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1. 发明授权

US5753346A Cationically co-curable polysiloxane release coatings 失效
标题翻译：阳离子共可聚合的聚硅氧烷脱模涂层
公开(公告)号：US5753346A
公开(公告)日：1998-05-19
申请号：US747475
申请日：1996-11-12
申请人： Charles M. Leir , William R. Berggren , William R. Bronn , David J. Kinning , Olester Benson, Jr.
发明人： Charles M. Leir , William R. Berggren , William R. Bronn , David J. Kinning , Olester Benson, Jr.
IPC分类号： C08L83/06 , C08F2/50 , C08L83/04 , C08L83/07 , C09D4/06 , C09D183/04 , C09D183/06 , C09D183/08 , C09D183/10 , C09J7/02 , B32B9/04 , C08J7/04
CPC分类号： C09J7/0228 , C09D183/06 , C09D183/08 , C09D183/10 , C09D4/06 , C09J7/0232 , C09J2205/31 , C09J2483/005 , Y10T428/24388 , Y10T428/24446 , Y10T428/31598 , Y10T428/31601 , Y10T428/31663 , Y10T428/31667 , Y10T442/2098 , Y10T442/2107
摘要： The invention provides a radiation curable release coating composition comprising: (a) about 1 to about 50 percent by weight of a cationically reactive polydiorganosiloxane liquid rubber having the following formula: ##STR1## wherein R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl wherein at least about 50% of the total number of silicon atoms have two methyl groups bonded thereto; E is an organic monovalent functional group comprising from about 1 to about 20 carbon atoms having at least one cationically co-reactive functional group; a and b both represent integers, wherein the sum of a plus b is an integer of about 10 to about 1200; b has a value ranging from about 0 to about 0.2 a; a is an integer of about 10 to about 1000; and M is a silyl group which must contain at least one cationically co-reactive functional group when b=0 and may contain at least one cationically co-reactive group when b is greater than 0; (b) about 50 to about 99 percent by weight of at least one cationically co-reactive monomer copolymerizable with said cationically co-reactive functional group of said polydiorganosiloxane liquid rubber; wherein the percentages of (a) and (b) are based on the total weight of (a) plus (b); and (c) about 0.5 to about 4 parts by weight of a photoactive radiation activatable cationically reactive catalyst based on the weight of (a) plus (b). The invention also provides release coatings and methods of making release coatings.
摘要翻译：本发明提供了一种可辐射固化的脱模涂料组合物，其包含：（a）约1至约50重量％的具有下式的阳离子反应性聚二有机硅氧烷液体橡胶：其中R是可以相同的一价部分，选自烷基，取代的烷基，芳基和取代的芳基的不同，其中硅原子总数的至少约50％具有与其键合的两个甲基; E是包含具有至少一个阳离子共反应性官能团的约1至约20个碳原子的有机单价官能团; a和b均表示整数，其中加号b的和为约10至约1200的整数; b的值为约0至约0.2a; a为约10至约1000的整数; 当b = 0时，M是甲硅烷基，其必须含有至少一个阳离子共反应性官能团，当b大于0时可以含有至少一个阳离子共反应基团; （b）约50至约99重量％的至少一种可与所述聚二有机硅氧烷液体橡胶的所述阳离子共反应性官能团共聚的阳离子共反应性单体; 其中（a）和（b）的百分比基于（a）加（b）的总重量; 和（c）基于（a）加（b）的重量，约0.5至约4重量份的光活性辐射可激活阳离子反应催化剂。本发明还提供了剥离涂层和制备剥离涂层的方法。

