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1. 发明申请

US20060063898A1 Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby 有权
标题翻译：制备极性烯烃共聚物和极性烯烃共聚物的方法
公开(公告)号：US20060063898A1
公开(公告)日：2006-03-23
申请号：US11253963
申请日：2005-10-20
申请人： Yoshihisa Inoue , Shigekazu Matsui , Yasuhiko Suzuki , Yasunori Yoshida , Yukihiro Takagi , Terunori Fujita , Tomoaki Matsugi , Takashi Nakano
发明人： Yoshihisa Inoue , Shigekazu Matsui , Yasuhiko Suzuki , Yasunori Yoshida , Yukihiro Takagi , Terunori Fujita , Tomoaki Matsugi , Takashi Nakano
IPC分类号： C08F4/44
CPC分类号： C08F210/02 , C08F4/619 , C08F4/639 , C08F4/659 , C08F10/00 , C08F4/54 , C08F4/64048 , C08F220/06 , C08F2500/20 , C08F2500/17 , C08F220/12 , C08F220/04 , C08F232/00 , C08F222/06 , C08F4/6812 , C08F4/6912 , C08F4/7022 , C08F4/64044 , C08F4/68112 , C08F4/69112 , C08F4/69474 , C08F4/68474 , C08F4/64189 , C08F4/64051 , C08F4/68129 , C08F4/69129 , C08F4/68293 , C08F4/64186 , C08F4/68465 , C08F4/69465 , C08F4/69103 , C08F4/68103
摘要： A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M′ is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is —O—, —Si—, —Se—, —N(R6)—, n is a number satisfying a valence of M′, R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.
摘要翻译：一种制备极性烯烃共聚物的方法，包括在选自元素周期表第4,5,6和11族的过渡金属化合物存在下使非极性烯烃和极性烯烃共聚合，其由下式（ IV）：

2. 发明申请

US20180244812A1 Spherical Supported Transition Metal Catalyst 审中-公开
公开(公告)号：US20180244812A1
公开(公告)日：2018-08-30
申请号：US15747268
申请日：2016-02-19
申请人： PetroChina Company Limited
发明人： Yuan Yuan , Tianxu Sun , Jianjun Yi , Shan Xue , Kefeng Wang , Kuilong Tan , Li Wang , Rongbo Li
IPC分类号： C08F10/02 , C08F10/06
CPC分类号： C08F10/02 , C08F4/02 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/06 , C08F110/02 , C08F110/06 , C08F2410/03 , C08F2420/02 , C08F4/69181 , C08F4/6812 , C08F4/64048 , C08F4/7034 , C08F4/7006 , C08F4/7042 , C08F4/707
摘要： The present invention provides a spherical supported transition metal catalyst. The catalyst carrier is a spherical titanium/zirconium hydrophosphate compound, the primary catalyst is a transition metal compound, the co-catalyst is methylaluminoxane; the spherical titanium/zirconium hydrophosphate compound comprises one or several combinations of titanium hydrophosphate, modified titanium hydrophosphate and zirconium hydrophosphate. The present invention also provides a preparation method of said spherical supported transition metal catalyst and a use thereof in olefin polymerization, as well as the spherical titanium/zirconium hydrophosphate compound and its preparation method. The spherical, supported transition metal catalyst in the present invention has a high catalytic activity, and the polymer particles obtained have good morphology.

