体的总量。
    • 10. 发明授权
    • Fluoroacrylate-mercaptofunctional copolymers
    • 氟丙烯酸酯 - 巯基官能共聚物
    • US07291688B2
    • 2007-11-06
    • US11027605
    • 2004-12-28
    • Zai-Ming QiuJohn C. ClarkRamesh C. Kumar
    • Zai-Ming QiuJohn C. ClarkRamesh C. Kumar
    • C08F12/20C08G75/04
    • C08F220/38
    • A copolymer comprises repeating units derived from at least one co-reactant comprising two or more mercapto functional groups, and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
    • 共聚物包含衍生自至少一种包含两个或多个巯基官能团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元,该重复单元包含以下反应产物:(a)至少一种由下式表示的含氟醇: -line-formula description =“In-line Formulas”end =“lead”?> C 3 -X-OH <?in-line-formula description = “直链式”末端=“尾”→其中:R =氢或1至4个碳原子的烷基,m = 2至8,R f = C n n = 1〜5,y = 0〜6,q = 1〜8; (b)至少一种非支化的对称二异氰酸酯; 和(c)至少一种羟基封端的(甲基)丙烯酸烷基酯或其亚烷基部分具有2至约30个碳原子的2-氟丙烯酸酯单体。