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    • 73. 发明申请
    • Atomic layer deposition methods of forming silicon dioxide comprising layers
    • 形成二氧化硅层的原子层沉积方法
    • US20050061234A1
    • 2005-03-24
    • US10669667
    • 2003-09-23
    • Li LiWeimin LiGurtej Sandhu
    • Li LiWeimin LiGurtej Sandhu
    • C23C16/40C23C16/44C23C16/455C30B23/00C30B25/00C30B28/12C30B28/14
    • C23C16/45527C23C16/402
    • A substrate is positioned within a deposition chamber. Trimethylsilane is flowed to the chamber and a first inert gas is flowed to the chamber under conditions effective to chemisorb a first species monolayer comprising silicon onto the substrate. The first inert gas is flowed at a first rate. After forming the first species monolayer, an oxidant is flowed to the chamber and a second inert gas is flowed to the chamber under conditions effective to react the oxidant with the chemisorbed first species and form a monolayer comprising silicon dioxide on the substrate. The second inert gas flowing is at a second rate which is less than the first rate. The a) trimethylsilane and first inert gas flowing and the b) oxidant and second inert gas flowing are successively repeated effective to form a silicon dioxide comprising layer on the substrate. Other implementations and aspects are contemplated.
    • 衬底位于沉积室内。 三甲基硅烷流到室中,并且第一惰性气体在有效地化学吸附包含硅的第一物质单层到衬底上的条件下流动到室中。 第一惰性气体以第一速率流动。 在形成第一物质单层之后,氧化剂流到室,并且在有效使氧化剂与化学吸附的第一种类反应的条件下,将第二惰性气体流入室,并在衬底上形成包含二氧化硅的单层。 第二惰性气体流动的速度小于第一速率。 a)三甲基硅烷和第一惰性气体流动,b)氧化剂和第二惰性气体流动相继重复有效地在基底上形成含二氧化硅的层。 考虑其他实现和方面。
    • 76. 发明授权
    • Multiple step methods for forming conformal layers
    • 用于形成保形层的多步法
    • US06489199B2
    • 2002-12-03
    • US09919313
    • 2001-07-31
    • Weimin LiGurtej S. Sandhu
    • Weimin LiGurtej S. Sandhu
    • H01L218242
    • H01L21/76868C23C16/045C23C16/34H01L21/76843H01L21/76877H01L21/76897H01L28/60
    • A two-step formation process provides conformal coverage at both the bottom surface and one or more side walls of an opening for various applications, e.g., high aspect ratio contact liners or storage cell capacitor electrode applications, and provides conformal coverage on any features requiring such coverage. A method for forming a conformal layer in the fabrication of integrated circuits includes providing a substrate assembly including at least a generally horizontal first surface and a second surface extending therefrom. A first portion of the layer is formed selectively on the horizontal first surface during a first period of time and a second portion of the layer is deposited selectively on the second surface during a second period of time. Further, one illustrative process for forming tungsten nitride in the fabrication of integrated circuits includes forming tungsten nitride on the horizontal first surface during a first period of time and depositing tungsten nitride on the second surface during a second period of time by plasma enhanced chemical vapor deposition. The tungsten nitride may be formed on the first surface by plasma enhanced chemical vapor deposition using a first reactant gas mixture including WF6, at least one of NF3 and N2, and H2 with the tungsten nitride being deposited on the second surface by plasma enhanced chemical vapor deposition using a second reactant gas mixture including WF6, at least one of NF3 and N2, H2, and He.
    • 两步形成工艺在用于各种应用的开口的底表面和一个或多个侧壁(例如,高纵横比接触衬垫或存储单元电容器电极应用)上提供适形覆盖,并且对要求这样的任何特征提供适形覆盖 覆盖面 在集成电路的制造中形成保形层的方法包括提供包括至少大致水平的第一表面和从其延伸的第二表面的基板组件。 选择性地在第一时间段内在水平的第一表面上形成该层的第一部分,并且在第二时间段期间该层的第二部分选择性地沉积在第二表面上。 此外,在集成电路的制造中形成氮化钨的一个说明性方法包括在第一时间段内在水平的第一表面上形成氮化钨,并且在第二时间段内通过等离子体增强化学气相沉积在第二表面上沉积氮化钨 。 可以通过使用包括WF6,NF3和N2中的至少一种的第一反应气体混合物和通过等离子体增强化学蒸气沉积在第二表面上的H 2与等离子体增强化学气相沉积在第一表面上形成氮化钨 使用包括WF6,NF3和N2,H2和He中的至少一种的第二反应气体混合物进行沉积。
    • 77. 发明授权
    • Chemical treatment of semiconductor substrates
    • 半导体衬底的化学处理
    • US06395647B1
    • 2002-05-28
    • US09388570
    • 1999-09-02
    • Li LiWeimin Li
    • Li LiWeimin Li
    • H01L2131
    • H01L21/316H01L21/76232H01L21/76826H01L21/76828H01L21/76837Y10S438/902
    • A method is disclosed for removing liquids from a semiconductor substrate by contacting the liquid on the substrate with a liquid which attracts the liquid on the substrate, separating the liquids from the substrate, and inducing a phase transition in a layer on the substrate. In particular, the method is applicable to removing water from a water-containing layer on the substrate by contacting the layer with a hygroscopic liquid. Trenches on a substrate can be isolated by filling the trenches with a water-containing gel formed by reacting silane and hydrogen peroxide. The gel is contacted with sulfuric acid to remove a portion of the water from the gel before annealing to form silica in the trenches. Unlike filled trenches formed by conventional technology, there are no voids in the bottom of the trenches. The method is also applicable to forming dielectric layers which cover metal lines, low-dielectric layers, and interlayer dielectric layers. The liquid may be applied to the substrate by chemical vapor deposition or by spin-applying.
