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31. 发明申请

US20130267622A1 Hydrophilic vinylidene fluoride polymers 有权
标题翻译：亲水性偏氟乙烯聚合物
公开(公告)号：US20130267622A1
公开(公告)日：2013-10-10
申请号：US13995454
申请日：2011-12-13
申请人： Julio A. Abusleme , Roberto Biancardi , Fabien Roblot , Anna Maria Bertasa , Giulio Brinati
发明人： Julio A. Abusleme , Roberto Biancardi , Fabien Roblot , Anna Maria Bertasa , Giulio Brinati
IPC分类号： C08F14/22 , C08F8/00
CPC分类号： C08F14/22 , B01D71/32 , B01D71/78 , B01D2323/38 , C08F8/00 , C08F214/225 , C08F251/02 , C08F290/02 , C08F290/10 , C08F214/22
摘要： The present invention pertains to a process for the manufacture of a grafted fluorinated polymer comprising at least one grafted side chain comprising one or more glycosidic recurring units [polymer (F)], said process comprising polymerizing: vinylidene fluoride (VDF), optionally, one or more other fluorinated monomers [monomers (F)], and optionally, one or more (meth)acrylic monomers [monomers (MA)], in the presence of at least one polysaccharide derivative [derivative (P)], said polysaccharide derivative having a dynamic viscosity of less than 15 mPa×s, as measured according to ASTM D445 at 20° C. in an aqueous solution at a concentration of 2% by weight, and by further providing novel polymers (F) as defined above.
摘要翻译：本发明涉及制备接枝氟化聚合物的方法，其包含至少一个包含一个或多个糖苷重复单元[聚合物（F）]的接枝侧链，所述方法包括聚合：偏二氟乙烯（VDF），任选的一种或更多的其它氟化单体[单体（F）]和任选的一种或多种（甲基）丙烯酸单体[单体（MA）]在至少一种多糖衍生物[衍生物（P）]的存在下，所述多糖衍生物具有动态粘度小于15mPa×s，根据ASTM D445在20℃下在浓度为2重量％的水溶液中测量，并进一步提供如上所述的新型聚合物（F）。

32. 发明授权

US08481661B2 Fluoroelastomer, curable composition and cured rubber article 有权
标题翻译：氟弹性体，可固化组合物和固化橡胶制品
公开(公告)号：US08481661B2
公开(公告)日：2013-07-09
申请号：US13143511
申请日：2010-03-05
申请人： Shigeru Morita , Masanori Kitaichi , Shouji Fukuoka , Daisuke Ota
发明人： Shigeru Morita , Masanori Kitaichi , Shouji Fukuoka , Daisuke Ota
IPC分类号： C08F214/22 , C08F214/16 , C08C19/32 , C08F2/22
CPC分类号： C08F214/22 , C08K5/0025 , C08L27/16 , C08F214/18 , C08F214/26
摘要： A noncrystalline fluoroelastomer which is a copolymer consisting essentially of vinylidene fluoride and a fluoromonomer represented by the general formula (1): CH2═CFRf (1) wherein Rf is a straight or branched fluoroalkyl group containing 1 to 12 carbon atoms, and has a vinylidene fluoride units/fluoromonomer units mol ratio of 78/22 to 22/78 and a glass transition temperature of not higher than 25° C.
摘要翻译：基本上由偏二氟乙烯和由通式（1）表示的含氟单体共聚物的非结晶含氟弹性体：CH2 = CFRf（1）其中Rf是含有1至12个碳原子的直链或支链氟代烷基，并且具有亚乙烯基氟单体/含氟单体摩尔比为78/22〜22/78，玻璃化转变温度为25℃以下。