3. 发明申请

US20150274937A1 METHOD TO PRODUCE ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE 有权
标题翻译：生产超高分子量聚乙烯的方法
公开(公告)号：US20150274937A1
公开(公告)日：2015-10-01
申请号：US14242497
申请日：2014-04-01
申请人： KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
发明人： MAMDOUH AHMAD AL-HARTHI , OMER YAHYA BAKATHER , SADHAN KUMAR DE , REYAD AWWAD KHALAF SHAWABKEH
IPC分类号： C08K9/02 , C08F110/02
CPC分类号： C08K9/02 , C08F110/02 , C08F2500/01 , C08K2003/2241 , C08K2003/2258 , C08K2201/011 , C08F2500/03 , C08F4/6812 , C08L23/06
摘要： The method to produce ultra-high-molecular-weight polyethylene (UHMWPE) incorporates tungsten-doped titania (TiO2/W) nanofiller during the ethylene polymerization process. The UHMWPE possesses improved mechanical and thermal properties. The process for producing the UHMWPE includes contacting ethylene under polymerization conditions with a polymerization catalyst (a vanadium (III) complex bearing bidentate salicylaldiminato ligands) in the presence of TiO2/W nanofiller and a co-catalyst in a reactor. The reactor is charged with solvent (e.g., toluene) and heated to a temperature suitable for polymerization, e.g., about 30° C. Following heating, the ethylene monomer is fed into the reactor and allowed to saturate for at least 10 minutes, and a methyl aluminum dichloride co-catalyst (MADC) is added to initiate polymerization of ethylene. Polymerization is quenched by adding methanol containing HCl incorporated with titania-tungsten nanofillers, which is then washed and dried to yield UHMWPE.
摘要翻译：生产超高分子量聚乙烯（UHMWPE）的方法在乙烯聚合过程中掺入掺杂钨的二氧化钛（TiO2 / W）纳米填料。 UHMWPE具有改进的机械和热性能。制备UHMWPE的方法包括在聚合条件下将乙烯与TiO2 / W纳米填料和助催化剂在反应器中的聚合催化剂（带有二齿水杨醛亚胺配体的钒（III）络合物）接触。向反应器中加入溶剂（例如甲苯）并加热至适于聚合的温度，例如约30℃。加热后，将乙烯单体进料至反应器中并使其饱和至少10分钟，加入甲基二氯化铝助催化剂（MADC）以引发乙烯的聚合。通过加入含有掺入二氧化钛 - 钨纳米填料的HCl的甲醇淬灭聚合，然后将其洗涤并干燥以产生UHMWPE。

4. 发明授权

US07053159B2 Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby 有权
标题翻译：制备极性烯烃共聚物和极性烯烃共聚物的方法
公开(公告)号：US07053159B2
公开(公告)日：2006-05-30
申请号：US09897111
申请日：2001-07-03
申请人： Yoshihisa Inoue , Shigekazu Matsui , Yasuhiko Suzuki , Yasunori Yoshida , Yukihiro Takagi , Terunori Fujita , Tomoaki Matsugi , Takashi Nakano
发明人： Yoshihisa Inoue , Shigekazu Matsui , Yasuhiko Suzuki , Yasunori Yoshida , Yukihiro Takagi , Terunori Fujita , Tomoaki Matsugi , Takashi Nakano
IPC分类号： C08F4/44 , C08F4/602 , C08F4/605 , C08F4/10
CPC分类号： C08F210/02 , C08F4/619 , C08F4/639 , C08F4/659 , C08F10/00 , C08F4/54 , C08F4/64048 , C08F220/06 , C08F2500/20 , C08F2500/17 , C08F220/12 , C08F220/04 , C08F232/00 , C08F222/06 , C08F4/6812 , C08F4/6912 , C08F4/7022 , C08F4/64044 , C08F4/68112 , C08F4/69112 , C08F4/69474 , C08F4/68474 , C08F4/64189 , C08F4/64051 , C08F4/68129 , C08F4/69129 , C08F4/68293 , C08F4/64186 , C08F4/68465 , C08F4/69465 , C08F4/69103 , C08F4/68103
摘要： A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M′ is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is —O—, —Si—, —Se—, —N(R6)—, n is a number satisfying a valence of M′, R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.
摘要翻译：一种制备极性烯烃共聚物的方法，包括在选自元素周期表第4,5,6和11族的过渡金属化合物存在下使非极性烯烃和极性烯烃共聚合，其由下式（ IV）：其中M'是选自元素周期表第4,5,6和11族的过渡金属原子，m是1至6的整数，A是-O - ， - Si-，-Se-， - N（R 6） - ，n是满足M'，R 1至R 4和R 6的价数的数各自为氢原子，卤素原子，烃基等，X为卤素原子，氧原子，烃基等，以及至少一种选自以下的化合物（B）：由有机金属化合物（B-1），有机铝氧化合物（B-2）和离子电离化合物（B-3）组成的组。因此，该方法能够获得在温和聚合条件下具有优异性能的极性烯烃共聚物。