2. 发明授权

US5079090A Adhesive compositions made with condensed phase polymers and sheet materials coated therewith 失效
标题翻译：用冷凝相聚合物制成的粘合剂组合物和用其涂覆的片材
公开(公告)号：US5079090A
公开(公告)日：1992-01-07
申请号：US424558
申请日：1989-10-20
申请人： Eugene G. Joseph , Spencer F. Silver , William R. Bronn
发明人： Eugene G. Joseph , Spencer F. Silver , William R. Bronn
IPC分类号： C08F297/04 , C09J153/00
CPC分类号： C08F297/046 , C09J153/00 , Y10T428/28
摘要： The present invention relates to pressure-sensitive adhesive compositions comprising tackified elastomeric copolymers or block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The invention also provides sheet materials coated with the adhesive compositions. The polymers of the present invention are made by a method which comprises the step of reacting under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic-substituted styrene condensing agent. The reactants may be added simultaneously to produce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone. The resultant polymers may be further reacted with a linking agent to form multi-arm copolymers. The resultant elastomeric polymers are compatible with any of a wide variety of known tackifier resins and plasticizers to produce unique pressure-sensitive adhesive compositions.
摘要翻译：本发明涉及包含增粘的弹性共聚物或嵌段共聚物的压敏粘合剂组合物，例如基于苯乙烯/异戊二烯，具有新颖的凝聚相结构，其中聚合物分支沿着聚合物主链在预定位置或在随机位置。本发明还提供涂覆有粘合剂组合物的片材。本发明的聚合物通过包括在聚合条件下使烃基锂引发剂，至少一种阴离子可聚合化合物和有机金属取代的苯乙烯缩合剂反应的步骤的方法制备。可以同时加入反应物以产生具有沿聚合物骨架无规定位的聚合物支链段的共聚物，或者依次制备具有沿聚合物主链位于相同预定位置的分支的共聚物。所得聚合物可进一步与连接剂反应形成多臂共聚物。所得的弹性体聚合物与各种已知的增粘剂树脂和增塑剂中的任何一种相容以制备独特的压敏粘合剂组合物。

3. 发明授权

US4857615A Method of making condensed phase polymers 失效
标题翻译：制备凝聚相聚合物的方法
公开(公告)号：US4857615A
公开(公告)日：1989-08-15
申请号：US107262
申请日：1987-10-09
申请人： William R. Bronn , Spencer F. Silver , Eugene G. Joseph
发明人： William R. Bronn , Spencer F. Silver , Eugene G. Joseph
IPC分类号： C08F297/04 , C09J153/00
CPC分类号： C08F297/046 , C09J153/00
摘要： The present invention relates to a method of making elastomeric copolymers and block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The method comprises the step of reacting, under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic- substituted styrene condensing agent. The reactants may be added simultaneously to produce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone. The resultant polymers may be further reacted with a linking agent to form multi-arm copolymers.
摘要翻译：本发明涉及一种制备弹性体共聚物和嵌段共聚物的方法，例如基于苯乙烯/异戊二烯，具有新颖的凝聚相结构，其中聚合物分支沿着聚合物主链在预定位置或在随机位置发生。该方法包括在聚合条件下使烃基锂引发剂，至少一种阴离子聚合性化合物和有机金属取代的苯乙烯缩合剂反应的步骤。可以同时加入反应物以产生具有沿聚合物骨架无规定位的聚合物支链段的共聚物，或者依次制备具有沿聚合物主链位于相同预定位置的分支的共聚物。所得聚合物可进一步与连接剂反应形成多臂共聚物。

4. 发明授权

US5115034A Condensed phase polymers 失效
标题翻译：冷凝相聚合物
公开(公告)号：US5115034A
公开(公告)日：1992-05-19
申请号：US607838
申请日：1990-10-31
申请人： Spencer F. Silver , William R. Bronn , Eugene G. Joseph
发明人： Spencer F. Silver , William R. Bronn , Eugene G. Joseph
IPC分类号： C08F297/04 , C09J153/00
CPC分类号： C09J153/00 , C08F297/046
摘要： The present invention relates to elastomeric copolymers and block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The polymers are made by a method which comprises the step of reacting, under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic-substituted styrene condensing agent. The reactants may be added simultaneously to produce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone. The resultant polymers may be further reacted with a linking agent to form multi-arm copolymers.
摘要翻译：本发明涉及弹性体共聚物和嵌段共聚物，例如基于苯乙烯/异戊二烯，具有新颖的凝聚相结构，其中聚合物分支沿着聚合物主链在预定位置或在随机位置发生。聚合物通过包括在聚合条件下使烃基锂引发剂，至少一种阴离子聚合性化合物和有机金属取代的苯乙烯缩合剂反应的方法制备。可以同时加入反应物以产生具有沿聚合物骨架无规定位的聚合物支链段的共聚物，或者依次制备具有沿着聚合物主链位于相同预定位置的分支的共聚物。所得聚合物可进一步与连接剂反应形成多臂共聚物。