33. 发明申请

US20130171447A1 MULTI-LAYERED SHEET AND METHOD OF PREPARING SAME 有权
标题翻译：多层薄片及其制备方法
公开(公告)号：US20130171447A1
公开(公告)日：2013-07-04
申请号：US13695739
申请日：2011-04-29
申请人： Hyun Cheol Kim , Hyun Seong Ko , Hyo Soon Park , Yoon Kyung Kwon , Do Won Ahn
发明人： Hyun Cheol Kim , Hyun Seong Ko , Hyo Soon Park , Yoon Kyung Kwon , Do Won Ahn
IPC分类号： H01L31/048
CPC分类号： H01L31/0481 , B32B27/304 , C08F214/22 , C08F214/222 , C08J7/042 , C08J2367/02 , C08J2427/16 , C08J2433/10 , C08J2433/12 , H01L31/049 , H02S99/00 , Y02E10/50 , Y10T428/264 , Y10T428/265 , Y10T428/266 , Y10T428/31504 , Y10T428/31507 , Y10T428/3154 , Y10T428/31544 , Y10T428/31551 , Y10T428/31678 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935
摘要： Provided are a multi-layered sheet, a backsheet for a photovolatic cell, a method of preparing the same and a photovoltaic module. The multi-layered sheet in which a resin layer including a fluorine-based resin has excellent durability and weather resistance, and also exhibits strong interfacial adhesion to a substrate or polymer coating layer is provided. When a drying process is performed at a low temperature in preparation of the multi-layered sheet, production cost can be reduced, producibility can be increased, and degradation in the quality of a product caused by thermal deformation or thermal shock can be prevented. Such a multi-layered sheet may be effectively used as a backsheet for various photovoltaic cells.
摘要翻译：提供了一种多层片材，用于光电池的底片，其制备方法和光伏模块。提供了其中包含氟基树脂的树脂层具有优异的耐久性和耐候性，并且还显示出对基材或聚合物涂层的强界面粘合性的多层片材。当在多层片材的制备中进行低温干燥处理时，可以降低生产成本，提高生产率，并且可以防止由热变形或热冲击引起的产品质量下降。这样的多层片材可以有效地用作各种光伏电池的底片。

34. 发明申请

US20130079461A1 AQUEOUS PROCESS FOR MAKING A STABLE FLUOROPOLYMER DISPERSION 有权
标题翻译：制备稳定的氟聚合物分散体的水性方法
公开(公告)号：US20130079461A1
公开(公告)日：2013-03-28
申请号：US13681648
申请日：2012-11-20
申请人： Ramin Amin-Sanayei , Christyn B. Olmstead
发明人： Ramin Amin-Sanayei , Christyn B. Olmstead
IPC分类号： C08L33/14 , C08L29/10
CPC分类号： C08L33/14 , C08F14/22 , C08F214/22 , C08K5/06 , C08L27/16 , C08L29/10 , C08L71/02 , C08F2/30 , C08F2/20 , C08L27/12 , C08L2666/14
摘要： A novel aqueous polymerization process for making fluoropolymer dispersions is disclosed in which non-ionic non-fluorinated emulsifier is used to produce fluoropolymer emulsions. The emulsifiers used in the invention are those that contain segments of polyethylene glycol, polypropylene glycol, and/or polytetamethylene glycol with repeating units of 3 to 100. The process and fluoropolymer produced contain no fluorinated surfactant.
摘要翻译：公开了一种用于制备含氟聚合物分散体的新型水性聚合方法，其中非离子非氟化乳化剂用于生产含氟聚合物乳液。本发明中使用的乳化剂是含有聚乙二醇，聚丙二醇和/或聚亚甲基二醇的重复单元为3〜100的链段。所制备的方法和含氟聚合物不含氟化表面活性剂。

35. 发明授权

US08337725B2 Vinylidene fluoride copolymers 有权
标题翻译：偏二氟乙烯共聚物
公开(公告)号：US08337725B2
公开(公告)日：2012-12-25
申请号：US12596475
申请日：2008-04-22
申请人： Julio Abusleme , Riccardo Pieri , Emma Barchiesi
发明人： Julio Abusleme , Riccardo Pieri , Emma Barchiesi
IPC分类号： H01B1/06 , C08L27/12 , C08F236/16
CPC分类号： C08F214/22 , B01D69/02 , B01D71/34 , B01D71/40 , B01D71/76 , B01D2325/36 , C08F214/225 , C08J5/2237 , C08J2327/16 , H01M4/621
摘要： The present invention pertains to a linear semi-crystalline copolymer [polymer (A)] comprising recurring units derived from vinylidene fluoride (VDF) monomer and at least one hydrophilic (meth)acrylic monomer (MA) of formula: wherein each of R1, R2, R3, equal or different from each other, is independently an hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group, said polymer (A) comprising from 0.05 to 10% by moles of recurring units derived from said hydrophilic (meth)acrylic monomer (MA) and being characterized by a fraction of randomly distributed units (MA) of at least 40%, having improved thermal stability, to a process for its manufacture, to a composition comprising the same, and to its use as binder in batteries or for the manufacture of hydrophilic membranes.
摘要翻译：本发明涉及包含衍生自偏氟乙烯（VDF）单体和至少一种下式的亲水（甲基）丙烯酸单体（MA））的重复单元的线性半结晶共聚物[聚合物（A）]：其中R1，R2 相同或不同的R 3独立地为氢原子或C 1 -C 3烃基，ROH为氢或包含至少一个羟基的C 1 -C 5烃部分，所述聚合物（A）包含0.05 至10％（摩尔）衍生自所述亲水性（甲基）丙烯酸类单体（MA）的重复单元，其特征在于其制造方法中具有至少40％的随机分布单元（MA）的分数具有改善的热稳定性涉及包含其的组合物，以及其作为电池中的粘合剂或用于制造亲水膜的用途。

