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    • 53. 发明授权
    • Integration of barrier layer and seed layer
    • 势垒层和种子层的整合
    • US06936906B2
    • 2005-08-30
    • US09965373
    • 2001-09-26
    • Hua ChungLing ChenJick YuMei Chang
    • Hua ChungLing ChenJick YuMei Chang
    • C23C14/34C23C16/34H01L21/285H01L21/768H01L23/532H01L23/58H01L27/095
    • H01L23/53238C23C14/046C23C14/165C23C14/3414C23C16/045C23C16/34C23C16/45525H01L21/2855H01L21/28562H01L21/76843H01L21/76846H01L21/76862H01L21/76864H01L21/76871H01L2221/1089H01L2924/0002Y10S438/903H01L2924/00
    • The present invention generally relates to filling of a feature by depositing a barrier layer, depositing a seed layer over the barrier layer, and depositing a conductive layer over the seed layer. In one embodiment, the seed layer comprises a copper alloy seed layer deposited over the barrier layer. For example, the copper alloy seed layer may comprise copper and a metal, such as aluminum, magnesium, titanium, zirconium, tin, and combinations thereof. In another embodiment, the seed layer comprises a copper allloy seed layer deposited over the barrier layer and a second seed layer deposited over the copper alloy seed layer. The copper alloy seed layer may comprise copper and a metal, such as aluminum, magnesium, titanium, zirconium, tin, and combinations thereof The second seed layer may comprise a metal, such as undoped copper. In still another embodiment, the seed layer comprises a first seed layer and a second seed layer. The first seed layer may comprise a metal, such as aluminum, magnesium, titanium, zirconium, tin, and combinations thereof. The second seed layer may comprise a metal, such as undoped copper.
    • 本发明一般涉及通过沉积阻挡层,在阻挡层上沉积种子层,以及在种子层上沉积导电层来填充特征。 在一个实施例中,种子层包括沉积在阻挡层上的铜合金种子层。 例如,铜合金种子层可以包括铜和金属,例如铝,镁,钛,锆,锡及其组合。 在另一个实施例中,种子层包括沉积在阻挡层上的铜合金晶种层和沉积在铜合金晶种层上的第二晶种层。 铜合金种子层可以包括铜和金属,例如铝,镁,钛,锆,锡及其组合。第二种子层可以包括金属,例如未掺杂的铜。 在另一个实施例中,种子层包括第一种子层和第二种子层。 第一种子层可以包括金属,例如铝,镁,钛,锆,锡及其组合。 第二种子层可以包括金属,例如未掺杂的铜。
    • 54. 发明授权
    • Cyclical deposition of refractory metal silicon nitride
    • 难熔金属氮化硅的循环沉积
    • US07892602B2
    • 2011-02-22
    • US11422826
    • 2006-06-07
    • Hua ChungLing ChenBarry L. Chin
    • Hua ChungLing ChenBarry L. Chin
    • C23C16/34
    • C23C16/45531C23C16/34H01L21/28562H01L21/76843
    • Methods for depositing a metal silicon nitride layer on a substrate during an atomic layer deposition (ALD) process. The methods provide positioning a substrate within a process chamber containing a centralized expanding channel that conically tapers towards and substantially covers the substrate, flowing a process gas into the centralized expanding channel to form a circular flow pattern, exposing the substrate to the process gas having the circular flow pattern, and exposing the substrate sequentially to chemical precursors during an ALD process to form a metal silicon nitride material. In one example, the ALD process provides sequentially pulsing a metal precursor, a nitrogen precursor, and a silicon precursor into the process gas having the circular flow pattern. The metal silicon nitride material may contain tantalum or titanium. In other examples, the process gas or the substrate may be exposed to a plasma.
    • 在原子层沉积(ALD)工艺中在衬底上沉积金属氮化硅层的方法。 该方法提供了将处理室中的衬底定位在处理室内,该处理室包含集中的扩展通道,该通道朝向并基本上覆盖衬底呈锥形锥形,将工艺气体流入集中扩展通道以形成圆形流动图案,将衬底暴露于具有 圆形流动图案,并且在ALD工艺期间将衬底依次暴露于化学前体以形成金属氮化硅材料。 在一个实例中,ALD工艺顺序地将金属前体,氮前体和硅前体顺序地引入到具有圆形流动图案的工艺气体中。 金属氮化硅材料可以包含钽或钛。 在其它实例中,工艺气体或衬底可以暴露于等离子体。