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    • 3. 发明授权
    • Low resistivity W using B2H6 nucleation step
    • 使用B2H6成核步骤的低电阻率W
    • US06206967B1
    • 2001-03-27
    • US09594234
    • 2000-06-14
    • Alfred MakKevin LaiCissy LeungDennis Sauvage
    • Alfred MakKevin LaiCissy LeungDennis Sauvage
    • B05C1100
    • C23C16/0281C23C16/14H01L21/28556
    • A multiple step chemical vapor deposition process for depositing a tungsten film on a substrate. A first step of the deposition process includes a nucleation step in which a process gas including a tungsten-containing source, a group III or V hydride and a reduction agent are flowed into a deposition zone of a substrate processing chamber while the deposition zone is maintained at or below a first pressure level. During this first deposition stage, other process variables are maintained at conditions suitable to deposit a first layer of the tungsten film over the substrate. Next, during a second deposition stage after the first stage, the flow of the group III or V hydride into the deposition zone is stopped, and afterwards, the pressure in the deposition zone is increased to a second pressure above the first pressure level and other process parameters are maintained at conditions suitable for depositing a second layer of the tungsten film on the substrate. In a preferred embodiment, the flow of the tungsten-containing source is stopped along with the flow of the group III or V hydride and after a period of between 5 and 30 seconds, the flow of the tungsten-containing source is restarted when the pressure is in the deposition zone is increased to the second pressure level.
    • 用于在基板上沉积钨膜的多步化学气相沉积工艺。 沉积工艺的第一步包括成核步骤,其中包含含钨源,III或V族氢化物和还原剂的工艺气体在保持沉积区的同时流入衬底处理室的沉积区 处于或低于第一压力水平。 在该第一沉积阶段期间,其它工艺变量被保持在适于将第一层钨膜沉积在衬底上的条件下。 接下来,在第一阶段之后的第二沉积阶段期间,停止将III或V族氢化物流入沉积区的流动,之后,沉积区中的压力增加到高于第一压力水平的第二压力和其它 工艺参数保持在适合于在衬底上沉积第二层钨膜的条件下。 在一个优选的实施方案中,随着III或V族氢化物的流动停止含钨源的流动,并且在5至30秒之间的时间段内,当含有钨的源的流量在压力 在沉积区中增加到第二压力水平。
    • 4. 发明授权
    • Low resistivity W using B.sub.2 H.sub.6 nucleation step
    • 使用B2H6成核步骤的低电阻率W
    • US6099904A
    • 2000-08-08
    • US982844
    • 1997-12-02
    • Alfred MakKevin LaiCissy LeungDennis Sauvage
    • Alfred MakKevin LaiCissy LeungDennis Sauvage
    • C23C16/02C23C16/14H01L21/28H01L21/285C23C16/08
    • C23C16/0281C23C16/14H01L21/28556
    • A multiple step chemical vapor deposition process for depositing a tungsten film on a substrate. A first step of the deposition process includes a nucleation step in which a process gas including a tungsten-containing source, a group III or V hydride and a reduction agent are flowed into a deposition zone of a substrate processing chamber while the deposition zone is maintained at or below a first pressure level. During this first deposition stage, other process variables are maintained at conditions suitable to deposit a first layer of the tungsten film over the substrate. Next, during a second deposition stage after the first stage, the flow of the group III or V hydride into the deposition zone is stopped, and afterwards, the pressure in the deposition zone is increased to a second pressure above the first pressure level and other process parameters are maintained at conditions suitable for depositing a second layer of the tungsten film on the substrate. In a preferred embodiment, the flow of the tungsten-containing source is stopped along with the flow of the group III or V hydride and after a period of between 5 and 30 seconds, the flow of the tungsten-containing source is restarted when the pressure is in the deposition zone is increased to the second pressure level.
    • 用于在基板上沉积钨膜的多步化学气相沉积工艺。 沉积工艺的第一步包括成核步骤,其中包含含钨源,III或V族氢化物和还原剂的工艺气体在保持沉积区的同时流入衬底处理室的沉积区 处于或低于第一压力水平。 在该第一沉积阶段期间,其它工艺变量被保持在适于将第一层钨膜沉积在衬底上的条件下。 接下来,在第一阶段之后的第二沉积阶段期间,停止将III或V族氢化物流入沉积区的流动,之后,沉积区中的压力增加到高于第一压力水平的第二压力和其它 工艺参数保持在适合于在衬底上沉积第二层钨膜的条件下。 在一个优选的实施方案中,随着III或V族氢化物的流动停止含钨源的流动,并且在5至30秒之间的时间段内,当含有钨的源的流量在压力 在沉积区中增加到第二压力水平。
    • 7. 发明授权
    • Formation of boride barrier layers using chemisorption techniques
    • 使用化学吸附技术形成硼化物阻挡层
    • US07501343B2
    • 2009-03-10
    • US11739545
    • 2007-04-24
    • Jeong Soo ByunAlfred Mak
    • Jeong Soo ByunAlfred Mak
    • H01L21/44
    • C23C16/45529C23C16/38C23C16/45531C23C16/45553H01L21/28562H01L21/76843H01L21/76846
    • In one embodiment, a method for depositing a boride-containing barrier layer on a substrate is provided which includes exposing the substrate sequentially to a boron-containing compound and a metal precursor to form a first boride-containing layer during a first sequential chemisorption process and exposing the substrate to the boron-containing compound, the metal precursor, and a second precursor to form a second boride-containing layer on the first boride-containing layer during a second sequential chemisorption process. In one example, the metal precursor contains tungsten hexafluoride and the boron-containing compound contains diborane. In another embodiment, a contact layer is deposited over the second boride-containing layer. The contact layer may contain tungsten and be deposited by a chemical vapor deposition process. Alternatively, the contact layer may contain copper and be deposited by a physical vapor deposition process. In other examples, boride-containing layers may be formed at a temperature of less than about 500° C.