36. 发明授权

US08303875B2 Method for producing vinylidene fluoride resin transparent film 有权
标题翻译：偏二氟乙烯树脂透明膜的制造方法
公开(公告)号：US08303875B2
公开(公告)日：2012-11-06
申请号：US12287992
申请日：2008-10-15
申请人： Kazuhito Wada , Yukihiro Shimamoto
发明人： Kazuhito Wada , Yukihiro Shimamoto
IPC分类号： B32B37/08 , B32B37/15 , B32B27/16 , B32B27/28 , B32B27/30
CPC分类号： B32B27/304 , B32B27/08 , B32B27/30 , B32B27/308 , C08F2/00 , C08F14/08 , C08F214/22 , C08J5/18 , C08J2327/16 , Y10T428/2991 , Y10T428/2998 , Y10T428/3154 , Y10T428/31544 , Y10T428/31909 , Y10T428/31928 , Y10T428/31935
摘要： A method for producing a vinylidene fluoride resin film having excellent transparency, weather resistance, chemical resistance, break resistance and formability is provided. The film is shaped by sandwiching a vinylidene fluoride resin in a molten state between rollers or metal belts so as to let them cool down, thus realizing polyvinylidene fluoride with a fine average spherocrystal diameter. Thus, the vinylidene fluoride resin film having the above-stated properties can be obtained.
摘要翻译：提供了具有优异的透明性，耐候性，耐化学性，耐断裂性和成形性的偏二氟乙烯树脂膜的制造方法。通过将熔融状态的偏二氟乙烯树脂夹在辊或金属带之间以使其冷却来形成膜，从而实现平均球晶直径的聚偏二氟乙烯。因此，可以获得具有上述特性的偏氟乙烯树脂膜。

37. 发明授权

US08080621B2 Aqueous process for making fluoropolymers 有权
标题翻译：制备含氟聚合物的水性方法
公开(公告)号：US08080621B2
公开(公告)日：2011-12-20
申请号：US11635954
申请日：2006-12-08
申请人： Ramin Amin-Sanayei , Mehdi Durali , Patrick Kappler , Greylan Burch
发明人： Ramin Amin-Sanayei , Mehdi Durali , Patrick Kappler , Greylan Burch
IPC分类号： C08F18/20
CPC分类号： C08F14/18 , C08F214/22 , C08K5/06 , C08L27/16 , C08L71/02 , C08F2/30 , C08F2/20 , C08L27/12 , C08L2666/14
摘要： A novel aqueous polymerization process for making fluoropolymer dispersions is disclosed in which non-ionic non-fluorinated emulsifier is used to produce fluoropolymer emulsions. The emulsifiers contain blocks of polyethylene glycol, polypropylene glycol and/or polytetramethylene glycol. The process and fluoropolymer produced contain no fluorinated surfactant. The fluoropolymers have excellent resistance to discoloration.
摘要翻译：公开了一种用于制备含氟聚合物分散体的新型水性聚合方法，其中非离子非氟化乳化剂用于生产含氟聚合物乳液。乳化剂含有聚乙二醇，聚丙二醇和/或聚四亚甲基二醇的嵌段。制备的方法和含氟聚合物不含氟化表面活性剂。含氟聚合物具有优异的抗变色性。

38. 发明申请

US20110082271A1 Vinylidene fluoride and trifluoroethylene containing polymers 有权
标题翻译：偏二氟乙烯和含三氟乙烯的聚合物
公开(公告)号：US20110082271A1
公开(公告)日：2011-04-07
申请号：US12995214
申请日：2009-05-26
申请人： Giulio Brinati , Alessio Marrani , Bernard Goffaux
发明人： Giulio Brinati , Alessio Marrani , Bernard Goffaux
IPC分类号： C08F214/22 , C08F214/18 , C08F2/00 , C08F4/32
CPC分类号： H01L41/193 , C08F214/182 , C08F214/22 , H01L37/025 , C08F2/26 , C08F2/20
摘要： A polymer comprising recurring units derived from vinylidene fluoride (VDF) and trifluoroethylene (TrFE), such polymer comprising end groups of formula —CF2H and/or —CF2CH3 in an amount of at least 60 mmoles per kg of VDF recurring units [polymer (F)], a process for its manufacture and the use thereof as ferroelectric, piezoelectric, dielectric or pyroelectric material in electric/electronic devices.
摘要翻译：包含衍生自偏氟乙烯（VDF）和三氟乙烯（TrFE）的重复单元的聚合物，包含至少60mmol / kg VDF重复单元的量的式-CF 2 H和/或-CF 2 CH 3的端基的聚合物[聚合物（F ）]，其制造方法及其在电气/电子设备中的铁电，压电，电介质或热电材料的使用。