5. 发明授权

US06897176B2 Olefin polymerization catalyst and process for producing olefin polymer with the catalyst 有权
标题翻译：烯烃聚合催化剂和催化剂生产烯烃聚合物的方法
公开(公告)号：US06897176B2
公开(公告)日：2005-05-24
申请号：US10078670
申请日：2002-02-21
申请人： Yasushi Nakayama , Hideyuki Kaneko , Hideki Bandoh , Yoshiho Sonobe , Junji Saito , Shinichi Kojoh , Makoto Mitani , Yasuhiko Suzuki , Shigekazu Matsui , Norio Kashiwa , Terunori Fujita
发明人： Yasushi Nakayama , Hideyuki Kaneko , Hideki Bandoh , Yoshiho Sonobe , Junji Saito , Shinichi Kojoh , Makoto Mitani , Yasuhiko Suzuki , Shigekazu Matsui , Norio Kashiwa , Terunori Fujita
IPC分类号： C08F4/76 , C08F4/16 , C08F4/626 , C08F4/68 , C08F4/78 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , B01J31/00 , C08F4/44
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/68 , C08F4/62 , C08F4/626 , C08F4/025 , C08F4/16 , C08F2500/17 , C08F2500/03 , C08F210/06 , C08F4/68112 , C08F4/6812 , C08F4/68181 , C08F4/68224 , C08F4/68293 , C08F4/6831 , C08F4/68413 , C08F4/68396 , C08F4/64044 , C08F4/64048 , C08F4/64072 , C08F4/64079 , C08F4/7042 , C08F4/7006
摘要： A novel olefin polymerization catalyst is provided which comprises (A) a transition metal compound or lanthanoid compound containing two or more atoms selected from the group consisting of boron, nitrogen, oxygen, phosphorus, sulfur, and selenium; and (B) a Lewis acid. A process for producing an olefin polymer is also provided. The catalyst has a high olefin polymerization activity without a combined use of an expensive organoaluminum oxy-compound or organoboron compound, and can maintain the high activity for a long polymerization time.
摘要翻译：提供一种新型的烯烃聚合催化剂，其包含（A）含有选自硼，氮，氧，磷，硫和硒中的两个或多个原子的过渡金属化合物或镧系元素化合物; 和（B）路易斯酸。还提供了一种生产烯烃聚合物的方法。催化剂具有高的烯烃聚合活性，而不需要昂贵的有机铝氧化合物或有机硼化合物的组合使用，并且可以在长时间聚合时保持高的活性。

6. 发明申请

US20040077890A1 Complexed compounds and use thereof for the polymerisation of olefins 失效
标题翻译：复合化合物及其用于烯烃聚合的用途
公开(公告)号：US20040077890A1
公开(公告)日：2004-04-22
申请号：US10467169
申请日：2003-08-13
发明人： Marc Oliver Kristen , Benno Bildstein , Alexander Krajete
IPC分类号： C07F013/00 , C07F011/00
CPC分类号： C08F10/02 , C07F7/003 , C07F9/005 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2500/17 , C08F210/14 , C08F4/64048 , C08F4/6812
摘要： Complexes of the formulae I a and I b 1 where MnullTi, Zr, Hf, V, Nb or Ta, can be used for the polymerization and copolymerization of olefins, for example in suspension polymerization processes, gas-phase polymerization processes and bulk polymerization processes.
摘要翻译：其中M = Ti，Zr，Hf，V，Nb或Ta的式I a和I b的络合物可用于烯烃的聚合和共聚，例如在悬浮聚合方法中，气相聚合方法和本体聚合过程。

