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    • 56. 发明授权
    • Ethylene copolymer and process for producing the same, resin composition containing the copolymer, and uses of these
    • 乙烯共聚物及其制造方法,含有共聚物的树脂组合物及其用途
    • US06462136B1
    • 2002-10-08
    • US09582274
    • 2000-06-23
    • Junji SaitoKeiji OkadaKenichi MorizonoMakoto MitaniTerunori Fujita
    • Junji SaitoKeiji OkadaKenichi MorizonoMakoto MitaniTerunori Fujita
    • C08L2308
    • C08L23/04C08F210/16C08L23/0815C08L23/10C08L2314/06C08F4/64048C08L2666/04C08F210/06C08F2500/17C08F2500/03C08F2500/19C08F2500/20C08F210/08C08F4/64189C08F4/68
    • The present invention is intended to provide an ethylene copolymer having excellent mechanical properties and moldability, a process for preparing the copolymer, a resin composition containing the copolymer and uses thereof. The ethylene copolymer has the following properties: the copolymer comprises 90 to 99% by mol of ethylene constituent units and 1 to 60% by mol of C3-20 &agr;-olefin constituent units; the ratio (Mz/Mw) of a Z average molecular weight (Mz) to a weight-average molecular weight (Mw), each molecular weight being measured by GPC, is in the range of 10 to 30, and said ratio (Mz/Mw) and the ratio (Mw/Mn) of a weight-average molecular weight (Mw) to a number-average molecular weight (Mn), each molecular weight being measured by GPC, satisfy the relation (Mz/Mw)>(Mw/Mn); the intrinsic viscosity is in the range of 0.5 to 9 dl/g; the ratio (n*0.01/n*8) of a melt viscosity (&eegr;*0.01) at a shear rate of 0.01 rad/sec, as measured at 190° C., to a melt viscosity (&eegr;*8) at a shear rate of 8 rad/sec, as measured at 190° C., and the intrinsic viscosity (&eegr;) satisfy the relation (&eegr;*0.01/&eegr;*8)≧0.893×(&eegr;)+1.0; and the absolute value of an activation energy (Ea) of a shift factor of melt viscoelasticity is not more than 4×104 J/mol.K.
    • 本发明旨在提供具有优异的机械性能和成型性的乙烯共聚物,制备共聚物的方法,含有该共聚物的树脂组合物及其用途。 乙烯共聚物具有以下性质:共聚物包含90-99摩尔%的乙烯构成单元和1至60摩尔%的C 3-20α-烯烃构成单元; 通过GPC测定的各分子量的Z平均分子量(Mz)与重均分子量(Mw)的比(Mz / Mw)在10〜30的范围内,所述比例(Mz / Mw)和通过GPC测定的各分子量的重均分子量(Mw)与数均分子量(Mn)的比(Mw / Mn)满足关系式(Mz / Mw)>(Mw / Mn); 特性粘度在0.5〜9dl / g的范围内; 在190℃下,剪切速率为0.01rad / sec的熔体粘度(η* 0.01)与剪切时的熔体粘度(ηa* 8)的比(n * 0.01 / n * 8) 速度为8rad / sec,在190℃下测定,特性粘度(eta)满足关系式(eta * 0.01 / eta * 8)> = 0.893x(eta)+1.0; 熔体粘弹性变化系数的活化能(Ea)的绝对值不大于4×104J / mol·K。
    • 57. 发明授权
    • Catalyst for olefin polymerization and method of polymerizing olefin
    • 用于烯烃聚合的催化剂和烯烃聚合方法
    • US06313243B1
    • 2001-11-06
    • US09485637
    • 2000-02-15
    • Yasushi TohiShigekazu MatsuiTerunori Fujita
    • Yasushi TohiShigekazu MatsuiTerunori Fujita
    • C08F444
    • C08F10/00C08F10/02C08F4/7047C08F4/704
    • The present invention is intended to provide an olefin polymerization catalyst exhibiting excellent olefin polymerization activity and capable of producing polyolefins of excellent properties and to provide a process for olefin polymerization using this catalyst. The olefin polymerization catalyst comprises a transition metal imine compound (A) represented by the following formula (I) and at least one compound (B) selected from an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and a compound (B-3) which reacts with the transition metal imine compound (A) to form an ion pair; wherein M is a transition metal atom of Group 8 to Group 11 of the periodic table; R1 to R4 are each a hydrogen atom, a hydrocarbon group or the like; R5 and R6 are each a hydrocarbon group or the like; R1 and R5, R2 and R6, R1 and R3, and R2 and R4 may be each bonded to form a ring; R3 and R4 may be bonded to form a ring; n is a number satisfying a valence of M; X is a halogen atom or the like; and Y is an atom of Group 16 of the periodic table.
    • 本发明旨在提供一种表现出优异的烯烃聚合活性且能够生产出优异性能的聚烯烃并提供使用该催化剂的烯烃聚合方法的烯烃聚合催化剂。 烯烃聚合催化剂包含由下式(I)表示的过渡金属亚胺化合物(A)和至少一种选自有机金属化合物(B-1),有机铝氧化合物(B-2) 和与过渡金属亚胺化合物(A)反应形成离子对的化合物(B-3);其中M是周期表第8族至第11族的过渡金属原子; R 1〜R 4各自为氢原子,烃基等; R5和R6各自为烃基等; R1和R5,R2和R6,R1和R3,以及R2和R4各自键合形成环; R3和R4可以键合形成环; n是满足M价的数; X是卤素原子等; Y是元素周期表第16族的原子。