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    • 1. 发明申请
    • Manufacturing method of high resistivity silicon single crystal
    • 高电阻率硅单晶的制造方法
    • US20050000410A1
    • 2005-01-06
    • US10828555
    • 2004-04-21
    • Nobumitsu TakaseHideshi NishikawaMakoto ItoKouji SueokaShinsuke Sadamitsu
    • Nobumitsu TakaseHideshi NishikawaMakoto ItoKouji SueokaShinsuke Sadamitsu
    • C30B15/00C30B29/06C30B23/00C30B25/00C30B28/12C30B28/14
    • C30B29/06C30B15/00
    • To suppress a fluctuation in resistivity around a target value to thereby stably manufacture high resistivity silicon single crystals having almost the same resistivity values in a manufacturing method wherein a silicon raw material is molten to manufacture a high resistivity silicon single crystal in the range of from 100 to 2000 Ω cm with a CZ method. In a case where poly-silicon produced with a Siemens method using trichlorosilane as raw material is used as the silicon raw material, an impurity concentration in the silicon raw material is selected so as to be controlled in the range of from −5 to 50 ppta method in terms of (a donor concentration—an acceptor concentration) and the selected poly-silicon is used. In a case of a MCZ method, the poly-silicon is selected in the range of from −25 to 20 ppta and the selected poly-silicon is used. Instead of the raw material, poly-silicon produced with a Siemens method using monosilane as raw material is used. Alternatively, a silicon crystal manufactured with a CZ method or a MCZ method using poly-silicon raw material is used.
    • 为了抑制围绕目标值的电阻率的波动,从而在将硅原料熔融以制造范围为100的高电阻率硅单晶的制造方法中稳定地制造具有几乎相同的电阻率值的高电阻率硅单晶 到2000欧米加厘米与CZ方法。 在使用以三氯硅烷为原料的西门子方法制造的多晶硅作为硅原料的情况下,选择硅原料中的杂质浓度以控制在-5〜50ppta的范围内 使用(供体浓度 - 受体浓度)和选择的多晶硅的方法。 在MCZ方法的情况下,多晶硅的选择范围为-25〜20ppta,使用所选择的多晶硅。 使用以硅烷为原料的西门子法生产的多晶硅代替原料。 或者,使用以CZ法制造的硅晶体或使用多晶硅原料的MCZ法。