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1. 发明授权

US06495483B1 Linear metallocene polymers containing acetylenic and inorganic units and thermosets and ceramics therefrom 失效
标题翻译：含有炔属和无机单元的线性茂金属聚合物及其热固性和陶瓷
公开(公告)号：US06495483B1
公开(公告)日：2002-12-17
申请号：US08818193
申请日：1997-03-14
申请人： Teddy M. Keller , Eric J. Houser
发明人： Teddy M. Keller , Eric J. Houser
IPC分类号： C04B35571
CPC分类号： C04B35/571 , C08G77/56 , C08G77/58
摘要： Transition metal-containing ceramic or carbonaeous material are formed from novel linear polymers containing a random distribution of repeating acetylenic units, organotransition metal complexes, siloxane, boron, silicon, and/or carborane-siloxane units. The precursor thermosets are formed by crosslinking of the linear polymers through the acetylenic units in the polymer backbone. The ceramics may also be formed directly by pyrolysis of the linear polymers. The preceramic polymers are potentially useful for fabricating ceramic fibers and composite materials having enhanced strength, hardness and toughness as well as superior mechanical, optical, electrical and/or magnetic properties.
摘要翻译：由含有重复炔属单元，有机转移金属络合物，硅氧烷，硼，硅和/或碳硼烷 - 硅氧烷单元的无规分布的新型线性聚合物形成含过渡金属的陶瓷或碳质材料。前体热固性材料通过线性聚合物通过聚合物骨架中的炔属单元的交联而形成。陶瓷也可以直接通过线性聚合物的热解形成。陶瓷聚合物潜在地用于制造具有增强的强度，硬度和韧性以及优异的机械，光学，电学和/或磁性能的陶瓷纤维和复合材料。

2. 发明授权

US5844052A Linear metallocene polymers containing acetylenic and inorganic units and thermosets and ceramics therefrom 失效
标题翻译：含有炔属和无机单元的线性茂金属聚合物及其热固性和陶瓷
公开(公告)号：US5844052A
公开(公告)日：1998-12-01
申请号：US818686
申请日：1997-03-14
申请人： Teddy M. Keller , Eric J. Houser
发明人： Teddy M. Keller , Eric J. Houser
IPC分类号： C04B35/571 , C08G77/56 , C08G77/58
CPC分类号： C04B35/571 , C08G77/56 , C08G77/58
摘要： Thermally stable thermosets are formed from novel linear polymer containing acetylenic units and a random distribution of organotransition metal complexes, siloxane, boron, and/or carborane-siloxane units formed by crosslinking of the linear copolymers through the acetylene units in the polymer backbone. The thermosets can be used as structural components in high temperature and oxidizing environments or as pyrolytic precursors to metal containing ceramics, ceramic films and fibers having enhanced strength and toughness with superior mechanical, optical, electrical and/or magnetic properties.
摘要翻译：热稳定的热固性材料由含有炔属单元的新型线性聚合物和通过在聚合物主链中的乙炔单元交联而形成的有机过渡金属络合物，硅氧烷，硼和/或碳硼烷 - 硅氧烷单元的随机分布形成。热固性材料可用作高温和氧化环境中的结构组分，或作为含金属陶瓷，陶瓷膜和具有优异机械，光学，电学和/或磁性能的强度和韧性增强的纤维的热解前体。

3. 发明授权

US07132294B2 Functionalized small molecules for use in chemical sensors 有权
公开(公告)号：US07132294B2
公开(公告)日：2006-11-07
申请号：US10080403
申请日：2002-02-25
申请人： Eric J. Houser , Robert Andrew McGill
发明人： Eric J. Houser , Robert Andrew McGill
IPC分类号： G01N33/00 , G01N33/22 , G01N29/24 , C07F7/08 , C07F7/02 , C07F7/12 , C07C33/46 , C07C33/24
CPC分类号： C07F7/081 , Y10T436/14 , Y10T436/16 , Y10T436/163333 , Y10T436/170769 , Y10T436/173076
摘要： The invention provides a device for selective molecular recognition, the device comprising a sensing portion, wherein said sensing portion includes a substrate having coated thereon a layer comprising a non-volatile, small molecule compound having at least two pendant and terminal unsaturated groups, each being functionalized with at least one halogen substituted alcohol or phenol functional group. The compound of the invention preferably has one of the following general formulae: wherein A is a core moiety; B is a pendant and terminal unsaturated group;q is at least 1;r is at least 2;X is a linking group; andn is an integer designating the number of repeating units from 1 to 3, with the proviso that, if n is greater than 1, then the B groups differ from each other in at least two of the repeating units.The device is used to detect the molecules of a hydrogen bond accepting vapor such as an organophosphonate or nitroaromatic vapor.