5. 发明授权

US4996266A Method of making condensed phase polymers 失效
标题翻译：制备凝聚相聚合物的方法
公开(公告)号：US4996266A
公开(公告)日：1991-02-26
申请号：US328533
申请日：1989-03-24
申请人： William R. Bronn , Spencer F. Silver , Eugene G. Joseph
发明人： William R. Bronn , Spencer F. Silver , Eugene G. Joseph
IPC分类号： C08F4/00 , C08F297/04 , C09J153/00
CPC分类号： C09J153/00 , C08F297/046
摘要： The present invention relates to a method of making elastomeric copolymers and block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The method comprises the step of reacting, under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic- substituted styrene condensing agent. The reactants may be added simultaneously to produce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone. The resultant polymers may be further reacted with a linking agent to form multi-arm copolymers.
摘要翻译：本发明涉及一种制备弹性体共聚物和嵌段共聚物的方法，例如基于苯乙烯/异戊二烯，具有新颖的凝聚相结构，其中聚合物分支沿着聚合物主链在预定位置或在随机位置发生。该方法包括在聚合条件下使烃基锂引发剂，至少一种阴离子聚合性化合物和有机金属取代的苯乙烯缩合剂反应的步骤。可以同时加入反应物以产生具有沿聚合物骨架无规定位的聚合物支链段的共聚物，或者依次制备具有沿聚合物主链位于相同预定位置的分支的共聚物。所得聚合物可进一步与连接剂反应形成多臂共聚物。

6. 发明授权

US4857618A Condensed phase polymers 失效
标题翻译：冷凝相聚合物
公开(公告)号：US4857618A
公开(公告)日：1989-08-15
申请号：US107292
申请日：1987-10-09
申请人： Spencer F. Silver , William R. Bronn , Eugene G. Joseph
发明人： Spencer F. Silver , William R. Bronn , Eugene G. Joseph
IPC分类号： C08F297/04 , C09J153/00
CPC分类号： C09J153/00 , C08F297/046
摘要： The present invention relates to elastomeric copolymers and block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The polymers are made by a method which comprises the step of reacting, under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic- substituted styrene condensing agent. The reactants may be added simultaneously to proudce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone. The resultant polymers may be further reacted with a linking agent to form multi-arm copolymers.
摘要翻译：本发明涉及弹性体共聚物和嵌段共聚物，例如基于苯乙烯/异戊二烯，具有新颖的凝聚相结构，其中聚合物分支沿着聚合物主链在预定位置或在随机位置发生。聚合物通过包括在聚合条件下使烃基锂引发剂，至少一种阴离子聚合性化合物和有机金属取代的苯乙烯缩合剂反应的方法制备。反应物可以同时加入以使聚合物分枝段沿着聚合物骨架随机定位，或者顺序地产生共聚物，从而产生具有位于聚合物骨架相同的预定位置处的分支的共聚物。所得聚合物可以进一步与连接剂反应形成多臂共聚物。

7. 发明授权

US4824953A Multi-step process for producing 5-hydroxy-N-(6-oxo-piperidyl-methyl)-2-(2,2,2-trifluoro-ethoxy)-benzamid e and derivatives 失效
标题翻译： 5-羟基-N-（6-氧代 - 哌啶基 - 甲基）-2-（2,2,2-三氟 - 乙氧基） - 苯甲酰胺及其衍生物的多步法
公开(公告)号：US4824953A
公开(公告)日：1989-04-25
申请号：US10559
申请日：1987-02-03
申请人： William R. Bronn
发明人： William R. Bronn
IPC分类号： C07D211/78 , C07D213/64 , C07D211/76 , C07D213/56 , C07D213/75
CPC分类号： C07D213/64 , C07D211/78
摘要： Certain substituted pyridine compounds are useful synthetic intermediates for preparing compounds of pharmaceutical interest. A synthetic process for using these intermediates is also described.
摘要翻译：某些取代的吡啶化合物是制备药物化合物的有用的合成中间体。还描述了使用这些中间体的合成方法。