39. 发明申请

US20100286329A1 ULTRA LOW VISCOSITY IODINE CONTAINING AMORPHOUS FLUOROPOLYMERS 有权
标题翻译：超低粘度的含有非晶荧光体的碘
公开(公告)号：US20100286329A1
公开(公告)日：2010-11-11
申请号：US12677198
申请日：2008-09-11
申请人： Tatsuo Fukushi , Peter J. Scott , Cynthia N. Ferguson , Werner M.A. Grootaert , Denis Duchesne , Yeng Moua , Larry A. Last , Terri A. Shefelbine , Luke M.B. Rodgers
发明人： Tatsuo Fukushi , Peter J. Scott , Cynthia N. Ferguson , Werner M.A. Grootaert , Denis Duchesne , Yeng Moua , Larry A. Last , Terri A. Shefelbine , Luke M.B. Rodgers
IPC分类号： C09D127/12 , C08F14/18 , C08F4/30 , C08L27/12
CPC分类号： C09D127/16 , C08F2/16 , C08F14/16 , C08F14/18 , C08F214/16 , C08F214/18 , C08F214/22 , C08F214/28
摘要： Iodine containing amorphous fluoropolymers having at least one fluoropolymer with a cure site, where the fluoropolymer has a Mooney viscosity of 2 or less (ML 1+10) at 100° C. according to ASTM D1646, and a peel strength to a roll mill of 10 dN/cm or less and methods for making such iodine containing amorphous fluoropolymers are described. Articles derived from the cured product of such iodine containing amorphous fluoropolymers are also described. Solutions, dispersions and coatings derived from such iodine containing amorphous fluoropolymers are also described.
摘要翻译：含有至少一种具有固化部位的含氟聚合物的无定形含氟聚合物的碘，根据ASTM D1646，含氟聚合物在100℃下的门尼粘度为2或更小（ML 1 + 10），并且对辊磨机的剥离强度 10dN / cm以下，并描述制造这种含碘无定形含氟聚合物的方法。还描述了衍生自这种含碘无定形含氟聚合物的固化产物的制品。还描述了衍生自这种含碘无定形含氟聚合物的溶液，分散体和涂层。

40. 发明授权

US07807088B2 Polyvinylidene fluoride resin powder for melt molding and process for producing molding from the resin powder 有权
标题翻译：用于熔融成型的聚偏二氟乙烯树脂粉末和由树脂粉末制造成型的方法
公开(公告)号：US07807088B2
公开(公告)日：2010-10-05
申请号：US11665639
申请日：2005-10-13
申请人： Tsukasa Ikeda , Yasuhiro Suzuki , Kenichi Iwabuchi , Takumi Katsurao
发明人： Tsukasa Ikeda , Yasuhiro Suzuki , Kenichi Iwabuchi , Takumi Katsurao
IPC分类号： B29C45/48 , B29C45/73 , B29C45/74
CPC分类号： C08F14/08 , B29B2009/125 , B29C45/0001 , B29C47/00 , B29C47/0016 , B29C47/0019 , B29C47/0023 , C08F2/00 , C08F14/22 , C08F114/22 , C08F214/22 , C08J3/12 , C08J2327/16 , Y10T428/2982 , C08F2/18 , C08F2/22
摘要： Polyvinylidene fluoride resin powder for melt molding, which exhibits such particle size distribution characteristics that the average particle diameter (D50) is 80 to 250 μm, the proportion of resin powder having a particle diameter of at most 45 μm is at most 15.0% by weight, and the proportion of resin powder having a particle diameter of at least 355 μm is at most 10.0% by weight, and has a bulk density of 0.30 to 0.80 g/cm3 and an angle of repose of at most 40°, and a process for producing a molding, which comprises feeding the resin powder to an injection molding machine or extrusion molding machine, melting the resin powder, and injecting the resin melt into a mold.
摘要翻译：熔融成型用聚偏二氟乙烯树脂粉末，其平均粒径（D50）为80〜250μm，粒径为45μm以下的树脂粉末的比例为15.0％以下，粒径为355μm以上的树脂粉末的比例为10.0重量％以下，堆积密度为0.30〜0.80g / cm 3，休止角为40°以下，用于制造模制品，其包括将树脂粉末进料到注射成型机或挤出成型机，熔化树脂粉末，并将树脂熔体注入模具中。

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