4. 发明授权

US06630560B2 Linear and branched chemoselective siloxane polymers and methods for use in analytical and purification applications 有权
标题翻译：线性和分支化学选择性硅氧烷聚合物和用于分析和纯化应用的方法
公开(公告)号：US06630560B2
公开(公告)日：2003-10-07
申请号：US09895293
申请日：2001-07-02
申请人： Robert Andrew McGill , Eric J. Houser , Todd Mlsna
发明人： Robert Andrew McGill , Eric J. Houser , Todd Mlsna
IPC分类号： C08G7724
CPC分类号： C08G77/24 , B01J20/285 , C08G77/60 , C08L83/16 , Y10T428/31663 , Y10T436/163333 , Y10T436/17
摘要： This invention relates generally to a new class of chemoselective polymer materials. In particular, the invention relates to linear and branched polysiloxane compounds for use in various analytical applications involving sorbent polymer materials, including chromatography, chemical trapping, analyte collection, and chemical sensor applications. These polymers have pendant and terminal aryl, alkyl, alkenyl, and alkynyl groups that are functionalized with halogen substituted alcohol or halogen substituted phenol groups, having the general structure: wherein: n is an integer greater than 1; wherein at least one of R1 and R2 includes an alkyl, alkenyl, alkynyl, or aryl group having at least one halogen substituted alcohol or halogen substituted phenol group attached thereto; wherein any said R1 and R2 aryl groups are attached to said [Si—O—]n, the polymer backbone, directly or through a short hydrocarbon chain; wherein any remaining R1 or R2 group is an alkyl, alkenyl, alkynyl, or aryl group having between one and sixteen carbons; and Z is a polymer end group independently selected from the group consisting of saturated hydrocarbons, unsaturated hydrocarbons, alkyl silanes, aryl silanes, hydroxyl, hydride, alkoxides, halogen substituted alcohol, halogen substituted phenol, and combinations thereof. These polymeric materials are primarily designed to sorb hydrogen bond basic analytes such as organophosphonate esters (nerve agents and precursors) and nitro-substituted compounds (explosives).
摘要翻译：本发明一般涉及一类新的化学选择性聚合物材料。特别地，本发明涉及用于涉及吸收剂聚合物材料的各种分析应用中的直链和支链聚硅氧烷化合物，包括色谱法，化学捕获法，分析物收集法和化学传感器应用。这些聚合物具有侧链和末端芳基，被卤素取代的醇或卤素取代的酚基官能化的烷基，烯基和炔基，其具有以下通式：其中：n是大于1的整数;其中R' 1＆gt;和R 2包括具有至少一个卤素取代的醇或卤素取代的苯酚基团的烷基，烯基，炔基或芳基，其中任何所述R 1和R 2芳基连接到所述[Si-O-] n，聚合物主链，直接或通过短的烃链;其中任何残留的R 1或R 2基团是具有1至16个的烷基，烯基，炔基或芳基碳; 和Z是独立地选自饱和烃，不饱和烃，烷基硅烷，芳基硅烷，羟基，氢化物，醇盐，卤素取代的醇，卤素取代的苯酚及其组合的聚合物端基。这些聚合物材料主要设计成吸附氢键碱性分析物如有机膦酸酯（神经药物和前体）和硝基取代的化合物（爆炸物）。

