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    • 52. 发明授权
    • Lead-free glaze for alumina bodies
    • 氧化铝体无铅釉
    • US4120733A
    • 1978-10-17
    • US856225
    • 1977-12-01
    • Randy O. Knapp
    • Randy O. Knapp
    • C03C8/04C03C5/02
    • C03C8/04
    • A high-silica ceramic glaze, having a low coefficient of thermal expansion, suitable for application to alumina bodies, is disclosed. The glaze consists essentially, by weight percent, of 48 to 54 percent SiO.sub.2, from 7 to 11 percent Al.sub.2 O.sub.3, from 161/2 to 20 percent B.sub.2 O.sub.3, from 11 to 14 percent BaO, from 2 to 3 percent CaO, from 2 to 21/2 percent ZnO, from 41/4 to 51/4 percent Na.sub.2 O, and from 0.4 to 1 percent K.sub.2 O. Li.sub.2 O and MgO to the extent of up to about 1/4 percent and 1 percent, respectively, can also be tolerated, as can minor amounts of other impurities.
    • 公开了一种适用于氧化铝体的具有低热膨胀系数的高二氧化硅陶瓷釉。 釉料基本上由重量百分比组成为48至54%的SiO 2,7至11%的Al 2 O 3,161/2至20%的B 2 O 3,11至14%的BaO,2至3%的CaO,2至21 / 2%ZnO,41/4〜51/4%Na 2 O,0.4〜1%K 2 O。 Li2O和MgO分别达到约1/4%和1%的程度也是可以容许的,同样可以少量的其他杂质。
    • 54. 发明授权
    • Volatilizable frit composition forming oxidation-inhibiting vapors
    • 可挥发的玻璃料组合物形成氧化抑制蒸气
    • US4084975A
    • 1978-04-18
    • US710732
    • 1976-08-02
    • William D. Faust
    • William D. Faust
    • C04B41/86C03C3/062C03C3/064C03C3/066C03C3/14C03C8/02C03C8/06C03C8/22F24C14/00C03C5/02
    • F24C15/005C03C8/04C03C8/06C03C8/22C03C2205/04C03C2207/00
    • A frit composition is disclosed adapted to be applied to a metal substrate containing iron and fired to form a ceramic coat. The frit composition comprises a primary devitrifiable frit adapted to fuse at a firing temperature and upon cooling form devitrified particles; and a secondary frit containing a volatilizable metal oxide adapted to form at a firing temperature substantially an amorphous glass and precipitate crystals of the volatilizable metal oxide. The crystals at least partially volatilize at the firing temperature to provide protective vapors effective to inhibit oxidation of the substrate. Upon cooling, the amorphous glass of the secondary frit bonds the devitrified particles of the primary frit one to another. Preferably, the devitrified particles of the primary frit provide a porous ceramic coat such as on a surface of a self-cleaning cooking device exposed to cooking residues. In this case, the primary frit may also contain an oxidation catalyst.
    • 公开了适用于含铁的金属基材并烧制以形成陶瓷涂层的玻璃料组合物。 玻璃料组合物包含适于在烧制温度下熔融并在冷却时形成失透颗粒的主要失透玻璃料; 以及含有挥发性金属氧化物的次级玻璃料,其适于在基本上为无定形玻璃的烧制温度下形成,并沉淀出可挥发的金属氧化物的晶体。 晶体在烧制温度下至少部分挥发,以提供有效抑制底物氧化的保护性蒸汽。 冷却时,二次玻璃料的无定形玻璃将初级玻璃料的失透颗粒彼此粘合。 优选地,初级玻璃料的失透颗粒提供多孔陶瓷涂层,例如暴露于烹饪残余物的自清洁烹饪装置的表面上。 在这种情况下,初级玻璃料也可以含有氧化催化剂。