7. 发明申请

US20020055600A1 Olefin polymerization catalysts, transition metal compounds, processes for olefin polymerization, and alpha-olefin/conjugated diene copolymers 有权
公开(公告)号：US20020055600A1
公开(公告)日：2002-05-09
申请号：US09942636
申请日：2001-08-31
申请人： Mitsui Chemicals, Inc.
发明人： Terunori Fujita , Yasushi Tohi , Makoto Mitani , Shigekazu Matsui , Jungi Saito , Masatoshi Nitabaru , Kiyoaki Sugi , Haruyuki Makio , Toshiyuki Tsutsui
IPC分类号： C08F036/00 , C08F136/00 , C08F236/00
CPC分类号： C08F210/02 , C07F7/003 , C07F7/0803 , C07F9/005 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2500/17 , C08F2500/01 , C08F2500/03 , C08F236/06 , C08F210/06 , C08F4/64189 , C08F4/64048 , C08F4/7022 , C08F4/6812
摘要： The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal compound useful for the catalyst, and an null-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc. 1

8. 发明授权

US06309997B1 Olefin polymerization catalysts, transition metal compounds, processes for olefin polymerization, and &agr;-olefin/conjugated diene copolymers 失效
标题翻译：烯烃聚合催化剂，过渡金属化合物，烯烃聚合方法和α-烯烃/共轭二烯共聚物
公开(公告)号：US06309997B1
公开(公告)日：2001-10-30
申请号：US09065593
申请日：1998-04-24
申请人： Terunori Fujita , Yasushi Tohi , Makoto Mitani , Shigekazu Matsui , Junji Saito , Masatoshi Nitabaru , Kiyoaki Sugi , Haruyuki Makio , Toshiyuki Tsutsui
发明人： Terunori Fujita , Yasushi Tohi , Makoto Mitani , Shigekazu Matsui , Junji Saito , Masatoshi Nitabaru , Kiyoaki Sugi , Haruyuki Makio , Toshiyuki Tsutsui
IPC分类号： B01J2106
CPC分类号： C08F210/02 , C07F7/003 , C07F7/0803 , C07F9/005 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2500/17 , C08F2500/01 , C08F2500/03 , C08F236/06 , C08F210/06 , C08F4/64189 , C08F4/64048 , C08F4/7022 , C08F4/6812
摘要： The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal compound useful for the catalyst, and an &agr;-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc.
摘要翻译：本发明提供了表现出优异聚合活性的烯烃聚合催化剂，使用该催化剂的烯烃聚合方法，用于催化剂的新型过渡金属化合物和具有特定性能的α-烯烃/共轭二烯共聚物。本发明的烯烃聚合催化剂包含（A）式（I）或（II）的过渡金属化合物和（B）有机金属化合物，或者是含有氧化铝的氧化合物或离子化离子化合物。本发明的新型过渡金属化合物是式（I）的化合物，其中M是周期表第3或4族的过渡膳食原子; m为1〜3的整数。 R1是烃基等; R2至R5各自为H，卤素，烃基等; R6是卤素，烃基等; n是满足M价的数; X为卤素，烃基等