5. 发明授权

US07153582B2 Hyperbranched chemoselective silicon-based polymers for chemical sensor applications 有权
标题翻译：用于化学传感器应用的超支化化学选择性硅基聚合物
公开(公告)号：US07153582B2
公开(公告)日：2006-12-26
申请号：US10672272
申请日：2003-09-26
申请人： Eric J Houser , Robert Andrew McGill
发明人： Eric J Houser , Robert Andrew McGill
IPC分类号： G01N30/00
CPC分类号： G01N29/036 , C08G77/50 , C08G77/60 , G01N2291/0257 , Y10T428/31663 , Y10T436/163333 , Y10T436/17
摘要： The invention provides a device for selective molecular recognition, the device comprising a sensing portion, wherein said sensing portion includes a substrate having coated thereon a layer comprising a hyperbranched compound having: (1) a polymer backbone portion that is at least partly randomly branched; (2) at least one pendant group extending from the polymer backbone portion; and (3) at least one halogen substituted alcohol or phenol group substituted at the pendant group(s) of the polymer backbone portion. The compound of the invention preferably has the general formula: wherein A is the hyperbranched backbone portion of the polymer; L and M are independently selected pendant groups of said polymer backbone; X and Y are independently selected halogen substituted alcohol or phenol groups; q and r are independently selected and at least 1; and n is at least 3.
摘要翻译：本发明提供了一种用于选择性分子识别的装置，该装置包括感测部分，其中所述感测部分包括其上涂覆有包含超支化化合物的层的基底，其具有：（1）至少部分地随机分支的聚合物主链部分; （2）至少一个从聚合物主链部分延伸的侧基; 和（3）在聚合物主链部分的侧基取代的至少一个卤素取代的醇或苯酚基团。本发明的化合物优选具有以下通式：其中A是聚合物的超支化骨架部分; L和M独立地选自所述聚合物骨架的侧基; X和Y独立地选择卤素取代的醇或苯酚基团; q和r独立地选择并且至少为1; n为3以上。

6. 发明授权

US06225247B1 Polymer precursor composition, crosslinked polymers, thermosets and ceramics made with silyl and siloxyl substituted carboranes with unsaturated organic end groups 失效
标题翻译：聚合物前体组合物，交联聚合物，热固性材料和由具有不饱和有机端基的甲硅烷基和甲硅烷基取代的碳硼烷制成的陶瓷
公开(公告)号：US06225247B1
公开(公告)日：2001-05-01
申请号：US09336728
申请日：1999-06-21
申请人： Teddy M. Keller , Eric J. Houser
发明人： Teddy M. Keller , Eric J. Houser
IPC分类号： C04B3556
CPC分类号： C08L83/14 , C08G77/56
摘要： A precursor composition includes (1) at least one crosslinking compound represented by the formula: wherein: u and x are independently selected positive integers, v and w are independently selected integers greater than or equal to zero, R1, R2, R3, R4, R5, R6, R7 and R8 are independently selected from the group consisting of alkyl, aryl, alkylaryl, haloalkyl, haloaryl and mixtures thereof; A and E are independently selected from the group consisting of O, an aliphatic bridge, an aryl bridge and mixtures thereof; and R9 and R10 are unsubstituted or substituted vinyl or ethynyl groups, (2) at least one organosilicon compound containing at least two silicon hydride moieties per molecule, and (3) a hydrosilation catalyst, A cross-linked polymer is formed by reacting the crosslinking compound of formula I with the organosilicon compound via a hydrosilation reaction. A thermoset polymer is formed by thermally curing the crosslinked polymer. A boron-carbon-silicon ceramic formed by pyrolyzing the cross-linked polymer.
摘要翻译：前体组合物包括（1）至少一种由下式表示的交联化合物：其中：u和x独立选择正整数，v和w独立地选自大于或等于零的整数，R 1，R 2，R 3，R 4， R5，R6，R7和R8独立地选自烷基，芳基，烷基芳基，卤代烷基，卤代芳基及其混合物; A和E独立地选自O，脂族桥，芳基桥及其混合物; 并且R 9和R 10是未取代的或取代的乙烯基或乙炔基，（2）每分子含有至少两个氢化硅部分的至少一种有机硅化合物，和（3）硅氢化催化剂。交联聚合物通过使交联式I化合物与有机硅化合物通过硅氢化反应。通过热固化交联聚合物形成热固性聚合物。通过热解交联聚合物形成的硼 - 碳 - 硅陶瓷。