    • 公开了一种通过使衬底上的液体接触吸附衬底上的液体的液体,将液体与衬底分离并引起衬底上的层中的相变来从半导体衬底去除液体的方法。 特别地,该方法适用于通过使该层与吸湿性液体接触来从基底上的含水层除去水分。 通过用硅烷和过氧化氢反应形成的含水凝胶填充沟槽可以分离衬底上的沟槽。 将凝胶与硫酸接触以在退火之前从凝胶中除去一部分水以在沟槽中形成二氧化硅。 与常规技术形成的填充沟槽不同,沟槽底部没有空隙。 该方法也适用于形成覆盖金属线,低电介质层和层间电介质层的电介质层。 液体可以通过化学气相沉积或通过旋涂施加到基底上。
    • 78. 发明授权
    • Multiple step methods for forming conformal layers
    • 用于形成保形层的多步法
    • US06281072B1
    • 2001-08-28
    • US09629998
    • 2000-08-01
    • Weimin LiGurtej S. Sandhu
    • Weimin LiGurtej S. Sandhu
    • H01L218242
    • H01L21/76868C23C16/045C23C16/34H01L21/76843H01L21/76877H01L21/76897H01L28/60
    • A two-step formation process provides conformal coverage at both the bottom surface and one or more side walls of an opening for various applications, e.g., high aspect ratio contact liners or storage cell capacitor electrode applications, and provides conformal coverage on any features requiring such coverage. A method for forming a conformal layer in the fabrication of integrated circuits includes providing a substrate assembly including at least a generally horizontal first surface and a second surface extending therefrom. A first portion of the layer is formed selectively on the horizontal first surface during a first period of time and a second portion of the layer is deposited selectively on the second surface during a second period of time. Further, one illustrative process for forming tungsten nitride in the fabrication of integrated circuits includes forming tungsten nitride on the horizontal first surface during a first period of time and depositing tungsten nitride on the second surface during a second period of time by plasma enhanced chemical vapor deposition. The tungsten nitride may be formed on the first surface by plasma enhanced chemical vapor deposition using a first reactant gas mixture including WF6, at least one of NF3 and N2, and H2 with the tungsten nitride being deposited on the second surface by plasma enhanced chemical vapor deposition using a second reactant gas mixture including WF6, at least one of NF3 and N2, H2, and He.
    • 两步形成工艺在用于各种应用的开口的底表面和一个或多个侧壁(例如,高纵横比接触衬垫或存储单元电容器电极应用)上提供适形覆盖,并且对要求这样的任何特征提供适形覆盖 覆盖面 在集成电路的制造中形成保形层的方法包括提供包括至少大致水平的第一表面和从其延伸的第二表面的基板组件。 选择性地在第一时间段内在水平的第一表面上形成该层的第一部分,并且在第二时间段期间该层的第二部分选择性地沉积在第二表面上。 此外,在集成电路的制造中形成氮化钨的一个说明性方法包括在第一时间段内在水平的第一表面上形成氮化钨,并且在第二时间段内通过等离子体增强化学气相沉积在第二表面上沉积氮化钨 。 可以通过使用包括WF6,NF3和N2中的至少一种的第一反应气体混合物和通过等离子体增强化学蒸气沉积在第二表面上的H 2与等离子体增强化学气相沉积在第一表面上形成氮化钨 使用包括WF6,NF3和N2,H2和He中的至少一种的第二反应气体混合物进行沉积。
    • 79. 发明授权
    • Semiconductor processing methods of forming insulative materials
    • 形成绝缘材料的半导体加工方法
    • US6156674A
    • 2000-12-05
    • US200035
    • 1998-11-25
    • Weimin LiZhiping Yin
    • Weimin LiZhiping Yin
    • H01L21/316H01L21/469
    • H01L21/02126H01L21/02211H01L21/02271H01L21/02274H01L21/02277H01L21/31633H01L21/31658
    • In one aspect, the invention encompasses a semiconductor processing method wherein a first gaseous precursor compound is combined with a second gaseous precursor compound to form a material comprising carbon, silicon and oxygen. A layer of the material is formed over a semiconductive substrate. In another aspect, the invention encompasses another semiconductor processing method. Methylsilane is combined with a form of oxygen other than H.sub.2 O.sub.2 to form an insulative compound comprising silicon bound to CH.sub.3 groups and oxygen. A layer of the insulative compound is formed over a semiconductive substrate. In yet another aspect, the invention encompasses yet another semiconductor processing method. Methylsilane is subjected to a plasma treatment to form a layer over a semiconductive substrate, the layer comprises silicon bound to CH.sub.3 groups. The layer is exposed to oxygen to convert the layer to an insulative compound comprising silicon bound to oxygen as well as the CH.sub.3 groups.
    • 在一个方面,本发明包括半导体加工方法,其中第一气态前体化合物与第二气态前体化合物组合以形成包含碳,硅和氧的材料。 一层材料形成在半导体衬底上。 在另一方面,本发明包括另一种半导体处理方法。 甲基硅烷与除H 2 O 2以外的氧气形式组合以形成包含结合至CH 3基团和氧的硅的绝缘化合物。 一层绝缘化合物形成在半导体衬底上。 在另一方面,本发明还包括另一种半导体处理方法。 对甲基硅烷进行等离子体处理以在半导体基底上形成层,该层包含与CH3基团结合的硅。 该层暴露于氧气以将该层转化为包含与氧结合的硅以及CH 3基团的绝缘化合物。