9. 发明授权

US09145492B1 Method to produce ultra-high molecular weight polyethylene 有权
标题翻译：生产超高分子量聚乙烯的方法
公开(公告)号：US09145492B1
公开(公告)日：2015-09-29
申请号：US14242497
申请日：2014-04-01
申请人： KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
发明人： Mamdouh Ahmad Al-Harthi , Omer Yahya Bakather , Sadhan Kumar De , Reyad Awwad Khalaf Shawabkeh
IPC分类号： C08K9/02 , C08F110/02 , C08K3/22
CPC分类号： C08K9/02 , C08F110/02 , C08F2500/01 , C08K2003/2241 , C08K2003/2258 , C08K2201/011 , C08F2500/03 , C08F4/6812 , C08L23/06
摘要： The method to produce ultra-high-molecular-weight polyethylene (UHMWPE) incorporates tungsten-doped titania (TiO2/W) nanofiller during the ethylene polymerization process. The UHMWPE possesses improved mechanical and thermal properties. The process for producing the UHMWPE includes contacting ethylene under polymerization conditions with a polymerization catalyst (a vanadium (III) complex bearing bidentate salicylaldiminato ligands) in the presence of TiO2/W nanofiller and a co-catalyst in a reactor. The reactor is charged with solvent (e.g., toluene) and heated to a temperature suitable for polymerization, e.g., about 30° C. Following heating, the ethylene monomer is fed into the reactor and allowed to saturate for at least 10 minutes, and a methyl aluminum dichloride co-catalyst (MADC) is added to initiate polymerization of ethylene. Polymerization is quenched by adding methanol containing HCl incorporated with titania-tungsten nanofillers, which is then washed and dried to yield UHMWPE.
摘要翻译：生产超高分子量聚乙烯（UHMWPE）的方法在乙烯聚合过程中掺入掺杂钨的二氧化钛（TiO2 / W）纳米填料。 UHMWPE具有改进的机械和热性能。制备UHMWPE的方法包括在聚合条件下将乙烯与TiO2 / W纳米填料和助催化剂在反应器中的聚合催化剂（带有二齿水杨醛亚胺配体的钒（III）络合物）接触。向反应器中加入溶剂（例如甲苯）并加热至适于聚合的温度，例如约30℃。加热后，将乙烯单体进料至反应器中并使其饱和至少10分钟，加入甲基二氯化铝助催化剂（MADC）以引发乙烯的聚合。通过加入含有掺入二氧化钛 - 钨纳米填料的HCl的甲醇淬灭聚合，然后将其洗涤并干燥以产生UHMWPE。

10. 发明授权

US07312284B2 Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby 有权
标题翻译：制备极性烯烃共聚物和极性烯烃共聚物的方法
公开(公告)号：US07312284B2
公开(公告)日：2007-12-25
申请号：US11253963
申请日：2005-10-20
申请人： Yoshihisa Inoue , Shigekazu Matsui , Yasuhiko Suzuki , Yasunori Yoshida , Yukihiro Takagi , Terunori Fujita , Tomoaki Matsugi , Takashi Nakano
发明人： Yoshihisa Inoue , Shigekazu Matsui , Yasuhiko Suzuki , Yasunori Yoshida , Yukihiro Takagi , Terunori Fujita , Tomoaki Matsugi , Takashi Nakano
IPC分类号： C08F4/44 , C08F4/602 , C08F4/605 , C08F220/00
CPC分类号： C08F210/02 , C08F4/619 , C08F4/639 , C08F4/659 , C08F10/00 , C08F4/54 , C08F4/64048 , C08F220/06 , C08F2500/20 , C08F2500/17 , C08F220/12 , C08F220/04 , C08F232/00 , C08F222/06 , C08F4/6812 , C08F4/6912 , C08F4/7022 , C08F4/64044 , C08F4/68112 , C08F4/69112 , C08F4/69474 , C08F4/68474 , C08F4/64189 , C08F4/64051 , C08F4/68129 , C08F4/69129 , C08F4/68293 , C08F4/64186 , C08F4/68465 , C08F4/69465 , C08F4/69103 , C08F4/68103
摘要： A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M′ is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is —O—, —Si—, —Se—, —N(R6)—, n is a number satisfying a valence of M′, R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.
摘要翻译：一种制备极性烯烃共聚物的方法，包括在选自元素周期表第4,5,6和11族的过渡金属化合物存在下使非极性烯烃和极性烯烃共聚合，其由下式（ IV）：其中M'是选自元素周期表第4,5,6和11族的过渡金属原子，m是1至6的整数，A是-O - ， - Si-，-Se-， - N（R 6） - ，n是满足M'，R 1至R 4和R 6的价数的数各自为氢原子，卤素原子，烃基等，X为卤素原子，氧原子，烃基等，以及至少一种选自以下的化合物（B）：由有机金属化合物（B-1），有机铝氧化合物（B-2）和离子电离化合物（B-3）组成的组。因此，该方法能够获得在温和聚合条件下具有优异性能的极性烯烃共聚物。

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