7. 发明授权

US07939337B2 Carbosilane polymers and methods for use in analytical and purification applications 有权
标题翻译：碳硅烷聚合物和用于分析和纯化应用的方法
公开(公告)号：US07939337B2
公开(公告)日：2011-05-10
申请号：US11589734
申请日：2006-10-31
申请人： Robert A. McGill , Eric J. Houser
发明人： Robert A. McGill , Eric J. Houser
IPC分类号： G01N7/00
CPC分类号： C08G77/60 , Y10T436/163333 , Y10T436/17
摘要： This invention relates generally to a new class of chemoselective polymer materials primarily designed to sorb hydrogen bond basic analytes such as organophosphonate esters (nerve agents and precursors) and nitro-substituted compounds (explosives). In particular, the invention relates to linear polycarbosilane compounds for use in various analytical applications involving sorbent polymer materials, including chromatography, chemical trapping, analyte collection, and chemical sensor applications. These polymers have pendant and terminal aryl, alkyl, alkenyl, and alkynyl groups that are functionalized with halogen substituted alcohol or phenol groups, having the general structure: wherein n is an integer greater than 1; wherein at least one of R1 and R2 is a pendant group having at least one aryl group independently selected from the group consisting of a phenol, a halogen substituted phenol, and an aryl hydrocarbon with a halogen substituted alcohol substitutent, or combinations thereof; wherein any said R1 and R2 aryl groups are attached to said [Si—X—], either directly or through a short hydrocarbon chain; wherein any remaining said R1 or R2 group is a hydrocarbon or carbosilane group; wherein X is a polymer component selected from the group consisting of alkylene, alkenylene, alkynylene, arylene groups, and combinations thereof; and wherein Z1 and Z2 are end groups independently selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, alkyl silanes, aryl silanes, hydroxyl, silicon hydride, alkoxides, phenols, halogen substituted alcohols, halogen substituted phenols, organosilyl, and combinations thereof.
摘要翻译：本发明一般涉及一类新型化学选择性聚合物材料，主要设计用于吸附氢键碱性分析物如有机膦酸酯（神经剂和前体）和硝基取代的化合物（爆炸物）。特别地，本发明涉及用于涉及吸收剂聚合物材料的各种分析应用中的直链聚碳硅烷化合物，包括色谱法，化学捕获法，分析物收集法和化学传感器应用。这些聚合物具有用卤素取代的醇或酚基官能化的侧基和末端芳基，烷基，烯基和炔基，其具有以下通式结构：其中n是大于1的整数; 其中R 1和R 2中的至少一个是具有至少一个芳基的侧基，所述芳基独立地选自苯酚，卤素取代的酚和具有卤素取代的醇取代基的芳基，或其组合; 其中任何所述R 1和R 2芳基直接或通过短烃链连接到所述[Si-X-]上; 其中任何剩余的所述R 1或R 2基团是烃或碳硅烷基团; 其中X是选自亚烷基，亚烯基，亚炔基，亚芳基及其组合的聚合物组分; 并且其中Z 1和Z 2是独立地选自烷基，烯基，炔基，芳基，烷基硅烷，芳基硅烷，羟基，氢化硅，烷氧基化物，酚，卤素取代的醇，卤素取代的酚，有机甲硅烷基和组合其中。

8. 发明申请

US20100034703A1 MICRO SCALE FLOW THROUGH SORBENT PLATE COLLECTION DEVICE 审中-公开
标题翻译：通过同步板收集装置的微尺度流动
公开(公告)号：US20100034703A1
公开(公告)日：2010-02-11
申请号：US12572807
申请日：2009-10-02
申请人： Eric J. Houser , Robert Andrew McGill , David J. Nagel , Stanley Vincent Stepnowski
发明人： Eric J. Houser , Robert Andrew McGill , David J. Nagel , Stanley Vincent Stepnowski
IPC分类号： B01L3/00
CPC分类号： B01L7/00 , B01L3/502753 , B01L2200/10 , B01L2300/069 , B01L2300/1827 , B82Y30/00 , G01N1/02 , G01N1/2214 , G01N1/2273 , G01N1/40 , G01N1/405 , G01N30/08 , G01N33/0011 , G01N2001/022 , G01N2030/062 , G01N2030/121 , Y10T436/25 , Y10T436/255
摘要： In the invention, a collection device includes a first micro scale plate having a sorbent surface and a through hole. The through hole provides for the passage of an analyte fluid flow through the plate and it has a volume and geometry to provide contact between the fluid and the sorbent surface in an amount effective to absorb a sufficient amount of analyte for subsequent detection of the analyte. The sorbent surface can be provided by a sorbent coating such as an active sensing film, e.g. a conducting or optically active material, examples of which include conducting polymers, polymer/carbon composites, carbon nanotubes. and dye-containing materials. The analyte collection device preferably includes a heating source, e.g. a heating element formed from a resistive trace, or a plurality of resistive traces on or within the first microscale plate, for effecting a thermal release of collected analyte from the plate.
摘要翻译：在本发明中，收集装置包括具有吸附剂表面和通孔的第一微尺度板。通孔提供了分析物流体通过板的通道，并且其具有体积和几何形状以提供流体和吸附剂表面之间的接触，其量有效地吸收足够量的分析物以便随后检测分析物。吸附剂表面可以由吸附剂涂层提供，例如主动感测膜，例如，导电或光学活性材料，其实例包括导电聚合物，聚合物/碳复合材料，碳纳米管。和含染料的材料。分析物收集装置优选地包括加热源，例如，由电阻迹线形成的加热元件或在第一微米板上或第一微米板上的多个电阻迹线，用于实现从板上热收集分析物的释放。