    • 在一个实施例中,提供了一种用于在衬底上沉积含硼化物阻挡层的方法,其包括在第一顺序化学吸附过程期间将衬底依次暴露于含硼化合物和金属前体以形成第一含硼化物层, 在第二顺序化学吸附过程期间,将基底暴露于含硼化合物,金属前体和第二前体,以在第一含硼化物层上形成第二含硼化物层。 在一个实例中,金属前体含有六氟化钨,含硼化合物含有乙硼烷。 在另一个实施方案中,在第二含硼化物层上沉积接触层。 接触层可以含有钨并通过化学气相沉积工艺进行沉积。 或者,接触层可以含有铜并通过物理气相沉积工艺进行沉积。 在其他实例中,含硼化物的层可以在小于约500℃的温度下形成。
    • 8. 发明申请
    • MASK ETCH PROCESSING APPARATUS
    • 掩模加工设备
    • US20070007660A1
    • 2007-01-11
    • US11530676
    • 2006-09-11
    • Khiem NguyenPeter SatitpunwaychaAlfred Mak
    • Khiem NguyenPeter SatitpunwaychaAlfred Mak
    • H01L23/52
    • H01L21/68707H01J37/321H01J37/32623H01L21/68735
    • Method and apparatus for supporting and transferring a substrate in a semiconductor wafer processing system are provided. In one aspect, an apparatus is provided for supporting a substrate comprising a cover ring comprising a base having a bore disposed therethough, the base having an upper surface and one or more raised surfaces disposed adjacent the bore, wherein the raised surface comprise one or more first substrate support members disposed adjacent an edge of the bore and a capture ring disposed on the cover ring, the capture ring comprising a semi-circular annular ring having an inner perimeter corresponding to the bore of the cover ring and one or more second substrate support members disposed on the inner perimeter and adapted to receive a substrate, wherein the capture ring is adapted to mate with the cover ring and form one contiguous raised surface on the cover ring.
    • 提供了用于在半导体晶片处理系统中支撑和转移衬底的方法和装置。 在一个方面,提供了一种用于支撑衬底的装置,其包括盖环,该盖环包括其上设置有孔的基部,所述基部具有上表面和邻近所述孔布置的一个或多个凸起表面,其中所述凸起表面包括一个或多个 第一衬底支撑构件邻近孔的边缘设置,并且捕获环设置在覆盖环上,捕获环包括半圆环形环,其具有对应于盖环的孔的内周边和一个或多个第二衬底支撑件 设置在内周上并适于接收基底的构件,其中捕获环适于与盖环配合并在盖环上形成一个连续的凸起表面。
    • 10. 发明申请
    • Mask etch processing apparatus
    • 掩模蚀刻处理装置
    • US20050082007A1
    • 2005-04-21
    • US10689783
    • 2003-10-21
    • Khiem NguyenPeter SatitpunwaychaAlfred Mak
    • Khiem NguyenPeter SatitpunwaychaAlfred Mak
    • H01J37/32H01L21/687H01L21/44
    • H01L21/68707H01J37/321H01J37/32623H01L21/68735
    • Method and apparatus for supporting and transferring a substrate in a semiconductor wafer processing system are provided. In one aspect, an apparatus is provided for supporting a substrate comprising-a cover ring comprising a base having a bore disposed therethough, the base having an upper surface and one or more raised surfaces disposed adjacent the bore, wherein the raised surface comprise one or more first substrate support members disposed adjacent an edge of the bore and a capture ring disposed on the cover ring, the capture ring comprising a semi-circular annular ring having an inner perimeter corresponding to the bore of the cover ring and one or more second substrate support members disposed on the inner perimeter and adapted to receive a substrate, wherein the capture ring is adapted to mate with the cover ring and form one contiguous raised surface on the cover ring.
    • 提供了用于在半导体晶片处理系统中支撑和转移衬底的方法和装置。 在一个方面,提供了一种用于支撑衬底的装置,包括:盖环,包括具有设置在其上的孔的基部,所述基部具有上表面和邻近所述孔设置的一个或多个凸起表面,其中所述凸起表面包括一个或 邻近孔的第一衬底支撑构件和设置在盖环上的捕获环,捕获环包括半圆环形环,其具有对应于盖环的孔的内周边和一个或多个第二衬底 支撑构件,其布置在内周边上并且适于接收基底,其中所述捕获环适于与所述盖环配合并在所述盖环上形成一个相邻的凸起表面。