8. 发明授权

US4013670A Derivatives of pyrrolidine and piperidine 失效
标题翻译：吡咯啉和哌啶的衍生物
公开(公告)号：US4013670A
公开(公告)日：1977-03-22
申请号：US580890
申请日：1975-05-27
申请人： Elden H. Banitt , William R. Bronn
发明人： Elden H. Banitt , William R. Bronn
IPC分类号： C07D207/08 , C07D207/14 , C07D211/26 , C07D211/56 , C07D211/58 , C07D213/40 , C07D213/75 , C07D213/26
CPC分类号： C07D213/40 , C07D207/08 , C07D207/14 , C07D211/26 , C07D211/56 , C07D211/58 , C07D213/75 , Y10S514/821
摘要： Certain compounds in which a carbon atom of a pyrrolidine or piperidine ring is bonded directly or through a methylene group to the nitrogen of a substituted benzamido group, and their pharmaceutically acceptable salts, are found to be active as antiarrhythmic agents.

9. 发明授权

US5792554A Diblock and triblock polydiorganosiloxane-polyurea block copolymers 失效
标题翻译：二嵌段和三嵌段聚二有机硅氧烷 - 聚脲嵌段共聚物
公开(公告)号：US5792554A
公开(公告)日：1998-08-11
申请号：US862054
申请日：1997-05-22
申请人： Charles M. Leir , William R. Bronn , Patricia J. A. Brandt
发明人： Charles M. Leir , William R. Bronn , Patricia J. A. Brandt
IPC分类号： B32B27/00 , C08G18/28 , C08G18/61 , C08G18/80 , C08G77/458 , C08L83/10 , C09J7/02 , B32B7/12
CPC分类号： C09J7/0228 , C08G18/289 , C08G18/809 , C08G77/458 , C08L83/10 , C09J2205/114 , C09J2453/005 , C09J2475/005 , C09J2483/005 , Y10T428/2839 , Y10T428/2848 , Y10T428/31544 , Y10T428/31663 , Y10T428/31667
摘要： Diblock (B-A) and triblock (B-A-B) polydiorganosiloxane-polyurea block copolymers comprise non-functional polydiorganosiloxane endblock B and polyurea block A. When used to provide release coatings, the block copolymers allow for easier release compared to traditional block copolymers of the (AB).sub.n type having comparable amounts of polydiorganosiloxane. Articles incorporating the copolymers as a release material are also disclosed.
摘要翻译：二嵌段（BA）和三嵌段（BAB）聚二有机硅氧烷 - 聚脲嵌段共聚物包含非官能的聚二有机硅氧烷端嵌段B和聚脲嵌段A.当用于提供剥离涂层时，与传统的（AB）嵌段共聚物相比，嵌段共聚物允许更容易的脱模， n型具有相当量的聚二有机硅氧烷。还公开了将共聚物作为剥离材料的制品。

10. 发明授权

US4656285A Compound 2-acetamidomethyl-6-methoxy-pyridine 失效
标题翻译：化合物2-乙酰氨基甲基-6-甲氧基 - 吡啶
公开(公告)号：US4656285A
公开(公告)日：1987-04-07
申请号：US773203
申请日：1985-09-06
申请人： William R. Bronn
发明人： William R. Bronn
IPC分类号： C07D211/78 , C07D213/64 , C07D213/75
CPC分类号： C07D211/78 , C07D213/64
摘要： Certain substituted pyridine compounds are useful synthetic intermediates for preparing compounds of pharmaceutical interest. A synthetic process for using these intermediates is also described.
摘要翻译：某些取代的吡啶化合物是制备药物化合物的有用的合成中间体。还描述了使用这些中间体的合成方法。

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