9. 发明授权

US07157052B1 Linear chemoselective carbosilane polymers and methods for use in analytical and purification applications 有权
公开(公告)号：US07157052B1
公开(公告)日：2007-01-02
申请号：US10683316
申请日：2003-10-10
申请人： Robert A. McGill , Eric J. Houser
发明人： Robert A. McGill , Eric J. Houser
IPC分类号： G01N7/00
CPC分类号： C08G77/60 , Y10T436/163333 , Y10T436/17
摘要： This invention relates generally to a new class of chemoselective polymer materials. In particular, the invention relates to linear polycarbosilane compounds for use in various analytical applications involving sorbent polymer materials, including chromatoghraphy, chemical trapping, analyte collection, and chemical sensor applications. These polymers have pendant and terminal aryl, alkyl, alkenyl, and alkynyl groups that are functionalized with halogen substituted alcohol or phenol groups, having the general structure: wherein n is an integer greater than 1; wherein at least one of R1 and R2 is a linear or branched arm having at least one group independently selected from the group consisting of alkyl, alkenyl, alkynyl, and aryl groups, or combinations thereof, and having at least one halogen substituted alcohol or phenol groups attached thereto; wherein any said R1 and R2 aryl groups are attached to said [Si—X—]n either directly or through a short hydrocarbon chain; wherein any remaining said R1 or R2 group is a hydrocarbon or carbosilane group; wherein X is a polymer component selected from the group consisting of alkylene, alkenylene, alkynylene, arylene groups, and combinations thereof; and wherein Z1 and Z2 are end groups independently selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, alkyl silanes, aryl silanes, hydroxyl, silicon hydride, alkoxides, phenols, halogen substituted alcohols, halogen substituted phenols, organosilyl, and combinations thereof. These polymeric materials are primarily designed to sorb hydrogen bond basic analytes such as organophosphonate esters (nerve agents and precursors) and nitro-substituted compounds (explosives).

10. 发明授权

US07140265B2 Miniature particle and vapor collector 失效
公开(公告)号：US07140265B2
公开(公告)日：2006-11-28
申请号：US10384925
申请日：2003-03-06
申请人： Robert A. McGill , Jennifer L. Stepnowski , Stanley V. Stepnowski , Viet Nguyen , Russell Chung , Eric J. Houser , Stephen C. Francesconi , Ronald L. Kelly
发明人： Robert A. McGill , Jennifer L. Stepnowski , Stanley V. Stepnowski , Viet Nguyen , Russell Chung , Eric J. Houser , Stephen C. Francesconi , Ronald L. Kelly
IPC分类号： G01N1/00
CPC分类号： B01D45/08
摘要： An apparatus for collecting particles or vapor from air or surfaces comprising: a housing comprising an inlet open to the air to be sampled and an outlet; and a fan having one or more open areas within the housing capable of being driven at a speed effective to cause collection on the surface of the fan of particles or vapor in the air. A method of collecting a particulate sample from air comprising the step of driving a fan having one or more open areas within a housing comprising an inlet open to the air to be sampled and an outlet, at a speed effective to cause collection on the surface of the fan of particles in the air.

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